复合阴极材料电-Fenton法处理难降解有机废水研究进展
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摘要
叙述了近年来国内外关于电-Fenton技术改进阴极、制备复合阴极材料方面处理难降解废水的研究进展。重点介绍了玻璃碳、网状玻璃碳、碳纳米管等碳素材料以及气凝胶、金属铁氧化物等非碳素材料用于改进、制备复合阴极材料方面的研究现状。总结了优良的复合阴极材料具有的特点,具有丰富的孔隙率,高的比表面积,优良的导电性等特性。提出要制备高效、成熟的复合阴极材料,仍需要进一步对新型碳素材料进行氮掺杂改性研究,强化新型气凝胶材料的导电性研究,认为还需要进行中试进一步确定其对实际废水的处理效果。
The research progress of the improvement of cathodes and the preparation of composite cathodes by electro-Fenton techniques for the treatment of refractory organic wastewater at home and abroad was overviewed. Research status of carbon materials such as glassy carbon, reticulated glassy carbon and carbon nanotubes, as well as non-carbon materials such as aerogel and metal iron oxide were introduced, which were used to improve and prepare the research status of composite cathode materials. The characteristics of the excellent composite cathode material were summarized, which had rich porosity, high specific surface area and excellent electrical conductivity. It is proposed that for prepare high-efficiency and mature composite cathode materials, further study on the nitrogen doping modification for new type of carbon material, deep research on strengthen the conductivity of the new aerogel materials and the pilot test on the verification the actual wastewater treatment effect were needed.
The research progress of the improvement of cathodes and the preparation of composite cathodes by electro-Fenton techniques for the treatment of refractory organic wastewater at home and abroad was overviewed. Research status of carbon materials such as glassy carbon, reticulated glassy carbon and carbon nanotubes, as well as non-carbon materials such as aerogel and metal iron oxide were introduced, which were used to improve and prepare the research status of composite cathode materials. The characteristics of the excellent composite cathode material were summarized, which had rich porosity, high specific surface area and excellent electrical conductivity. It is proposed that for prepare high-efficiency and mature composite cathode materials, further study on the nitrogen doping modification for new type of carbon material, deep research on strengthen the conductivity of the new aerogel materials and the pilot test on the verification the actual wastewater treatment effect were needed.
引文
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[24]易东,刘秘,周贵方,等.苯酚-三聚氰胺-甲醛气凝胶的制备与表征研究[J].功能材料,2017,48(4):141-144.
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[26]ZHAO H,QIAN L,CHEN Y,et al.Selective catalytic two-electron O2reduction for onsite efficient oxidation reaction in heterogeneous electro-Fenton process[J].Chemical Engineering Journal,2018,332(15):486-498
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[28]WEN S,NIU Z,ZHEN Z,et al.In-situ synthesis of 3D GA on titanium wire as a binder-free electrode for electro-Fenton removing of EDTA-Ni[J].Journal of Hazardous Materials,2017,341:128.
[29]HARRELD J,DAVE B C,DUNN B,et al.Synthesis and properties of polypyrrole-vanadium oxide hybrid aerogels[J].Journal of NonCrystalline Solids,1998,225(1):319-324.
[30]DONG W,SAKAMOTO J,DUNN B.Electrochemical properties of vanadium oxide aerogels and aerogel nanocomposites[J].Journal of Sol-Gel Science and Technology,2003,26(1/3):641-644.
[31]蒋婵杰,林志勇,林松柏,等.介孔材料制备及研究进展[J].材料导报,2003,17(11):53-55.
[32]CHEN Y,WANG M,TIAN M,et al.An innovative electro-fenton degradation system self-powered by triboelectric nanogenerator using biomass-derived carbon materials as cathode catalyst[J].Nano Energy,2017,42:314-321.
[33]DO T M,JI Y B,SANG H K.An electro-Fenton system using magnetite coated metallic foams as cathode for dye degradation[J].Catalysis Today,2017,295:48-55.
