反渗透浓水中难降解有机物的去除技术研究进展
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摘要
有机污染物是阻碍反渗透RO浓水达标排放或资源化利用的关键因素之一。对RO浓水难降解有机物的去除方法进行概括总结,阐述了生物法、铁炭微电解法和高级氧化法的研究现状,尤其对高级氧化法的研究进展和存在问题进行了详细的分析。在此基础上,提出高级氧化-活性炭吸附、高级氧化-生物等联合技术是今后研究的主要方向。
Organic pollutants are one of the key factors which obstruct RO concentrate to achieve discharge standard or resource utilization. In the paper,the methods for removing non-degradable organic substances in RO concentrate are concluded and summarized. The present research status of biological method,Fe/C micro-electrolysis method,and advanced oxidation processes(AOPs) are expounded in detail,and the research progress and existing problems are analyzed especially in detail. Based on these,it is proposed that the united technologies of advanced oxidationactivated carbon adsorption,advanced oxidation-biology,etc. are the main research directions in the future.
Organic pollutants are one of the key factors which obstruct RO concentrate to achieve discharge standard or resource utilization. In the paper,the methods for removing non-degradable organic substances in RO concentrate are concluded and summarized. The present research status of biological method,Fe/C micro-electrolysis method,and advanced oxidation processes(AOPs) are expounded in detail,and the research progress and existing problems are analyzed especially in detail. Based on these,it is proposed that the united technologies of advanced oxidationactivated carbon adsorption,advanced oxidation-biology,etc. are the main research directions in the future.
引文
[1]张培龙,于丽,庞立飞,等.微气泡曝气O3/H2O2处理RO浓水的效能及影响因素[J].环境工程学报,2014,8(1):242-248.
[2]夏季祥.炼化企业反渗透浓水处理技术现状及发展趋势分析[J].安全、健康和环境,2013,13(7):29-31.
[3]赵春霞,顾平,张光辉.反渗透浓水处理现状与研究进展[J].中国给水排水,2009,25(18):1-5.
[4]刘增军,童祯恭,侯煜堃,等.原水有机物分子量分布及去除特性研究基于北方某水厂实测数据[J].华东交通大学学报,2014,31(4):123-129.
[5]郭富斌.反渗透浓水处理中试方案的初步研究[J].化工管理,2015(17):225.
[6]雷云,解庆林,李艳红.高盐度废水处理研究进展[J].环境科学与管理,2007,32(6):94-98.
[7]邹小玲,丁丽丽,赵明宇,等.高盐度废水生物处理研究[J].工业水处理,2008,28(9):1-4.
[8]朱砂砾,谢康,夏四清.盐度对序批式反应器与间歇曝气膜生物反应器污水处理效果的影响[J].环境污染与防治,2012,34(2):14-18.
[9]杨玉旺.移动床生物膜反应器处理污水的研究应用进展[J].工业水处理,2004,24(2):12-15.
[10]叶杰旭,穆永杰,孙德智,等.MBBR-MBR组合工艺处理生活垃圾沥滤液的研究[J].工业水处理,2013,33(1):20-24.
[11]李坤,徐军,云干,等.复合耐盐微生物菌剂强化MBBR工艺处理高盐废水[J].环境工程学报,2015,9(6):2829-2834.
[12]王小蓉,郝广平,李文翠.生物活性炭技术在水处理中的研究与应用[J].化工进展,2010,29(5):932-937.
[13]李进,王光华,李文兵,等.生物活性炭技术深度处理焦化废水的中试研究[J].工业水处理,2015,35(9):69-72.
[14]徐传海,魏新,郦和生,等.生物活性炭工艺处理炼油厂反渗透浓缩水[J].化工环保,2011,31(2):148-151.
[15]彭勃,彭书传,王进,等.混凝-生物强化联合处理环氧树脂高盐废水[J].环境工程学报,2015,9(6):2595-2600.
[16]杨波,郝建安,张晓青,等.复合嗜盐微生物处理高含盐废水的研究[J].盐业与化工,2015,44(11):33-39.
[17]哈斯毕力格,于海龙,杨林.一株苯酚降解耐盐菌对苯酚的降解性能研究[J].内蒙古科技与经济,2015(3):116-118.
