石墨烯基三元复合材料在超级电容器中的应用
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摘要
电极材料是决定超级电容器性能的关键.石墨烯比表面积大、导电性好、具有良好的环境稳定性,但单独作为电极材料时面临着比容量和能量密度欠佳的困境.制备石墨烯复合材料是解决该问题的途径之一,石墨烯二元复合材料已经显示出优于石墨烯的储电性能.三元或多元复合材料在微观尺度、维度和结构上具有更丰富的设计、组合模式,相应地,其电化学性能也有更多的可能性和自身特有的发展空间.文章综述了几类石墨烯三元复合材料的研究进展,比较并探讨了每一类石墨烯三元复合物作为超级电容器电极材料的性能和优点、存在的问题、可能的解决方案及发展趋势.
Electrode material is key to the performances of supercapacitors.Graphene becomes a competitive electrode material for its large specific area,excellent conductivity and good environmental stability.However,its specific capacitance and energy density are hard to improve.The preparation of graphene composites may be one of the solutions to solve this problem.Some binary graphene complex materials show superior electrochemical energy storage properties than graphene.Ternary or multiple composite materials have richer design and combination patterns on microscopic scale,dimension and structure.Accordingly,there are more possibilities and special development space for ternary or multiple graphene-based composite materials.This paper overviews several kinds of graphene-based ternary or multiple electrode materials,discusses the performances,advantages and problems existed in each kind of material and the corresponding eliminating strategies as well as their development trends.
Electrode material is key to the performances of supercapacitors.Graphene becomes a competitive electrode material for its large specific area,excellent conductivity and good environmental stability.However,its specific capacitance and energy density are hard to improve.The preparation of graphene composites may be one of the solutions to solve this problem.Some binary graphene complex materials show superior electrochemical energy storage properties than graphene.Ternary or multiple composite materials have richer design and combination patterns on microscopic scale,dimension and structure.Accordingly,there are more possibilities and special development space for ternary or multiple graphene-based composite materials.This paper overviews several kinds of graphene-based ternary or multiple electrode materials,discusses the performances,advantages and problems existed in each kind of material and the corresponding eliminating strategies as well as their development trends.
引文
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