稀土钽酸盐在热障涂层中的研究与应用
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  • 英文篇名:Research and Application of Rare Earth Tantalate Ceramics for Thermal Barrier Coatings
  • 作者:宗若菲 ; 吴福硕 ; 冯晶
  • 英文作者:ZONG Ruofei;WU Fushuo;FENG Jing;Faculty of Material Science and Engineering, Kunming University of Science and Technology;
  • 关键词:热障涂层 ; 氧化钇稳定氧化锆(YSZ) ; 热导率 ; 热膨胀 ; 稀土钽酸盐 ; 铁弹增韧
  • 英文关键词:Thermal barrier coatings;;Yttria stalized zirconia(YSZ);;Thermal conductivity;;Thermal expansion;;Rareearth tantalate;;Ferroelastic toughening
  • 中文刊名:HKGJ
  • 英文刊名:Aeronautical Manufacturing Technology
  • 机构:昆明理工大学材料科学与工程学院;
  • 出版日期:2019-02-01
  • 出版单位:航空制造技术
  • 年:2019
  • 期:v.62
  • 语种:中文;
  • 页:HKGJ201903010
  • 页数:12
  • CN:03
  • ISSN:11-4387/V
  • 分类号:17-28
摘要
热障涂层(Thermal Barrier Coatings,TBCs)是推进超高速飞行器与先进航空发动机发展的关键技术。目前最常用的热障涂层材料是氧化钇稳定氧化锆(YSZ),但是由于其存在高温相变会产生体积差这一致命缺陷,已不能满足下一代发动机的发展需求。故而,开发新一代热障涂层已势在必行。经试验证明,采用固相法所制备的稀土钽酸盐致密块体具有更加优异的热物理性能和机械性能:极低的高温热导率(1.1~1.3W/(m·K),1000℃),相比YSZ系列热导率值下降了50%;更大的降温梯度(300~500℃);基于高温铁弹增韧机制的良好断裂韧性。此外,稀土钽酸盐作为非氧离子缺陷型热导化合物,是一种氧离子传输的绝缘体,能够有效阻止热氧化物(Thermal Growth Oxidies,TGO)层的生长,大大延长热障涂层的热循环使用寿命,有望成为新一代应用于超高速飞行器和航空发动机的热障涂层材料。
        Thermal barrier coatings(TBCs) is the key technology for the hypersonic aircraft and the aero-engine. At present, yttria stalized zirconia(YSZ) is widely used as the thermal barrier coatings ceramic top-coatings. However, it cannot use for the next generation of engine in the future, owing to the volume difference caused by T–M phase transformation of ZrO_2. Obviously, it is imperative to find a kind of more advanced TBCs. The experiments have shown that the rare earth tantalate prepared by the solid-state reaction has more excellent thermophysical and mechanical properties, such as lower thermal conductivity(1.1–1.3 W/(m·K), 1000℃), higher temperature gradient(300–500℃) and better fracture toughness.Besides, the rare earth tantalate is transmitted at a much lower rate than YSZ through O_2– anions, which can effectively prevent the growth of thermal growth oxides(TGO). Considering the above advantages, the rare earth tantalate would be the great potential TBCs in the next generation of gas turbine.
引文
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