[18]渠光华,张智,尹晓静,等.铁炭微电解法预处理超高盐榨菜腌制废水[J].环境工程学报,2011,5(12):2761-2766.
[19]冯雅丽,张茜,李浩然,等.铁炭微电解预处理高浓度高盐制药废水[J].环境工程学报,2012,6(11):3855-3860.
[20]范树军,张焕彬,付建军.铁炭微电解/Fenton氧化预处理高浓度煤化工废水的研究[J].工业水处理,2010,30(8):93-95.
[21]聂丽君,周如金,钟华文,等.铁炭微电解-混凝沉淀-生物滤池组合工艺处理松节油加工废水研究[J].工业用水与废水,2014,45(5):19-22.
[22]许丹宇,石岩,张洪雷.印染废水处理与回用的工艺设计与应用[J].给水排水,2015,41(3):49-53.
[23]王晓.炼油废水处理与回用技术应用研究[J].给水排水,2015,41(2):59-61.
[24]马厚悦,刘燕韶,许修祯.Fenton流化床氧化技术在制浆造纸废水深度处理中的应用[J].中国造纸,2014,33(8):35-39.
[25]郭鹏,覃茜,钱超宏,等.芬顿氧化法处理APMP制浆废水的工程应用[J].造纸科学与技术,2012,31(6):143-145.
[26]李常青,刘发强,江岩,等.电-类Fenton法处理石化反渗透浓水[J].石化技术与应用,2015,33(3):258-262.
[27]Zhou M,Tan Q,Wang Q,et al.Degradation of organics in reverse osmosis concentrate by electro-Fenton process[J].Journal of Hazardous Materials,2012,215/216(10):287-293.
[28]李亮,阮晓磊,滕厚开,等.臭氧催化氧化处理炼油废水反渗透浓水的研究[J].工业水处理,2011,31(4):43-45.
[29]沈洪源,李忠才.炼化废水深度处理回用技术与运行实践[J].工业水处理,2015,35(8):110-112.
[30]Bagastyo A Y,Batstone D J,Rabaey K,et al.Electrochemical oxidation of electrodialysed reverse osmosis concentrate on Ti/Pt-Ir O2,Ti/Sn O2-Sb and boron-doped diamond electrodes[J].Water Research,2014,279(1):242-250.
[31]王超,赵旭,侯子义,等.光电催化氧化处理反渗透浓水[J].环境工程学报,2014,1(8):3189-3194.
[32]Westerhoff P,Moon H,Minakata D,et al.Oxidation of organics in retentates from reverse osmosis wastewater reuse facilities[J].Water Research,2009,43(16):3992-3998.
[33]Umar M,Roddick F,Fan L.Recent advancements in the treatment of municipal wastewater reverse os mosis concentrate-an overview[J].Critical Reviews in Environmental Science and Technology,2015,45(3):193-248.
[34]Liao C H,Kang S F,Wu F A.Hydroxyl radical scavenging role of chloride and bicarbonate ions in the H2O2/UV process[J].Chemosphere,2001,44(5):1193-1200.
[35]Zhou M,Liu L,Jiao Y,et al.Treatment of high-salinity reverse osmosis concentrate by electrochemical oxidation on BDD and DSA electrodes[J].Desalination,2011,277(1/2/3):201-206.
[36]Umar M,Roddick F,Fan L.Comparison of coagulation efficiency of aluminium and ferric-based coagulants as pre-treatment for UVC/H2O2treatment of wastewater RO concentrate[J].Chemical Engineering Journal,2016,284:841-849.
[37]李勇,张晓健,陈超,等.基于有机物分子质量分布的饮用水处理工艺选择[J].中国给水排水,2008,24(21):1-4.
[38]王丽丽,顾平,赵春霞,等.活性炭微孔对RO浓水中小分子有机物的吸附[J].中国给水排水,2013,29(13):87-90.
[39]张华,吴百春,刘光全,等.臭氧及花生壳活性炭对RO浓水的处理[J].化工进展,2011(S1):853-858.
[40]张国珍,王家福,武福平,等.臭氧-活性炭技术处理炼化企业RO浓水[J].环境工程,2012,30(5):1-4.
