MoV系复合多金属氧化物催化剂用于丙烷氧化制取丙烯酸(腈)的研究进展
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摘要
丙烯腈和丙烯酸在合成化工材料中十分重要,广泛应用于清洁剂、吸附剂、粘合剂和纺织品等生产领域,是重要的有机化工原料。以丙烷为原料合成丙烯酸(腈),工艺路线短,能耗低,不仅能带来巨大的经济效益,而且也更为环境友好。Mo系多金属氧化物催化剂是丙烷氧化制取丙烯酸(腈)的必须元素,本文主要就Mo系复合多金属氧化物催化剂用于制取丙烯酸(腈)的作用机理及最近的研究进展进行了叙述和讨论。包括制备工艺的改进、新型催化剂的研究、催化剂活化方式及活性相的研究以及其他方面的研究。
Acrylonitrile and acrylic acid are very important materials in the synthesis of chemical industry,widely used in cleaning agent,adsorbent,adhesive and textile production.Taking propane as raw material for the synthesis of acrylic( acrylic),short process route,low energy consumption,not only can bring huge economic benefits,but also more friendly environment.Mo-based multi metal oxide catalyst is vitally needed for oxidation from propane to acrylic acid( nitrile).In this paper,Mo-based multi metal oxide catalyst for preparing acrylic( acrylic) progress in the action mechanism and recent advances are described and discussed,including the improvement of preparation,new catalysts,catalyst activation method,research of the active phase and other aspects.
Acrylonitrile and acrylic acid are very important materials in the synthesis of chemical industry,widely used in cleaning agent,adsorbent,adhesive and textile production.Taking propane as raw material for the synthesis of acrylic( acrylic),short process route,low energy consumption,not only can bring huge economic benefits,but also more friendly environment.Mo-based multi metal oxide catalyst is vitally needed for oxidation from propane to acrylic acid( nitrile).In this paper,Mo-based multi metal oxide catalyst for preparing acrylic( acrylic) progress in the action mechanism and recent advances are described and discussed,including the improvement of preparation,new catalysts,catalyst activation method,research of the active phase and other aspects.
引文
[1]张文钲.钼基催化剂技术发展现状[J],中国钼业,2011,35(2):1-6.
[2]Kenzo Oshihara,Yasuhiro Nakamura,Mayumi Sakumaa,Wataru Uedab.Hydrothermal synthesis of novel crystalline Mo-V-M-O(M-Al,Ga,Fe)mixed oxide in the presence of triethylammonium chloride and their catalytic performance for selective ethane oxidation[J].Catalysis Today,2001,71:1-2.
[3]Botella P,Solsona B,Martinez-Arias A.Selective oxidation of propane to acrylic acid on Mo VNb Te mixed oxides catalysts prepared by hydrothermal synthesis[J].Catal.Lett.,2001,74:149-154.
[4]Guliants V V,Bhandari R.A study of the surface region of the Mo-V-Te-O catalysts for propane oxidation to acrylic acid[J].J.Phys.Chem.B,2005,109:10234-10242.
[5]Guliants V V,Bhandari R,Hughett A R.Probe molecule chemisorption-low energy lon scattering study of surface active sites present in the orthorhombic Mo-V-(Te-Nb)-O catalysts for propane(amm)oxidation[J].J.Phys.Chem.B,2006,110:6129-6140.
[6]Grasselli R K,Burrington J D,Buttrey D J.Multifunctionality of active centers in(amm)oxidation catalysts:from Bi–Mo–Oxto Mo–V–Nb–(Te2Sb)–Ox[J].Top.Catal.,2003,23:5-22.
[7]Lin M.M.Complex metal-oxide catalysts for selective oxidation of propane and derivatives:I.catalysts preparation and application in propane selective oxidation to acrylic acid[J].Appl.Catal.A,2003,250:305-318.
[8]Katou T,Vitry D,Ueda W.Structure dependency of Mo-V-O-based complex oxide catalysts in the oxidations of hydrocarbons[J].Catal.Today,2004,91-92:237-240.
[9]Grasselli R K.Structure dependency of Mo-V-O-based complex oxide catalysts in the oxidations of hydrocarbons[J].Catal.Today,2005,99:23-31.
