纳米纤维素对两性蠕虫胶束线性黏弹性的影响
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摘要
对两性蠕虫胶束(Z-WLM)溶液添加不同类型纳米纤维素(NCs)后的耐温性能进行了研究,并通过线性流变学方法分析了不同浓度的NCs对Z-WLM的动态黏弹性、触变性、蠕变性等流变行为的影响。研究结果表明,质量分数为4wt%的芥酸酰胺丙基二甲基甜菜碱表面活性剂溶液可形成蠕虫胶束(WLM)结构,具有剪切稀释性、黏弹性、蠕变性及良好的触变回复性等特性。与其它类型NCs相比,长径比大、羧基含量高的NCs对WLM溶液拥有更好的增黏作用,同时可增加体系的松弛时间、弹性模量,延长其剪切黏度及动态模量触变回复时间,改善其蠕变回复性和耐温性,适用于70～100℃的中高温油藏增产作业使用。随着NCs添加量的增加,复合体系的黏弹性和蠕变回复性增强,触变回复性减弱。
The thermal stability of zwitterionic wormlike micelle(Z-WLM)solution with different nanocelluloses(NCs)was investigated.The effects of NCs concentration on the dynamic viscoelastic behavior,thixotropy and creep of Z-WLM were studied by linear rheological methods.The experimental result shows that a wormlike micelle(WLM)structure is formed by 4 wt% erucy lamidopropyl betaine surfactant solution with many unique rheological properties,including shear thinning behavior,viscoelastic behavior,creep behavior and higher thixotropy recovery behavior,et al.Compared to other NCs,the NCs with high —COOH mass fraction and large aspect ratio possess better thickening efficiency.Moreover,the NCs can increase the Z-WLM solution's relaxation time and storage modulus,extend its thixotropy recovery time of shear viscosity and dynamic modulus,improve its creep recovery performance and thermal stability,which can use as a stimulation fluid in high temperature reservoirs from 70℃to100℃.With the increase of NCs concentration,the viscoelasticity and creep recovery performance of composite systems are increased and its thixotropy recovery performance is decreased.
The thermal stability of zwitterionic wormlike micelle(Z-WLM)solution with different nanocelluloses(NCs)was investigated.The effects of NCs concentration on the dynamic viscoelastic behavior,thixotropy and creep of Z-WLM were studied by linear rheological methods.The experimental result shows that a wormlike micelle(WLM)structure is formed by 4 wt% erucy lamidopropyl betaine surfactant solution with many unique rheological properties,including shear thinning behavior,viscoelastic behavior,creep behavior and higher thixotropy recovery behavior,et al.Compared to other NCs,the NCs with high —COOH mass fraction and large aspect ratio possess better thickening efficiency.Moreover,the NCs can increase the Z-WLM solution's relaxation time and storage modulus,extend its thixotropy recovery time of shear viscosity and dynamic modulus,improve its creep recovery performance and thermal stability,which can use as a stimulation fluid in high temperature reservoirs from 70℃to100℃.With the increase of NCs concentration,the viscoelasticity and creep recovery performance of composite systems are increased and its thixotropy recovery performance is decreased.
引文
[1] CHASE B,CHMILOWSKI W,MARCINEW R,et al.Clear fracturing fluids for increased well productivity[J].Oilfield Review,1997,9(3):20-33.
[2] KEFI S,LEE J,POPE T L,et al.Expanding applications for viscoelastic surfactants[J].Oilfield Review,2004,16(4):10-23.
[3] BALZER D,VARWIG S,WEIHRAUCH M.Viscoelasticity of personal care products[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,1995,99(2):233-246.
[4] SHI H F,WANG Y,FANG B,et al.Light-responsive threadlike micelles as drag reducing fluids with enhanced heat-transfer capabilities[J].Langmuir,2011,27(10):5806-5813.
[5] YANG J,YANG Z,LU Y J,et al.Rheological properties of zwitterionic wormlike micelle in presence of solvents and cosurfactant at high temperature[J].Journal of Dispersion Science and Technology,2013,34(8):1124-1129.
[6]秦文龙,乐雷,贾帅,等.纳米碳管对蠕虫状胶束流体流变特性的影响[J].石油学报(石油加工),2016,32(5):1068-1074.QIN Wenlong,YUE Lei,JIA Shuai,et al.Effect of carbon nanotubes on rheological properties of wormlike micelle solution[J].Acta Petrolei Sinica(Petroleum Processing Section),2016,32(5):1068-1074(in Chinese).
[7]罗明良,贾自龙,孙厚台,等.纳米TiO2改性MES黏弹性胶束溶液的性能[J].石油学报(石油加工),2012,28(3):457-462.LUO Mingliang,JIA Zilong,SUN Houtai,et al.Performance of nano-TiO2 modified MES viscoelastic micelle solution[J].Acta Petrolei Sinica(Petroleum Processing Section),2012,28(3):457-462(in Chinese).
[8] QIN W L,YUE L,LIANG G Q,et al.Effect of multiwalled carbon nanotubes on linear viscoelastic behavior and microstructure of zwitterionic wormlike micelle at high temperature[J].Chemical Engineering Research&Design,2017,123:14-22.
