黄腐酸分级及结构研究
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摘要
简述了黄腐酸的性质和应用,介绍了国内外黄腐酸的分级方法研究进展,并对各种分级方法的优缺点进行比较。分析了凝胶、透析和超滤等现代技术在黄腐酸分级中的应用,归纳总结了黄腐酸分级后活性组分在各级分中分布特征,最后对分级与分离技术发展前景进行展望。
The properties and applications of fulvic acid are briefly described. The research progress of classification methods of fulvic acid at home and abroad is introduced,and the advantages and disadvantages of various classification methods are compared. The applications of gel,dialysis and ultrafiltration in the grading of fulvic acid were analyzed,and the distribution characteristics of the active components at different levels after the grading of fulvic acid were summarized. Finally,the prospect of classification and separation technology is prospected.
The properties and applications of fulvic acid are briefly described. The research progress of classification methods of fulvic acid at home and abroad is introduced,and the advantages and disadvantages of various classification methods are compared. The applications of gel,dialysis and ultrafiltration in the grading of fulvic acid were analyzed,and the distribution characteristics of the active components at different levels after the grading of fulvic acid were summarized. Finally,the prospect of classification and separation technology is prospected.
引文
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[7]刘诚仪,袁申元,朱良湘,等.不同分子量黄腐酸钠对家兔血浆环磷酸腺苷和皮质醇影响的初步研究[J].锦州医科大学学报,1983(1):18-21.
[8]张德和,宋恩兰,杨国仪,等.风化煤黄腐酸的结构表征[J].化学学报,1981(5):22-30.
[9]陈荣峰,王天立,林素凤,等.风化煤黄腐酸的凝胶分级及结构特征[J].化学通报,1980(6):19-25.
[10] Anderson H A,Hepburn A. Fractionation of humic acid by gel permeation chromatography[J]. European Journal of Soil Science,1977,28(4):634-644.
[11] Qin Y,Zhu H,Zhang M,et al. GC-MS Analysis of membrane-graded fulvic acid and its activity on promoting wheat seed germination[J]. Molecules,2016,21(10):1363-1374.
[12]朱辉,孙家英,杜惠蓉,等.不同产地膜分级乙醇溶解黄腐酸挥发性化学成分对比分析[J].分析试验室,2017(5):518-522.
[13]张水花,刘建珍,李宝才,等.化学法降解云南年青褐煤制备药用黄腐酸的化学组成及结构表征[C]//第七届全国绿色环保肥料(农药)新技术,新产品交流会论文集.北京:中国腐殖酸工业协会,2009.
[14] Li L,Zhao Z,Huang W,et al. Characterization of humic acids fractionated by ultrafiltration[J]. Organic Geochemistry,2004,35(9):1025-1037.
[15] Li J,Liu H,Zhao X,et al. Effect of preozonation on the characteristic transformation of fulvic acid and its subsequent trichloromethane formation potential:Presence or absence of bicarbonate[J]. Chemosphere,2008,71(9):1639-1645.
[16]张静茹.包头矿区土壤腐殖酸的分离、提取及其与稀土离子吸附络合反应研究[D].呼和浩特:内蒙古工业大学,2015.
[17] Schellekens J,Buurman P,Kalbitz K,et al. Molecular features of humic acids and fulvic acids from contrasting environments[J]. Environmental Science&Technology,2017,51(3):1330-1339.
[18]文鹏丽.风化煤中黄腐酸提取关键技术的研究[D].太原:山西大学,2012.
[2] Zhou Y,Zhang Y,Li G,et al. Effects of metal cations on the fulvic acid(FA)adsorption onto natural iron oxide in iron ore pelletizing process[J]. Powder Technology,2016,302:90-99.
[3] Xiaoli C,Shimaoka T,Qiang G,et al. Characterization of humic and fulvic acids extracted from landfill by elemental composition,C CP/MAS NMR and TMAH-Py-GC/MS[J]. Waste Management,2008,28(5):896-903.
[4] Li L,Qi G,Wang B,et al. Fulvic acid anchored layered double hydroxides:A multifunctional composite adsorbent for the removal of anionic dye and toxic metal[J]. Journal of Hazardous Materials,2017,343(5):19-28.
[5]周莉娜,孙丽蓉,毛晖,等.黄腐酸抗旱营养剂对小麦和玉米生长的影响[J].干旱地区农业研究,2012,30(1):154-158.
[6] Cornejo A,Jiménez J M,Caballero L,et al. Fulvic acid inhibits aggregation and promotes disassembly of tau fibrils associated with Alzheimer’s disease[J]. Journal of Alzheimers Disease Jad,2011,27(1):143-145.
[7]刘诚仪,袁申元,朱良湘,等.不同分子量黄腐酸钠对家兔血浆环磷酸腺苷和皮质醇影响的初步研究[J].锦州医科大学学报,1983(1):18-21.
[8]张德和,宋恩兰,杨国仪,等.风化煤黄腐酸的结构表征[J].化学学报,1981(5):22-30.
[9]陈荣峰,王天立,林素凤,等.风化煤黄腐酸的凝胶分级及结构特征[J].化学通报,1980(6):19-25.
[10] Anderson H A,Hepburn A. Fractionation of humic acid by gel permeation chromatography[J]. European Journal of Soil Science,1977,28(4):634-644.
[11] Qin Y,Zhu H,Zhang M,et al. GC-MS Analysis of membrane-graded fulvic acid and its activity on promoting wheat seed germination[J]. Molecules,2016,21(10):1363-1374.
[12]朱辉,孙家英,杜惠蓉,等.不同产地膜分级乙醇溶解黄腐酸挥发性化学成分对比分析[J].分析试验室,2017(5):518-522.
[13]张水花,刘建珍,李宝才,等.化学法降解云南年青褐煤制备药用黄腐酸的化学组成及结构表征[C]//第七届全国绿色环保肥料(农药)新技术,新产品交流会论文集.北京:中国腐殖酸工业协会,2009.
[14] Li L,Zhao Z,Huang W,et al. Characterization of humic acids fractionated by ultrafiltration[J]. Organic Geochemistry,2004,35(9):1025-1037.
[15] Li J,Liu H,Zhao X,et al. Effect of preozonation on the characteristic transformation of fulvic acid and its subsequent trichloromethane formation potential:Presence or absence of bicarbonate[J]. Chemosphere,2008,71(9):1639-1645.
[16]张静茹.包头矿区土壤腐殖酸的分离、提取及其与稀土离子吸附络合反应研究[D].呼和浩特:内蒙古工业大学,2015.
[17] Schellekens J,Buurman P,Kalbitz K,et al. Molecular features of humic acids and fulvic acids from contrasting environments[J]. Environmental Science&Technology,2017,51(3):1330-1339.
[18]文鹏丽.风化煤中黄腐酸提取关键技术的研究[D].太原:山西大学,2012.