PP/柠檬酸掺杂聚苯胺抗静电材料
|
摘要
以聚丙烯(PP)为基体,聚苯胺为抗静电剂,通过开炼机混合,平板硫化机压片制备得到一系列PP/聚苯胺抗静电板材(聚苯胺含量:0,2%,4%,6%,8%)。测试PP/聚苯胺材料的体积电阻率和拉伸性能,结果发现2%的聚苯胺使得PP的电阻率降低5个数量级,从10 1 6Ω·cm下降到101 1Ω·cm,同时拉伸性能保持在使用要求范围内。
With polypropylene as the matrix and polyaniline as an antistatic agent, a series of PP/polyaniline antistatic sheets was prepared by mixing in the open mill and then sheeting on a plate vulcanizing press. By testing the volume resistivity and tensile properties of the sheets containing the polyaniline content of 0 wt%, 2 wt%, 4 wt%, 6 wt% or 8 wt%, it was found that the polyaniline content of 2 wt% made the volume resistivity of PP sheet decrease five orders of magnitude, from 10~(16) to 10~(11) Ω·cm, while maintained the tensile properties within the operating range.
With polypropylene as the matrix and polyaniline as an antistatic agent, a series of PP/polyaniline antistatic sheets was prepared by mixing in the open mill and then sheeting on a plate vulcanizing press. By testing the volume resistivity and tensile properties of the sheets containing the polyaniline content of 0 wt%, 2 wt%, 4 wt%, 6 wt% or 8 wt%, it was found that the polyaniline content of 2 wt% made the volume resistivity of PP sheet decrease five orders of magnitude, from 10~(16) to 10~(11) Ω·cm, while maintained the tensile properties within the operating range.
引文
[1]Karger-Kocis.Polypropylene:Structure,Blends and Composites[M].Springer,1995.
[2]Kawasumi M,Hasegawa N,Kato M,et al.Preparation and mechanical properties of polypropylene-clay hybrids[J].Macromolecules,1997,30(20):6333-6338.
[3]Hasegawa N,Kawasumi M,Kato M,et al.Preparation and mechanical properties of polypropylene-clay hybrids using a maleic anhydride-modi fied polypropylene oligomer[J].Journal of Applied Polymer Science,1998,67(1):87-92.
[4]Li C,Liang T,Lu W,et al.Improving the antistatic ability of polypropylene fibers by inner antistatic agent filled with carbon nanotubes[J],Composites Science and Technology,2004,64(13):2089-2096.
[5]KARGER KOCSIS J.Polypropylene:an AZreference[M].Chapman&Hall,1999,03.
[6]贺天禄,李宝芳,罗英武,等.复合抗静电剂在PP上的应用研究[J].塑料工业,2003,31(5):43-45.
[7]王雅珍,李栋,朱清梅,等.聚丙烯杭静电剂的研究现状及发展趋势[J].塑料工业,2008,36(7),11-13.
[8]Iwamiya S,Shima K,Yano H.Process for the manufacture of antistatic and biaxially oriented polypropylene film[P].US Patent:4000102,1976-12-28.
[9]Chen D,Yu X,Xu Y.Progress in Research on Electric Conductive Polymer Materials[J].Chemistry and Adhesion,2012,6:019.
[10]Hou P,Zhou K,Wang M.Research Progress in Antistatic Agents for Polymers[J].China Plastics,2011,7:007.
[11]Li Yingping,Wang Xianhong.Intrinsically Conducting Polymers and Their Composites for Anticorrosion and Antistatic Applications[J].Semiconducting Polymer Composites:Principles,Morphologies,Properti es and Applications,2013,27.
[12]Bhandari H,Singh S,Choudhary V,et al.Conducting films of poly(aniline-co-1-amino-2-naphthol-4-sulfonic acid)blended.with LDPE for its application as antistatic encapsulation material[J].Polymers for Advanced Technologies,2011,22(9):1319-1328.
[13]Tao Y,Shen Y,Yang L,et al.Hierarchical self-assembly of hexagonal single-crystal nanosheets into 3D layered superlattices with high conductivity[J].Nanoscale,2012,4(12):3729-3733.
[14]Wu G,More K L,Johnston C M,et al.High-performance electrocatalysts for oxygen reduction derived from polyaniline,iron,and cobalt[J].Science,2011,332(6028):443-447.
[15]Stejskal J,Sapurina I,Trchov a M.Polyaniline nanostructures and the role of anilineoligomers in their formation[J].Progress in Polymer Science,2010,35(12):1420-1481.
[2]Kawasumi M,Hasegawa N,Kato M,et al.Preparation and mechanical properties of polypropylene-clay hybrids[J].Macromolecules,1997,30(20):6333-6338.
[3]Hasegawa N,Kawasumi M,Kato M,et al.Preparation and mechanical properties of polypropylene-clay hybrids using a maleic anhydride-modi fied polypropylene oligomer[J].Journal of Applied Polymer Science,1998,67(1):87-92.
[4]Li C,Liang T,Lu W,et al.Improving the antistatic ability of polypropylene fibers by inner antistatic agent filled with carbon nanotubes[J],Composites Science and Technology,2004,64(13):2089-2096.
[5]KARGER KOCSIS J.Polypropylene:an AZreference[M].Chapman&Hall,1999,03.
[6]贺天禄,李宝芳,罗英武,等.复合抗静电剂在PP上的应用研究[J].塑料工业,2003,31(5):43-45.
[7]王雅珍,李栋,朱清梅,等.聚丙烯杭静电剂的研究现状及发展趋势[J].塑料工业,2008,36(7),11-13.
[8]Iwamiya S,Shima K,Yano H.Process for the manufacture of antistatic and biaxially oriented polypropylene film[P].US Patent:4000102,1976-12-28.
[9]Chen D,Yu X,Xu Y.Progress in Research on Electric Conductive Polymer Materials[J].Chemistry and Adhesion,2012,6:019.
[10]Hou P,Zhou K,Wang M.Research Progress in Antistatic Agents for Polymers[J].China Plastics,2011,7:007.
[11]Li Yingping,Wang Xianhong.Intrinsically Conducting Polymers and Their Composites for Anticorrosion and Antistatic Applications[J].Semiconducting Polymer Composites:Principles,Morphologies,Properti es and Applications,2013,27.
[12]Bhandari H,Singh S,Choudhary V,et al.Conducting films of poly(aniline-co-1-amino-2-naphthol-4-sulfonic acid)blended.with LDPE for its application as antistatic encapsulation material[J].Polymers for Advanced Technologies,2011,22(9):1319-1328.
[13]Tao Y,Shen Y,Yang L,et al.Hierarchical self-assembly of hexagonal single-crystal nanosheets into 3D layered superlattices with high conductivity[J].Nanoscale,2012,4(12):3729-3733.
[14]Wu G,More K L,Johnston C M,et al.High-performance electrocatalysts for oxygen reduction derived from polyaniline,iron,and cobalt[J].Science,2011,332(6028):443-447.
[15]Stejskal J,Sapurina I,Trchov a M.Polyaniline nanostructures and the role of anilineoligomers in their formation[J].Progress in Polymer Science,2010,35(12):1420-1481.