[9] TANG L R,HUANG B,DAI D S,et al.Spectrum and rheological properties of nanocellulose crystal prepared with cation exchange resin[J].Polymer Materials Science&Engineering,2011,27(6):45-48.
[10] LEE J,DENG Y.Increased mechanical properties of aligned and isotropic electrospun PVA nanofiber webs by cellulose nanowhisker reinforcement[J]. Macromolecular Research,2012,20(1):76-83.
[11] BOUFI S,KADDAMI H,DUFRESNE A.Mechanical performance and transparency of nanocellulose reinforced polymer nanocomposites[J].Macromolecular Materials&Engineering,2014,299(5):560-568.
[12]刘桦,罗丙红,陈睿鹏,等.纳米纤维素晶须增强增韧聚(L-乳酸)复合材料的制备与表征[J].复合材料学报,2015,32(6):1703-1713.LIU Hua,LUO Binghong,CHEN Ruipeng,et al.Preparation and characterization of nano cellulose whiskers reinforced and toughened poly(L-lactic acid)based composites[J].Acta Materiae Compositae Sinica,2015,32(6):1703-1713(in Chinese).
[13] FORSRE S,KONRAD M,LINDNER P.Shear thinning and orientational ordering of wormlike micelles[J].Physical Review Letters,2005,94(1):017803.
[14] LUO M L,JIA Z L,SUN H T,et al.Rheological behavior and microstructure of an anionic surfactant micelle solution with pyroelectric nanoparticle[J].Colloids&Surfaces A:Physicochemical&Engineering Aspects,2012,395(395):267-275.
[15]张为灿,李干佐,李英.表面活性剂蠕虫状胶束缔合体系研究进展[J].日用化学工业,1999(5):34-41.ZHANG Weican,LI Ganzuo,LI Ying.Statics and dynamics of wormlike surfactant micelles[J].China Surfactant Detergent&Cosmetics,1999(5):34-41(in Chinese).
[16] HELGESON M E,HODGDON T K,KALER E W,et al.Formation and rheology of viscoelastic“double networks”in wormlike micelle-nanoparticle mixtures[J].Langmuir the Acs Journal of Surfaces&Colloids,2010,26(11):8049-8060.
[17]周逸凝,崔伟香,杨江,等.一种新型超分子复合压裂液的性能研究[J].油田化学,2015,32(2):180-184.ZHOU Yining,CUI Weixiang,YANG Jiang,et al.Performance evaluation of a novel supramolecular fracturing fluid[J].Oilfield Chemistry,2015,32(2):180-184(in Chinese).
[18]吕少一,邵自强,张振玲,等.新型含能纤维素基凝胶推进剂的流变性能研究[J].化学学报,2012,70(2):200-206.LV Shaoyi,SHAO Ziqiang,ZHANG Zhenling,et al.Studies on rheological properties of gelled propellant based on new energetic cellulose[J].Acta Chimica Sinica,2012,70(2):200-206(in Chinese).
[19]王海朋,张蓉,张晓华,等.沥青砂动态剪切蠕变特性[J].山东大学学报(工学版),2016,46(4):68-75.WANG Haipeng,ZHANG Rong,ZHANG Xiaohua,et al.Dynamic shear creep characteristics of asphalt mortar[J].Journal of Shandong University(Engineering Science),2016,46(4):68-75(in Chinese).
[20]孙全力,王爱蓉,张军,等.疏水缔合聚合物APP4流变性能实验研究[J].成都理工大学学报(自科版),2012,39(1):104-106.SUN Quanli,WANG Airong,ZHANG Jun,et al.Rheological properties of hydrophobic associative polymer APP4[J].Journal of Chengdou University of Technology(Science&Technology Edition),2012,39(1):104-106(in Chinese).
[21] GRATTONI C A,ALSHARJI H H,YANG C,et al.Rheology and permeability of crosslinked polyacrylamide gel[J].Journal of Colloid&Interface Science,2001,240(2):601-607.
[22] MACOSKO C W.Rheology,principles,measurements and applications[M].New York:Wiley-VCH,1994:119-121.
[2] KEFI S,LEE J,POPE T L,et al.Expanding applications for viscoelastic surfactants[J].Oilfield Review,2004,16(4):10-23.
[3] BALZER D,VARWIG S,WEIHRAUCH M.Viscoelasticity of personal care products[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,1995,99(2):233-246.
[4] SHI H F,WANG Y,FANG B,et al.Light-responsive threadlike micelles as drag reducing fluids with enhanced heat-transfer capabilities[J].Langmuir,2011,27(10):5806-5813.
[5] YANG J,YANG Z,LU Y J,et al.Rheological properties of zwitterionic wormlike micelle in presence of solvents and cosurfactant at high temperature[J].Journal of Dispersion Science and Technology,2013,34(8):1124-1129.
