燃煤烟气同时脱硫脱硝技术研究现状与展望
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摘要
以处理方法为主线,综述了干法、湿法同时脱硫脱硝的机理、优缺点及研究现状,并对烟气同时脱硫脱硝技术的发展提出展望。
Focusing on treatment method,this paper reviews the mechanism,advantages,disadvantages and current research status of simultaneous desulfurization and denitrification in dry and wet processes,and proposes a prospect for simultaneous desulfurization and denitrification technology in treating with flue gas.
Focusing on treatment method,this paper reviews the mechanism,advantages,disadvantages and current research status of simultaneous desulfurization and denitrification in dry and wet processes,and proposes a prospect for simultaneous desulfurization and denitrification technology in treating with flue gas.
引文
[1]方宁杰.烟气脱硫脱硝技术的现状和发展趋势[J].四川化工,2016,19(5):29-32.
[2]中国环境科学研究院.GB 13223—2011.火电厂大气污染物排放标准[S].北京:中国环境科学出版社,2012.
[3]史风华.炭基稀土氧化物脱硫脱硝实验研究[D].北京:北京化工大学,2013.
[4]岳菲菲,房姗姗.烟气同时脱硫脱硝技术进展研究[J].环境科学与管理,2016,41(4):57-60.
[5]Xie Y,Chen Y,Ma Y,et al.Investigation of simultaneous adsorption of SO2and NO onγ-alumina at low temperature using DRIFTS[J].Journal of Hazardous Materials,2011,195(195):223-229.
[6]张代生.燃煤烟气脱硫脱硝一体化技术的研究[J].低碳世界,2016,(17):263-264.
[7]李鹏.还原法烟气同时脱硫脱硝催化剂的研究[D].北京:北京化工大学,2014.
[8]Huang L,Dang Y. Removal of SO2,and NOx,by pulsed corona combined with in situ,Ca(OH)2,Absorption[J].Chinese Journal of Chemical Engineering,2011,19(3):518-522.
[9]Basfar A A,Fageeha O I,Kunnummal N,et al.Electron beam flue gas treatment(EBFGT)technology for simultaneous removal of SO2,and NOx,from combustion of liquid fuels[J].Fuel,2008,87(8):1446-1452.
[10]Tan E,nal Suat,Dogan A,et al.New“wet type”electron beam flue gas treatment pilot plant[J]. Radiation Physics&Chemistry,2016,119:109-115.
[11]郭炎鹏,张君,孔春林.等离子烟气硫、硝、汞一体化脱除的中试研究[J].广州化工,2017,(21):61-63,68.
[12]Xu Fei,Luo Zhongyang,Cao Wei,et al. Simultaneous oxidation of NO,SO2and Hg O from flue gas by pulsed corona discharge[J].Journal of Environmental Sciences,2009,21(3):328-332.
[13]党永霞.脉冲电晕结合现场吸收法脱硫脱硝中试实验研究[D].杭州:浙江工业大学,2011.
[14]Xie G,Liu Z,Zhu Z,et al.Simultaneous removal of SO2,and NOx,from flue gas using a CuO/Al2O3,catalyst sorbent:I.Deactivation of SCR activity by SO2,at low temperatures[J]. Journal of Catalysis,2004,224(1):36-41.
[15]李远涛,易红宏,唐晓龙,等.Ni-Cu金属氧化物改性活性炭同时脱硫脱硝性能研究[J].工业安全与环保,2017,43(5):4-8.
[16]Lau L C,Lee K T,Mohamed A R.Effect of operating conditions towards simultaneous removal of SO2,and NO using copper modified rice husk ash:Role as sorbent and catalyst[J].Journal of Environmental Chemical Engineering,2013,1(4):755-761.
[17]王婷,丁林,宋永吉,等.Y2O3/AC催化剂的烟气同时脱硫脱硝性能[J].环境工程学报,2016,10(11):6555-6562.
