填充型高导热环氧树脂复合材料研究进展
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摘要
本文总结了近年来填充型高导热环氧树脂复合材料研究进展,分析了其导热机理。综述了填料种类、尺寸、填充量等因素对热导率的影响,并对高导热环氧树脂复合材料的未来发展方向进行了展望。
The recent progress of the thermal conductive composites based on filled epoxy resins wassummarized,and its thermal conducting mechanism was analyzed. The influence of filler type,size and fillingamount on thermal conductivity was reviewed. Finally the future development of epoxy resin composites with highthermal conductivity was prospected.
The recent progress of the thermal conductive composites based on filled epoxy resins wassummarized,and its thermal conducting mechanism was analyzed. The influence of filler type,size and fillingamount on thermal conductivity was reviewed. Finally the future development of epoxy resin composites with highthermal conductivity was prospected.
引文
[1]DU F,YANG W,ZHANG F,et al.Enhancing the heat transfer efficiency in graphene-epoxy nanocomposites using a magnesium oxide-graphene hybrid structure[J].Acs Applied Materials&Interfaces,2015,7(26):14397-14403.
[2]王唯贻,杨彪.高导热填充型环氧树脂复合材料研究进展[J].中国塑料,2015,29(7):13-19.
[3]QIN L,LI G,HOU J,et al.Preparation,characterization,and thermal properties of poly(methyl methacrylate)/boron nitride composites by bulk polymerization[J].Polymer Composites,2015,36(9):1675-1684.
[4]周文英.高导热绝缘高分子复合材料研究[D].西北工业大学,2007.
[5]李名英,周曦亚,王达,等.聚合物基绝缘导热复合材料的研究进展[J].材料导报,2013,27(1):80-84.
[6]SU Z,WANG H,YE X,et al.Enhanced thermal conductivity of functionalized-graphene/boron nitride flexible laminated composite adhesive via a facile latex approach[J].Composites Part A Applied Science&Manufacturing,2017,99.
[7]李红强,钟勇,吴文剑,等.填充型导热环氧树脂复合材料的研究进展[J].粘接,2015(4):83-86.
[8]AKATSUKA M,TAKEZAWA Y.High thermal conductive epoxy resins with controlled high order structure[J].Journal of Applied Polymer Science,2010,89(9):2464-2467.
[9]OHKI Y.Development of epoxy resin composites with high thermal conductivity[J].Electrical Insulation Magazine IEEE,2010,26(1):48-49.
[10]MO H,HUANG X,LIU F,et al.Nanostructured electrical insulating epoxy thermosets with high thermal conductivity,high thermal stability,high glass transition temperatures and excellent dielectric properties[J].IEEETransactions on Dielectrics&Electrical Insulation,2015,22(2):906-915.
[11]周文英,张亚婷.本征型导热高分子材料[J].合成树脂及塑料,2010,27(2):69-73.
[12]XIONG X,YANG M,LIU C,et al.Thermal conductivity of cross-linked polyethylene from molecular dynamics simulation[J].Journal of Applied Physics,2017,122(3):984.
[13]虞锦洪.高导热聚合物基复合材料的制备与性能研究[D].上海交通大学,2012.
[14]吴清良,赖燕玲,顾海静,等.导热系数测试方法的综述[J].佛山陶瓷,2011,21(12):20-22.
[15]闵凯,刘斌,温广.导热系数测量方法与应用分析[J].保鲜与加工,2005,5(6):40-43.
[16]贾斐霖,李林,史庆藩.稳态法测算导热系数的原理[J].材料科学与工程学报,2011(4):609-613.
[17]刘世杰,吴鹏章,王梦蛟,等.一种基于稳态热流法的导热系数测定仪器及方法[J].橡塑技术与装备,2017,43(17):45-47.
[18]司荣.有机热载体导热系数测定方法探究[J].中国特种设备安全,2017,33(7):62-65.
[19]HAN Z,FINA A.Thermal conductivity of carbon nanotubes and their polymer nanocomposites:A review[J].Progress in Polymer Science,2011,36(7):914-944.
[20]丁峰,谢维章.导热树脂基复合材料[J].复合材料学报,1993,10(3):19-24.
