天然高分子絮凝剂处理印染废水研究进展
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摘要
综述了壳聚糖、淀粉、纤维素、木质素等天然高分子絮凝剂的改性及其在印染废水处理中的应用。与纯天然高分子絮凝剂相比,改性天然高分子絮凝剂对印染废水的絮凝效果得到明显提升。另外,将天然高分子絮凝剂与无机小分子絮凝剂、无机高分子絮凝剂或有机人工合成高分子絮凝剂复配,制备出相应的复合型高分子絮凝剂,也在处理印染废水时表现出了较为优异的性能。
The modification of natural polymer flocculants, such as chitosan, starch, cellulose and lignin,as well as their application in treatment of printing and dyeing wastewater were reviewed. Compared with pure natural polymer flocculants, the modified natural polymer flocculants showed improved flocculation performances in treatment of printing and dyeing wastewater. In addition, the compound flocculants, which were prepared by mixing of natural polymer flocculants with inorganic small molecule flocculants, inorganic polymer flocculants or organic synthetic polymer flocculants, also showed excellent performance in treatment of printing and dyeing wastewater.
The modification of natural polymer flocculants, such as chitosan, starch, cellulose and lignin,as well as their application in treatment of printing and dyeing wastewater were reviewed. Compared with pure natural polymer flocculants, the modified natural polymer flocculants showed improved flocculation performances in treatment of printing and dyeing wastewater. In addition, the compound flocculants, which were prepared by mixing of natural polymer flocculants with inorganic small molecule flocculants, inorganic polymer flocculants or organic synthetic polymer flocculants, also showed excellent performance in treatment of printing and dyeing wastewater.
引文
[1]李凤霄,王彦博,杜夕铭,等.絮凝法处理印染废水的研究进展[J].中国科技纵横,2015(20):2.
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[4]刘路.纺织印染废水处理技术研究现状及进展[J].上海工程技术大学学报,2017,31(2):174-177.
[5]ZHU X,NI J,LAI P.Advanced treatment of biologically pretreated cok-ing wastewater by electrochemical oxidation using boron-doped dia-mond electrodes[J].Water Research,2009,43(17):4 347-4 355.
[6]MARTíNEZ-HUITLE C A,BRILLAS E.Decontamination of wastewa-ters containing synthetic organic dyes by electrochemical methods:ageneral review[J].Applied Catalysis B Environmental,2009,87(3-4):105-145.
[7]FORGACS E,CSERHáTI T,OROS G.Removal of synthetic dyes fromwastewaters:a review[J].Environment International,2004,30(7):953-971.
[8]VERMA A K,DASH R R,BHUNIA P.A review on chemical coagula-tion/flocculation technologies for removal of colour from textile waste-waters[J].Journal of Environmental Management,2012,93(1):154-168.
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[14]彭亚娟,王晓雪.羧甲基壳聚糖絮凝剂的制备及对印染废水的处理研究[J].资源节约与环保,2016(3):75.
[15]范大和,蔡照胜.两性壳聚糖复合絮凝剂对印染废水的絮凝性能研究[J].工业水处理,2008,28(9):47-50.
[16]赖悦腾,梁亮,袁毅桦,等.壳聚糖改性缩聚物的制备及吸附性能研究[J].广州化工,2011,39(22):58-60.
[17]谢思思,姚春才,王锦涛.微波辐射下改性壳聚糖的制备及其絮凝性能[J].化工环保,2010,30(6):534-538.
[18]李燕卿,刘金彦,李雪.H2O2存在下壳聚糖处理印染废水的实验研究[J].工业水处理,2014,34(10):65-68.
[19]岳思羽,王圆广,赵丹,等.复合型絮凝剂PSAFC-CTS的制备及其对印染废水处理效果的影响[J].湖北农业科学,2014,53(22):5 391-5 394.
[20]王圆广,陈晓.聚合氯化铝铁与壳聚糖复合絮凝剂的制备及其对印染废水的处理[J].安徽化工,2014(6):46-47.
