两种硫酸根介导的铀酰-葫芦脲配位聚合物的合成、结构和理化性质表征
|
摘要
本文通过引入小分子竞争配体,利用高温水热法成功合成了两种新的硫酸根介导的葫芦脲铀酰配合物(UO_2)_2(CB5)(SO_4)_2(H_2O)_2·5H_2O (U-CB5-SO_4)和(UO_2)(CB6)_(0.5)(SO_4)(H_2O)·4H_2O (U-CB6-SO_4).通过单晶X射线衍射、粉末衍射(PXRD)、热重分析(TGA)、傅里叶变换红外光谱(FTIR)和荧光光谱(FL)对配合物进行表征,解析了配合物的结构并研究了它们的理学性质. U-CB5-SO_4属于正交晶系,空间群为Pnma, U-CB6-SO_4属于单斜晶系,空间群为I2/m. U-CB5-SO_4晶体在a轴上是折线形的走向,晶体为黄色风车形多棱柱多晶,而U-CB6-SO_4晶体在a轴上是直线形,晶体为较长的黄色棒状单晶.本文提出了一种"竞争配体"用于介导复杂体系配位合成的新思路,同时丰富和发展了铀酰-葫芦脲-硫酸三元体系的配位化学相关研究.
In this article, with the aid of additional ligands,(UO_2)_2(CB5)(SO_4)_2(H_2O)_2·5H_2O(U-CB5-SO_4) and(UO_2)-(CB6)_(0.5)(SO_4)(H_2O)·4H_2O(U-CB6-SO_4) were synthesized by hydrothermal method at high temperature. Their structures and physico-chemical properties were characterized by a combination of single-crystal X-ray diffraction,PXRD, TG-DSC, FTIR, UV-Vis and fluorescence spectra. U-CB5-SO_4 crystalized in orthorhombic system, and space group Pnma, while U-CB6-SO_4 crystalized in monoclinic system and space group I2/m. U-CB5-SO_4 forms a yellow windmill-like poly crystal, while U-CB6-SO_4 forms a yellow stick-like single crystal.
In this article, with the aid of additional ligands,(UO_2)_2(CB5)(SO_4)_2(H_2O)_2·5H_2O(U-CB5-SO_4) and(UO_2)-(CB6)_(0.5)(SO_4)(H_2O)·4H_2O(U-CB6-SO_4) were synthesized by hydrothermal method at high temperature. Their structures and physico-chemical properties were characterized by a combination of single-crystal X-ray diffraction,PXRD, TG-DSC, FTIR, UV-Vis and fluorescence spectra. U-CB5-SO_4 crystalized in orthorhombic system, and space group Pnma, while U-CB6-SO_4 crystalized in monoclinic system and space group I2/m. U-CB5-SO_4 forms a yellow windmill-like poly crystal, while U-CB6-SO_4 forms a yellow stick-like single crystal.
引文
1 Freeman WA,Mock WL,Shih NY.J Am Chem Soc,1981,103:7367-7368
2(a)Lee JW,Samal S,Selvapalam N,Kim HJ,Kim K.Acc Chem Res,2003,36:621-630;(b)Kim K,Selvapalam N,Oh DH.J Incl Phenom,2004,50:31;(c)Lagona J,Mukhopadhyay P,Chakrabarti S,Isaacs L.Angew Chem Int Ed,2005,44:4844-4870
3(a)Kim J,Jung IS,Kim SY,Lee E,Kang JK,Sakamoto S,Yamaguchi K,Kim K.J Am Chem Soc,2000,122:540-541;(b)Day A,Arnold AP,Blanch RJ,Snushall B.J Org Chem,2001,66:8094-8100;(c)Cheng XJ,Liang LL,Chen K,Ji NN,Xiao X,Zhang JX,Zhang YQ,Xue SF,Zhu QJ,Ni XL,Tao Z.Angew Chem,2013,125:7393-7396;(d)Li Q,Qiu SC,Zhang J,Chen K,Huang Y,Xiao X,Zhang Y,Li F,Zhang YQ,Xue SF,Zhu QJ,Tao Z,Lindoy LF,Wei G.Org Lett,2016,18:4020-4023