[21]ZHOU W.Effect of coupling agents on the thermal conductivity of aluminum particle/epoxy resin composites[J].Journal of Materials Science,2011,46(11):3883-3889.
[22]SAHA M,TAMBE P,PAL S,et al.Effect of non-ionic surfactant assisted modification of hexagonal boron nitride nanoplatelets on the mechanical and thermal properties of epoxy nanocomposites[J].Composite Interfaces,2015,22(7):611-627.
[23]WATTANAKUL K,MANUSPIYA H,YANUMET N.The adsorption of cationic surfactants on BN surface:its effects on the thermal conductivity and mechanical properties of BN-epoxy composite[J].Colloids&Surfaces A Physicochemical&Engineering Aspects,2010,369(1):203-210.
[24]HUANG X,KIM C,JIANG P,et al.Influence of aluminum nanoparticle surface treatment on the electrical properties of polyethylene composites[J].Journal of Applied Physics,2009,105(1):1776.
[25]TSAI M H,TSENG I H,CHIANG J C,et al.Flexible polyimide films hybrid with functionalized boron nitride and graphene oxide simultaneously to improve thermal conduction and dimensional stability.[J].Acs Applied Materials&Interfaces,2014,6(11):8639-8645.
[26]HUANG X,ZHI C,JIANG P,et al.Polyhedral oligosilsesquioxane-modified boron nitride nanotube based epoxy nanocomposites:an ideal dielectric material with high thermal conductivity[J].Advanced Functional Materials,2013,23(14):1824-1831.
[27]SHEN H,GUO J,WANG H,et al.Bioinspired modification of h-BN for high thermal conductive composite films with aligned structure[J].Acs Applied Materials&Interfaces,2015,7(10):5701-5708.
[28]WU H,KESSLER M R.Multifunctional cyanate ester nanocomposites reinforced by hexagonal boron nitride after noncovalent biomimetic functionalization[J].ACS Applied Materials&Interfaces,2015,7(10):5915-5926.
[29]周柳,熊传溪,董丽杰.氧化锌晶须/环氧树脂导热绝缘复合材料的制备与性能[J].高分子材料科学与工程,2009,25(5):165-167.
[30]WANG Z,CHENG Y,WANG H,et al.Sandwiched epoxyalumina composites with synergistically enhanced thermal conductivity and breakdown strength[J].Journal of Materials Science,2017,52(8):4299-4308.
[31]WU X,WANG Y,XIE L,et al.Thermal and electrical properties of epoxy composites at high alumina loadings and various temperatures[J].Iranian Polymer Journal,2013,22(1):61-73.
[32]JIANG F,CUI S,SONG N,et al.Hydrogen bond regulated boron nitride network structures for improved thermal conductive property of polyamide-imide composites[J].Acs Applied Materials&Interfaces,2018,10(19):16812-16821.
[33]CHUNG S L,LIN J S.Thermal conductivity of epoxy resin composites filled with combustion synthesized h-BNparticles[J].Molecules,2016,21(5):670.
[34]ZENG X,YAO Y,GONG Z,et al.Ice-templated assembly strategy to construct 3D boron nitride nanosheet networks in polymer composites for thermal conductivity improvement[J].Small,2016,11(46):6205-6213.
[35]HALLORAN J.Making better ceramic composites with ice[J].Science,2006,311(5760):479-480.
[36]DEVILLE S,SAIZ E,TOMSIA A P.Freeze casting of hydroxyapatite scaffolds for bone tissue engineering[J].Biomaterials,2006,27(32):5480-5489.
[37]HU J,HUANG Y,YAO Y,et al.Polymer composite with improved thermal conductivity by constructing a hierarchically ordered three-dimensional interconnected network of BN[J].Acs Applied Materials&Interfaces,2017,9(15):13544-13553.
[38]CHEN J,HUANG X,ZHU Y,et al.Cellulose nanofiber supported 3D interconnected BN nanosheets for epoxy nanocomposites with ultrahigh thermal management capability[J].Advanced Functional Materials,2016,27(5):1604754.