[21]徐华,王金龙,周桃玉,等.印染硫化黑废水的铝盐壳聚糖絮凝试验[J].工业水处理,2016,36(6):54-57.
[22]尚玉婷,陈莉.壳聚糖-Ti O2复合絮凝剂的制备及其在印染废水处理中的应用[J].天津工业大学学报,2013,32(3):56-60.
[23]陈忻,袁毅桦,潘坚定,等.羧甲基壳聚糖和稀土联合使用处理印染废水[J].环境科学与技术,2010,33(1):154-158.
[24]张倩倩,邱业先,朱艳霞,等.阳离子淀粉絮凝剂的制备及对印染废水的处理[J].苏州科技学院学报:自然科学版,2011,28(3):45-49.
[25]胡巧开,夏晚良.改性红薯淀粉的制备及其对印染废水的脱色处理研究[J].印染助剂,2008,25(2):31-33.
[26]马冰洁,李艳平,鄢冬茂,等.阳离子淀粉絮凝剂制备及脱色性能研究[J].中国粮油学报,2009,24(7):113-115.
[27]张淑娟,林亲铁,张旭兰.淀粉基复合絮凝剂的制备及其絮凝效果研究[J].安徽农业科学,2013,41(6):2 613-2 614.
[28]壮亚峰,姚国胜,李杰励.氢氧化镁-淀粉复合絮凝剂对印染废水的脱色研究[J].化学与生物工程,2007,24(2):29-31.
[29]张倩倩.环境友好型改性淀粉复合絮凝剂的制备和应用初步研究[D].苏州:苏州科技学院,2011.
[30]陈纯馨,陈忻,袁毅桦,等.变性淀粉在印染废水处理中的应用研究[J].食品科学,2007,28(10):245-247.
[31]曾媛,蒋文举,金燕,等.无机-有机复合絮凝剂PACSAM的制备及其脱色性能[J].化工环保,2007,27(3):263-267.
[32]马永梅,胡涛.经济型阳离子淀粉絮凝剂的制备及其对印染废水的处理效果[J].化工环保,2007,27(5):452-455.
[33]甘亮.纤维素季铵盐处理染料废水的试验研究[D].武汉:武汉科技大学,2014.
[34]夏旭林,古绪鹏.季胺盐改性木质素及其絮凝性能试验[J].广州化工,2010,38(4):87-89.
[2]张宇峰,滕洁,张雪英,等.印染废水处理技术的研究进展[J].工业水处理,2003,23(4):23-27.
[3]陈玉峰.物理法处理染料废水的研究进展[J].煤炭与化工,2013(3):72-74.
[4]刘路.纺织印染废水处理技术研究现状及进展[J].上海工程技术大学学报,2017,31(2):174-177.
[5]ZHU X,NI J,LAI P.Advanced treatment of biologically pretreated cok-ing wastewater by electrochemical oxidation using boron-doped dia-mond electrodes[J].Water Research,2009,43(17):4 347-4 355.
[6]MARTíNEZ-HUITLE C A,BRILLAS E.Decontamination of wastewa-ters containing synthetic organic dyes by electrochemical methods:ageneral review[J].Applied Catalysis B Environmental,2009,87(3-4):105-145.
[7]FORGACS E,CSERHáTI T,OROS G.Removal of synthetic dyes fromwastewaters:a review[J].Environment International,2004,30(7):953-971.
[8]VERMA A K,DASH R R,BHUNIA P.A review on chemical coagula-tion/flocculation technologies for removal of colour from textile waste-waters[J].Journal of Environmental Management,2012,93(1):154-168.
[9]孙圆媛.新型无机高分子絮凝剂处理印染废水的研究[D].西安:西北大学,2012.
[10]孙圆媛,赵彬侠,党丽萍.新型无机高分子絮凝剂处理H-酸印染废水[J].化工进展,2011(s1):356-358.
[11]SAKKAYAWONG N,THIRAVETYAN P,NAKBANPOTE W.Adsor-ption mechanism of synthetic reactive dye wastewater by chitosan[J].Journal of Colloid&Interface Science,2005,286(1):36-42.