[41]王东梅,刘丹,龚正君,等.Fenton氧化-絮凝-吸附法处理垃圾渗滤液反渗透浓缩液[J].科学技术与工程,2013,13(18):5423-5426.
[42]何辉,张玉先,张叶来,等.臭氧-生物活性炭处理反渗透浓排水工艺研究[J].给水排水,2008,34(11):180-183.
[43]郭兴芳,陈立,陶润先,等.臭氧-生物活性炭工艺预处理海水试验研究[J].水处理技术,2011,37(10):79-82.
[44]Lu J,Fan L,Roddick F A.Potential of BAC combined with UVC/H2O2for reducing organic matter from highly saline reverse osmosis concentrate produced from municipal wastewater reclamation[J].Chemosphere,2013,93(4):683-688.
[45]姜元臻,简磊,李炳辉,等.Fenton-BAF处理印染RO浓水工程实例[J].广东化工,2015,42(13):306-307.
[2]夏季祥.炼化企业反渗透浓水处理技术现状及发展趋势分析[J].安全、健康和环境,2013,13(7):29-31.
[3]赵春霞,顾平,张光辉.反渗透浓水处理现状与研究进展[J].中国给水排水,2009,25(18):1-5.
[4]刘增军,童祯恭,侯煜堃,等.原水有机物分子量分布及去除特性研究基于北方某水厂实测数据[J].华东交通大学学报,2014,31(4):123-129.
[5]郭富斌.反渗透浓水处理中试方案的初步研究[J].化工管理,2015(17):225.
[6]雷云,解庆林,李艳红.高盐度废水处理研究进展[J].环境科学与管理,2007,32(6):94-98.
[7]邹小玲,丁丽丽,赵明宇,等.高盐度废水生物处理研究[J].工业水处理,2008,28(9):1-4.
[8]朱砂砾,谢康,夏四清.盐度对序批式反应器与间歇曝气膜生物反应器污水处理效果的影响[J].环境污染与防治,2012,34(2):14-18.
[9]杨玉旺.移动床生物膜反应器处理污水的研究应用进展[J].工业水处理,2004,24(2):12-15.
[10]叶杰旭,穆永杰,孙德智,等.MBBR-MBR组合工艺处理生活垃圾沥滤液的研究[J].工业水处理,2013,33(1):20-24.
[11]李坤,徐军,云干,等.复合耐盐微生物菌剂强化MBBR工艺处理高盐废水[J].环境工程学报,2015,9(6):2829-2834.
[12]王小蓉,郝广平,李文翠.生物活性炭技术在水处理中的研究与应用[J].化工进展,2010,29(5):932-937.
[13]李进,王光华,李文兵,等.生物活性炭技术深度处理焦化废水的中试研究[J].工业水处理,2015,35(9):69-72.
[14]徐传海,魏新,郦和生,等.生物活性炭工艺处理炼油厂反渗透浓缩水[J].化工环保,2011,31(2):148-151.
[15]彭勃,彭书传,王进,等.混凝-生物强化联合处理环氧树脂高盐废水[J].环境工程学报,2015,9(6):2595-2600.
[16]杨波,郝建安,张晓青,等.复合嗜盐微生物处理高含盐废水的研究[J].盐业与化工,2015,44(11):33-39.
[17]哈斯毕力格,于海龙,杨林.一株苯酚降解耐盐菌对苯酚的降解性能研究[J].内蒙古科技与经济,2015(3):116-118.
[18]渠光华,张智,尹晓静,等.铁炭微电解法预处理超高盐榨菜腌制废水[J].环境工程学报,2011,5(12):2761-2766.
[19]冯雅丽,张茜,李浩然,等.铁炭微电解预处理高浓度高盐制药废水[J].环境工程学报,2012,6(11):3855-3860.
[20]范树军,张焕彬,付建军.铁炭微电解/Fenton氧化预处理高浓度煤化工废水的研究[J].工业水处理,2010,30(8):93-95.
[21]聂丽君,周如金,钟华文,等.铁炭微电解-混凝沉淀-生物滤池组合工艺处理松节油加工废水研究[J].工业用水与废水,2014,45(5):19-22.
[22]许丹宇,石岩,张洪雷.印染废水处理与回用的工艺设计与应用[J].给水排水,2015,41(3):49-53.
