水镁石复合阻燃材料的研究进展
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摘要
随着经济和生产力发展,高分子材料被应用在越来越广泛的领域。在高分子材料中添加环境友好型阻燃剂是近年来的研究重点,无卤、低烟、低毒、高效新型阻燃剂是当今阻燃剂的研究方向。无机阻燃剂水镁石被越来越广泛的应用在各类阻燃材料中,并取得了相当不错的阻燃效果。本文主要对不同类型的水镁石复合阻燃材料的研究进展做一综述,为今后的研究和应用提供一定的参考依据。
With the development of economy and productivity,polymer materials have been applied in more and more fields. Polymer materials added environment-friendly flame retardants are the focus in recent years. Halogen-free,low-smoke,low-toxic and high-efficient new flame retardants are the research directions of the flame retardants.Inorganic flame retardant brucite has been widely applied in various kinds of flame retardants,and has achieved quite good flame retardancy. The research progress of different types of brucite composite flame retardants was reviewed,which will provide some references for future research and application.
With the development of economy and productivity,polymer materials have been applied in more and more fields. Polymer materials added environment-friendly flame retardants are the focus in recent years. Halogen-free,low-smoke,low-toxic and high-efficient new flame retardants are the research directions of the flame retardants.Inorganic flame retardant brucite has been widely applied in various kinds of flame retardants,and has achieved quite good flame retardancy. The research progress of different types of brucite composite flame retardants was reviewed,which will provide some references for future research and application.
引文
[1]陈浩然,李晓丹.阻燃剂的研究发展现状[J].纤维复合材料,2012,18(1):18-21.
[2]李飞龙,胡永琪,刘润静,等.中国塑料阻燃剂应用现状和发展趋势[J].无机盐工业,2015,47(3):1-3.
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[4]Pang H C,Wang X S,Zhu X K,et al.Nanoengineering of brucite@Si O2for enhanced mechanical properties and flame retardant behaviors[J].Polymer Degradation and Stability,2015,120:410-418.
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[6]张宏鹏,庞洪昌,宁桂玲,等.水母粉对水镁石基阻燃剂/混合塑料复合材料性能的影响[J].山东化工,2016,45(11):9-11.
[7]张宏鹏,庞洪昌,朱行坤,等.CF对水镁石基阻燃剂阻燃EVAC复合材料性能的影响[J].工程塑料应用,2016,44(2):120-123.
[8]Wang X S,Pang H C,Chen W D,et al.Nanoengineering core/shell structured brucite@polyphosphate@amine hybrid system for enhanced flame retardant properties[J].Polymer Degradation and Stability,2013,98(12):2609-2616.
[9]玉立娟,孙鹏,李广义,等.阻燃剂的研究进展[J].上海塑料,2013(3):21-24.
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[11]张清辉,郑水林,张强,等.氢氧化镁/氢氧化铝复合阻燃剂的制备及其在EVA材料中的应用[J].北京科技大学学报,2007(10):1027-1030.
[12]孟平蕊,李良波,解竹柏,等.超细氢氧化镁在HDPE与CPE共混材料中的应用研究[J].济南大学学报(自然科学版),2003,17(4):380-382.
[13]Wang N,Zhang J,Fang Q H,et al.Influence of mesoporous fillers with PP-g-MA on flammability and tensile behavior of polypropylene composites[J].Composites Part B,2013,44(1):467-471.
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[15]孙英娟,高明.氢氧化镁在膨胀阻燃聚丙烯体系中的协效作用研究[J].塑料科技,2016,44(12):77-82.
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[18]刘生鹏,张文祥,危淼,等.纳米氢氧化镁的制备及其表面改性研究进展[J].河北化工,2010,33(6):3-6.
[19]陈一,赵芳,杨军.纳米氢氧化镁及其复合体系阻燃改性HDPE研究[J].湖南工业大学学报,2009,23(4):33-36.
[20]王其磊.硅氧烷包裹氢氧化镁纳米复合阻燃剂改性制备及性能研究[J].化工新型材料,2017,45(11):251-254.
[21]赖密玲,王立艳,盖广清,等.纳米氢氧化镁阻燃剂的研究进展[J].吉林建筑大学学报,2016,33(6):31-34.
[22]针涛,张扬,欧德培,等.浅析氢氧化镁协同高效阻燃聚丙烯[J].广东化工,2017,44(6):50-51.
[23]Ye L,Miao Y Y,Yan H,et al.The synergistic effects of boroxo siloxanes with magnesium hydroxide in halogen-free flame retardant EVA/MH blends[J].Polymer Degradation and Stability,2013,98(4):868-874.
[24]Liu H,Fang Z P,Peng M,et al.The effects of irradiation crosslinking on the thermal degradation and flame-retardant properties of the HDPE/EVA/magnesium hydroxide composites[J].Radiation Physics and Chemistry,2009,78(11):922-926.
