甲酸液相分解制氢非均相催化剂研究进展
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摘要
氢气作为一种清洁的可再生能源载体,是最有希望替代化石燃料的能源之一。然而,如何实现氢气的安全存储和快速释放是氢能利用的难点。甲酸作为极具应用潜力的液态化学储氢材料,其分解制氢逐渐成为研究热点。从实际应用角度考虑,设计与开发高效非均相催化剂对于甲酸分解的应用十分重要,而载体在非均相催化剂中通常具有重要作用。作者综述了近年来国内外非均相催化甲酸液相分解制氢的研究现状,以载体分类为主线,重点概述了以碳材料、金属氧化物、二氧化硅(含分子筛)、复合材料及树脂、金属有机框架(MOFs)作为载体制备的催化剂在甲酸分解过程中的应用,其目的在于强调在该领域取得的成果以及对今后的研究提出建议。
Hydrogen is a renewable and clean energy regarded as one of the most promising candidates for fossil energy replacement. However, safe storage and rapid release of hydrogen is the difficulty in hydrogen utilization. Decomposition of formic acid(FA) for hydrogen generation increasingly becomes research hotspot. It is important to develop high-performance heterogeneous catalysts for FA dehydrogenation. Therefore, studies of hydrogen generation from liquid-phase formic acid using heterogeneous catalysts were reviewed. Carbon, metal oxides, silica(zeolites), composite materials, resins and metal-organic frameworks(MOFs) as catalyst supports were focused. Remarkable advances achieved are emphasized and future research directions are discussed.
Hydrogen is a renewable and clean energy regarded as one of the most promising candidates for fossil energy replacement. However, safe storage and rapid release of hydrogen is the difficulty in hydrogen utilization. Decomposition of formic acid(FA) for hydrogen generation increasingly becomes research hotspot. It is important to develop high-performance heterogeneous catalysts for FA dehydrogenation. Therefore, studies of hydrogen generation from liquid-phase formic acid using heterogeneous catalysts were reviewed. Carbon, metal oxides, silica(zeolites), composite materials, resins and metal-organic frameworks(MOFs) as catalyst supports were focused. Remarkable advances achieved are emphasized and future research directions are discussed.
引文
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