[34]秦国旭,王新,王新运,等.介孔Zr O2-Ti O2复合材料的制备及电催化还原2-吡啶甲醛性能研究[J].化工新型材料,2016(6):97-100.
[35]ZHANG Y,GAO M,WANG S G,et al.Integrated electro-Fenton process enabled by a rotating Fe3O4/gas diffusion cathode for simultaneous generation and activation of H2O2[J].Electrochimica Acta,2017,231:694-704.
[2]刘静,王杰,孙金诚,等.Fenton及改进Fenton氧化处理难降解有机废水的研究进展[J].水处理技术,2015,41(2):6-10.
[3]徐夫元,祝社民,陈英文,等.氧还原合成过氧化氢电极的研究进展[J].材料导报,2009,23(1):32-35.
[4]CHMAYSSEM A,TAHA S,HAUCHARD D.Scaled-up electrochemical reactor with a fixed bed three-dimensional cathode for electro-Fenton process:Application to the treatment of bisphenol A[J].Electrochimica Acta,2017,225:435-442.
[5]ELLOUZE S,KESSEMTINI S,CLEMATIS D,et al.Application of Doehlert design to the electro-Fenton treatment of Bismarck Brown Y[J].Journal of Electroanalytical Chemistry,2017,799:34-39.
[6]刘剑洪,吴双泉,何传新,等.碳纳米管和碳微米管的结构、性质及其应用[J].深圳大学学报(理工版),2013,30(1):1-11.
[7]PAJOOTAN E,ARAMI M.Structural and electrochemical characterization of carbon electrode modified by multi-walled carbon nanotubes and surfactant[J].Electrochimica Acta,2013,112(3):505-514.
[8]ES'HAGHZADE Z,PAJOOTAN E,BAHRAMI H,et al.Facile synthesis of Fe3O4,nanoparticles via aqueous based electro chemical route for heterogeneous electro-Fenton removal of azo dyes[J].Journal of the Taiwan Institute of Chemical Engineers,2016,71:91-105.
[9]LIN H,OTURAN N,WU J,et al.Cold incineration of sucralose in aqueous solution by electro-Fenton process[J].Separation&Purification Technology,2017,173:218-225.
[10]FERNANDES A,LABIADH L,CIR魱ACO L,et al.Electro-Fenton oxidation of reverse osmosis concentrate from sanitary landfill leachate:Evaluation of operational parameters[J].Chemosphere,2017,184:1223.
[11]DOMINGUEZ C M,OTURAN N,ROMERO A,et al.Optimization of electro fenton process for effective degradation of organochlorine pesticide lindane[J].Catalysis Today,DOI:http://dx.doi.org/10.10116/j.cattod.2017.10.028.
[12]周蕾,周明华.电-Fenton技术的研究进展[J].水处理技术,2013,39(10):6-11.
[13]WU T,HUANG K,LIU S,et al.Hydrothermal ammoniated treatment of PAN-graphite felt for vanadium redox flow battery[J].Journal of Solid State Electrochemistry,2012,16(2):579-585.
[14]钱国才,李宝琛,许逸达,等.石墨毡掺氮对直接液流甲醇燃料电池性能的影响[J].化学工业与工程,2016,33(6):26-31.
[15]YU J,LIU T,LIU H,et al.Electro-polymerization fabrication of PANI@GF electrode and its energy-effective electrocatalytic performance in electro-Fenton process[J].Chinese Journal of Catalysis,2016,37(12):2079-2085.
[16]Khataee A,Sajjadi S,Pouran S R,et al.Efficient electrochemical generation of hydrogen peroxide by means of plasma-treated graphite electrode and activation in electro-Fenton[J].Journal of Industrial and Engineering Chemistry,2017,56(25):312-320.