[39]BURGER N,LAACHACHI A,FERRIOL M,et al.Review of thermal conductivity in composites:mechanisms,parameters and theory[J].Progress in Polymer Science,2016,61:1-28.
[40]ZHU H,LI Y,FANG Z,et al.Highly thermally conductive papers with percolative layered boron nitride nanosheets[J].Acs Nano,2014,8(4):3606-3613.
[41]RENTERIA J D,RAMIREZ S,MALEKPOUR H,et al.Strongly anisotropic thermal conductivity of free-standing reduced graphene oxide films annealed at high temperature[J].Advanced Functional Materials,2015,25(29):4664-4672.
[42]韩硕.碳化硅/环氧树脂电子封装材料的研究[D].秦皇岛:燕山大学,2015.
[43]HUANG Y,HU J,YAO Y,et al.Manipulating orientation of silicon carbide nanowire in polymer composites to achieve high thermal conductivity[J].Advanced Materials Interfaces,2017,4(17):1700446.
[44]LIAN G,TUAN C C,LI L,et al.Vertically aligned and interconnected graphene networks for high thermal conductivity of epoxy composites with ultralow loading[J].Chemistry of Materials,2016,28(17):6096-6104.
[45]PONGSA U,SOMWANGTHANAROJ A.Effective thermal conductivity of 3,5-diaminobenzoyl-functionalized multiwalled carbonnanotubes/epoxy composites[J].Journal of Applied Polymer Science,2014,130(5):3184-3196.
[46]GU J,YANG X,LV Z,et al.Functionalized graphite nanoplatelets/epoxy resin nanocomposites with high thermal conductivity[J].International Journal of Heat&Mass Transfer,2016,92:15-22.
[47]SHEN X,WANG Z,WU Y,et al.Multi-layer graphene enables higher efficiency in improving thermal conductivities of graphene/epoxy composites[J].Nano Letters,2016,16(6):3585-3593.
[48]RIBEIRO H,TRIGUEIRO J P C,SILVA W M,et al.Hybrid MoS2/h-BN nanofillers as synergic heat dissipation and reinforcement additives in epoxy nanocomposites[J].ACS Applied Materials&Interfaces,2017.
[49]WANG Z,CHENG Y,SHAO Y,et al.Thermal conductivity and electric breakdown strength properties of epoxy/alumina/boron nitride nanosheets composites[C].IEEEInternational Conference on Dielectrics,2016,1:355-358.
[50]CHEN L,ZHAO P,XIE H,et al.Thermal properties of epoxy resin based thermal interfacial materials by filling Ag nano-particle-decorated graphene nanosheets[J].Composites Science&Technology,2016,125:17-21.
[2]王唯贻,杨彪.高导热填充型环氧树脂复合材料研究进展[J].中国塑料,2015,29(7):13-19.
[3]QIN L,LI G,HOU J,et al.Preparation,characterization,and thermal properties of poly(methyl methacrylate)/boron nitride composites by bulk polymerization[J].Polymer Composites,2015,36(9):1675-1684.
[4]周文英.高导热绝缘高分子复合材料研究[D].西北工业大学,2007.
[5]李名英,周曦亚,王达,等.聚合物基绝缘导热复合材料的研究进展[J].材料导报,2013,27(1):80-84.
[6]SU Z,WANG H,YE X,et al.Enhanced thermal conductivity of functionalized-graphene/boron nitride flexible laminated composite adhesive via a facile latex approach[J].Composites Part A Applied Science&Manufacturing,2017,99.
[7]李红强,钟勇,吴文剑,等.填充型导热环氧树脂复合材料的研究进展[J].粘接,2015(4):83-86.
[8]AKATSUKA M,TAKEZAWA Y.High thermal conductive epoxy resins with controlled high order structure[J].Journal of Applied Polymer Science,2010,89(9):2464-2467.
[9]OHKI Y.Development of epoxy resin composites with high thermal conductivity[J].Electrical Insulation Magazine IEEE,2010,26(1):48-49.
[10]MO H,HUANG X,LIU F,et al.Nanostructured electrical insulating epoxy thermosets with high thermal conductivity,high thermal stability,high glass transition temperatures and excellent dielectric properties[J].IEEETransactions on Dielectrics&Electrical Insulation,2015,22(2):906-915.