[18]王禹.络合吸收法烟气同时脱硫脱硝[J].科技视界,2016,(3):183-183.
[19]田雪洁.吸收法烟气同时脱硫脱硝吸收剂的研究[D].北京:北京石油化工学院,2015.
[20]Bei Y,Yang J,Meng G,et al.Study on NO enhanced absorption using FeⅡEDTA in(NH4)2SO3,solution[J].Journal of Industrial&Engineering Chemistry,2014,20(4):2528-2534.
[21]Adewuyi Y G,Khan M A. Nitric oxide removal from flue gas by combined persulfate and ferrous-EDTA solutions:Effects of persulfate and EDTA concentrations,temperature,pH and SO2[J].Chemical Engineering Journal,2016,304:793-807.
[22]Wang J,Zhong W. Simultaneous desulfurization and denitrification of sintering flue gas via composite absorbent[J].Chinese Journal of Chemical Engineering,2016,24(8):1104-1111.
[23]张忠梅,盛洪产,林孝鑫,等.KMnO4氧化复合Na OH液相吸收同时脱硫脱硝的实验研究[J].环境工程,2017,35(8):102-107.
[24]白云峰,李永旺,吴树志,等.钙基吸收剂液相氧化法协同脱硫脱硝试验[J].环境科学学报,2009,29(3):505-510.
[25]Hao R,Zhao Y,Yuan B,et al. Establishment of a novel advanced oxidation process for economical and effective removal of SO2and NO[J].Journal of Hazardous Materials,2016,318:224-232.
[26]Guo S,Lv L,Jia Z,et al.Simultaneous removal of SO2and NOxwith ammonia combined with gas-phase oxidation of NO using ozone[J].Chemical Industry&Chemical Engineering Quarterly,2015,21:29-29.
[27]Wu H G,Jin M,Wang F,et al.Performance of sodium chlorite/urea on simultaneous desulfurization and denitrification in a rotating packed bed[J]. Advanced Materials Research,2014,908:183-186.
[28]Jia Y,Du D,Zhang X,et al. Simultaneous removal of SO2,and NOx,with ammonia absorbent in a packed column[J].Korean Journal of Chemical Engineering,2013,30(9):1735-1740.
[29]谢红银,熊源泉,郑守忠,等.尿素/铵根溶液湿法同时脱硫脱硝特性实验研究[J].西安交通大学学报,2011,45(12):123-128.
[2]中国环境科学研究院.GB 13223—2011.火电厂大气污染物排放标准[S].北京:中国环境科学出版社,2012.
[3]史风华.炭基稀土氧化物脱硫脱硝实验研究[D].北京:北京化工大学,2013.
[4]岳菲菲,房姗姗.烟气同时脱硫脱硝技术进展研究[J].环境科学与管理,2016,41(4):57-60.
[5]Xie Y,Chen Y,Ma Y,et al.Investigation of simultaneous adsorption of SO2and NO onγ-alumina at low temperature using DRIFTS[J].Journal of Hazardous Materials,2011,195(195):223-229.
[6]张代生.燃煤烟气脱硫脱硝一体化技术的研究[J].低碳世界,2016,(17):263-264.
[7]李鹏.还原法烟气同时脱硫脱硝催化剂的研究[D].北京:北京化工大学,2014.
[8]Huang L,Dang Y. Removal of SO2,and NOx,by pulsed corona combined with in situ,Ca(OH)2,Absorption[J].Chinese Journal of Chemical Engineering,2011,19(3):518-522.
[9]Basfar A A,Fageeha O I,Kunnummal N,et al.Electron beam flue gas treatment(EBFGT)technology for simultaneous removal of SO2,and NOx,from combustion of liquid fuels[J].Fuel,2008,87(8):1446-1452.
[10]Tan E,nal Suat,Dogan A,et al.New“wet type”electron beam flue gas treatment pilot plant[J]. Radiation Physics&Chemistry,2016,119:109-115.
