松香多元酸对小地老虎的拒食活性研究
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摘要
以松香为原料经Diels-Alder加成反应合成了松香多元酸如丙烯海松酸(APA)、富马海松酸(FPA)及马来海松酸(MPA)。采用浸叶法,研究了松香多元酸以及脱氢枞酸对小地老虎(Agrotis ypsilon)的拒食活性。结果显示:质量浓度为1 g/L时,脱氢枞酸、丙烯海松酸、马来海松酸和富马海松酸对4龄小地老虎幼虫的24 h拒食率分别为0. 68%、78. 41%、13. 41%和79. 94%,其中丙烯海松酸及富马海松酸对小地老虎的拒食活性较高,而马来海松酸对小地老虎的拒食活性较弱,脱氢枞酸几乎没有拒食活性。丙烯海松酸及富马海松酸对小地老虎的拒食中质量浓度(AFC50)分别为0. 04和0. 06 g/L,可以进行田间试验,进一步明确其在生产中的实际防治效果。
Polyacid derivatives of rosin such as acrylpimaric acid( APA),fumaropimaric acid( FPA) and maleopimaric acid( MPA) were synthesized by Diels-Alder addition reaction from rosin. The antifeedant activities of polyacid derivatives of rosin and dehydroabietic acid against Agrotis ypsilon were investigated by leaf disc method. The results showed that antifeedant rates of dehydroabietic acid,acrylpimaric acid,maleopimaric acid and fumaropimaric acid against Agrotis ypsilon reached 0. 68%,78. 41%,13. 41% and 79. 94% at 1 g/L after 24 hours,respectively. Acrylpimaric acid and fumaropimaric acid had good antifeedant activities against Agrotis ypsilon,while maleopimaric acid exhibited weak antifeedant activities against Agrotis ypsilon and dehydroabietic acid almost didn't have antifeedant activity. The 50% antifeedant mass concentrations( AFC50) for acrylpimaric acid and fumaropimaric acid were 0. 04 and 0. 06 g/L,respectively. Field experiment could be carried out to further detect its actual control effect in production.
Polyacid derivatives of rosin such as acrylpimaric acid( APA),fumaropimaric acid( FPA) and maleopimaric acid( MPA) were synthesized by Diels-Alder addition reaction from rosin. The antifeedant activities of polyacid derivatives of rosin and dehydroabietic acid against Agrotis ypsilon were investigated by leaf disc method. The results showed that antifeedant rates of dehydroabietic acid,acrylpimaric acid,maleopimaric acid and fumaropimaric acid against Agrotis ypsilon reached 0. 68%,78. 41%,13. 41% and 79. 94% at 1 g/L after 24 hours,respectively. Acrylpimaric acid and fumaropimaric acid had good antifeedant activities against Agrotis ypsilon,while maleopimaric acid exhibited weak antifeedant activities against Agrotis ypsilon and dehydroabietic acid almost didn't have antifeedant activity. The 50% antifeedant mass concentrations( AFC50) for acrylpimaric acid and fumaropimaric acid were 0. 04 and 0. 06 g/L,respectively. Field experiment could be carried out to further detect its actual control effect in production.
引文
[1]陈一心.中国农区地老虎[M].北京:农业出版社,1986:34-35.
[2]张俊峰,王晋瑜,赵书文.影响小地老虎发生为害程度的主要因子分析[J].农业技术与装备,2016(6):49-51.
[3]朱昌雄.我国生物农药产业化现状与发展趋势[J].生物产业技术,2009(2):42-47.
[4]石元春.发展生物质产业[J].发明与创新,2006,8(1):1-5.
[5]王爱军,袁丛英.绿色生物农药研究现状及发展[J].河北化工,2006(1):54-56.
[6]单绍军,哈成勇.萜类化合物为手性源合成拒食剂研究进展[J].化学通报,2004,67(7):493-498.
[7]韩招久,郑卫青,姜志宽,等.萜类蚜虫拒食剂的筛选研究[J].江西农业大学学报,2010,32(1):78-84.
[8]KOUL O.Phytochemicals and insect control:An antifeedant approach[J].Critical Reviews in Plant Sciences,2008,27(1):1-24.
[9]WELLSOW J,GRAYER R J,VEITCH N C,et al.Insect-antifeedant and antibacterial activity of diterpenoids from species of Plectranthus[J].Phytochemistry,2006,67(16):1818-1825.
[10]LUO S,HUA J,LI C,et al.New antifeedant C20 terpenoids from Leucosceptrum canum[J].Organic Letters,2012,14(22):5768-5771.
[11]宋湛谦.松香的精细化工利用(I)---松香的组成与性质.林产化工通讯[J].生物质化学工程,2002,36(4):29-33.
