超交联多孔聚合物的研究进展
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摘要
超交联多孔聚合物(HCP)是一种具有高表比面积的微孔聚合物,其稳定性好,合成简便,是一种性能极为优异的吸附材料。本文从合成、分类及应用等三个方面对HCP材料的研究进展进行了综述,并总结了其发展的不足和对未来的展望。
Hyper cross-linked porous polymer(HCP) is a kind of microporous polymer with high specific surface area. It has excellent stability and is easy to synthesis. It is an excellent absorption material. In this paper, the research progress of HCP materials is discussed from the aspects of synthesis, classification and application of HCP materials.Besides, the development of HCP materials and their future prospects are summarized.
Hyper cross-linked porous polymer(HCP) is a kind of microporous polymer with high specific surface area. It has excellent stability and is easy to synthesis. It is an excellent absorption material. In this paper, the research progress of HCP materials is discussed from the aspects of synthesis, classification and application of HCP materials.Besides, the development of HCP materials and their future prospects are summarized.
引文
[1]Olajire A A.Synthesis of bare and functionalized porous adsorbent materials for CO2capture[J].Greenhouse Gases Sci Tech,2017,7(3):1-61.
[2]Tsyurupa M P,Davankov V A.The study of macronet isoporous styrene polymers by gel permeation chromatography[J].J Polym Sci Pol Chem,1980,18(4):1399-1406.
[3]谭良骁,谭必恩.超交联微孔聚合物研究进展[J].化学学报,2015,73(6):530-540.
[4]Tan L,Tan B.Hypercrosslinked porous polymer materials:design,synthesis,and applications[J].Chem Soc Rev,2017,46(11):3322-3356.
[5]Urska Sevsek,Ji ríBrus,Karel Jerabek,et al.Post polymerisation hypercrosslinking of styrene/divinylbenzene poly(HIPE)s:Creating micropores within macroporous polymer[J].Polymer,2014,55(1):410-415.
[6]Jing J,Feng T,Yan M,et al.Novel magnetic carboxyl modified hypercrosslinked resins for effective removal of typical PPCPs[J].Chemosphere,2017,185:563-573.
[7]Liu Q,Xia B,Huang J,et al.Hypercrosslinked polystyrene microspheres with ultrahigh surface area and their application in gas storage[J].Mater Chem Phys,2017,199:616-622.
[8]Zhang T,Huang J.N-vinylimidazole modified hypercross-linked resins and their adsorption toward Rhodamine B:Effect of the cross-linking degree[J].JTaiwan Inst Chem?,2017.80:293-300.
[9]Kuang W,Liu Y N,Huang J.Phenol-modified hypercross-linked resins with almost all micro/mesopores and their adsorption to aniline.[J].J Colloid Interf Sci,2017,487:31-37.
[10]Castaldo R,Avolio R,Cocca M,et al.A Versatile Synthetic Approach toward Hyper-Cross-Linked StyreneBased Polymers and Nanocomposites[J].Macromolecules,2017,50(11):4132-4143.
[11]Ghafari M,Atkinson J D.One-step hyper-cross-linking of porous styrenic polymers using dichloroalkane crosslinkers to maintain hydrophobicity[J].Polymer,2017,116:278-286.
[12]Gao H,Ding L,Bai H,et al.Microporous Organic Polymers Based on Hyper-Crosslinked Coal Tar:Preparation and Application for Gas Adsorption[J].Chemsuschem,2017,10(3):618-624.
[13]Li B,Gong R,Wang W,et al.A New Strategy to Microporous Polymers:Knitting Rigid Aromatic Building Blocks by External Cross-Linker[J].Macromolecules,2011,44(8):2410-2414.
[14]Saleh M,Han M L,Kemp K C,et al.Highly Stable CO2/N2and CO2/CH4Selectivity in Hyper-Cross-Linked Heterocyclic Porous Polymers[J].Acs Appl Mater Inter,2014,6(10):7325-7333.
[15]Wang J,Wang W Q,Hao Z,et al.A superhydrophobic hyper-cross-linked polymer synthesized at room temperature used as an efficient adsorbent for volatile organic compounds[J].Rsc Adv,2016,6:97048-97054.
[16]Jiang X,Liu Y,Liu J,et al.Hypercrosslinked conjugated microporous polymers for carbon capture and energy storage[J].New J.Chem,2017.41:3915-3919.
[17]Liang S,Wang L,Fan Y,et al.Hyper-crosslinked porous polymer based on bulk rigid monomer for gas and dye absorptions[J].Chem Res Chinese U,2017,33(3):479-483.
[18]Gonte R,Balasubramanian K.Heavy and toxic metal uptake by mesoporous hypercrosslinked SMA beads:Isotherms and kinetics[J].J Saudi Chem Soc,2016,20(S1):S579-S590.
[19]Li Q,Zhan Z,Jin S,et al.Wettable magnetic hypercrosslinked microporous nanoparticle as an efficient adsorbent for water treatment[J].Chem Eng J,2017,(326):109-116.
[20]Riegger B R,B?urer B,Mirzayeva A,et al.Systematic approach for preparation of chitosan nanoparticles via emulsion crosslinking as potential adsorbent in wastewater treatment[J].Carbohyd Polym,2017,180:46-54.
[21]Li H,Meng B,Chai S H,et al.Hyper-crosslinkedβ-cyclodextrin porous polymer:an adsorption-facilitated molecular catalyst support for transformation of watersoluble aromatic molecules[J].Chem.Sci,2016,7(2):905-909.
