水玻璃/聚氨酯复合材料的研究现状及进展
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摘要
水玻璃/聚氨酯复合材料具有性能可调、形态多样、廉价和环保等优点,是一种具有广泛应用前景的新型材料。主要对前人关于反应机理和分子结构的相关研究进行了归纳总结,重点介绍近几年水玻璃/聚氨酯复合材料取得的研究进展,并对水玻璃/聚氨酯复合材料的研究方向进行了展望。
As a new material with wide application prospect,sodium silicate/polyurethane composites have quantities of advantages including adjustable properties,various appearances,low-price and environmental friendliness.Correlative researches of reaction mechanism and molecule structure were summarized,recent research progresses were introduced importantly,and the research direction of sodium silicate/polyurethane composites was prospected.
As a new material with wide application prospect,sodium silicate/polyurethane composites have quantities of advantages including adjustable properties,various appearances,low-price and environmental friendliness.Correlative researches of reaction mechanism and molecule structure were summarized,recent research progresses were introduced importantly,and the research direction of sodium silicate/polyurethane composites was prospected.
引文
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[27]刘玉亭,孙德文,冉千平,等.一种亲水型双组份灌浆堵漏材料:CN,CN104559138A[P].2015-04-29.
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[29]滕德强,杨春满,王群,等.一种煤矿加固煤岩体用双组分注浆材料:CN,CN104177052A[P].2014-12-03.
[30]杨绍斌,王阳,董伟,等.一种用于煤矿井下的聚氨酯瓦斯封孔材料及其制备方法:CN,CN103724581A[P].2014-04-16.
[31]柏广峰.制备聚氨酯泡沫塑料的组合料:CN,CN103497303A[P].2014-01-08.
[32]王洪波.浇注聚氨酯自保温墙体及其制造成型方法:CN,CN106167538A[P].2016-11-30.
[33]王颐.硬质聚氨酯隔热保温材料及制备方法和隔音隔热保温板:CN,CN105462235A[P].2016-04-06.
[2] Villa J L.Curing liquid polyurethane prepolymers:US,US3975316A[P].1976-08-17.
[3] Summers J E,Hadley J F.Sodium silicate extended polyurethane foam:US,US4057519A[P].1977-11-08.
[4] Blount D H.Process for the production of polyisocyanate organic silicate solid/cellular solid product:US,US4153764 A[P].1979-05-08.
[5] Grdes Knud D R.Soil consolidation-by injection of organomineral resin contg.isocyanate and modified water glass:DE,DE3921938[P].1991-01-17.
[6] Cornely W,Samek P,Czysollek O,et al.Organo-mineral system obtained by reaction of polyisocyanates with water glass in the presence of aminosilanes:EP,WO2002094903A1[P].2002-11-28.
[7] Grishchuk S,CastellN,Karger-Kocsis J.Hybrid resins from polyisocyanate/vinylester/water glass systems:structure and properties[J].European Polymer Journal,2007,43(4):1245-1257.
[8] Karger-Kocsis J,CastellN,Grishchuk S.Hybrid resins from polyisocyanate,vinyl ester,melamine formaldehyde and water glass:structure and properties[J].Plastics Rubber&Composites Macromolecular Engineering,2008,37(5):204-209.
[9] CastellN,Grishchuk S,Karger-Kocsis J,et al.Hybrid thermosets from polyisocyanate/water glass/emulsifier systems:effects of melamine-formaldehyde resin[J].Journal of Applied Polymer Science,2010,119(1):7-14.
[10] CastellN,Grishchuk S,Karger-Kocsis J,et al.Hybrid resins from polyisocyanate,epoxy resin and water glass:chemistry,structure and properties[J].Journal of Materials Science,2010,45(7):1734-1743.
[11]李幼荣,张明,中北里志,等.含硅聚氨酯弹性体的合成初探[J].聚氨酯工业,2000,15(4):18-20.
