雷达红外兼容吸波涂层失效分析与预防研究
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摘要
概述了雷达红外兼容吸波涂层的工作原理,简述了涂层失效的定义、表现形式和分类方法;引入了失效分析模型,对其失效原因进行了分析;综述了涂层与基材间的结合机理,从基材表面状态和涂层应力两个角度,论述了其对吸波涂层与基材间结合力的影响,并针对性地提出了基材表面前处理和涂料树脂体系改性优化等提高附着力的方法。为吸波涂料配方的设计提供理论指导,指明了涂装前处理的必要性和重要性,为后续涂装质量和涂层性能的发挥奠定了基础。对雷达红外兼容吸波涂层技术和涂层失效检测及修复技术的发展前景进行了展望。
The absorbing mechanism of radar-infrared absorbing coatings(RIAC) was introduced.The definition, characters and types of film failure were described. An analysis model was applied to analyze the film failure. The adhesion behavior between the coating and the substrate was reviewed.The effects of the film tension and the surface structure of the substrate on the adhesion between RIAC and substrate were examined. The methods for the improvement of adhesion via substrate pretreatment and modification of the binders were proposed accordingly, which provided a referential guide for the formulation design and surface pretreatment of RIAC. Finally, the prospects of the process, the film failure monitoring technology and the maintenance of RIAC were presented.
The absorbing mechanism of radar-infrared absorbing coatings(RIAC) was introduced.The definition, characters and types of film failure were described. An analysis model was applied to analyze the film failure. The adhesion behavior between the coating and the substrate was reviewed.The effects of the film tension and the surface structure of the substrate on the adhesion between RIAC and substrate were examined. The methods for the improvement of adhesion via substrate pretreatment and modification of the binders were proposed accordingly, which provided a referential guide for the formulation design and surface pretreatment of RIAC. Finally, the prospects of the process, the film failure monitoring technology and the maintenance of RIAC were presented.
引文
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[3]王连杰,高焕方.吸波涂料概述[J].表面技术,2004,33(6):13-14.
[4]陈亮,郑国禹,王艳艳,等.雷达吸波涂料的研究进展[J]表面技术,2007,36(2):54-55.
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[24]王金鑫,浅谈表面预处理对钢结构防护涂层附着力的影响[J].中国涂料,2008,23(5):66-68.
[25]王传忠,张磊,曹志刚,等.浅析表面粗糙度对涂装的影响[J].现代涂料与涂装,2011,14(5):66-68.
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[29]陶宇,陶志萍.雷达隐身技术的研究现状及其展望[J].材料导报,2011,25(11):40-45.
[30]王结良,黄英,梁国正,等.雷达吸波涂层用材料的研究进展[J].现代涂料与涂装,2003,16(2):28-31.
[31]周金向,黄慧萍,龚荣洲.雷达吸波涂料用环氧树脂改性的研究[J].热固性树脂,2005,20(3):36-38.
[32]何益艳,杜仕国.偶联剂在涂料中的应用[J].化工时刊,2002(2):3-7.
[33]ARKLES.Taliloring surface with silanes[J].Chemtech,1977,7(12):766-778.
[34]陈立庄,高延敏,缪文桦.偶联剂在涂料中的作用机理及其应用[J].全面腐蚀控制,2005,19(4):24-27.
[35]谢国先,邱大健,李朝阳,等.氨基硅烷偶联剂对环氧涂层附着力的影响[J].材料保护,2008,41(3):22-24.
[36]FRIEDRICH J,KUHNG,MIX R.Polymer Surface Modification with Monofunctional Groups of Variable Types and Densities[J].Adhesion Sci Tech,2003,17(12):1591.
[2]张政权,李铁虎,经德齐.雷达吸波材料的研究现状及其进展[J].材料导报,2007,21(5):307-309.
[3]王连杰,高焕方.吸波涂料概述[J].表面技术,2004,33(6):13-14.
[4]陈亮,郑国禹,王艳艳,等.雷达吸波涂料的研究进展[J]表面技术,2007,36(2):54-55.
[5]刑丽英.隐身材料[M].北京:化学工业出版社,2004.
[6]邓龙江,周佩珩,陆海鹏,等.多频谱隐身涂层材料研究进展[J].中国材料进展,2013,32(8):499-462.