[10]Vitry D,Morikawa Y,Dubois J L.Mo-V-Te-(Nb)-O mixed metal oxides prepared by hydrothermal synthesis for catalytic selective oxidations of propane and propene to acrylic acid[J].Appl.Catal.,A,2003,251:411-424.
[11]Ueda W,Vitry D,Katou T.Crystalline Mo-V-O based complex oxides as selective oxidation catalysts of propane[J].Catal.Today,2005,99:43-49.
[12]韩智三,伊晓东,林洪,等.Mo-V-Co-O催化剂的丙烷氧化脱氢性能研究[J].厦门大学学报,2005,44:67-70.
[13]Sam D S;Soenen V;Volta J C,Oxidation dehydrogenation of propane over V-Mg-O catalysts[J].J.Catal.,1990,123:417-435.
[14]Chen K D,Xie S B,Bell A T.Alkali effects on molybdenum oxide catalyst s for the oxidation dehydrogenation of propane[J].J.Catal.,2000,195(2):244-252.
[15]Thorsteninson E M,Wison T P,Young F G.Theoxidation dehydrogenation of ethane over catalyst s containing mixed oxides of molybdenum and vanadium[J].J.Catal.,1978,52:116-132.
[16]Burch R,Swarnakar R.Oxidative dehydrogenation of ethane on vanadium-molybdenum oxide and vanadium-ni-bi-um-molybdenum oxide catalysts[J].Appl.Catal.A:Gen.,1991,70:129-135.
[17]Ruth K,Burch R.Mo2V2Nb oxide catalyst s for the partialoxidation of ethane 2II chemical and catalytic-propertiesand structure function relationships[J].J.Catal.,1998,175:27-39.
[18]Botella P,García2González E,Nieto J M L.Mo VTe Nb O multifunctional catalysts:Correlation between constituent crystalline phases and catalytic performance.Solid State Sci[J].2005,7:507-519.
[19]Concepción P,Botella P,Nieto J ML.Catalytic and FT-IR study on the reaction pathway for oxidation of propane and propylene on V-or Mo–V-based catalysts[J].Appl.Catal.A,2004,278:45-56.
[20]谢方友.丙烷氨氧化制丙烯腈催化剂设计进展[J].工业催化,2003,11(8):38-42.
[21]Hinago H,Komada S.Ammoxidation catalyst for use in producing acrylonitrile or methacrylonitrile from propane or isobutene by ammoxidation.美国,US 6063728[P],2000-05-16.
[22]住田勇一,屠新林,新妻裕志,等,金属氧化物催化剂的制备方法.中国,CN 200480010210[P].2006-05-17.
[23]祝宝东,王鉴,董群,等.丙烷选择氧化制备丙烯酸Mo-V-Te-Nb-O催化剂[J].石油化工高等学校学报,2009,22(4):26-29.
[24]Botella P,Nieto J ML,Solsona B.The preparation,characterization,and catalytic behavior of Mo VTe Nb O catalysts prepared by hydrothermal synthesis[J].J.Catal.,2002,209:445-455.
[25]Katou T,Vitry D,Ueda W.Structure dependency of Mo-V-O-based complex oxide catalysts in the oxidations of hydrocarbons[J].Catal.Today,2004,91-92:237-240.
[26]李洪波,杨萍,刘杰,等.负载型催化剂上丙烷选择氧化制丙烯酸的研究[J].精细化工,2003,20(12):728-730.
[2]Kenzo Oshihara,Yasuhiro Nakamura,Mayumi Sakumaa,Wataru Uedab.Hydrothermal synthesis of novel crystalline Mo-V-M-O(M-Al,Ga,Fe)mixed oxide in the presence of triethylammonium chloride and their catalytic performance for selective ethane oxidation[J].Catalysis Today,2001,71:1-2.
[3]Botella P,Solsona B,Martinez-Arias A.Selective oxidation of propane to acrylic acid on Mo VNb Te mixed oxides catalysts prepared by hydrothermal synthesis[J].Catal.Lett.,2001,74:149-154.
[4]Guliants V V,Bhandari R.A study of the surface region of the Mo-V-Te-O catalysts for propane oxidation to acrylic acid[J].J.Phys.Chem.B,2005,109:10234-10242.
[5]Guliants V V,Bhandari R,Hughett A R.Probe molecule chemisorption-low energy lon scattering study of surface active sites present in the orthorhombic Mo-V-(Te-Nb)-O catalysts for propane(amm)oxidation[J].J.Phys.Chem.B,2006,110:6129-6140.