[17]CAO Z,ZHENG X,CAO H,et al.Efficient reuse of anode scrap from lithium-ion batteries as cathode for pollutant degradation in electro-Fenton process:Role of different recovery processes[J].Chemical Engineering Journal,DOI:https://doi.org/10.1016/j.cej.2017.12.104.
[18]于琦,梁锦霞.石墨烯制备与功能化应用的研究进展[J].中国科学:化学,2017,47(10):1149-1160.
[19]SHAO Y,SUI J,YIN G,et al.Nitrogen-doped carbon nanostructures and their composites as catalytic materials for proton exchange membrane fuel cell[J].Applied Catalysis B Environmental,2008,79(1):89-99.
[20]TIAN J,GAO F,YU X,et al.Preparation of nitrogen-doped graphene by high-gravity technology and its application in oxygen reduction[J].Particuology,2017,34(5):110-117.
[21]周国珺,叶志凯,石微微,等.三维(3D)石墨烯及其复合材料的应用[J].化学进展,2014,26(6):950-960.
[22]MOUSSET E,WANG Z,HAMMAKER J,et al.Physico-chemical properties of pristine graphene and its performance as electrode material for electro-Fenton treatment of wastewater[J].Electrochimica Acta,2016,214:217-230.
[23]刘霞平,王会才,孙强,等.石墨烯、3D石墨烯及其复合材料的研究进展[J].化工进展,2018,37(1):168-174.
[24]易东,刘秘,周贵方,等.苯酚-三聚氰胺-甲醛气凝胶的制备与表征研究[J].功能材料,2017,48(4):141-144.
[25]刘冬,沈军,李亚捷,等.碳气凝胶的孔结构及其对电化学超级电容器性能的影响[J].物理化学学报,2012,28(4):843-849.
[26]ZHAO H,QIAN L,CHEN Y,et al.Selective catalytic two-electron O2reduction for onsite efficient oxidation reaction in heterogeneous electro-Fenton process[J].Chemical Engineering Journal,2018,332(15):486-498
[27]PENG Q,ZHAO H,QIAN L,et al.Design of a neutral photo-electroFenton system with 3D-ordered macroporous Fe2O3/carbon aerogel cathode:High activity and low energy consumption[J].Applied Catalysis B Environmental,2015,S174/175:157-166.
[28]WEN S,NIU Z,ZHEN Z,et al.In-situ synthesis of 3D GA on titanium wire as a binder-free electrode for electro-Fenton removing of EDTA-Ni[J].Journal of Hazardous Materials,2017,341:128.
[29]HARRELD J,DAVE B C,DUNN B,et al.Synthesis and properties of polypyrrole-vanadium oxide hybrid aerogels[J].Journal of NonCrystalline Solids,1998,225(1):319-324.
[30]DONG W,SAKAMOTO J,DUNN B.Electrochemical properties of vanadium oxide aerogels and aerogel nanocomposites[J].Journal of Sol-Gel Science and Technology,2003,26(1/3):641-644.
[31]蒋婵杰,林志勇,林松柏,等.介孔材料制备及研究进展[J].材料导报,2003,17(11):53-55.
[32]CHEN Y,WANG M,TIAN M,et al.An innovative electro-fenton degradation system self-powered by triboelectric nanogenerator using biomass-derived carbon materials as cathode catalyst[J].Nano Energy,2017,42:314-321.
[33]DO T M,JI Y B,SANG H K.An electro-Fenton system using magnetite coated metallic foams as cathode for dye degradation[J].Catalysis Today,2017,295:48-55.
[34]秦国旭,王新,王新运,等.介孔Zr O2-Ti O2复合材料的制备及电催化还原2-吡啶甲醛性能研究[J].化工新型材料,2016(6):97-100.
[35]ZHANG Y,GAO M,WANG S G,et al.Integrated electro-Fenton process enabled by a rotating Fe3O4/gas diffusion cathode for simultaneous generation and activation of H2O2[J].Electrochimica Acta,2017,231:694-704.