[7]庄海燕,郑添水,任润桃.等.红外隐身涂料的研究现状及发展趋势[J].材料开发与应用,2006,21(3):43-46.
[8]曾裕,龚荣洲.红外-雷达隐身匹配设计及其兼容特性研究[J].功能材料,2012,43(24):3355-3358.
[9]李凤雷.低发射率材料及其与雷达吸波材料的兼容性研究[D].南京:南京航空航天大学,2010.
[10]李凤雷,徐国跃,余慧娟,等.红外隐身涂层的制备及其与雷达吸波涂料的兼容性研究[J].红外技术,2009,31(7):415-419.
[11]赵东林,周万城.涂敷型吸波材料及其涂层结构设计[J].兵器材料科学与工程,1998,21(4):58-62.
[12]张华,陈智勇.有机涂层户外失效分析及对策[J].环境试验,2011(1):25-28.
[13]殷宗莲,周学梅,王俊芳.吸波涂层失效因素研究[J].表面技术,2015,44(7):76-80.
[14]赫丽华,刘平桂,王晓红.雷达吸波涂层的失效行为[J].失效分析与预防,2009,4(3):182-187.
[15]翟兰兰,凌国平.高分子涂层与金属的附着力及其研究进展[J].材料导报,2005,19(7):79-81.
[16]刘海定,曹旭东,贺文海,等.吸波涂层界面结合机理(Ⅰ):涂层力学性能影响因素分析[J].功能材料,2007,38(7):1045-1048.
[17]曲敬信,汪泓宏.表面工程手册[M].北京:化学工业出版社,1998.
[18]苏修梁,张欣宇.表面涂层与基体间的界面结合强度及其测定[J].电镀与环保,2004,24(2):6-11.
[19]刘有成.润湿现象的解释[J].重庆师范学院学报(自然科学版),2000,17(6):143-147.
[20]LEE HO YOUNG,et al,Adhesion Strength and Failure Path[J].J AdhesSci Techn,2003,17(2):195-201.
[21]HO-YOUNG LEE,et al.Fracture behaviors of Nanowirecoated Metal/Polymer Systems Under Mode-I Loading Condition[J].ActaMaterialia,2004(52):5815-5828.
[22]王雷,孙杰,安成强.粗糙度对彩色涂层与基体间附着力的影响[J].电镀与精饰,2010,32(5):41-43.
[23]李敏风.浅谈钢结构表面处理的粗糙度[J].上海涂料,2001,39(3):24-26.
[24]王金鑫,浅谈表面预处理对钢结构防护涂层附着力的影响[J].中国涂料,2008,23(5):66-68.
[25]王传忠,张磊,曹志刚,等.浅析表面粗糙度对涂装的影响[J].现代涂料与涂装,2011,14(5):66-68.
[26]于喜年.金属防腐涂层附着力影响因素分析[J].大连铁道学院学报,2006,27(2):42-45.
[27]PERERA D Y.On Adhesion and Stress in Organic Coatings[J].Progress in Organic Coatings,1996,28(1):21-23.
[28]张德琪,周光华.防雷达波隐身涂料前处理工艺研究[J].四川兵工学报,2004,6(8):37-38.
[29]陶宇,陶志萍.雷达隐身技术的研究现状及其展望[J].材料导报,2011,25(11):40-45.
[30]王结良,黄英,梁国正,等.雷达吸波涂层用材料的研究进展[J].现代涂料与涂装,2003,16(2):28-31.
[31]周金向,黄慧萍,龚荣洲.雷达吸波涂料用环氧树脂改性的研究[J].热固性树脂,2005,20(3):36-38.
[32]何益艳,杜仕国.偶联剂在涂料中的应用[J].化工时刊,2002(2):3-7.
[33]ARKLES.Taliloring surface with silanes[J].Chemtech,1977,7(12):766-778.
[34]陈立庄,高延敏,缪文桦.偶联剂在涂料中的作用机理及其应用[J].全面腐蚀控制,2005,19(4):24-27.
[35]谢国先,邱大健,李朝阳,等.氨基硅烷偶联剂对环氧涂层附着力的影响[J].材料保护,2008,41(3):22-24.
[36]FRIEDRICH J,KUHNG,MIX R.Polymer Surface Modification with Monofunctional Groups of Variable Types and Densities[J].Adhesion Sci Tech,2003,17(12):1591.