含铬革屑脱铬提取胶原蛋白的研究进展
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摘要
制革含铬革屑的主要成分为胶原蛋白和铬,具有较大的资源化利用价值。国内外对含铬革屑资源化作了大量的工作,提出了氧化法、水解法及结合法等脱铬提取胶原蛋白的技术。为实现含铬革屑资源化,促进制革工业生态化和可持续发展。以含铬革屑脱铬率与胶原蛋白提取率为主要评价指标,简要介绍了各种含铬革屑的资源化技术,分析各种资源化技术的特点与优缺点。提出结合法应为含铬革屑脱铬提取胶原蛋白的最佳方法,并对含铬革屑的资源化利用前景作了展望。
The main components of chrome leather shavings were collagen and chromium,therefore it had greater value of resource utilization.A great deal of work had been done on the resource utilization of chrome leather shavings at home and abroad.The technology of dechroming and extracting collagen from chrome leather shavings had been proposed,such as oxidation,hydrolysis and combination methods.In order to realize resource utilization of chrome leather shavings and promote the ecological and sustainable development of leather industry.In this paper,the dechroming rate and collagen extraction rate were use as main evaluation indexes,the technologies of resource utilization of chrome leather shavings were introduced briefly,and the characteristics,advantages and disadvantages of these technologies were analyzed.The combination method was put forward as the best method for dechroming and extracting collagen from chrome leather shavings,and the prospect of resource utilization of chrome leather shavings was prospected.
The main components of chrome leather shavings were collagen and chromium,therefore it had greater value of resource utilization.A great deal of work had been done on the resource utilization of chrome leather shavings at home and abroad.The technology of dechroming and extracting collagen from chrome leather shavings had been proposed,such as oxidation,hydrolysis and combination methods.In order to realize resource utilization of chrome leather shavings and promote the ecological and sustainable development of leather industry.In this paper,the dechroming rate and collagen extraction rate were use as main evaluation indexes,the technologies of resource utilization of chrome leather shavings were introduced briefly,and the characteristics,advantages and disadvantages of these technologies were analyzed.The combination method was put forward as the best method for dechroming and extracting collagen from chrome leather shavings,and the prospect of resource utilization of chrome leather shavings was prospected.
引文
[1]吕凌云,马兴元,余梅.铬革屑资源化利用的研究进展[J].中国皮革,2011,40(3):49-53.
[2]Chunqi Fang,Xuguang Jiang,Guojun Lv,et al.Nitrogen-containing gaseous products of chrome-tanned leather shavings during pyrolysis and combustion[J].Waste Management,2018,78:553-558.
[3]Katarzyna Fela,Krystyna Wieczorek-Ciurowa,Michal Konopka,et al.Present and prospective leather industry waste disposal[J].Polish Journal of Chemical Technology, 2011,13(3):53-55.
[4]张文斌,王全杰,韩静,等.含铬革屑的再生资源化进展[J].皮革科学与工程,2016,26(2):39-42.
[5]Agustín Marsal,M.Elena Bautista,Albert M.Manich,et al.Use of modified leather shavings in the adsolubilization of 2-naphthol:Thermodynamic and kinetics studies[J]. Chemical Engineering Journal,2013,222:77-84.
[6]Anupama Pati,Rubina Chaudhary,Saravanabhavan Subramani.A review on management of chrometanned leather shavings:a holistic paradigm to combat the environmental issues[J].Environmental Science and Pollution Research,2014,21(19):11266-11282.
[7]L.F.Cabeza,M.M.Taylor,G.L.DiMaio,et al.Processing of leather waste:pilot scale studies on chrome shavings.Isolation of potentially valuable protein products and chromium[J].Waste Management,1998,18:211-218.
[8]韩姣姣,朱剑,但卫华,等.制革含铬废物脱铬方法的进展[J].皮革科学与工程2010,20(1):32-36.
[9]陈驰.利用含铬革屑提取物制备服饰用纤维的研究[D].四川.四川大学,2006:1-92.
