金纳米的制备及其应用研究进展
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摘要
介绍了金纳米的光学性质及制备的研究进展,总结了空心金纳米球、金纳米棒及金纳米簇在食品检测、催化、有毒有害物质的检测及生物医学领域的显著应用。并对今后的研究重点进行了展望。
The paper gives a brief review of optical properties and preparation of gold nanomateirals.The applications of hollow gold nanospheres,gold nanorods and gold nanoclusters are summarized,including food detection,catalytic,detection of toxic and harmful substances and biomedicine.The research priorities in the future are also prospected.
The paper gives a brief review of optical properties and preparation of gold nanomateirals.The applications of hollow gold nanospheres,gold nanorods and gold nanoclusters are summarized,including food detection,catalytic,detection of toxic and harmful substances and biomedicine.The research priorities in the future are also prospected.
引文
[1]Chen G Z,Wang J,Ren H J,et al.Research Progress of Gold Nanorods Application[J].Appl Chem Ind,2014,43(1):159-161(in Chinese).(陈国珍,王军,任海晶,等.关于金纳米棒应用的研究进展[J].应用化工,2014,43(1):159-161.)
[2]Wang G J,Yao G W,Ma S Y,et al.Effects of Different Reductants on the Synthesis of Au Nanoparticles[J].Chem World,2011,52(3):129-132(in Chinese).(王国军,姚瑰玮,马士禹,等.不同还原剂对金纳米颗粒合成的影响[J].化学世界,2011,52(3):129-132.)
[3]Wang Q Y.Preparation of Tunable Gold Nanostructures by APTES[D].Jilin:Jilin University,2017(in Chinese).(王琪瑶.APTES调控金纳米结构的制备[D].吉林:吉林大学,2017.)
[4]Wang Y,Jiao T F,Xie D Y,et al.Research Progress on Preparation and Application of Gold Nanoparticles[J].Chin J Inorg Anal Chem,2012,2(4):15-21(in Chinese).(王莹,焦体峰,谢丹阳,等.金纳米颗粒制备及应用研究进展[J].中国无机分析化学,2012,2(4):15-21.)
[5]Li N N.Synthesis,Coating and Catalytic Property of Gold Nanoparticles[D].Harbin:Harbin Institute of Technology,2015(in Chinese).(李宁宁.金纳米粒子的合成与包覆以及催化性能研究[D].哈尔滨:哈尔滨工业大学,2015.)
[6]Li J X,Liu R D,Zhang Y C,et al.Application of DNA Functionalized Gold Nanoparticles[J].Sci Chin Chem,2015,45(11):1 112-1 144(in Chinese).(李久兴,刘如迪,张益聪,等.DNA功能化金纳米及其应用[J].中国科学:化学,2015,45(11):1 112-1 144.)
[7]Ma Q C,Wang Y L,Song W L,et al.Modulation of the Optics Properties of Au Nanostrcture[J].Chem World,2017,58(8):468-472(in Chinese).(马青翠,王亚兰,宋雯莉,等.金纳米结构表面形貌对吸收-发光特性调控研究[J].化学世界,2017,58(8):468-472.)
[8]Liu Y X,Xiao S M,Yu Y,et al.Colorimetric Assay of Trace Amitrole in Water with p-Aminobenzamidemodified Gold Nanoparticles[J].J Nachang Univ(Nat Sci),2017,41(4):330-335(in Chinese).(刘英霞,肖石妹,余勇,等.基于对氨基甲酰胺修饰的金纳米比色法测定水样中痕量杀草强[J].南昌大学学报(理科版),2017,41(4):330-335.)
[9]Su X Y,Chen X Y,Sun C B,et al.Preparation of Au Nanoparticles with Different Morphologies and Study of Their Property as Surface Enhanced Raman Scattering Substrates[J].Spectrosc Spectral Anal,2017,37(1):7-12(in Chinese).(苏晓越,陈小燕,孙成彬,等.不同形貌金纳米粒子的制备及其表面增强拉曼散射效应的研究[J].光谱学与光谱分析,2017,37(1):7-12.)
[10]Yang S,Ji X H,Yang W S.Mechanism in the Preparation of Gold Nanoflowers by Ascorbic Acid Reduction[J].Chem J Chin Univ,2016,37(12):2 125-2 131(in Chinese).(杨爽,纪小会,杨文胜.抗坏血酸还原法制备金纳米花的机理[J].高等学校化学学报,2016,37(12):2 125-2 131.)