4(a)Kim SY,Jung IS,Lee E,Kim J,Sakamoto S,Yamaguchi K,Kim K.Angew Chem Int Ed,2001,40:2119-2121;(b)Day AI,Blanch RJ,Arnold AP,Lorenzo S,Lewis GR,Dance I.Angew Chem Int Ed,2002,41:275;(c)Jeon WS,Moon K,Park SH,Chun H,Ko YH,Lee JY,Lee ES,Samal S,Selvapalam N,Rekharsky MV,Sindelar V,Sobransingh D,Inoue Y,Kaifer AE,Kim K.J Am Chem Soc,2005,127:12984-12989;(d)Jin YJ,Kim SY,Ho Ko Y,Sakamoto S,Yamaguchi K,Kim K.Org Biomol Chem,2005,3:2122;(e)Liu S,Zavalij PY,Isaacs L.J Am Chem Soc,2005,127:16798-16799;(f)Liu S,Shukla AD,Gadde S,Wagner BD,Kaifer AE,Isaacs L.Angew Chem Int Ed,2008,47:2657-2660;(g)Ko YH,Kim H,Kim Y,Kim K.Angew Chem Int Ed,2008,47:4106-4109;(h)Li Q,Sun J,Zhou J,Hua B,Shao L,Huang F.Org Chem Front,2018,5:1940-1944;(i)Wang H,Ji X,Li Z,Huang F.Adv Mater,2017,29:1606117
5(a)Mock WL.Top Curr Chem,1995,175:1;(b)Kim K.Chem Soc Rev,2002,31:96-107
6 Lim S,Kim H,Selvapalam N,Kim KJ,Cho SJ,Seo G,Kim K.Angew Chem Int Ed,2008,47:3352-3355
7(a)Freeman WA.Acta Crystlogr B Struct Sci,1984,40:382-387;(b)Buschmann HJ,Cleve E,Schollmeyer E.Inorg Chim Acta,1992,193:93-97;(c)Jeon YM,Kim J,Whang D,Kim K.J Am Chem Soc,1996,118:9790-9791;(d)Whang D,Heo J,Park JH,Kim K.Angew Chem Int Ed,1998,37:78-80;(e)Heo J,Kim SY,Whang D,Kim K.Angew Chem Int Ed,1999,38:641-643;(f)Heo J,Kim J,Whang D,Kim K.Inorg Chim Acta,2000,297:307-312;(g)Zhang F,Yajima T,Li YZ,Xu GZ,Chen HL,Liu QT,Yamauchi O.Angew Chem Int Ed,2005,44:3402-3407;(h)Liu JX,Long LS,Huang RB,Zheng LS.Cryst Growth Des,2006:62611;(i)Liang LL,Ni XL,Zhao Y,Chen K,Xiao X,Zhang YQ,Redshaw C,Zhu QJ,Xue SF,Tao Z.Inorg Chem,2013,52:1909-1915;(j)Chen WJ,Yu DH,Xiao X,Zhang YQ,Zhu QJ,Xue SF,Tao Z,Wei G.Inorg Chem,2011,50:6956-6964
8(a)Samsonenko DG,Lipkowski J,Gerasko OA,Virovets AV,Sokolov MN,Fedin VP,Platas JG,Hernandez-Molina R,Mederos A.Eur J Inorg Chem,2002,2002:2380-2388;(b)Samsonenko DG,Gerasko OA,Lipkowski J,Virovets AV,Fedin VP.Rus Chem Bull,2002,51:1915-1918;(c)Samsonenko DG,Sokolov MN,Gerasko OA,Virovets AV,Lipkowski J,Fenske D,Fedin VP.Rus Chem Bull,2003,52:2132-2139;(d)Gerasko OA,Sokolov MN,Fedin VP.Pure Appl Chem,2004,76:1633-1646;(e)Liu JX,Long LS,Huang RB,Zheng LS.Inorg Chem,2007,46:10168-10173;(f)Gerasko OA,Mainicheva EA,Naumova MI,Yurjeva OP,Alberola A,Vicent C,Llusar R,Fedin VP.Eur J Inorg Chem,2008,2008:416-424