[10]L.Chabaane, S.Tahiri, A.Albizane,et al.Immobilization of vegetable tannins on tannery chrome shavings and their use for the removal of hexavalent chromium from contaminated water[J]. Chemical Engineering Journal, 2011,174:310-317.
[11]H.Lakrafli,S.Tahiri,A.Albizane,et al.Effect of wet blue chrome shaving and buffing dust of leather industry on the thermal conductivity of cement and plaster based materials[J]. Construction and Building Materials, 2012,30:590-596.
[12]罗凤香.含铬革屑的资源化利用[J].西部皮革,2014,36(04):28-31.
[13]赵航航,张继林,李琛.制革废弃物资源化利用研究现状[J].西部皮革,2015,37(16):34-37.
[14]周文,但卫华.制革工业含铬革屑资源化利用途径[J].西部皮革,2011,33(18):50-56.
[15]裴海燕.从废弃铬鞣皮屑中提取胶原蛋白类水解物的研究[D].郑州.郑州大学,2002:2-56.
[16]林海,但卫华.制革固体废弃物资源化利用研究进展[J].北京皮革:中外皮革信息版(中),2004,(10):80-84.
[17]Mehmet Erdem.Chromium recovery from chrome shaving generated in tanning process[J].Journal of Hazardous Materials,2006,129:143-146.
[18]孙丹红.超声波对制革过程的影响及含铬废革屑的氧化脱铬[D].四川.四川大学,2003:1-183.
[19]袁文慧.含铬革屑的脱铬水解及回收[D].北京.北京服装学院,2010:1-47.
[20]孙丹红,石碧,曹明蓉.含铬废革屑氧化脱铬方法的研究[J].皮革科学与工程,2002,12(3):31-36.
[21]孙丹红,石碧,彭必雨,等.含铬废革屑在超声波作用下的氧化脱铬[J].四川大学学报(工程科学版),2003,35(6):71-74.
[22]袁文慧,张丽平,李宏伟,等.含铬革屑氧化法脱铬工艺研究[J].皮革与化工,2011,28(2):6-9.
[23]陈驰,但卫华,曾睿,等.含铬革屑氧化脱铬的研究[J].皮革科学与工程,2006,16(2):22-25.
[24]张锐.革屑脱铬提取饲料用胶原肽的研究[D].福建.福建农林大学,2012:1-69.
[25]廖隆理.制革工艺学(上册)[M].北京:科学出版社,2005:300-301.
[26]杨晓峰,李曼尼.革屑水解及应用[J].内蒙古科技与经济,2003,(4):98-98.
[27]王瑞瑞,王鸿儒,废弃胶原制备功能材料的研究进展[J].西部皮革,2017,37(2):57-60.
[28]Daniel Veras Ribeiro,Shi Yung Yuan,Marcio Raymundo Morelli. Effect of Chemically Treated Leather Shaving Addition on Characteristics and Microstructure of OPC Mortars[J]. Materials Research, 2012, 15(1):136-143.
[29] Edivaldo E.Garcia,Cláudia C.M.Kimura,Ariovaldo C.Martins,et al. characteriza-tion of products isolated from chrome shavings[J]. Brazilian Archives of Biology and Technology,1999,42(3):281-290.
[30]马金辉,付丽红.有机酸脱铬机理探讨[J].中国皮革,2007,36(17):23-28.
[31]霍鹏.皮革废料提取皮革明胶中铬的去除研究[D].河北.河北科技大学,2011:1-55.
[32]王希安,付丽红.蓝湿革乳酸脱铬的研究[J].中国皮革,2009,38(1):14-17.
[33]王希安,付丽红.蓝湿革磷酸脱铬的研究[J].西部皮革,2009,31(19):20-24.
[34]杨春江,田荟琳,付丽红.羧基对羟基酸脱铬性能的影响[J].西部皮革,2015,38(7):36-41.
[35]聂林杉,强西怀,章川波.皮革厂固体废弃物处理的进展[J].环境污染与防治,2001,23(5):268-270.
[36]王远亮.铬鞣废皮屑的脱铬方法[J].中国皮革,1990,19(10):4-8.
