改性聚乙烯醇膜对二氧化碳分离应用综述
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摘要
以PVA为基体,综述了聚乙烯醇气体分离膜经接枝和共混改性对二氧化碳气体分离性能的影响。PVA膜的改性能调整膜的结构和形态,能提高PVA分离膜的渗透性和选择性,使其朝着对气体分离有利的方向发展。最后,对改性的PVA膜在气体处理领域的工业应用前景进行了展望。
The effects of polyvinyl alcohol( PVA) membranes on the carbon dioxide gas separation performance are reviewed. As a polymer matrix,modification method of PVA includes grafting or blending. It has been found that the internal structure and morphology of the modified PVA membrane are changed. The modification of the gas separation membrane makes it develop in a favorable direction,and improves gas separation performance. Finally,the application of modified PVA membranes is prospected in the field of gas treatment.
The effects of polyvinyl alcohol( PVA) membranes on the carbon dioxide gas separation performance are reviewed. As a polymer matrix,modification method of PVA includes grafting or blending. It has been found that the internal structure and morphology of the modified PVA membrane are changed. The modification of the gas separation membrane makes it develop in a favorable direction,and improves gas separation performance. Finally,the application of modified PVA membranes is prospected in the field of gas treatment.
引文
[1] Bemardo P,Drioli E,Golemme G. Membrane gas separation:a review/state of the art[J]. Industrial&Engineering Chemistry Research,2009,48(10):4638-4663.
[2] Pedram M Z,Omidkhah M,Amooghin A E. Synthesis and characterization of diethanolamine-impregnated crosslinked polyvinylalcohol/glutaraldehyde membranes for CO2/CH4separation[J]. Journal of Industrial and Engineering Chemistry,2014,20(1):74-82.
[3] Hodge R M,Edward G H,Simon G P. Water absorption and states of water in semicrystalline poly(vinyl alcohol)films[J]. Polymer,1996,37(8):1371-1376.
[4]周田田.利用多巴胺粘合特性调控膜内多级结构和多重作用的研究[D].天津:天津大学,2015.
[5] Peng F,Jiang Z,Hoek E M V. Tuning the molecular structure,separation performance and interfacial properties of poly(vinyl alcohol)-polysulfone interfacial composite membranes[J]. Journal of Membrane Science,2011,368(1/2):26-33.
[6] Saeed M,Deng L. CO2facilitated transport membrane promoted by mimic enzyme[J]. Journal of Membrane Science,2015,494:196-204.
[7]孙载坚.接枝共聚合[M].北京:化学工业出版社,1992.
[8] Park M S,Choi Y,Lee K B,et al. Synthesis of PVA-g-POEM graft copolymers and their use in highly permeable thin film composite membranes[J]. Chemical Engineering Journal,2018,346:739-747.
[9] Zhang Q G,Liu Q L,Chen Y,et al. Dehydration of isopropanol by novel poly(vinyl alcohol)-silicone hybrid membranes[J]. Industrial&Engineering Chemistry Research,2007,46(3):913-920.
[10] Luo J,Zhu T,Song Y,et al. Improved permeability by incorporating polysiloxane in SBS block copolymers for CH4/N2gas separation[J]. Polymer,2017,127:52-65.
[11] Xing R,Ho W S W. Crosslinked polyvinylalcohol-polysiloxane/fumed silica mixed matrix membranes containing amines for CO2/H2separation[J]. Journal of Membrane Science,2011,367(1/2):91-102.
[12] Saeed M,Deng L. Carbon nanotube enhanced PVA-mimic enzyme membrane for post-combustion CO2capture[J].International Journal of Greenhouse Gas Control,2016,53:254-262.
[13] Ansaloni L,Zhao Y,Jung B T,et al. Facilitated transport membranes containing amino-functionalized multi-walled carbon nanotubes for high-pressure CO2separations[J].Journal of Membrane Science,2015,490:18-28.
[14] Dilshad M R,Islam A,Sabir A,et al. Fabrication and performance characterization of novel zinc oxide filled crosslinked PVA/PEG600 blended membranes for CO2/N2separation[J]. Journal of Industrial and Engineering Chemistry,2017,55:65-73.
[15] Guerrero G,Hgg M B,Simon C,et al. CO2separation in nanocomposite membranes by the addition of amidine and lactamide functionalized POSSnanoparticles into a PVA layer[J]. Membranes,2018,8(2):28.
[16] Amooghin A E,Omidkhah M,Kargari A. Enhanced CO2transport properties of membranes by embedding nanoporous zeolite particles into Matrimid5218 matrix[J].RSC Advances,2015,5(12):8552-8565.