9(a)Ni XL,Xiao X,Cong H,Zhu QJ,Xue SF,Tao Z.Acc Chem Res,2014,47:1386-1395;(b)Ji NN,Cheng XJ,Zhao Y,Liang LL,Chen K,Xiao X,Zhang YQ,Zhu QJ,Xue SF,Tao Z.Eur J Inorg Chem,2014,2014:1435-1438;(c)Ji NN,Cheng XJ,Zhao Y,Liang LL,Ni XL,Xiao X,Zhu QJ,Xue SF,Dong N,Tao Z.Inorg Chem,2014,53:21-23;(d)Zhao Y,Liang LL,Chen K,Ji NN,Cheng XJ,Xiao X,Zhang YQ,Xue SF,Zhu QJ,Dong N,Tao Z.Dalton Trans,2014,43:929-932
10(a)Roh SG,Park KM,Park GJ,Sakamoto S,Yamaguchi K,Kim K.Angew Chem Int Ed,1999,38:637-641;(b)Liu JX,Long LS,Huang RB,Zheng LS,Ng SW.Acta Crystlogr E Struct Rep Online,2005,61:m1021-m1023
11(a)Thuéry P.CrystEngComm,2008,10:1126;(b)Thuéry.Cryst Growth Des,2009,9:1208-1215
12 Kushwaha S,Rao SA,Sudhakar PP.Inorg Chem,2012,51:267-273
13(a)Mei L,Wang L,Yuan L,An S,Zhao Y,Chai Z,Burns PC,Shi W.Chem Commun,2015,51:11990-11993;(b)Xie ZN,Mei L,Hu KQ,Xia LS,Chai ZF,Shi WQ.Inorg Chem,2017,56:3227-3237;(c)Mei L,Xie ZN,Hu KQ,Yuan LY,Gao ZQ,Chai ZF,Shi WQ.Chem Eur J,2017,23:13995-14003;(d)Ge YC,Mei L,Xie ZN,Hu KQ,Xia CQ,Wang XL,Chai ZF,Shi WQ.Chem Eur J,2017,23:8380-8384
14 Grenthe I,Drozdzynski JFT,Buck EC,Albrecht-Schmitt TE,Wolf SF.Uranium.In:Morss LR,Edelstein NM,Fuger J,eds.The Chemistry of the Actinide and Transactinide Elements.Dordrecht:Springer,2008.253-698
15 Luo SG.The Treatment and Disposal of Radioactive Waste.Beijing:China Environmental Science Press,2007(in Chinese)[罗上庚.放射性废物的处理和处置.北京:中国环境科学出版社,2007]
16 Day A,Arnold AP,Blanch RJ,Snushall B.J Org Chem,2001,66:8094-8100
17 Dolomanov OV,Bourhis LJ,Gildea RJ,Howard JAK,Puschmann H.J Appl Crystlogr,2009,42:339-341
18 Sheldrick GM.Acta Crystlogr C Struct Chem,2015,71:3-8
19 Kim JH,Hwang HJ,Oh JS,Sacanna S,Yi GR.J Am Chem Soc,2018,140:9230-9235
20 di Gregorio MC,Ranjan P,Houben L,Shimon LJW,Rechav K,Lahav M,van der Boom ME.J Am Chem Soc,2018,140:9132-9139
21(a)Buttress GD,Hughes MA.J Chem Soc A,1968,0:1985-1989;(b)Dollimore D,Jones LF,Nicklin T,Spooner P.J Chem Soc Faraday Trans1,1973,69:1827;(c)Ceti?li H,??lg?GK,Donat R.J Therm Anal Calorim,2012,108:1213-1222
22(a)Sutton J.Nature,1952,169:235-236;(b)McGlynn SP,Smith JK,Neely WC.J Chem Phys,1961,35:105-116
2(a)Lee JW,Samal S,Selvapalam N,Kim HJ,Kim K.Acc Chem Res,2003,36:621-630;(b)Kim K,Selvapalam N,Oh DH.J Incl Phenom,2004,50:31;(c)Lagona J,Mukhopadhyay P,Chakrabarti S,Isaacs L.Angew Chem Int Ed,2005,44:4844-4870