[37]王鸿儒,向卫林.从铬革屑中提取胶原产物的方法[J].LEATHER CHEMICALS,2001,18(3):6-9.
[38]JIANG Ting-da,ZHANG Chun-ping,QIN Fei.Reclamation treatment of the chrome leather scrap[J].Journal of Environmental Science,2000,12(3):375-379.
[39]曹健,陈秀金,曾实,等.碱法水解脱铬革屑制备胶原蛋白水解物的研究[J].中国皮革,2003,32(21):12-14.
[40]方晓林,徐志刚,王萍,等.废铬革屑的综合回收利用[J].化学研究与应用,2008,20(1):100-103.
[41]苏德强,胡杨,王坤余,等.氢氧化钠水解铬革屑提取水解胶原的研究[J].皮革科学与工程,2008,18(5):8-11.
[42]罗艳华,王全杰,陈沛海. CaO、NaOH对铬革屑水解效果的比较[J].皮革与化工,2017,34(3):1-12.
[43]王兴杰,许长通,王旭.废革屑碱水解条件的研究[J].西部皮革,2012,34(14):14-17.
[44]马宏瑞,孙文岳,周建军.含铬革屑有机酸盐脱铬的研究[J].中国皮革,2017,46(3):11-15.
[45]丁伟,周建飞,廖学品,等.含铬废皮渣脱铬方法的研究进展[J].中国皮革,2012,41(1):48-52.
[46]陈秀金,曹健,魏明,等.碱性蛋白酶水解脱铬革屑制备胶原水解物的研究[J].中国皮革,2004,33(1):42-44.
[47]杜山山,朱晓磊,杜斌斌,等.铬革屑酶解工艺条件的研究[J].西部皮革,2013,35(24):29-32.
[48]张小燕,范晓东,王晓刚,等.铬革屑的酶法提取蛋白质新工艺[J].西北大学学报(自然科学版),2003,33(5):550-553.
[49]蒋旭光,方纯琪,金余其,等.含铬制革废弃物处理的研究现状和研究思路[J].化工进展,2018,39(23):752-760.
[50]黄义.一种从废铬革屑中提取胶原蛋白的工艺方法[P].中国专利:201110201144.X,2013.01.23.
[51]付丽红,张铭让,曲健健,等.利用皮革含铬固体废弃物提取明胶[J].中国皮革,2002,31(19):43-47.
[52]强西怀,冯洪燕,张辉,等.碱酶结合法从废铬革屑中提取胶原蛋白的工艺方法[J].中国皮革,2011,40(1):5-8.
[53]王小卓,温会涛,梁永贤,等.含铬革屑碱酶结合水解提取胶原蛋白[J].西部皮革,2018,40(3):41-45.
[54]张东方,刘晓文,刘彦.碱-酶两步法水解铬革屑工艺条件优化[J].皮革科学与工程,2018,28(5):36-41.
[55]胡杨,刘兰,但卫华,等.酸-酶结合法用于制革含铬废弃物脱铬的研究[J].皮革科学与工程,2010,20(6):47-51.
[56]邵泽恩,谢守岭,李士英.削匀革屑脱铬制造宠物饲料[J].中国皮革,2001,30(19):15-17.
[2]Chunqi Fang,Xuguang Jiang,Guojun Lv,et al.Nitrogen-containing gaseous products of chrome-tanned leather shavings during pyrolysis and combustion[J].Waste Management,2018,78:553-558.
[3]Katarzyna Fela,Krystyna Wieczorek-Ciurowa,Michal Konopka,et al.Present and prospective leather industry waste disposal[J].Polish Journal of Chemical Technology, 2011,13(3):53-55.
[4]张文斌,王全杰,韩静,等.含铬革屑的再生资源化进展[J].皮革科学与工程,2016,26(2):39-42.
[5]Agustín Marsal,M.Elena Bautista,Albert M.Manich,et al.Use of modified leather shavings in the adsolubilization of 2-naphthol:Thermodynamic and kinetics studies[J]. Chemical Engineering Journal,2013,222:77-84.