[11]Lee K C,Chen W J,Chen Y C.Using Dextranencapsulated Gold Nanoparticles as Insulin Carriers to Prolong Insulin Activitu[J].Nanomedicine,2017,12(15):1 823-1 834.
[12]Yang Y M,Dong Q M,Liang P,et al.Preparation of Flower-like Gold Nanoparticle with Controlled Morphology and Size Through Step by Step Seeding Approach[J].J Instrum Anal,2014,33(2):222-226(in Chinese).(杨艳敏,董前民,梁培,等.步步种子法制备形态及尺寸可控的花状金纳米粒子[J].分析测试学报,2014,33(2):222-226.)
[13]Dang J,Ai Y Y,Zheng X W.the Synthesis of Au/SiO2 Nanocomposites Using Chitosan/PEI Composite Nanohydrogel as Template[J].J Shangxi Norm Univ(Nat Sci Ed),2014,42(1):56-61(in Chinese).(党婕,艾媛媛,郑行望.壳聚糖/PEI凝胶模板法制备Au/SiO2复合纳米粒子[J].陕西师范大学学报(自然科学版),2014,42(1):56-61.)
[14]Shi J Q,Lu J W,Ma H F.Research Progress on the Preparation and Application of Au Nanostar[J].JSynth Cryst,2016,45(10):2 519-2 524(in Chinese).(史佳卿,陆嘉文,马鸿飞.星状金纳米晶的制备及应用研究进展[J].人工晶体学报,2016,45(10):2 519-2 524.)
[15]Liu K,Chen T,He S Y,et al.Observation and I-dentification of an Atomic Oxygen Structure on Catalytic Gold Nanoparticles[J].Angewa Chem Int Ed,2017,56(42):12 952-12 957.
[16]Negru B,Mcanally M O,Mayhew H E,et al.Fabrication of Gold Nanosphere Oligomers for Surface-enhanced Femtosecond Stimulated Raman Spectroscopy[J].J Phy Chem C,2017,121(48):27 004-727 008.
[17]Pu Y C,SONG F,Zhang W C,et al.Size-tunable Synthesis of Hollow Gold Nanospheres Through Control of Reaction Temperature[J].Adv Sci News,2017,34(8):1 600 255-1 600 263.
[18]Chen L,Lu L L,Wang S F,et al.Valence States Modulation Strategy for Picomole Level Assay of Hg2+in Drinking and Environmental Water by Directional Self-assembly of Gold Nanorods[J].ACSSens,2017,2(6):781-788.
[19]Xu L P,Nao A M,Han B L,et al.Determination of Vitamin C by Gold Nanorods Colorimetric Probe[J].J Food Saf Qual,2016,7(5):1 991-1 995(in Chinese).(徐丽萍,瑙阿敏,韩博林,等.金纳米棒比色探针法测定维生素C的初步研究[J].食品安全质量检测学报,2016,7(5):1 991-1 995.)
[20]Xu C Y,Liu L,Fu Y Y,et al.Preparation and Characterization of a Rationmetric Fluorescent pHProbe Based on Gold Nanoclusters[J].J Huazhong Agric Univ,2016,35(3):77-82(in Chinese).(许朝用,刘琳,付艺颖,等.基于金纳米团簇的比率型pH荧光探针制备及表征[J].华中农业大学学报,2016,35(3):77-82.)
[21]Li R P,Xu P P,Fan J,et al.Sensitive Iodate Sensor Based on Fluorescence Quenching of Gold Nanocluster[J].Anal Chim Acta,2014,827(3):80-85.
[22]Bai Z Q,Ren X L,Gong Z,et al.11-Mercaptoundecanoic Acid Functionalized Gold Nanoclusters as Fluorescent Probes for the Sensitive Detection of Cu2+and Fe3+Ions[J].Chin Chem Lett,2017,28(9):1 901-1 904.
[23]Xu P P,Li R P,Tu Y F,et al.A Gold Nanoclusterbased Sensor for Sensitive Uric Acid Detection[J].Talanta,2015,144(7):704-709.
