高滑石型难选钼矿选矿进展
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摘要
高滑石型钼矿原矿钼品位高,开发价值大,但选矿难度也大。针对高滑石型难选钼矿高效选矿的难题,介绍了高滑石型钼矿的特点,从工艺、药剂和设备等角度阐述了高滑石型钼矿的选矿进展并进行了分析。对于钼与滑石分离的难题,建议从高效抑制剂角度和选矿流程两个方面进行攻关,实现该类资源的高效开发利用。
Molybdenum grade is high in high talcum type molybdenum ore,have high development value,but it is difficult to beneficiation.Introduce the dressing characteristics of high talc molybdenum ore,and expound the beneficiation progress of high talc molybdenum ore from the aspects of technology,reagents and equipment.For the problem of separation of molybdenum and talc,it is suggested to deal the problem from two aspects of efficient inhibitors and ore processing process,so as to realize the efficient development and utilization of such resources.
Molybdenum grade is high in high talcum type molybdenum ore,have high development value,but it is difficult to beneficiation.Introduce the dressing characteristics of high talc molybdenum ore,and expound the beneficiation progress of high talc molybdenum ore from the aspects of technology,reagents and equipment.For the problem of separation of molybdenum and talc,it is suggested to deal the problem from two aspects of efficient inhibitors and ore processing process,so as to realize the efficient development and utilization of such resources.
引文
[1] 马晶,李枢本,张文钲.钼矿选矿[M].北京:冶金工业出版社,2008.
[2] 向铁根.钼冶金[M].长沙:中南大学出版社,2005.
[3] LASKOWSID J S.Angegaton of inherenhy hydrophobic solids using hudrophobic agglomerants and flocculants[J].Polym Miner Process,2000(1):293-308.
[4] CASTRO S,LOPEZ-VALSIVIESO A,LASKOWSKI J S.Review of the flotation of molybdenite.PartⅠ:Surface properties and flotation and flotability[J].International Journal of Mineral Processing,2016,148(8):48-58.
[5] 汤雁斌.国内外钼矿选矿技术进步与创新[J].铜业工程,2010(1):29-33.
[6] 赵平,孙春辉,郭珍旭.滑石辉钼矿分离选矿工艺研究及设备选择[J].中国矿业,2016,25(2):134-138,155.
[7] 邱章伟,欧乐明,石晴,等.某高滑石型铜硫矿选矿工艺[J].有色金属工程,2018,8(4):73-78.
[8] 赵玉卿,黄秉雄,刘磊,等.蛇纹石、绿泥石、滑石的可浮性及抑制方法综述[J].矿产综合利用,2018(2):7-11.
[9] 孙大勇,祁忠旭,董宗良,等.承德某难选铜矿250 t/d选矿工业试验研究[J].矿业研究与开发,2018,38(9):63-66.
[10] 张小云,黎铉海.辉钼矿与滑石的分选试验[J].湖南有色金属,1997(1):15-16.
[11] 李瑞生.钼矿预选脱除滑石[J].中国钼业,1998(6):45-47.
[12] 董燧珍.含滑石钼矿的选别工艺试验研究[J].矿产综合利用,2006(1):7-12.
[13] 蒋玉珍.从含铜多金属矿中综合回收滑石的试验研究[J].矿产保护与利用,1999(6):41-43.
[14] 高滑石、细粒难选钼矿选矿新技术取得进展[J].矿产保护与利用,2010(2):19.
[15] 王振,钱云楼,徐龙华,等.某含滑石铜钼混合精矿的分离[J].矿冶工程,2015,35(1):51-53,60.
[16] ZIMIN A V, ARUSTAMYAM M A, NAGAEVA S P,et al. Method of flotation enrichment of sulphide ores,involves grinding ore,open-cycle bulk flotation of two and more metals in alkaline medium produced by line and re-cleaning of reground crude concentrate:RU2403981-C1[P].2010-11-20.
[17] 俞国庆,姚云芳.肯尼柯特犹他铜矿铜-钼选矿厂[J].中国钼业,1998(4):95-98.
[18] 张文钲.钼选矿学技术发展现状与展望[J].中国钼业,2011,35(1):1-6.
[19] 欧乐明,齐超.非极性表面矿物滑石与辉钼矿浮选分离中的多糖抑制[J].金属矿山,2015(5):85-89.
[20] 张其东.辉钼矿与滑石可浮性差异调控基础研究[D].沈阳:东北大学,2016.
[21] 罗彤彤,孙立田,陈雁南,等.植物胶型抑制剂选矿试验探索研究[J].有色金属:选矿部分,2018(5):101-104.
[22] BRAGA P FA,CHAVES A P,LUZ A B, et al.The use of dextrin in purification by flotation of molybdenite concentrates[J].International Journal of Mineral Processing, 2014,127(10):23-27.
[23] KELEBEK S, YORUK S,SMITH W G.Wetting behavior of molybdenite and talc in lignosulphonate/MIBC solutions and their separation by flotation[J].Separation on Science & Technology,2006,36(2): 145-157.
[24] KUHN M C. Mthods for the recovery of molybdenum, US200800667112A1[P].2008-9-10.
[25] 潘高产.羧甲基纤维素和古尔胶在硫化矿和滑石浮选分离中的作用进行了研究[D].长沙:中南大学,2011.
[26] 齐超,欧乐明,邱章伟,等.不同种CMC对两种非极性矿物表面的抑制研究[J].有色金属科学与工程,2015,6(6):88-94.
[27] 张其东,袁致涛,刘炯天,等.葡聚糖对辉钼矿与滑石浮选分离的影响[J].中国有色金属学报,2016,26(4):884-890.