[17] Deng F,Guan Y,Shi Z,et al. The effect of dopamine modified titanium dioxide nanoparticles on the performance of poly(vinyl alcohol)/titanium dioxide composites[J].Composites Science and Technology,2017,150:120-127.
[18]廖家友.分离CO2固定载体膜中高效微环境设计研究[D].天津:天津大学,2015.
[19] Xing R,Ho W S W. Synthesis and characterization of crosslinked polyvinylalcohol/polyethyleneglycol blend membranes for CO2/CH4separation[J]. Journal of the Taiwan Institute of Chemical Engineers,2009,40(6):654-662.
[20] Mondal A,Mandal B. CO2separation using thermally stable crosslinked poly(vinyl alcohol)membrane blended with polyvinylpyrrolidone/polyethyleneimine/tetraethylenepentamine[J]. Journal of Membrane Science,2014,460:126-138.
[21] Zhao Y,Ho W S W. CO2-selective membranes containing sterically hindered amines for CO2/H2separation[J]. Industrial&Engineering Chemistry Research,2012,52(26):8774-8782.
[22] Deng L,Hagg M B. Fabrication and evaluation of a blend facilitated transport membrane for CO2/CH4separation[J]. Industrial&Engineering Chemistry Research,2015,54(44):11139-11150.
[23] Yi C,Wang Z,Li M,et al. Facilitated transport of CO2through polyvinylamine/polyethlene glycol blend membranes[J]. Desalination,2006,193(1/2/3):90-96.
[24] Matsuyama H,Matui K,Kitamura Y,et al. Effects of membrane thickness and membrane preparation condition on facilitated transport of CO2through ionomer membrane[J]. Separation and Purification Technology,1999,17(3):235-241.
[25] Jahan Z,Niazi M B K,Hagg M B,et al. Cellulose nanocrystal/PVA nanocomposite membranes for CO2/CH4separation at high pressure[J]. Journal of Membrane Science,2018,554:275-281.
[26]刘茜. PVA基促进传递膜的制备及其吸附分离性能研究[D].北京:北京工商大学,2016.
[27]李奕帆.聚氧乙烯基CO2分离膜的可控制备与传递机制强化[D].天津:天津大学,2014.
[28] Jiang X,Zhang X,Ye D,et al. Modification of poly(vinyl alcohol)films by the addition of magnesium chloride hexahydrate[J]. Polymer Engineering&Science,2012,52(7):1565-1570.
[29] Esmaeili M,Madaeni S S,Barzin J. Morphology and gaspermeation analyses for poly(ether sulfone)/poly(vinyl alcohol)electrolyte composite membranes in the facilitated transport process[J]. Journal of Applied Polymer Science,2013,129(3):1569-1585.
[30]刘茜,田华峰,戈翔,等. PVA/Cu SO4·5H2O复合膜的制备及其结构与性能研究[J].中国塑料,2016,30(1):92-97.
[2] Pedram M Z,Omidkhah M,Amooghin A E. Synthesis and characterization of diethanolamine-impregnated crosslinked polyvinylalcohol/glutaraldehyde membranes for CO2/CH4separation[J]. Journal of Industrial and Engineering Chemistry,2014,20(1):74-82.
[3] Hodge R M,Edward G H,Simon G P. Water absorption and states of water in semicrystalline poly(vinyl alcohol)films[J]. Polymer,1996,37(8):1371-1376.
[4]周田田.利用多巴胺粘合特性调控膜内多级结构和多重作用的研究[D].天津:天津大学,2015.
[5] Peng F,Jiang Z,Hoek E M V. Tuning the molecular structure,separation performance and interfacial properties of poly(vinyl alcohol)-polysulfone interfacial composite membranes[J]. Journal of Membrane Science,2011,368(1/2):26-33.
[6] Saeed M,Deng L. CO2facilitated transport membrane promoted by mimic enzyme[J]. Journal of Membrane Science,2015,494:196-204.
[7]孙载坚.接枝共聚合[M].北京:化学工业出版社,1992.
[8] Park M S,Choi Y,Lee K B,et al. Synthesis of PVA-g-POEM graft copolymers and their use in highly permeable thin film composite membranes[J]. Chemical Engineering Journal,2018,346:739-747.
[9] Zhang Q G,Liu Q L,Chen Y,et al. Dehydration of isopropanol by novel poly(vinyl alcohol)-silicone hybrid membranes[J]. Industrial&Engineering Chemistry Research,2007,46(3):913-920.