[22]Dou Z,Xu L,Zhi Y,et al.Metalloporphyrin-Based Hypercrosslinked Polymers Catalyze Hetero-DielsAlderReactions of Unactivated Aldehydes with Simple Dienes:A Fascinating Strategy for the Construction of Heterogeneous Catalysts[J].Chemistry,2016,22(29):9919-9922.
[23]Zhang C,Kong R,Wang X,et al.Porous carbons derived from hypercrosslinked porous polymers for gas adsorption and energy storage[J].Carbon,2017,114:608-618.
[2]Tsyurupa M P,Davankov V A.The study of macronet isoporous styrene polymers by gel permeation chromatography[J].J Polym Sci Pol Chem,1980,18(4):1399-1406.
[3]谭良骁,谭必恩.超交联微孔聚合物研究进展[J].化学学报,2015,73(6):530-540.
[4]Tan L,Tan B.Hypercrosslinked porous polymer materials:design,synthesis,and applications[J].Chem Soc Rev,2017,46(11):3322-3356.
[5]Urska Sevsek,Ji ríBrus,Karel Jerabek,et al.Post polymerisation hypercrosslinking of styrene/divinylbenzene poly(HIPE)s:Creating micropores within macroporous polymer[J].Polymer,2014,55(1):410-415.
[6]Jing J,Feng T,Yan M,et al.Novel magnetic carboxyl modified hypercrosslinked resins for effective removal of typical PPCPs[J].Chemosphere,2017,185:563-573.
[7]Liu Q,Xia B,Huang J,et al.Hypercrosslinked polystyrene microspheres with ultrahigh surface area and their application in gas storage[J].Mater Chem Phys,2017,199:616-622.
[8]Zhang T,Huang J.N-vinylimidazole modified hypercross-linked resins and their adsorption toward Rhodamine B:Effect of the cross-linking degree[J].JTaiwan Inst Chem?,2017.80:293-300.
[9]Kuang W,Liu Y N,Huang J.Phenol-modified hypercross-linked resins with almost all micro/mesopores and their adsorption to aniline.[J].J Colloid Interf Sci,2017,487:31-37.
[10]Castaldo R,Avolio R,Cocca M,et al.A Versatile Synthetic Approach toward Hyper-Cross-Linked StyreneBased Polymers and Nanocomposites[J].Macromolecules,2017,50(11):4132-4143.
[11]Ghafari M,Atkinson J D.One-step hyper-cross-linking of porous styrenic polymers using dichloroalkane crosslinkers to maintain hydrophobicity[J].Polymer,2017,116:278-286.
[12]Gao H,Ding L,Bai H,et al.Microporous Organic Polymers Based on Hyper-Crosslinked Coal Tar:Preparation and Application for Gas Adsorption[J].Chemsuschem,2017,10(3):618-624.
[13]Li B,Gong R,Wang W,et al.A New Strategy to Microporous Polymers:Knitting Rigid Aromatic Building Blocks by External Cross-Linker[J].Macromolecules,2011,44(8):2410-2414.
[14]Saleh M,Han M L,Kemp K C,et al.Highly Stable CO2/N2and CO2/CH4Selectivity in Hyper-Cross-Linked Heterocyclic Porous Polymers[J].Acs Appl Mater Inter,2014,6(10):7325-7333.
[15]Wang J,Wang W Q,Hao Z,et al.A superhydrophobic hyper-cross-linked polymer synthesized at room temperature used as an efficient adsorbent for volatile organic compounds[J].Rsc Adv,2016,6:97048-97054.
[16]Jiang X,Liu Y,Liu J,et al.Hypercrosslinked conjugated microporous polymers for carbon capture and energy storage[J].New J.Chem,2017.41:3915-3919.
[17]Liang S,Wang L,Fan Y,et al.Hyper-crosslinked porous polymer based on bulk rigid monomer for gas and dye absorptions[J].Chem Res Chinese U,2017,33(3):479-483.
[18]Gonte R,Balasubramanian K.Heavy and toxic metal uptake by mesoporous hypercrosslinked SMA beads:Isotherms and kinetics[J].J Saudi Chem Soc,2016,20(S1):S579-S590.
[19]Li Q,Zhan Z,Jin S,et al.Wettable magnetic hypercrosslinked microporous nanoparticle as an efficient adsorbent for water treatment[J].Chem Eng J,2017,(326):109-116.
[20]Riegger B R,B?urer B,Mirzayeva A,et al.Systematic approach for preparation of chitosan nanoparticles via emulsion crosslinking as potential adsorbent in wastewater treatment[J].Carbohyd Polym,2017,180:46-54.
[21]Li H,Meng B,Chai S H,et al.Hyper-crosslinkedβ-cyclodextrin porous polymer:an adsorption-facilitated molecular catalyst support for transformation of watersoluble aromatic molecules[J].Chem.Sci,2016,7(2):905-909.
[22]Dou Z,Xu L,Zhi Y,et al.Metalloporphyrin-Based Hypercrosslinked Polymers Catalyze Hetero-DielsAlderReactions of Unactivated Aldehydes with Simple Dienes:A Fascinating Strategy for the Construction of Heterogeneous Catalysts[J].Chemistry,2016,22(29):9919-9922.
[23]Zhang C,Kong R,Wang X,et al.Porous carbons derived from hypercrosslinked porous polymers for gas adsorption and energy storage[J].Carbon,2017,114:608-618.