[25]黄建智,成晓玲.油酸包覆纳米片Al(OH)3/Mg(OH)2复合阻燃剂的制备[J].广东工业大学学报,2016,33(2):71-75.
[26]Matusinovic Z,Wilkie C A.Fire retardancy and morphology of layered double hydroxide nanocomposites:A review[J].Journal of Materials Chemistry,2012,22(36):18701-18704.
[2]李飞龙,胡永琪,刘润静,等.中国塑料阻燃剂应用现状和发展趋势[J].无机盐工业,2015,47(3):1-3.
[3]李雪,程沛,侯睿,等.轻烧粉氨气法制备氢氧化镁阻燃剂的研究[J].无机盐工业,2016,48(11):21-24.
[4]Pang H C,Wang X S,Zhu X K,et al.Nanoengineering of brucite@Si O2for enhanced mechanical properties and flame retardant behaviors[J].Polymer Degradation and Stability,2015,120:410-418.
[5]Hull T R,Witkowski A,Hollingbery L.Fire retardant action of mineral fillers[J].Polym Degrad Stabil,2011,96(8):1462-1469.
[6]张宏鹏,庞洪昌,宁桂玲,等.水母粉对水镁石基阻燃剂/混合塑料复合材料性能的影响[J].山东化工,2016,45(11):9-11.
[7]张宏鹏,庞洪昌,朱行坤,等.CF对水镁石基阻燃剂阻燃EVAC复合材料性能的影响[J].工程塑料应用,2016,44(2):120-123.
[8]Wang X S,Pang H C,Chen W D,et al.Nanoengineering core/shell structured brucite@polyphosphate@amine hybrid system for enhanced flame retardant properties[J].Polymer Degradation and Stability,2013,98(12):2609-2616.
[9]玉立娟,孙鹏,李广义,等.阻燃剂的研究进展[J].上海塑料,2013(3):21-24.
[10]张铁江.常见阻燃剂的利与弊[J].煤炭技术,2010,29(2):204-206.
[11]张清辉,郑水林,张强,等.氢氧化镁/氢氧化铝复合阻燃剂的制备及其在EVA材料中的应用[J].北京科技大学学报,2007(10):1027-1030.
[12]孟平蕊,李良波,解竹柏,等.超细氢氧化镁在HDPE与CPE共混材料中的应用研究[J].济南大学学报(自然科学版),2003,17(4):380-382.
[13]Wang N,Zhang J,Fang Q H,et al.Influence of mesoporous fillers with PP-g-MA on flammability and tensile behavior of polypropylene composites[J].Composites Part B,2013,44(1):467-471.
[14]石延超,王国建.有机磷阻燃剂的合成及在阻燃高分子材料中的应用研究进展[J].高分子材料科学与工程,2016,32(5):170-l71.
[15]孙英娟,高明.氢氧化镁在膨胀阻燃聚丙烯体系中的协效作用研究[J].塑料科技,2016,44(12):77-82.
[16]Wu H H,Gao C J,Luo B J,et al.Progress in preparationof nano-sized magnesium hydroxide from concentratedseawater and brine[J].Advanced Materials Research,2014,989/994:540-543.
[17]申红艳,刘有智.纳米氢氧化镁的制备及其原位改性[J].化工进展,2017,36(1):294-298.
[18]刘生鹏,张文祥,危淼,等.纳米氢氧化镁的制备及其表面改性研究进展[J].河北化工,2010,33(6):3-6.
[19]陈一,赵芳,杨军.纳米氢氧化镁及其复合体系阻燃改性HDPE研究[J].湖南工业大学学报,2009,23(4):33-36.
[20]王其磊.硅氧烷包裹氢氧化镁纳米复合阻燃剂改性制备及性能研究[J].化工新型材料,2017,45(11):251-254.
[21]赖密玲,王立艳,盖广清,等.纳米氢氧化镁阻燃剂的研究进展[J].吉林建筑大学学报,2016,33(6):31-34.
[22]针涛,张扬,欧德培,等.浅析氢氧化镁协同高效阻燃聚丙烯[J].广东化工,2017,44(6):50-51.
[23]Ye L,Miao Y Y,Yan H,et al.The synergistic effects of boroxo siloxanes with magnesium hydroxide in halogen-free flame retardant EVA/MH blends[J].Polymer Degradation and Stability,2013,98(4):868-874.
[24]Liu H,Fang Z P,Peng M,et al.The effects of irradiation crosslinking on the thermal degradation and flame-retardant properties of the HDPE/EVA/magnesium hydroxide composites[J].Radiation Physics and Chemistry,2009,78(11):922-926.
[25]黄建智,成晓玲.油酸包覆纳米片Al(OH)3/Mg(OH)2复合阻燃剂的制备[J].广东工业大学学报,2016,33(2):71-75.
[26]Matusinovic Z,Wilkie C A.Fire retardancy and morphology of layered double hydroxide nanocomposites:A review[J].Journal of Materials Chemistry,2012,22(36):18701-18704.