人工合成类天然产物防污剂的研究进展
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摘要
综述了人工合成类天然产物防污剂,主要包括异噻唑啉酮类、辣素类、吲哚类、呋喃类、树脂类防、吡啶类和二硫代类的研究进展。重点论述了以天然产物为先导化合物,通过合成手段研制防污剂的目前现状。
The marine biofouling caused serious adverse impact on oceanographic equipment or instruments. Although toxic antifouling agents, such as tributyltin(TBT) are effective for removing or reducing biofouling, they have been prohibited due to environmental concerns. Thus, it is necessary to develop environment- friendly antifouling agents. Natural substances used as marine antifouling agents are a hot topic recently, which may possess many advantages, such as nontoxic, efficient, rapid degradable and environment-friendly. The main problem of the development of natural antifouling agent is the shortage of natural substances actually. However such natural substances can be obtained by large-scale chemical synthesis, therewith, which may create a huge potential to meet the need of antifouling agents. In this review, we summarized the recent research progress of synthetic substances of marine antifouling agents, including isothiazolinone derivatives, capsaicin derivatives, indoles derivatives, furan derivatives, resinous, derivatives, pyridine derivatives, and dithio derivatives. Finally, taking natural substances as reference, the further development trend of antifoulantsvia synthesis is proposed in detail.
The marine biofouling caused serious adverse impact on oceanographic equipment or instruments. Although toxic antifouling agents, such as tributyltin(TBT) are effective for removing or reducing biofouling, they have been prohibited due to environmental concerns. Thus, it is necessary to develop environment- friendly antifouling agents. Natural substances used as marine antifouling agents are a hot topic recently, which may possess many advantages, such as nontoxic, efficient, rapid degradable and environment-friendly. The main problem of the development of natural antifouling agent is the shortage of natural substances actually. However such natural substances can be obtained by large-scale chemical synthesis, therewith, which may create a huge potential to meet the need of antifouling agents. In this review, we summarized the recent research progress of synthetic substances of marine antifouling agents, including isothiazolinone derivatives, capsaicin derivatives, indoles derivatives, furan derivatives, resinous, derivatives, pyridine derivatives, and dithio derivatives. Finally, taking natural substances as reference, the further development trend of antifoulantsvia synthesis is proposed in detail.
引文
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