烷基糖苷与辛基咪唑啉复配体系的性能研究
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摘要
用烷基糖苷APG0810与两性离子表面活性剂辛基咪唑啉进行复配,测定了复配体系的表面活性、泡沫性能、润湿力和乳化性能。结果表明,APG0810与辛基咪唑啉的复配体系具有一定的协同增效作用。当m(APG0810)∶m(辛基咪唑啉)=5∶1时,对表面活性的增效作用最好,其临界胶束浓度(cmc)为577.53 mg/L,最低表面张力(γcmc)为28.20 m N/m。同时,通过与APG0810进行复配,辛基咪唑啉的润湿力和乳化性能均得到改善,并且在m(APG0810)∶m(辛基咪唑啉)=5∶1时,效果达到最好。
The blend system composed of alkyl polyglucoside( APG0810) and zwitterionic surfactant octyl imidazoline was prepared. Its surface activity,foaming performance,wetting power and emulsifying performance were investigated. The results showed that the blend system of APG0810 and octyl imidazoline displays a good synergistic effect. When the mass ratio between APG0810 and octyl imidazoline is 5∶ 1,the synergistic effect is the best. And in that condition,the value of the critical micelle concentration is 577. 53 mg / L and the minimum value of γcmcis 28. 20 m N / m. The wetting power and emulsifying performance are also improved,and when the mass ratio between APG0810 and octyl imidazoline is 5∶ 1,the effects achieve the best.
The blend system composed of alkyl polyglucoside( APG0810) and zwitterionic surfactant octyl imidazoline was prepared. Its surface activity,foaming performance,wetting power and emulsifying performance were investigated. The results showed that the blend system of APG0810 and octyl imidazoline displays a good synergistic effect. When the mass ratio between APG0810 and octyl imidazoline is 5∶ 1,the synergistic effect is the best. And in that condition,the value of the critical micelle concentration is 577. 53 mg / L and the minimum value of γcmcis 28. 20 m N / m. The wetting power and emulsifying performance are also improved,and when the mass ratio between APG0810 and octyl imidazoline is 5∶ 1,the effects achieve the best.
引文
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[11]WANG R T,LI Y L,LI Q X.Synthesis and properties of dodecyldiethoxylamine oxide[J].J Surfact Deterg,2013,16(4):509-514.
[12]王金涛,王万绪,王丰收,等.糖苷季铵盐与α-烯基磺酸钠复配体系的表面活性[J].日用化学工业,2009,39(3):162-165.
[13]杜世宇,范振忠.环保型稠油乳化剂十二烷基糖苷的性能评价[J].油气田地面工程,2014(6):104-105.
[14]徐晓丽,王业飞,李丹丹,等.乳化性能差异对中低渗岩心驱油效果的影响[J].断块油气田,2013(3):388-391.
[15]孙琳,蒲万芬,吴雅丽,等.表面活性剂高温乳化性能研究[J].油田化学,2011(3):
[2]兰云军,鲍利红,李延.两性表面活性剂的类型、应用性能和发展概况[J].中国皮革,2003,32(13):20-24.
[3]石顺存,蒋华鹏,方茹苕,等.两性咪唑啉的合成及其缓蚀性能研究[J].湖南科技大学学报:自然科学版,2007(2):94-97.
[4]郭建龙.羧酸型咪唑啉两性表面活性剂的合成与性能研究[D].天津:天津理工大学,2008.
[5]陈亚琼,廖强强,董万田,等.柠檬酸介质中咪唑啉复配缓蚀剂对碳钢的缓蚀作用[J].腐蚀与防护,2012(12):1055-1056.
[6]陈旋,魏芳,张剑波.新型的绿色表面活性剂:烷基糖苷[J].化学教育,2011(6):3-6.
[7]郑艳,蒲晓林,白小东.烷基糖苷发展现状及新进展[J].日用化学品科学,2006,29(5):4-7.
[8]白亮,杨秀全.烷基糖苷的制备[J].日用化学品科学,2009,29(6):21-24.
[9]黄新霞,张丹云.烷基糖苷与表面活性剂[J].皮革科学与工程,2007(4):43-45.
[10]董万田.烷基糖苷的性能及应用[J].应用化工,2008(6):683-684.
[11]WANG R T,LI Y L,LI Q X.Synthesis and properties of dodecyldiethoxylamine oxide[J].J Surfact Deterg,2013,16(4):509-514.
[12]王金涛,王万绪,王丰收,等.糖苷季铵盐与α-烯基磺酸钠复配体系的表面活性[J].日用化学工业,2009,39(3):162-165.
[13]杜世宇,范振忠.环保型稠油乳化剂十二烷基糖苷的性能评价[J].油气田地面工程,2014(6):104-105.
[14]徐晓丽,王业飞,李丹丹,等.乳化性能差异对中低渗岩心驱油效果的影响[J].断块油气田,2013(3):388-391.
[15]孙琳,蒲万芬,吴雅丽,等.表面活性剂高温乳化性能研究[J].油田化学,2011(3):