3(a)Kim J,Jung IS,Kim SY,Lee E,Kang JK,Sakamoto S,Yamaguchi K,Kim K.J Am Chem Soc,2000,122:540-541;(b)Day A,Arnold AP,Blanch RJ,Snushall B.J Org Chem,2001,66:8094-8100;(c)Cheng XJ,Liang LL,Chen K,Ji NN,Xiao X,Zhang JX,Zhang YQ,Xue SF,Zhu QJ,Ni XL,Tao Z.Angew Chem,2013,125:7393-7396;(d)Li Q,Qiu SC,Zhang J,Chen K,Huang Y,Xiao X,Zhang Y,Li F,Zhang YQ,Xue SF,Zhu QJ,Tao Z,Lindoy LF,Wei G.Org Lett,2016,18:4020-4023
4(a)Kim SY,Jung IS,Lee E,Kim J,Sakamoto S,Yamaguchi K,Kim K.Angew Chem Int Ed,2001,40:2119-2121;(b)Day AI,Blanch RJ,Arnold AP,Lorenzo S,Lewis GR,Dance I.Angew Chem Int Ed,2002,41:275;(c)Jeon WS,Moon K,Park SH,Chun H,Ko YH,Lee JY,Lee ES,Samal S,Selvapalam N,Rekharsky MV,Sindelar V,Sobransingh D,Inoue Y,Kaifer AE,Kim K.J Am Chem Soc,2005,127:12984-12989;(d)Jin YJ,Kim SY,Ho Ko Y,Sakamoto S,Yamaguchi K,Kim K.Org Biomol Chem,2005,3:2122;(e)Liu S,Zavalij PY,Isaacs L.J Am Chem Soc,2005,127:16798-16799;(f)Liu S,Shukla AD,Gadde S,Wagner BD,Kaifer AE,Isaacs L.Angew Chem Int Ed,2008,47:2657-2660;(g)Ko YH,Kim H,Kim Y,Kim K.Angew Chem Int Ed,2008,47:4106-4109;(h)Li Q,Sun J,Zhou J,Hua B,Shao L,Huang F.Org Chem Front,2018,5:1940-1944;(i)Wang H,Ji X,Li Z,Huang F.Adv Mater,2017,29:1606117
5(a)Mock WL.Top Curr Chem,1995,175:1;(b)Kim K.Chem Soc Rev,2002,31:96-107
6 Lim S,Kim H,Selvapalam N,Kim KJ,Cho SJ,Seo G,Kim K.Angew Chem Int Ed,2008,47:3352-3355
7(a)Freeman WA.Acta Crystlogr B Struct Sci,1984,40:382-387;(b)Buschmann HJ,Cleve E,Schollmeyer E.Inorg Chim Acta,1992,193:93-97;(c)Jeon YM,Kim J,Whang D,Kim K.J Am Chem Soc,1996,118:9790-9791;(d)Whang D,Heo J,Park JH,Kim K.Angew Chem Int Ed,1998,37:78-80;(e)Heo J,Kim SY,Whang D,Kim K.Angew Chem Int Ed,1999,38:641-643;(f)Heo J,Kim J,Whang D,Kim K.Inorg Chim Acta,2000,297:307-312;(g)Zhang F,Yajima T,Li YZ,Xu GZ,Chen HL,Liu QT,Yamauchi O.Angew Chem Int Ed,2005,44:3402-3407;(h)Liu JX,Long LS,Huang RB,Zheng LS.Cryst Growth Des,2006:62611;(i)Liang LL,Ni XL,Zhao Y,Chen K,Xiao X,Zhang YQ,Redshaw C,Zhu QJ,Xue SF,Tao Z.Inorg Chem,2013,52:1909-1915;(j)Chen WJ,Yu DH,Xiao X,Zhang YQ,Zhu QJ,Xue SF,Tao Z,Wei G.Inorg Chem,2011,50:6956-6964
8(a)Samsonenko DG,Lipkowski J,Gerasko OA,Virovets AV,Sokolov MN,Fedin VP,Platas JG,Hernandez-Molina R,Mederos A.Eur J Inorg Chem,2002,2002:2380-2388;(b)Samsonenko DG,Gerasko OA,Lipkowski J,Virovets AV,Fedin VP.Rus Chem Bull,2002,51:1915-1918;(c)Samsonenko DG,Sokolov MN,Gerasko OA,Virovets AV,Lipkowski J,Fenske D,Fedin VP.Rus Chem Bull,2003,52:2132-2139;(d)Gerasko OA,Sokolov MN,Fedin VP.Pure Appl Chem,2004,76:1633-1646;(e)Liu JX,Long LS,Huang RB,Zheng LS.Inorg Chem,2007,46:10168-10173;(f)Gerasko OA,Mainicheva EA,Naumova MI,Yurjeva OP,Alberola A,Vicent C,Llusar R,Fedin VP.Eur J Inorg Chem,2008,2008:416-424