[12]夏赤丹,张春玲,余汉年,等.甲苯二异氰酸酯和泡花碱交联聚乙烯醇类建筑胶水的研究[J].绿色建筑,2003,19(2):36-39.
[13]夏赤丹,谌洁,余汉年,等.泡花碱和己二异氰酸酯同时对聚乙烯醇胶水改性的研究[J].中国胶粘剂,2003,12(3):26-29.
[14]秦升益,贾屹海,张雪芳.一种聚氨酯泡沫体及其制备方法:CN,CN103408923A[P].2013-11-27.
[15]唐国涛,张丽,郝德开,等.硅酸盐改性聚氨酯高分子材料及其制备方法:CN,CN102964565A[P].2013-03-13.
[16]武世凯,郭学锋,曹新鑫,等.石英砂和水玻璃改性聚氨酯复合膨胀材料[J].江苏建材,2015(1):15-18.
[17] Cheng J J,Zhou F B.Flame-retardant properties of sodium silicate/polyisocyanate organic-inorganic hybrid material[J].Journal of Thermal Analysis and Calorimetry,2016,125(2):1-6.
[18]单长兵,刘元雪.水玻璃改性聚氨酯注浆料的性能研究[J].建筑科学,2011,27(9):48-51.
[19] Mamunya Y P,Shtompel V I,Lebedev E V,et al.Structure and water sorption of polyurethane nanocomposites based on organic and inorganic components[J].European Polymer Journal,2004,40(10):2323-2331.
[20] Hong X,Dong W,Yang S,et al.Study on structure and performance of reactive silicate reinforced polyurethane composite[J].Polymer Engineering&Science,2015,55(10):2322-2327.
[21] Yang Z,Zhang W,Guan X,et al.Preparation,characterization,and properties of silicate/polyurethaneurea composites based on dipropylene glycol dibenzoate[J].Polymer Composites,2014,584(1):1818-1822.
[22]方超,夏茹,荣传新,等.原位法制备PU/水玻璃有机-无机杂化注浆材料及其性能研究[J].塑料工业,2016,44(7):7-10.
[23]王坤,庞浩,杨元龙.煤矿用聚氨酯水玻璃复合灌浆材料的研究[J].广州化学,2014,39(1):30-34.
[24]刘玄,杨政鹏,管学茂,等.聚醚基聚氨酯/水玻璃凝胶的制备及性能[J].化工新型材料,2015,43(7):224-226.
[25]贺正龙,李其峰,王军威,等.硅烷偶联剂对聚氨酯/水玻璃加固材料压缩强度的影响[C].太原:中国聚氨酯工业协会弹性体专业委员会,2015.
[26] He Z,Li Q,Wang J,et al.Effect of silane treatment on the mechanical properties of polyurethane/water glass grouting materials[J].Construction&Building Materials,2016,116:110-120.
[27]刘玉亭,孙德文,冉千平,等.一种亲水型双组份灌浆堵漏材料:CN,CN104559138A[P].2015-04-29.
[28]张虎仕,向剑飞.新型矿用化学注浆材料的研制与应用[J].煤炭科学技术,2012,40(2):36-39.
[29]滕德强,杨春满,王群,等.一种煤矿加固煤岩体用双组分注浆材料:CN,CN104177052A[P].2014-12-03.
[30]杨绍斌,王阳,董伟,等.一种用于煤矿井下的聚氨酯瓦斯封孔材料及其制备方法:CN,CN103724581A[P].2014-04-16.
[31]柏广峰.制备聚氨酯泡沫塑料的组合料:CN,CN103497303A[P].2014-01-08.
[32]王洪波.浇注聚氨酯自保温墙体及其制造成型方法:CN,CN106167538A[P].2016-11-30.
[33]王颐.硬质聚氨酯隔热保温材料及制备方法和隔音隔热保温板:CN,CN105462235A[P].2016-04-06.