[6]秦文龙,乐雷,贾帅,等.纳米碳管对蠕虫状胶束流体流变特性的影响[J].石油学报(石油加工),2016,32(5):1068-1074.QIN Wenlong,YUE Lei,JIA Shuai,et al.Effect of carbon nanotubes on rheological properties of wormlike micelle solution[J].Acta Petrolei Sinica(Petroleum Processing Section),2016,32(5):1068-1074(in Chinese).
[7]罗明良,贾自龙,孙厚台,等.纳米TiO2改性MES黏弹性胶束溶液的性能[J].石油学报(石油加工),2012,28(3):457-462.LUO Mingliang,JIA Zilong,SUN Houtai,et al.Performance of nano-TiO2 modified MES viscoelastic micelle solution[J].Acta Petrolei Sinica(Petroleum Processing Section),2012,28(3):457-462(in Chinese).
[8] QIN W L,YUE L,LIANG G Q,et al.Effect of multiwalled carbon nanotubes on linear viscoelastic behavior and microstructure of zwitterionic wormlike micelle at high temperature[J].Chemical Engineering Research&Design,2017,123:14-22.
[9] TANG L R,HUANG B,DAI D S,et al.Spectrum and rheological properties of nanocellulose crystal prepared with cation exchange resin[J].Polymer Materials Science&Engineering,2011,27(6):45-48.
[10] LEE J,DENG Y.Increased mechanical properties of aligned and isotropic electrospun PVA nanofiber webs by cellulose nanowhisker reinforcement[J]. Macromolecular Research,2012,20(1):76-83.
[11] BOUFI S,KADDAMI H,DUFRESNE A.Mechanical performance and transparency of nanocellulose reinforced polymer nanocomposites[J].Macromolecular Materials&Engineering,2014,299(5):560-568.
[12]刘桦,罗丙红,陈睿鹏,等.纳米纤维素晶须增强增韧聚(L-乳酸)复合材料的制备与表征[J].复合材料学报,2015,32(6):1703-1713.LIU Hua,LUO Binghong,CHEN Ruipeng,et al.Preparation and characterization of nano cellulose whiskers reinforced and toughened poly(L-lactic acid)based composites[J].Acta Materiae Compositae Sinica,2015,32(6):1703-1713(in Chinese).
[13] FORSRE S,KONRAD M,LINDNER P.Shear thinning and orientational ordering of wormlike micelles[J].Physical Review Letters,2005,94(1):017803.
[14] LUO M L,JIA Z L,SUN H T,et al.Rheological behavior and microstructure of an anionic surfactant micelle solution with pyroelectric nanoparticle[J].Colloids&Surfaces A:Physicochemical&Engineering Aspects,2012,395(395):267-275.
[15]张为灿,李干佐,李英.表面活性剂蠕虫状胶束缔合体系研究进展[J].日用化学工业,1999(5):34-41.ZHANG Weican,LI Ganzuo,LI Ying.Statics and dynamics of wormlike surfactant micelles[J].China Surfactant Detergent&Cosmetics,1999(5):34-41(in Chinese).
[16] HELGESON M E,HODGDON T K,KALER E W,et al.Formation and rheology of viscoelastic“double networks”in wormlike micelle-nanoparticle mixtures[J].Langmuir the Acs Journal of Surfaces&Colloids,2010,26(11):8049-8060.
[17]周逸凝,崔伟香,杨江,等.一种新型超分子复合压裂液的性能研究[J].油田化学,2015,32(2):180-184.ZHOU Yining,CUI Weixiang,YANG Jiang,et al.Performance evaluation of a novel supramolecular fracturing fluid[J].Oilfield Chemistry,2015,32(2):180-184(in Chinese).
[18]吕少一,邵自强,张振玲,等.新型含能纤维素基凝胶推进剂的流变性能研究[J].化学学报,2012,70(2):200-206.LV Shaoyi,SHAO Ziqiang,ZHANG Zhenling,et al.Studies on rheological properties of gelled propellant based on new energetic cellulose[J].Acta Chimica Sinica,2012,70(2):200-206(in Chinese).
[19]王海朋,张蓉,张晓华,等.沥青砂动态剪切蠕变特性[J].山东大学学报(工学版),2016,46(4):68-75.WANG Haipeng,ZHANG Rong,ZHANG Xiaohua,et al.Dynamic shear creep characteristics of asphalt mortar[J].Journal of Shandong University(Engineering Science),2016,46(4):68-75(in Chinese).
[20]孙全力,王爱蓉,张军,等.疏水缔合聚合物APP4流变性能实验研究[J].成都理工大学学报(自科版),2012,39(1):104-106.SUN Quanli,WANG Airong,ZHANG Jun,et al.Rheological properties of hydrophobic associative polymer APP4[J].Journal of Chengdou University of Technology(Science&Technology Edition),2012,39(1):104-106(in Chinese).
[21] GRATTONI C A,ALSHARJI H H,YANG C,et al.Rheology and permeability of crosslinked polyacrylamide gel[J].Journal of Colloid&Interface Science,2001,240(2):601-607.
[22] MACOSKO C W.Rheology,principles,measurements and applications[M].New York:Wiley-VCH,1994:119-121.