[6]Grasselli R K,Burrington J D,Buttrey D J.Multifunctionality of active centers in(amm)oxidation catalysts:from Bi–Mo–Oxto Mo–V–Nb–(Te2Sb)–Ox[J].Top.Catal.,2003,23:5-22.
[7]Lin M.M.Complex metal-oxide catalysts for selective oxidation of propane and derivatives:I.catalysts preparation and application in propane selective oxidation to acrylic acid[J].Appl.Catal.A,2003,250:305-318.
[8]Katou T,Vitry D,Ueda W.Structure dependency of Mo-V-O-based complex oxide catalysts in the oxidations of hydrocarbons[J].Catal.Today,2004,91-92:237-240.
[9]Grasselli R K.Structure dependency of Mo-V-O-based complex oxide catalysts in the oxidations of hydrocarbons[J].Catal.Today,2005,99:23-31.
[10]Vitry D,Morikawa Y,Dubois J L.Mo-V-Te-(Nb)-O mixed metal oxides prepared by hydrothermal synthesis for catalytic selective oxidations of propane and propene to acrylic acid[J].Appl.Catal.,A,2003,251:411-424.
[11]Ueda W,Vitry D,Katou T.Crystalline Mo-V-O based complex oxides as selective oxidation catalysts of propane[J].Catal.Today,2005,99:43-49.
[12]韩智三,伊晓东,林洪,等.Mo-V-Co-O催化剂的丙烷氧化脱氢性能研究[J].厦门大学学报,2005,44:67-70.
[13]Sam D S;Soenen V;Volta J C,Oxidation dehydrogenation of propane over V-Mg-O catalysts[J].J.Catal.,1990,123:417-435.
[14]Chen K D,Xie S B,Bell A T.Alkali effects on molybdenum oxide catalyst s for the oxidation dehydrogenation of propane[J].J.Catal.,2000,195(2):244-252.
[15]Thorsteninson E M,Wison T P,Young F G.Theoxidation dehydrogenation of ethane over catalyst s containing mixed oxides of molybdenum and vanadium[J].J.Catal.,1978,52:116-132.
[16]Burch R,Swarnakar R.Oxidative dehydrogenation of ethane on vanadium-molybdenum oxide and vanadium-ni-bi-um-molybdenum oxide catalysts[J].Appl.Catal.A:Gen.,1991,70:129-135.
[17]Ruth K,Burch R.Mo2V2Nb oxide catalyst s for the partialoxidation of ethane 2II chemical and catalytic-propertiesand structure function relationships[J].J.Catal.,1998,175:27-39.
[18]Botella P,García2González E,Nieto J M L.Mo VTe Nb O multifunctional catalysts:Correlation between constituent crystalline phases and catalytic performance.Solid State Sci[J].2005,7:507-519.
[19]Concepción P,Botella P,Nieto J ML.Catalytic and FT-IR study on the reaction pathway for oxidation of propane and propylene on V-or Mo–V-based catalysts[J].Appl.Catal.A,2004,278:45-56.
[20]谢方友.丙烷氨氧化制丙烯腈催化剂设计进展[J].工业催化,2003,11(8):38-42.
[21]Hinago H,Komada S.Ammoxidation catalyst for use in producing acrylonitrile or methacrylonitrile from propane or isobutene by ammoxidation.美国,US 6063728[P],2000-05-16.
[22]住田勇一,屠新林,新妻裕志,等,金属氧化物催化剂的制备方法.中国,CN 200480010210[P].2006-05-17.
[23]祝宝东,王鉴,董群,等.丙烷选择氧化制备丙烯酸Mo-V-Te-Nb-O催化剂[J].石油化工高等学校学报,2009,22(4):26-29.
[24]Botella P,Nieto J ML,Solsona B.The preparation,characterization,and catalytic behavior of Mo VTe Nb O catalysts prepared by hydrothermal synthesis[J].J.Catal.,2002,209:445-455.
[25]Katou T,Vitry D,Ueda W.Structure dependency of Mo-V-O-based complex oxide catalysts in the oxidations of hydrocarbons[J].Catal.Today,2004,91-92:237-240.
[26]李洪波,杨萍,刘杰,等.负载型催化剂上丙烷选择氧化制丙烯酸的研究[J].精细化工,2003,20(12):728-730.