[6]Anupama Pati,Rubina Chaudhary,Saravanabhavan Subramani.A review on management of chrometanned leather shavings:a holistic paradigm to combat the environmental issues[J].Environmental Science and Pollution Research,2014,21(19):11266-11282.
[7]L.F.Cabeza,M.M.Taylor,G.L.DiMaio,et al.Processing of leather waste:pilot scale studies on chrome shavings.Isolation of potentially valuable protein products and chromium[J].Waste Management,1998,18:211-218.
[8]韩姣姣,朱剑,但卫华,等.制革含铬废物脱铬方法的进展[J].皮革科学与工程2010,20(1):32-36.
[9]陈驰.利用含铬革屑提取物制备服饰用纤维的研究[D].四川.四川大学,2006:1-92.
[10]L.Chabaane, S.Tahiri, A.Albizane,et al.Immobilization of vegetable tannins on tannery chrome shavings and their use for the removal of hexavalent chromium from contaminated water[J]. Chemical Engineering Journal, 2011,174:310-317.
[11]H.Lakrafli,S.Tahiri,A.Albizane,et al.Effect of wet blue chrome shaving and buffing dust of leather industry on the thermal conductivity of cement and plaster based materials[J]. Construction and Building Materials, 2012,30:590-596.
[12]罗凤香.含铬革屑的资源化利用[J].西部皮革,2014,36(04):28-31.
[13]赵航航,张继林,李琛.制革废弃物资源化利用研究现状[J].西部皮革,2015,37(16):34-37.
[14]周文,但卫华.制革工业含铬革屑资源化利用途径[J].西部皮革,2011,33(18):50-56.
[15]裴海燕.从废弃铬鞣皮屑中提取胶原蛋白类水解物的研究[D].郑州.郑州大学,2002:2-56.
[16]林海,但卫华.制革固体废弃物资源化利用研究进展[J].北京皮革:中外皮革信息版(中),2004,(10):80-84.
[17]Mehmet Erdem.Chromium recovery from chrome shaving generated in tanning process[J].Journal of Hazardous Materials,2006,129:143-146.
[18]孙丹红.超声波对制革过程的影响及含铬废革屑的氧化脱铬[D].四川.四川大学,2003:1-183.
[19]袁文慧.含铬革屑的脱铬水解及回收[D].北京.北京服装学院,2010:1-47.
[20]孙丹红,石碧,曹明蓉.含铬废革屑氧化脱铬方法的研究[J].皮革科学与工程,2002,12(3):31-36.
[21]孙丹红,石碧,彭必雨,等.含铬废革屑在超声波作用下的氧化脱铬[J].四川大学学报(工程科学版),2003,35(6):71-74.
[22]袁文慧,张丽平,李宏伟,等.含铬革屑氧化法脱铬工艺研究[J].皮革与化工,2011,28(2):6-9.
[23]陈驰,但卫华,曾睿,等.含铬革屑氧化脱铬的研究[J].皮革科学与工程,2006,16(2):22-25.
[24]张锐.革屑脱铬提取饲料用胶原肽的研究[D].福建.福建农林大学,2012:1-69.
[25]廖隆理.制革工艺学(上册)[M].北京:科学出版社,2005:300-301.
[26]杨晓峰,李曼尼.革屑水解及应用[J].内蒙古科技与经济,2003,(4):98-98.
[27]王瑞瑞,王鸿儒,废弃胶原制备功能材料的研究进展[J].西部皮革,2017,37(2):57-60.
[28]Daniel Veras Ribeiro,Shi Yung Yuan,Marcio Raymundo Morelli. Effect of Chemically Treated Leather Shaving Addition on Characteristics and Microstructure of OPC Mortars[J]. Materials Research, 2012, 15(1):136-143.
[29] Edivaldo E.Garcia,Cláudia C.M.Kimura,Ariovaldo C.Martins,et al. characteriza-tion of products isolated from chrome shavings[J]. Brazilian Archives of Biology and Technology,1999,42(3):281-290.