[11]周文英,张亚婷.本征型导热高分子材料[J].合成树脂及塑料,2010,27(2):69-73.
[12]XIONG X,YANG M,LIU C,et al.Thermal conductivity of cross-linked polyethylene from molecular dynamics simulation[J].Journal of Applied Physics,2017,122(3):984.
[13]虞锦洪.高导热聚合物基复合材料的制备与性能研究[D].上海交通大学,2012.
[14]吴清良,赖燕玲,顾海静,等.导热系数测试方法的综述[J].佛山陶瓷,2011,21(12):20-22.
[15]闵凯,刘斌,温广.导热系数测量方法与应用分析[J].保鲜与加工,2005,5(6):40-43.
[16]贾斐霖,李林,史庆藩.稳态法测算导热系数的原理[J].材料科学与工程学报,2011(4):609-613.
[17]刘世杰,吴鹏章,王梦蛟,等.一种基于稳态热流法的导热系数测定仪器及方法[J].橡塑技术与装备,2017,43(17):45-47.
[18]司荣.有机热载体导热系数测定方法探究[J].中国特种设备安全,2017,33(7):62-65.
[19]HAN Z,FINA A.Thermal conductivity of carbon nanotubes and their polymer nanocomposites:A review[J].Progress in Polymer Science,2011,36(7):914-944.
[20]丁峰,谢维章.导热树脂基复合材料[J].复合材料学报,1993,10(3):19-24.
[21]ZHOU W.Effect of coupling agents on the thermal conductivity of aluminum particle/epoxy resin composites[J].Journal of Materials Science,2011,46(11):3883-3889.
[22]SAHA M,TAMBE P,PAL S,et al.Effect of non-ionic surfactant assisted modification of hexagonal boron nitride nanoplatelets on the mechanical and thermal properties of epoxy nanocomposites[J].Composite Interfaces,2015,22(7):611-627.
[23]WATTANAKUL K,MANUSPIYA H,YANUMET N.The adsorption of cationic surfactants on BN surface:its effects on the thermal conductivity and mechanical properties of BN-epoxy composite[J].Colloids&Surfaces A Physicochemical&Engineering Aspects,2010,369(1):203-210.
[24]HUANG X,KIM C,JIANG P,et al.Influence of aluminum nanoparticle surface treatment on the electrical properties of polyethylene composites[J].Journal of Applied Physics,2009,105(1):1776.
[25]TSAI M H,TSENG I H,CHIANG J C,et al.Flexible polyimide films hybrid with functionalized boron nitride and graphene oxide simultaneously to improve thermal conduction and dimensional stability.[J].Acs Applied Materials&Interfaces,2014,6(11):8639-8645.
[26]HUANG X,ZHI C,JIANG P,et al.Polyhedral oligosilsesquioxane-modified boron nitride nanotube based epoxy nanocomposites:an ideal dielectric material with high thermal conductivity[J].Advanced Functional Materials,2013,23(14):1824-1831.
[27]SHEN H,GUO J,WANG H,et al.Bioinspired modification of h-BN for high thermal conductive composite films with aligned structure[J].Acs Applied Materials&Interfaces,2015,7(10):5701-5708.
[28]WU H,KESSLER M R.Multifunctional cyanate ester nanocomposites reinforced by hexagonal boron nitride after noncovalent biomimetic functionalization[J].ACS Applied Materials&Interfaces,2015,7(10):5915-5926.
[29]周柳,熊传溪,董丽杰.氧化锌晶须/环氧树脂导热绝缘复合材料的制备与性能[J].高分子材料科学与工程,2009,25(5):165-167.
[30]WANG Z,CHENG Y,WANG H,et al.Sandwiched epoxyalumina composites with synergistically enhanced thermal conductivity and breakdown strength[J].Journal of Materials Science,2017,52(8):4299-4308.
[31]WU X,WANG Y,XIE L,et al.Thermal and electrical properties of epoxy composites at high alumina loadings and various temperatures[J].Iranian Polymer Journal,2013,22(1):61-73.