[24]Hao J F,Li Y X.Preparation of Polystyrene Sphere Supported Gold Nanoparticles and Their Catalytic Performance[J].Appl Chem Ind,2016,45(10):1 803-1 807(in Chinese).(郝杰夫,李云兴.聚苯乙烯球负载金纳米粒子的制备及其催化性能研究[J].应用化工,2016,45(10):1 803-1 807.)
[25]Kaboudin B,Khanmohammadi H,Kazemi F.Polymer Supported Gold Nanoparticles:Synthesis and Characterization of Functionalized Polystyrene-supported Gold Nanoparticles and Their Application in Catalytic Oxidation of Alcohols in Water[J].Appl Surf Sci,2017,425(12):400-406.
[26]Zheng B Z,Liu X X,Wu Y,et al.Surfactant-free Gold Nanoparticles:Rapid and Green Synthesis and Their Greatly Improved Catalytic Activities for 4-Nitrophenol Reduction[J].Inorg Chem Front,2017,4(6):1 268-1 272.
[27]Meng F W,Ma X Y,Duan N,et al.Ultrasensitive SERS Aptasensor for the Detection of Oxytetracycline Based on a Gold-enhanced Nano-assembly[J].Talanta,2017,165(4):412-418.
[28]Kang J Y,Zhang Y J,Li X,et al.a Rapid Colorimetric Sensor of Clenbuterol Based on Cysteamine Modified Gold Nanoparticles[J].ACS Appl Mater Interfaces,2016,8(1):1-5.
[29]Fu S Y,Guo X Y,Wang H,et al.Functionalized Au Nanoparticles for Label-free Raman Determination of Ppb Level Benzopyrene in Edible Oil[J].Sens Actuators B,2015,212(15):200-206.
[30]Haruta M,Yamada N,Kobayashi T,et al.Gold Catalysts Prepared by Coprecipitation for Low-temperature Oxidation of Hydrogen and of Cardon Monoxide[J].J Catal,1989,115(2):301-309.
[31]Meng Q N,Wang K,Tang Y F,et al.Preparation of Gold Nanoparticles Loaded Hollow Silica Spheres and Their Catalytic Performance[J].Chem J Chin Univ,2013,38(3):503-508(in Chinese).(孟庆男,王凯,汤玉斐,等.Au@SiO2中空微球的制备及催化性能[J].高等学校化学学报,2013,38(3):503-508.)
[32]Jia L Y,Guo Y H,Hong S N,et al.Label-free Detection of Pb2+Based on Aggregation-induced Emission Enhancement of Au-Nanoclusters[J].RSCAdv,2015,5(46):36 582-36 586.
[33]Gao B,Wang P F,Qiu Y F,et al.Colorimetric Detection of trace UO22+in Water Based on Phosphpric Acid Functional Gold Nanoparticles[J].Jiangxi Chem Indu,2015,6(5):130-133(in Chinese).(高豹,王攀峰,邱燕芳,等.磷酸化金纳米粒子对含铀废水的比色检测[J].江西化工,2015,6(5):130-133.)
[34]Wang S S.the Design and Application of Gold-nanomaterial-based Optical Sensing Methods in Environmental and Biological Analysis[D].Yantai:Yantai Instiute of Coastal zone Research Chinese Academy of Science,2016(in Chinese).(王莎莎.基于金纳米材料的光学传感方法设计及其在环境和生物分析中的应用[D].烟台:中国科学院烟台海岸带研究所,2016.)
[35]Guo J J,Zhang Y,Luo Y L,et al.Efficient Fluorescence Resonance Energy Transfer Between Oppositely Charged Cd Tequantum Dots and Gold Nanoparticles for Turn-on Fluorescence Detection of Glyphosate[J].Talanta,2014,125(11):385-392.
[36]Li C M.The Construction and Application of a Liver Cancer-targeting Drug Delivery Based on Gold Nanocages[D].Zhengzhou:Zhengzhou University,2015(in Chinese).(李春明.金纳米笼肝癌靶向给药系统的构建及应用研究[D].郑州:郑州大学,2015.)
[37]Zheng W,Wang Y S,Lu M M,et al.Janus Au-mesoporous Silica Nanocarriers for Chemo-photothermal Treatment of Liver Cancer Cells[J].RSC Adv,2016,6(50):44 498-44 505.