[30]马金辉,付丽红.有机酸脱铬机理探讨[J].中国皮革,2007,36(17):23-28.
[31]霍鹏.皮革废料提取皮革明胶中铬的去除研究[D].河北.河北科技大学,2011:1-55.
[32]王希安,付丽红.蓝湿革乳酸脱铬的研究[J].中国皮革,2009,38(1):14-17.
[33]王希安,付丽红.蓝湿革磷酸脱铬的研究[J].西部皮革,2009,31(19):20-24.
[34]杨春江,田荟琳,付丽红.羧基对羟基酸脱铬性能的影响[J].西部皮革,2015,38(7):36-41.
[35]聂林杉,强西怀,章川波.皮革厂固体废弃物处理的进展[J].环境污染与防治,2001,23(5):268-270.
[36]王远亮.铬鞣废皮屑的脱铬方法[J].中国皮革,1990,19(10):4-8.
[37]王鸿儒,向卫林.从铬革屑中提取胶原产物的方法[J].LEATHER CHEMICALS,2001,18(3):6-9.
[38]JIANG Ting-da,ZHANG Chun-ping,QIN Fei.Reclamation treatment of the chrome leather scrap[J].Journal of Environmental Science,2000,12(3):375-379.
[39]曹健,陈秀金,曾实,等.碱法水解脱铬革屑制备胶原蛋白水解物的研究[J].中国皮革,2003,32(21):12-14.
[40]方晓林,徐志刚,王萍,等.废铬革屑的综合回收利用[J].化学研究与应用,2008,20(1):100-103.
[41]苏德强,胡杨,王坤余,等.氢氧化钠水解铬革屑提取水解胶原的研究[J].皮革科学与工程,2008,18(5):8-11.
[42]罗艳华,王全杰,陈沛海. CaO、NaOH对铬革屑水解效果的比较[J].皮革与化工,2017,34(3):1-12.
[43]王兴杰,许长通,王旭.废革屑碱水解条件的研究[J].西部皮革,2012,34(14):14-17.
[44]马宏瑞,孙文岳,周建军.含铬革屑有机酸盐脱铬的研究[J].中国皮革,2017,46(3):11-15.
[45]丁伟,周建飞,廖学品,等.含铬废皮渣脱铬方法的研究进展[J].中国皮革,2012,41(1):48-52.
[46]陈秀金,曹健,魏明,等.碱性蛋白酶水解脱铬革屑制备胶原水解物的研究[J].中国皮革,2004,33(1):42-44.
[47]杜山山,朱晓磊,杜斌斌,等.铬革屑酶解工艺条件的研究[J].西部皮革,2013,35(24):29-32.
[48]张小燕,范晓东,王晓刚,等.铬革屑的酶法提取蛋白质新工艺[J].西北大学学报(自然科学版),2003,33(5):550-553.
[49]蒋旭光,方纯琪,金余其,等.含铬制革废弃物处理的研究现状和研究思路[J].化工进展,2018,39(23):752-760.
[50]黄义.一种从废铬革屑中提取胶原蛋白的工艺方法[P].中国专利:201110201144.X,2013.01.23.
[51]付丽红,张铭让,曲健健,等.利用皮革含铬固体废弃物提取明胶[J].中国皮革,2002,31(19):43-47.
[52]强西怀,冯洪燕,张辉,等.碱酶结合法从废铬革屑中提取胶原蛋白的工艺方法[J].中国皮革,2011,40(1):5-8.
[53]王小卓,温会涛,梁永贤,等.含铬革屑碱酶结合水解提取胶原蛋白[J].西部皮革,2018,40(3):41-45.
[54]张东方,刘晓文,刘彦.碱-酶两步法水解铬革屑工艺条件优化[J].皮革科学与工程,2018,28(5):36-41.
[55]胡杨,刘兰,但卫华,等.酸-酶结合法用于制革含铬废弃物脱铬的研究[J].皮革科学与工程,2010,20(6):47-51.
[56]邵泽恩,谢守岭,李士英.削匀革屑脱铬制造宠物饲料[J].中国皮革,2001,30(19):15-17.