[32]JIANG F,CUI S,SONG N,et al.Hydrogen bond regulated boron nitride network structures for improved thermal conductive property of polyamide-imide composites[J].Acs Applied Materials&Interfaces,2018,10(19):16812-16821.
[33]CHUNG S L,LIN J S.Thermal conductivity of epoxy resin composites filled with combustion synthesized h-BNparticles[J].Molecules,2016,21(5):670.
[34]ZENG X,YAO Y,GONG Z,et al.Ice-templated assembly strategy to construct 3D boron nitride nanosheet networks in polymer composites for thermal conductivity improvement[J].Small,2016,11(46):6205-6213.
[35]HALLORAN J.Making better ceramic composites with ice[J].Science,2006,311(5760):479-480.
[36]DEVILLE S,SAIZ E,TOMSIA A P.Freeze casting of hydroxyapatite scaffolds for bone tissue engineering[J].Biomaterials,2006,27(32):5480-5489.
[37]HU J,HUANG Y,YAO Y,et al.Polymer composite with improved thermal conductivity by constructing a hierarchically ordered three-dimensional interconnected network of BN[J].Acs Applied Materials&Interfaces,2017,9(15):13544-13553.
[38]CHEN J,HUANG X,ZHU Y,et al.Cellulose nanofiber supported 3D interconnected BN nanosheets for epoxy nanocomposites with ultrahigh thermal management capability[J].Advanced Functional Materials,2016,27(5):1604754.
[39]BURGER N,LAACHACHI A,FERRIOL M,et al.Review of thermal conductivity in composites:mechanisms,parameters and theory[J].Progress in Polymer Science,2016,61:1-28.
[40]ZHU H,LI Y,FANG Z,et al.Highly thermally conductive papers with percolative layered boron nitride nanosheets[J].Acs Nano,2014,8(4):3606-3613.
[41]RENTERIA J D,RAMIREZ S,MALEKPOUR H,et al.Strongly anisotropic thermal conductivity of free-standing reduced graphene oxide films annealed at high temperature[J].Advanced Functional Materials,2015,25(29):4664-4672.
[42]韩硕.碳化硅/环氧树脂电子封装材料的研究[D].秦皇岛:燕山大学,2015.
[43]HUANG Y,HU J,YAO Y,et al.Manipulating orientation of silicon carbide nanowire in polymer composites to achieve high thermal conductivity[J].Advanced Materials Interfaces,2017,4(17):1700446.
[44]LIAN G,TUAN C C,LI L,et al.Vertically aligned and interconnected graphene networks for high thermal conductivity of epoxy composites with ultralow loading[J].Chemistry of Materials,2016,28(17):6096-6104.
[45]PONGSA U,SOMWANGTHANAROJ A.Effective thermal conductivity of 3,5-diaminobenzoyl-functionalized multiwalled carbonnanotubes/epoxy composites[J].Journal of Applied Polymer Science,2014,130(5):3184-3196.
[46]GU J,YANG X,LV Z,et al.Functionalized graphite nanoplatelets/epoxy resin nanocomposites with high thermal conductivity[J].International Journal of Heat&Mass Transfer,2016,92:15-22.
[47]SHEN X,WANG Z,WU Y,et al.Multi-layer graphene enables higher efficiency in improving thermal conductivities of graphene/epoxy composites[J].Nano Letters,2016,16(6):3585-3593.
[48]RIBEIRO H,TRIGUEIRO J P C,SILVA W M,et al.Hybrid MoS2/h-BN nanofillers as synergic heat dissipation and reinforcement additives in epoxy nanocomposites[J].ACS Applied Materials&Interfaces,2017.
[49]WANG Z,CHENG Y,SHAO Y,et al.Thermal conductivity and electric breakdown strength properties of epoxy/alumina/boron nitride nanosheets composites[C].IEEEInternational Conference on Dielectrics,2016,1:355-358.
[50]CHEN L,ZHAO P,XIE H,et al.Thermal properties of epoxy resin based thermal interfacial materials by filling Ag nano-particle-decorated graphene nanosheets[J].Composites Science&Technology,2016,125:17-21.