[10] Luo J,Zhu T,Song Y,et al. Improved permeability by incorporating polysiloxane in SBS block copolymers for CH4/N2gas separation[J]. Polymer,2017,127:52-65.
[11] Xing R,Ho W S W. Crosslinked polyvinylalcohol-polysiloxane/fumed silica mixed matrix membranes containing amines for CO2/H2separation[J]. Journal of Membrane Science,2011,367(1/2):91-102.
[12] Saeed M,Deng L. Carbon nanotube enhanced PVA-mimic enzyme membrane for post-combustion CO2capture[J].International Journal of Greenhouse Gas Control,2016,53:254-262.
[13] Ansaloni L,Zhao Y,Jung B T,et al. Facilitated transport membranes containing amino-functionalized multi-walled carbon nanotubes for high-pressure CO2separations[J].Journal of Membrane Science,2015,490:18-28.
[14] Dilshad M R,Islam A,Sabir A,et al. Fabrication and performance characterization of novel zinc oxide filled crosslinked PVA/PEG600 blended membranes for CO2/N2separation[J]. Journal of Industrial and Engineering Chemistry,2017,55:65-73.
[15] Guerrero G,Hgg M B,Simon C,et al. CO2separation in nanocomposite membranes by the addition of amidine and lactamide functionalized POSSnanoparticles into a PVA layer[J]. Membranes,2018,8(2):28.
[16] Amooghin A E,Omidkhah M,Kargari A. Enhanced CO2transport properties of membranes by embedding nanoporous zeolite particles into Matrimid5218 matrix[J].RSC Advances,2015,5(12):8552-8565.
[17] Deng F,Guan Y,Shi Z,et al. The effect of dopamine modified titanium dioxide nanoparticles on the performance of poly(vinyl alcohol)/titanium dioxide composites[J].Composites Science and Technology,2017,150:120-127.
[18]廖家友.分离CO2固定载体膜中高效微环境设计研究[D].天津:天津大学,2015.
[19] Xing R,Ho W S W. Synthesis and characterization of crosslinked polyvinylalcohol/polyethyleneglycol blend membranes for CO2/CH4separation[J]. Journal of the Taiwan Institute of Chemical Engineers,2009,40(6):654-662.
[20] Mondal A,Mandal B. CO2separation using thermally stable crosslinked poly(vinyl alcohol)membrane blended with polyvinylpyrrolidone/polyethyleneimine/tetraethylenepentamine[J]. Journal of Membrane Science,2014,460:126-138.
[21] Zhao Y,Ho W S W. CO2-selective membranes containing sterically hindered amines for CO2/H2separation[J]. Industrial&Engineering Chemistry Research,2012,52(26):8774-8782.
[22] Deng L,Hagg M B. Fabrication and evaluation of a blend facilitated transport membrane for CO2/CH4separation[J]. Industrial&Engineering Chemistry Research,2015,54(44):11139-11150.
[23] Yi C,Wang Z,Li M,et al. Facilitated transport of CO2through polyvinylamine/polyethlene glycol blend membranes[J]. Desalination,2006,193(1/2/3):90-96.
[24] Matsuyama H,Matui K,Kitamura Y,et al. Effects of membrane thickness and membrane preparation condition on facilitated transport of CO2through ionomer membrane[J]. Separation and Purification Technology,1999,17(3):235-241.
[25] Jahan Z,Niazi M B K,Hagg M B,et al. Cellulose nanocrystal/PVA nanocomposite membranes for CO2/CH4separation at high pressure[J]. Journal of Membrane Science,2018,554:275-281.
[26]刘茜. PVA基促进传递膜的制备及其吸附分离性能研究[D].北京:北京工商大学,2016.
[27]李奕帆.聚氧乙烯基CO2分离膜的可控制备与传递机制强化[D].天津:天津大学,2014.
[28] Jiang X,Zhang X,Ye D,et al. Modification of poly(vinyl alcohol)films by the addition of magnesium chloride hexahydrate[J]. Polymer Engineering&Science,2012,52(7):1565-1570.
[29] Esmaeili M,Madaeni S S,Barzin J. Morphology and gaspermeation analyses for poly(ether sulfone)/poly(vinyl alcohol)electrolyte composite membranes in the facilitated transport process[J]. Journal of Applied Polymer Science,2013,129(3):1569-1585.
[30]刘茜,田华峰,戈翔,等. PVA/Cu SO4·5H2O复合膜的制备及其结构与性能研究[J].中国塑料,2016,30(1):92-97.