[11]郭炎鹏,张君,孔春林.等离子烟气硫、硝、汞一体化脱除的中试研究[J].广州化工,2017,(21):61-63,68.
[12]Xu Fei,Luo Zhongyang,Cao Wei,et al. Simultaneous oxidation of NO,SO2and Hg O from flue gas by pulsed corona discharge[J].Journal of Environmental Sciences,2009,21(3):328-332.
[13]党永霞.脉冲电晕结合现场吸收法脱硫脱硝中试实验研究[D].杭州:浙江工业大学,2011.
[14]Xie G,Liu Z,Zhu Z,et al.Simultaneous removal of SO2,and NOx,from flue gas using a CuO/Al2O3,catalyst sorbent:I.Deactivation of SCR activity by SO2,at low temperatures[J]. Journal of Catalysis,2004,224(1):36-41.
[15]李远涛,易红宏,唐晓龙,等.Ni-Cu金属氧化物改性活性炭同时脱硫脱硝性能研究[J].工业安全与环保,2017,43(5):4-8.
[16]Lau L C,Lee K T,Mohamed A R.Effect of operating conditions towards simultaneous removal of SO2,and NO using copper modified rice husk ash:Role as sorbent and catalyst[J].Journal of Environmental Chemical Engineering,2013,1(4):755-761.
[17]王婷,丁林,宋永吉,等.Y2O3/AC催化剂的烟气同时脱硫脱硝性能[J].环境工程学报,2016,10(11):6555-6562.
[18]王禹.络合吸收法烟气同时脱硫脱硝[J].科技视界,2016,(3):183-183.
[19]田雪洁.吸收法烟气同时脱硫脱硝吸收剂的研究[D].北京:北京石油化工学院,2015.
[20]Bei Y,Yang J,Meng G,et al.Study on NO enhanced absorption using FeⅡEDTA in(NH4)2SO3,solution[J].Journal of Industrial&Engineering Chemistry,2014,20(4):2528-2534.
[21]Adewuyi Y G,Khan M A. Nitric oxide removal from flue gas by combined persulfate and ferrous-EDTA solutions:Effects of persulfate and EDTA concentrations,temperature,pH and SO2[J].Chemical Engineering Journal,2016,304:793-807.
[22]Wang J,Zhong W. Simultaneous desulfurization and denitrification of sintering flue gas via composite absorbent[J].Chinese Journal of Chemical Engineering,2016,24(8):1104-1111.
[23]张忠梅,盛洪产,林孝鑫,等.KMnO4氧化复合Na OH液相吸收同时脱硫脱硝的实验研究[J].环境工程,2017,35(8):102-107.
[24]白云峰,李永旺,吴树志,等.钙基吸收剂液相氧化法协同脱硫脱硝试验[J].环境科学学报,2009,29(3):505-510.
[25]Hao R,Zhao Y,Yuan B,et al. Establishment of a novel advanced oxidation process for economical and effective removal of SO2and NO[J].Journal of Hazardous Materials,2016,318:224-232.
[26]Guo S,Lv L,Jia Z,et al.Simultaneous removal of SO2and NOxwith ammonia combined with gas-phase oxidation of NO using ozone[J].Chemical Industry&Chemical Engineering Quarterly,2015,21:29-29.
[27]Wu H G,Jin M,Wang F,et al.Performance of sodium chlorite/urea on simultaneous desulfurization and denitrification in a rotating packed bed[J]. Advanced Materials Research,2014,908:183-186.
[28]Jia Y,Du D,Zhang X,et al. Simultaneous removal of SO2,and NOx,with ammonia absorbent in a packed column[J].Korean Journal of Chemical Engineering,2013,30(9):1735-1740.
[29]谢红银,熊源泉,郑守忠,等.尿素/铵根溶液湿法同时脱硫脱硝特性实验研究[J].西安交通大学学报,2011,45(12):123-128.