9(a)Ni XL,Xiao X,Cong H,Zhu QJ,Xue SF,Tao Z.Acc Chem Res,2014,47:1386-1395;(b)Ji NN,Cheng XJ,Zhao Y,Liang LL,Chen K,Xiao X,Zhang YQ,Zhu QJ,Xue SF,Tao Z.Eur J Inorg Chem,2014,2014:1435-1438;(c)Ji NN,Cheng XJ,Zhao Y,Liang LL,Ni XL,Xiao X,Zhu QJ,Xue SF,Dong N,Tao Z.Inorg Chem,2014,53:21-23;(d)Zhao Y,Liang LL,Chen K,Ji NN,Cheng XJ,Xiao X,Zhang YQ,Xue SF,Zhu QJ,Dong N,Tao Z.Dalton Trans,2014,43:929-932
10(a)Roh SG,Park KM,Park GJ,Sakamoto S,Yamaguchi K,Kim K.Angew Chem Int Ed,1999,38:637-641;(b)Liu JX,Long LS,Huang RB,Zheng LS,Ng SW.Acta Crystlogr E Struct Rep Online,2005,61:m1021-m1023
11(a)Thuéry P.CrystEngComm,2008,10:1126;(b)Thuéry.Cryst Growth Des,2009,9:1208-1215
12 Kushwaha S,Rao SA,Sudhakar PP.Inorg Chem,2012,51:267-273
13(a)Mei L,Wang L,Yuan L,An S,Zhao Y,Chai Z,Burns PC,Shi W.Chem Commun,2015,51:11990-11993;(b)Xie ZN,Mei L,Hu KQ,Xia LS,Chai ZF,Shi WQ.Inorg Chem,2017,56:3227-3237;(c)Mei L,Xie ZN,Hu KQ,Yuan LY,Gao ZQ,Chai ZF,Shi WQ.Chem Eur J,2017,23:13995-14003;(d)Ge YC,Mei L,Xie ZN,Hu KQ,Xia CQ,Wang XL,Chai ZF,Shi WQ.Chem Eur J,2017,23:8380-8384
14 Grenthe I,Drozdzynski JFT,Buck EC,Albrecht-Schmitt TE,Wolf SF.Uranium.In:Morss LR,Edelstein NM,Fuger J,eds.The Chemistry of the Actinide and Transactinide Elements.Dordrecht:Springer,2008.253-698
15 Luo SG.The Treatment and Disposal of Radioactive Waste.Beijing:China Environmental Science Press,2007(in Chinese)[罗上庚.放射性废物的处理和处置.北京:中国环境科学出版社,2007]
16 Day A,Arnold AP,Blanch RJ,Snushall B.J Org Chem,2001,66:8094-8100
17 Dolomanov OV,Bourhis LJ,Gildea RJ,Howard JAK,Puschmann H.J Appl Crystlogr,2009,42:339-341
18 Sheldrick GM.Acta Crystlogr C Struct Chem,2015,71:3-8
19 Kim JH,Hwang HJ,Oh JS,Sacanna S,Yi GR.J Am Chem Soc,2018,140:9230-9235
20 di Gregorio MC,Ranjan P,Houben L,Shimon LJW,Rechav K,Lahav M,van der Boom ME.J Am Chem Soc,2018,140:9132-9139
21(a)Buttress GD,Hughes MA.J Chem Soc A,1968,0:1985-1989;(b)Dollimore D,Jones LF,Nicklin T,Spooner P.J Chem Soc Faraday Trans1,1973,69:1827;(c)Ceti?li H,??lg?GK,Donat R.J Therm Anal Calorim,2012,108:1213-1222
22(a)Sutton J.Nature,1952,169:235-236;(b)McGlynn SP,Smith JK,Neely WC.J Chem Phys,1961,35:105-116