[23]王晓.炼油废水处理与回用技术应用研究[J].给水排水,2015,41(2):59-61.
[24]马厚悦,刘燕韶,许修祯.Fenton流化床氧化技术在制浆造纸废水深度处理中的应用[J].中国造纸,2014,33(8):35-39.
[25]郭鹏,覃茜,钱超宏,等.芬顿氧化法处理APMP制浆废水的工程应用[J].造纸科学与技术,2012,31(6):143-145.
[26]李常青,刘发强,江岩,等.电-类Fenton法处理石化反渗透浓水[J].石化技术与应用,2015,33(3):258-262.
[27]Zhou M,Tan Q,Wang Q,et al.Degradation of organics in reverse osmosis concentrate by electro-Fenton process[J].Journal of Hazardous Materials,2012,215/216(10):287-293.
[28]李亮,阮晓磊,滕厚开,等.臭氧催化氧化处理炼油废水反渗透浓水的研究[J].工业水处理,2011,31(4):43-45.
[29]沈洪源,李忠才.炼化废水深度处理回用技术与运行实践[J].工业水处理,2015,35(8):110-112.
[30]Bagastyo A Y,Batstone D J,Rabaey K,et al.Electrochemical oxidation of electrodialysed reverse osmosis concentrate on Ti/Pt-Ir O2,Ti/Sn O2-Sb and boron-doped diamond electrodes[J].Water Research,2014,279(1):242-250.
[31]王超,赵旭,侯子义,等.光电催化氧化处理反渗透浓水[J].环境工程学报,2014,1(8):3189-3194.
[32]Westerhoff P,Moon H,Minakata D,et al.Oxidation of organics in retentates from reverse osmosis wastewater reuse facilities[J].Water Research,2009,43(16):3992-3998.
[33]Umar M,Roddick F,Fan L.Recent advancements in the treatment of municipal wastewater reverse os mosis concentrate-an overview[J].Critical Reviews in Environmental Science and Technology,2015,45(3):193-248.
[34]Liao C H,Kang S F,Wu F A.Hydroxyl radical scavenging role of chloride and bicarbonate ions in the H2O2/UV process[J].Chemosphere,2001,44(5):1193-1200.
[35]Zhou M,Liu L,Jiao Y,et al.Treatment of high-salinity reverse osmosis concentrate by electrochemical oxidation on BDD and DSA electrodes[J].Desalination,2011,277(1/2/3):201-206.
[36]Umar M,Roddick F,Fan L.Comparison of coagulation efficiency of aluminium and ferric-based coagulants as pre-treatment for UVC/H2O2treatment of wastewater RO concentrate[J].Chemical Engineering Journal,2016,284:841-849.
[37]李勇,张晓健,陈超,等.基于有机物分子质量分布的饮用水处理工艺选择[J].中国给水排水,2008,24(21):1-4.
[38]王丽丽,顾平,赵春霞,等.活性炭微孔对RO浓水中小分子有机物的吸附[J].中国给水排水,2013,29(13):87-90.
[39]张华,吴百春,刘光全,等.臭氧及花生壳活性炭对RO浓水的处理[J].化工进展,2011(S1):853-858.
[40]张国珍,王家福,武福平,等.臭氧-活性炭技术处理炼化企业RO浓水[J].环境工程,2012,30(5):1-4.
[41]王东梅,刘丹,龚正君,等.Fenton氧化-絮凝-吸附法处理垃圾渗滤液反渗透浓缩液[J].科学技术与工程,2013,13(18):5423-5426.
[42]何辉,张玉先,张叶来,等.臭氧-生物活性炭处理反渗透浓排水工艺研究[J].给水排水,2008,34(11):180-183.
[43]郭兴芳,陈立,陶润先,等.臭氧-生物活性炭工艺预处理海水试验研究[J].水处理技术,2011,37(10):79-82.
[44]Lu J,Fan L,Roddick F A.Potential of BAC combined with UVC/H2O2for reducing organic matter from highly saline reverse osmosis concentrate produced from municipal wastewater reclamation[J].Chemosphere,2013,93(4):683-688.
[45]姜元臻,简磊,李炳辉,等.Fenton-BAF处理印染RO浓水工程实例[J].广东化工,2015,42(13):306-307.