[12]初庆娣,朱小梅,王巧敏,等.微波辅助改性壳聚糖的制备及其絮凝性能[J].环境工程学报,2016,10(12):6 935-6 939.
[13]胡巧开.改性壳聚糖的制备及其对印染废水的脱色处理研究[J].印染助剂,2008,25(3):31-33.
[14]彭亚娟,王晓雪.羧甲基壳聚糖絮凝剂的制备及对印染废水的处理研究[J].资源节约与环保,2016(3):75.
[15]范大和,蔡照胜.两性壳聚糖复合絮凝剂对印染废水的絮凝性能研究[J].工业水处理,2008,28(9):47-50.
[16]赖悦腾,梁亮,袁毅桦,等.壳聚糖改性缩聚物的制备及吸附性能研究[J].广州化工,2011,39(22):58-60.
[17]谢思思,姚春才,王锦涛.微波辐射下改性壳聚糖的制备及其絮凝性能[J].化工环保,2010,30(6):534-538.
[18]李燕卿,刘金彦,李雪.H2O2存在下壳聚糖处理印染废水的实验研究[J].工业水处理,2014,34(10):65-68.
[19]岳思羽,王圆广,赵丹,等.复合型絮凝剂PSAFC-CTS的制备及其对印染废水处理效果的影响[J].湖北农业科学,2014,53(22):5 391-5 394.
[20]王圆广,陈晓.聚合氯化铝铁与壳聚糖复合絮凝剂的制备及其对印染废水的处理[J].安徽化工,2014(6):46-47.
[21]徐华,王金龙,周桃玉,等.印染硫化黑废水的铝盐壳聚糖絮凝试验[J].工业水处理,2016,36(6):54-57.
[22]尚玉婷,陈莉.壳聚糖-Ti O2复合絮凝剂的制备及其在印染废水处理中的应用[J].天津工业大学学报,2013,32(3):56-60.
[23]陈忻,袁毅桦,潘坚定,等.羧甲基壳聚糖和稀土联合使用处理印染废水[J].环境科学与技术,2010,33(1):154-158.
[24]张倩倩,邱业先,朱艳霞,等.阳离子淀粉絮凝剂的制备及对印染废水的处理[J].苏州科技学院学报:自然科学版,2011,28(3):45-49.
[25]胡巧开,夏晚良.改性红薯淀粉的制备及其对印染废水的脱色处理研究[J].印染助剂,2008,25(2):31-33.
[26]马冰洁,李艳平,鄢冬茂,等.阳离子淀粉絮凝剂制备及脱色性能研究[J].中国粮油学报,2009,24(7):113-115.
[27]张淑娟,林亲铁,张旭兰.淀粉基复合絮凝剂的制备及其絮凝效果研究[J].安徽农业科学,2013,41(6):2 613-2 614.
[28]壮亚峰,姚国胜,李杰励.氢氧化镁-淀粉复合絮凝剂对印染废水的脱色研究[J].化学与生物工程,2007,24(2):29-31.
[29]张倩倩.环境友好型改性淀粉复合絮凝剂的制备和应用初步研究[D].苏州:苏州科技学院,2011.
[30]陈纯馨,陈忻,袁毅桦,等.变性淀粉在印染废水处理中的应用研究[J].食品科学,2007,28(10):245-247.
[31]曾媛,蒋文举,金燕,等.无机-有机复合絮凝剂PACSAM的制备及其脱色性能[J].化工环保,2007,27(3):263-267.
[32]马永梅,胡涛.经济型阳离子淀粉絮凝剂的制备及其对印染废水的处理效果[J].化工环保,2007,27(5):452-455.
[33]甘亮.纤维素季铵盐处理染料废水的试验研究[D].武汉:武汉科技大学,2014.
[34]夏旭林,古绪鹏.季胺盐改性木质素及其絮凝性能试验[J].广州化工,2010,38(4):87-89.