[38]Yang Y.Preparation and Modification of Gold Nanoparticales for Tumor Diagnosis and Therapy[D].Shanghai:Shanghai Jiao Tong University,2015(in Chinese).(杨溢.基于金纳米颗粒的诊治结合靶向探针研究[D].上海:上海交通大学,2015.)
[39]Liu W F,Liu K,Zhao Y,et al.T1-Weighted MR/CT Dual-modality Imaging-guided Photothermal Therapy Using Gadolinium-functionalized Triangular Gold Nanoprism[J].RSC Adv,2017,7(26):15 702-15 708.
[2]Wang G J,Yao G W,Ma S Y,et al.Effects of Different Reductants on the Synthesis of Au Nanoparticles[J].Chem World,2011,52(3):129-132(in Chinese).(王国军,姚瑰玮,马士禹,等.不同还原剂对金纳米颗粒合成的影响[J].化学世界,2011,52(3):129-132.)
[3]Wang Q Y.Preparation of Tunable Gold Nanostructures by APTES[D].Jilin:Jilin University,2017(in Chinese).(王琪瑶.APTES调控金纳米结构的制备[D].吉林:吉林大学,2017.)
[4]Wang Y,Jiao T F,Xie D Y,et al.Research Progress on Preparation and Application of Gold Nanoparticles[J].Chin J Inorg Anal Chem,2012,2(4):15-21(in Chinese).(王莹,焦体峰,谢丹阳,等.金纳米颗粒制备及应用研究进展[J].中国无机分析化学,2012,2(4):15-21.)
[5]Li N N.Synthesis,Coating and Catalytic Property of Gold Nanoparticles[D].Harbin:Harbin Institute of Technology,2015(in Chinese).(李宁宁.金纳米粒子的合成与包覆以及催化性能研究[D].哈尔滨:哈尔滨工业大学,2015.)
[6]Li J X,Liu R D,Zhang Y C,et al.Application of DNA Functionalized Gold Nanoparticles[J].Sci Chin Chem,2015,45(11):1 112-1 144(in Chinese).(李久兴,刘如迪,张益聪,等.DNA功能化金纳米及其应用[J].中国科学:化学,2015,45(11):1 112-1 144.)
[7]Ma Q C,Wang Y L,Song W L,et al.Modulation of the Optics Properties of Au Nanostrcture[J].Chem World,2017,58(8):468-472(in Chinese).(马青翠,王亚兰,宋雯莉,等.金纳米结构表面形貌对吸收-发光特性调控研究[J].化学世界,2017,58(8):468-472.)
[8]Liu Y X,Xiao S M,Yu Y,et al.Colorimetric Assay of Trace Amitrole in Water with p-Aminobenzamidemodified Gold Nanoparticles[J].J Nachang Univ(Nat Sci),2017,41(4):330-335(in Chinese).(刘英霞,肖石妹,余勇,等.基于对氨基甲酰胺修饰的金纳米比色法测定水样中痕量杀草强[J].南昌大学学报(理科版),2017,41(4):330-335.)
[9]Su X Y,Chen X Y,Sun C B,et al.Preparation of Au Nanoparticles with Different Morphologies and Study of Their Property as Surface Enhanced Raman Scattering Substrates[J].Spectrosc Spectral Anal,2017,37(1):7-12(in Chinese).(苏晓越,陈小燕,孙成彬,等.不同形貌金纳米粒子的制备及其表面增强拉曼散射效应的研究[J].光谱学与光谱分析,2017,37(1):7-12.)
[10]Yang S,Ji X H,Yang W S.Mechanism in the Preparation of Gold Nanoflowers by Ascorbic Acid Reduction[J].Chem J Chin Univ,2016,37(12):2 125-2 131(in Chinese).(杨爽,纪小会,杨文胜.抗坏血酸还原法制备金纳米花的机理[J].高等学校化学学报,2016,37(12):2 125-2 131.)
[11]Lee K C,Chen W J,Chen Y C.Using Dextranencapsulated Gold Nanoparticles as Insulin Carriers to Prolong Insulin Activitu[J].Nanomedicine,2017,12(15):1 823-1 834.