[28] 胡瑞彪,黄光洪,陈典助,等.有色金属大型高效选矿设备的发展与应用[J].湖南有色金属,2011,27(1):52-56,63.
[29] 刘辉彦.大型立磨机研发及其在金属矿山选矿中的应用[J].世界有色金属,2017(10):280-282.
[30] 印万忠,吴尧,韩跃新,等.X射线辐射分选原理及应用[J].中国矿业,2011,20(12):88-92.
[31] 刘明宝,印万忠,韩跃新,等.X射线辐射分选机对含钼和含镍低品位矿石的预选试验研究[J].矿冶,2012,21(4):26-29.
[32] 彭团儿,郭珍旭,张艳娇.斜板分级机在某难选滑石型钼矿的应用研究[J].矿产保护与利用,2013(3):31-34.
[2] 向铁根.钼冶金[M].长沙:中南大学出版社,2005.
[3] LASKOWSID J S.Angegaton of inherenhy hydrophobic solids using hudrophobic agglomerants and flocculants[J].Polym Miner Process,2000(1):293-308.
[4] CASTRO S,LOPEZ-VALSIVIESO A,LASKOWSKI J S.Review of the flotation of molybdenite.PartⅠ:Surface properties and flotation and flotability[J].International Journal of Mineral Processing,2016,148(8):48-58.
[5] 汤雁斌.国内外钼矿选矿技术进步与创新[J].铜业工程,2010(1):29-33.
[6] 赵平,孙春辉,郭珍旭.滑石辉钼矿分离选矿工艺研究及设备选择[J].中国矿业,2016,25(2):134-138,155.
[7] 邱章伟,欧乐明,石晴,等.某高滑石型铜硫矿选矿工艺[J].有色金属工程,2018,8(4):73-78.
[8] 赵玉卿,黄秉雄,刘磊,等.蛇纹石、绿泥石、滑石的可浮性及抑制方法综述[J].矿产综合利用,2018(2):7-11.
[9] 孙大勇,祁忠旭,董宗良,等.承德某难选铜矿250 t/d选矿工业试验研究[J].矿业研究与开发,2018,38(9):63-66.
[10] 张小云,黎铉海.辉钼矿与滑石的分选试验[J].湖南有色金属,1997(1):15-16.
[11] 李瑞生.钼矿预选脱除滑石[J].中国钼业,1998(6):45-47.
[12] 董燧珍.含滑石钼矿的选别工艺试验研究[J].矿产综合利用,2006(1):7-12.
[13] 蒋玉珍.从含铜多金属矿中综合回收滑石的试验研究[J].矿产保护与利用,1999(6):41-43.
[14] 高滑石、细粒难选钼矿选矿新技术取得进展[J].矿产保护与利用,2010(2):19.
[15] 王振,钱云楼,徐龙华,等.某含滑石铜钼混合精矿的分离[J].矿冶工程,2015,35(1):51-53,60.
[16] ZIMIN A V, ARUSTAMYAM M A, NAGAEVA S P,et al. Method of flotation enrichment of sulphide ores,involves grinding ore,open-cycle bulk flotation of two and more metals in alkaline medium produced by line and re-cleaning of reground crude concentrate:RU2403981-C1[P].2010-11-20.
[17] 俞国庆,姚云芳.肯尼柯特犹他铜矿铜-钼选矿厂[J].中国钼业,1998(4):95-98.
[18] 张文钲.钼选矿学技术发展现状与展望[J].中国钼业,2011,35(1):1-6.
[19] 欧乐明,齐超.非极性表面矿物滑石与辉钼矿浮选分离中的多糖抑制[J].金属矿山,2015(5):85-89.
[20] 张其东.辉钼矿与滑石可浮性差异调控基础研究[D].沈阳:东北大学,2016.
[21] 罗彤彤,孙立田,陈雁南,等.植物胶型抑制剂选矿试验探索研究[J].有色金属:选矿部分,2018(5):101-104.
[22] BRAGA P FA,CHAVES A P,LUZ A B, et al.The use of dextrin in purification by flotation of molybdenite concentrates[J].International Journal of Mineral Processing, 2014,127(10):23-27.
[23] KELEBEK S, YORUK S,SMITH W G.Wetting behavior of molybdenite and talc in lignosulphonate/MIBC solutions and their separation by flotation[J].Separation on Science & Technology,2006,36(2): 145-157.
[24] KUHN M C. Mthods for the recovery of molybdenum, US200800667112A1[P].2008-9-10.
[25] 潘高产.羧甲基纤维素和古尔胶在硫化矿和滑石浮选分离中的作用进行了研究[D].长沙:中南大学,2011.
[26] 齐超,欧乐明,邱章伟,等.不同种CMC对两种非极性矿物表面的抑制研究[J].有色金属科学与工程,2015,6(6):88-94.
[27] 张其东,袁致涛,刘炯天,等.葡聚糖对辉钼矿与滑石浮选分离的影响[J].中国有色金属学报,2016,26(4):884-890.
[28] 胡瑞彪,黄光洪,陈典助,等.有色金属大型高效选矿设备的发展与应用[J].湖南有色金属,2011,27(1):52-56,63.
[29] 刘辉彦.大型立磨机研发及其在金属矿山选矿中的应用[J].世界有色金属,2017(10):280-282.
[30] 印万忠,吴尧,韩跃新,等.X射线辐射分选原理及应用[J].中国矿业,2011,20(12):88-92.
[31] 刘明宝,印万忠,韩跃新,等.X射线辐射分选机对含钼和含镍低品位矿石的预选试验研究[J].矿冶,2012,21(4):26-29.
[32] 彭团儿,郭珍旭,张艳娇.斜板分级机在某难选滑石型钼矿的应用研究[J].矿产保护与利用,2013(3):31-34.