[12]刘莉,高艳清,饶小平,等.脱氢枞基酰胺及亚胺衍生物对粘虫的拒食活性[J].生物质化学工程,2014,48(6):6-10.
[13]KLEJDYSZ T,LEGOSZ B,CZURYSZKIEWICZ D,et al.Biobased ionic liquids with abietate anion[J].ACS Sustainable Chemistry&Engineering,2016,4:6543-6550.
[14]饶小平.松香树脂酸衍生物的合成、表征及生物活性研究[D].北京:中国林业科学研究院博士学位论文,2007.
[15]李健.丙烯海松酸衍生物的合成、生物活性及QSAR研究[D].北京:中国林业科学研究院博士学位论文,2012.
[16]徐徐.富马海松酸改性水性聚氨酯的制备和性能研究[D].北京:中国林业科学研究院博士学位论文,2011.
[17]RAO X P,SONG Z Q,YAO X J,et al.Synthesis and crystal structure of maleopimaric acid[J].Natural Product Research,2008,22(10):854-859.
[18]陈立,徐汉虹,赵善欢.唐古特瑞香对菜粉蝶幼虫的拒食和胃毒活性[J].天然产物研究与开发,2000,12(6):22-26.
[19]吕敏.梣酮的杀虫活性及作用机理的初步研究[D].西安:西北农林科技大学博士学位论文,2009.
[20]JEYASANKAR A.Antifeedant,insecticidal and growth inhibitory activities of selected plant oils on black cutworm,Agrotis ipsilon,(Hufnagel)(Lepidoptera:Noctuidae)[J].Asian Pacific Journal of Tropical Disease,2012,2(S1):S347-S351.
[2]张俊峰,王晋瑜,赵书文.影响小地老虎发生为害程度的主要因子分析[J].农业技术与装备,2016(6):49-51.
[3]朱昌雄.我国生物农药产业化现状与发展趋势[J].生物产业技术,2009(2):42-47.
[4]石元春.发展生物质产业[J].发明与创新,2006,8(1):1-5.
[5]王爱军,袁丛英.绿色生物农药研究现状及发展[J].河北化工,2006(1):54-56.
[6]单绍军,哈成勇.萜类化合物为手性源合成拒食剂研究进展[J].化学通报,2004,67(7):493-498.
[7]韩招久,郑卫青,姜志宽,等.萜类蚜虫拒食剂的筛选研究[J].江西农业大学学报,2010,32(1):78-84.
[8]KOUL O.Phytochemicals and insect control:An antifeedant approach[J].Critical Reviews in Plant Sciences,2008,27(1):1-24.
[9]WELLSOW J,GRAYER R J,VEITCH N C,et al.Insect-antifeedant and antibacterial activity of diterpenoids from species of Plectranthus[J].Phytochemistry,2006,67(16):1818-1825.
[10]LUO S,HUA J,LI C,et al.New antifeedant C20 terpenoids from Leucosceptrum canum[J].Organic Letters,2012,14(22):5768-5771.
[11]宋湛谦.松香的精细化工利用(I)---松香的组成与性质.林产化工通讯[J].生物质化学工程,2002,36(4):29-33.
[12]刘莉,高艳清,饶小平,等.脱氢枞基酰胺及亚胺衍生物对粘虫的拒食活性[J].生物质化学工程,2014,48(6):6-10.
[13]KLEJDYSZ T,LEGOSZ B,CZURYSZKIEWICZ D,et al.Biobased ionic liquids with abietate anion[J].ACS Sustainable Chemistry&Engineering,2016,4:6543-6550.
[14]饶小平.松香树脂酸衍生物的合成、表征及生物活性研究[D].北京:中国林业科学研究院博士学位论文,2007.
[15]李健.丙烯海松酸衍生物的合成、生物活性及QSAR研究[D].北京:中国林业科学研究院博士学位论文,2012.
[16]徐徐.富马海松酸改性水性聚氨酯的制备和性能研究[D].北京:中国林业科学研究院博士学位论文,2011.
[17]RAO X P,SONG Z Q,YAO X J,et al.Synthesis and crystal structure of maleopimaric acid[J].Natural Product Research,2008,22(10):854-859.
[18]陈立,徐汉虹,赵善欢.唐古特瑞香对菜粉蝶幼虫的拒食和胃毒活性[J].天然产物研究与开发,2000,12(6):22-26.
[19]吕敏.梣酮的杀虫活性及作用机理的初步研究[D].西安:西北农林科技大学博士学位论文,2009.
[20]JEYASANKAR A.Antifeedant,insecticidal and growth inhibitory activities of selected plant oils on black cutworm,Agrotis ipsilon,(Hufnagel)(Lepidoptera:Noctuidae)[J].Asian Pacific Journal of Tropical Disease,2012,2(S1):S347-S351.