[12]Yang Y M,Dong Q M,Liang P,et al.Preparation of Flower-like Gold Nanoparticle with Controlled Morphology and Size Through Step by Step Seeding Approach[J].J Instrum Anal,2014,33(2):222-226(in Chinese).(杨艳敏,董前民,梁培,等.步步种子法制备形态及尺寸可控的花状金纳米粒子[J].分析测试学报,2014,33(2):222-226.)
[13]Dang J,Ai Y Y,Zheng X W.the Synthesis of Au/SiO2 Nanocomposites Using Chitosan/PEI Composite Nanohydrogel as Template[J].J Shangxi Norm Univ(Nat Sci Ed),2014,42(1):56-61(in Chinese).(党婕,艾媛媛,郑行望.壳聚糖/PEI凝胶模板法制备Au/SiO2复合纳米粒子[J].陕西师范大学学报(自然科学版),2014,42(1):56-61.)
[14]Shi J Q,Lu J W,Ma H F.Research Progress on the Preparation and Application of Au Nanostar[J].JSynth Cryst,2016,45(10):2 519-2 524(in Chinese).(史佳卿,陆嘉文,马鸿飞.星状金纳米晶的制备及应用研究进展[J].人工晶体学报,2016,45(10):2 519-2 524.)
[15]Liu K,Chen T,He S Y,et al.Observation and I-dentification of an Atomic Oxygen Structure on Catalytic Gold Nanoparticles[J].Angewa Chem Int Ed,2017,56(42):12 952-12 957.
[16]Negru B,Mcanally M O,Mayhew H E,et al.Fabrication of Gold Nanosphere Oligomers for Surface-enhanced Femtosecond Stimulated Raman Spectroscopy[J].J Phy Chem C,2017,121(48):27 004-727 008.
[17]Pu Y C,SONG F,Zhang W C,et al.Size-tunable Synthesis of Hollow Gold Nanospheres Through Control of Reaction Temperature[J].Adv Sci News,2017,34(8):1 600 255-1 600 263.
[18]Chen L,Lu L L,Wang S F,et al.Valence States Modulation Strategy for Picomole Level Assay of Hg2+in Drinking and Environmental Water by Directional Self-assembly of Gold Nanorods[J].ACSSens,2017,2(6):781-788.
[19]Xu L P,Nao A M,Han B L,et al.Determination of Vitamin C by Gold Nanorods Colorimetric Probe[J].J Food Saf Qual,2016,7(5):1 991-1 995(in Chinese).(徐丽萍,瑙阿敏,韩博林,等.金纳米棒比色探针法测定维生素C的初步研究[J].食品安全质量检测学报,2016,7(5):1 991-1 995.)
[20]Xu C Y,Liu L,Fu Y Y,et al.Preparation and Characterization of a Rationmetric Fluorescent pHProbe Based on Gold Nanoclusters[J].J Huazhong Agric Univ,2016,35(3):77-82(in Chinese).(许朝用,刘琳,付艺颖,等.基于金纳米团簇的比率型pH荧光探针制备及表征[J].华中农业大学学报,2016,35(3):77-82.)
[21]Li R P,Xu P P,Fan J,et al.Sensitive Iodate Sensor Based on Fluorescence Quenching of Gold Nanocluster[J].Anal Chim Acta,2014,827(3):80-85.
[22]Bai Z Q,Ren X L,Gong Z,et al.11-Mercaptoundecanoic Acid Functionalized Gold Nanoclusters as Fluorescent Probes for the Sensitive Detection of Cu2+and Fe3+Ions[J].Chin Chem Lett,2017,28(9):1 901-1 904.
[23]Xu P P,Li R P,Tu Y F,et al.A Gold Nanoclusterbased Sensor for Sensitive Uric Acid Detection[J].Talanta,2015,144(7):704-709.
[24]Hao J F,Li Y X.Preparation of Polystyrene Sphere Supported Gold Nanoparticles and Their Catalytic Performance[J].Appl Chem Ind,2016,45(10):1 803-1 807(in Chinese).(郝杰夫,李云兴.聚苯乙烯球负载金纳米粒子的制备及其催化性能研究[J].应用化工,2016,45(10):1 803-1 807.)
[25]Kaboudin B,Khanmohammadi H,Kazemi F.Polymer Supported Gold Nanoparticles:Synthesis and Characterization of Functionalized Polystyrene-supported Gold Nanoparticles and Their Application in Catalytic Oxidation of Alcohols in Water[J].Appl Surf Sci,2017,425(12):400-406.
[26]Zheng B Z,Liu X X,Wu Y,et al.Surfactant-free Gold Nanoparticles:Rapid and Green Synthesis and Their Greatly Improved Catalytic Activities for 4-Nitrophenol Reduction[J].Inorg Chem Front,2017,4(6):1 268-1 272.
[27]Meng F W,Ma X Y,Duan N,et al.Ultrasensitive SERS Aptasensor for the Detection of Oxytetracycline Based on a Gold-enhanced Nano-assembly[J].Talanta,2017,165(4):412-418.
[28]Kang J Y,Zhang Y J,Li X,et al.a Rapid Colorimetric Sensor of Clenbuterol Based on Cysteamine Modified Gold Nanoparticles[J].ACS Appl Mater Interfaces,2016,8(1):1-5.
[29]Fu S Y,Guo X Y,Wang H,et al.Functionalized Au Nanoparticles for Label-free Raman Determination of Ppb Level Benzopyrene in Edible Oil[J].Sens Actuators B,2015,212(15):200-206.
[30]Haruta M,Yamada N,Kobayashi T,et al.Gold Catalysts Prepared by Coprecipitation for Low-temperature Oxidation of Hydrogen and of Cardon Monoxide[J].J Catal,1989,115(2):301-309.
[31]Meng Q N,Wang K,Tang Y F,et al.Preparation of Gold Nanoparticles Loaded Hollow Silica Spheres and Their Catalytic Performance[J].Chem J Chin Univ,2013,38(3):503-508(in Chinese).(孟庆男,王凯,汤玉斐,等.Au@SiO2中空微球的制备及催化性能[J].高等学校化学学报,2013,38(3):503-508.)
[32]Jia L Y,Guo Y H,Hong S N,et al.Label-free Detection of Pb2+Based on Aggregation-induced Emission Enhancement of Au-Nanoclusters[J].RSCAdv,2015,5(46):36 582-36 586.
[33]Gao B,Wang P F,Qiu Y F,et al.Colorimetric Detection of trace UO22+in Water Based on Phosphpric Acid Functional Gold Nanoparticles[J].Jiangxi Chem Indu,2015,6(5):130-133(in Chinese).(高豹,王攀峰,邱燕芳,等.磷酸化金纳米粒子对含铀废水的比色检测[J].江西化工,2015,6(5):130-133.)
[34]Wang S S.the Design and Application of Gold-nanomaterial-based Optical Sensing Methods in Environmental and Biological Analysis[D].Yantai:Yantai Instiute of Coastal zone Research Chinese Academy of Science,2016(in Chinese).(王莎莎.基于金纳米材料的光学传感方法设计及其在环境和生物分析中的应用[D].烟台:中国科学院烟台海岸带研究所,2016.)
[35]Guo J J,Zhang Y,Luo Y L,et al.Efficient Fluorescence Resonance Energy Transfer Between Oppositely Charged Cd Tequantum Dots and Gold Nanoparticles for Turn-on Fluorescence Detection of Glyphosate[J].Talanta,2014,125(11):385-392.
[36]Li C M.The Construction and Application of a Liver Cancer-targeting Drug Delivery Based on Gold Nanocages[D].Zhengzhou:Zhengzhou University,2015(in Chinese).(李春明.金纳米笼肝癌靶向给药系统的构建及应用研究[D].郑州:郑州大学,2015.)
[37]Zheng W,Wang Y S,Lu M M,et al.Janus Au-mesoporous Silica Nanocarriers for Chemo-photothermal Treatment of Liver Cancer Cells[J].RSC Adv,2016,6(50):44 498-44 505.
[38]Yang Y.Preparation and Modification of Gold Nanoparticales for Tumor Diagnosis and Therapy[D].Shanghai:Shanghai Jiao Tong University,2015(in Chinese).(杨溢.基于金纳米颗粒的诊治结合靶向探针研究[D].上海:上海交通大学,2015.)
[39]Liu W F,Liu K,Zhao Y,et al.T1-Weighted MR/CT Dual-modality Imaging-guided Photothermal Therapy Using Gadolinium-functionalized Triangular Gold Nanoprism[J].RSC Adv,2017,7(26):15 702-15 708.