国产T700S碳纤维增强复合材料压力容器的成型工艺
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摘要
分别采用扫描电子显微镜、傅立叶变换红外光谱仪对国产T700S碳纤维表面形貌及表面涂层进行了表征,通过NOL环实验对两种树脂体系进行优选,找到了一种与国产T700S碳纤维匹配性较好的树脂体系,然后设计正交试验,对影响?150 mm复合材料压力容器成型的因素设置了不同的水平,通过正交试验比较,最终确定缠绕张力为40~50 N﹑封头补强方式为碳布补强环补强﹑胶槽温度55~60℃、刮胶板和滚胶筒间隙0.15~0.20 mm、缠绕后处理方式为玻璃布带环向/螺旋向各缠绕1层时,制作的复合材料压力容器特性指数最高(37.5 km),可作为国产T700S碳纤维进一步工程化应用的参考。
Using scanning electron microscopy and fourier transform infrared spectroscopy,the surface morphology and coating of domestic T700 S carbon fiber were characterized. By the NOL ring experiment, two kinds of resin system were optimized,and a better matching between the domestic T700 S carbon fiber and the resin system was found. By orthogonal test,the different levels for influence factors according to ?150 mm composite pressure vessel manufacturing process were set,through orthogonal test,the optimum conditions of the composite pressure vessels forming process were determined :the winding tension is 40~50 N,the type of dome reinforcement is carbon cloth ring reinforcing,the temperature of glue tank is 55~60℃,the gap between fractioning plate and roller is 0.15~0.20 mm,the type of winding postprocessing is one spiral-winding and one hoop-winding respectively using glass fiber strap,the vessel characteristic index value of the composite pressure vessels produced under the optimal conditions is highest(37.5 km). This work can be served as references for further application of the domestic T700 S carbon fiber.
Using scanning electron microscopy and fourier transform infrared spectroscopy,the surface morphology and coating of domestic T700 S carbon fiber were characterized. By the NOL ring experiment, two kinds of resin system were optimized,and a better matching between the domestic T700 S carbon fiber and the resin system was found. By orthogonal test,the different levels for influence factors according to ?150 mm composite pressure vessel manufacturing process were set,through orthogonal test,the optimum conditions of the composite pressure vessels forming process were determined :the winding tension is 40~50 N,the type of dome reinforcement is carbon cloth ring reinforcing,the temperature of glue tank is 55~60℃,the gap between fractioning plate and roller is 0.15~0.20 mm,the type of winding postprocessing is one spiral-winding and one hoop-winding respectively using glass fiber strap,the vessel characteristic index value of the composite pressure vessels produced under the optimal conditions is highest(37.5 km). This work can be served as references for further application of the domestic T700 S carbon fiber.
引文
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[2]罗益峰.世界PAN基碳纤维发展透析及对我国的研发建议[J].材料导报,2000,14(11):11–13.Luo Yifeng.Developing analysis of world’s PAN-based carbon fibers and it’s R&D suggestions in China[J].Materials Review,2000,14(11):11–13.
[3]张凤翻,申屠年.国产碳纤维规模化应用值得注意的几个工艺性问题[J].高科技纤维与应用,2008,33(3):1–4.Zhang Fengfan,Shen Tunian.Noteworthy technology problems of carbon fibers in the large scale application[J],Hi-Tech Fiber&Application,2008,33(3):1–4.
[4]罗益峰,申屠年.2007年中国高性能纤维展望[J].高科技纤维与应用,2007,32(1):1–3.Luo Yifeng,Shen Tunian.Prospects for China high performance fibers in 2007[J],Hi-Tech Fiber&Application,2007,32(1):1–3.
[5]徐樑华.高性能PAN基碳纤维国产化进展及发展趋势[J].中国材料进展,2012,31(10):7–13.Xu Lianghua.Development and trends of PAN-based high performance carbon fiber in China[J].Materials China,2012,31(10):7–13.
[6]冯闻,徐樑华.围绕市场发展国产碳纤维制备及其应用技术[J].高科技纤维与应用,2013,38(3):12–24.Feng Wen,Xu Lianghua.Based on the market to develop manufacture and application technologies of the native carbon fiber[J].HiTech Fiber&Application,2013,38(3):12–24.
[7]李崇俊,刘建军,刘勇琼,等.高性能聚丙烯腈基碳纤维工程化研制及应用进展[J].高科技纤维与应用,2011,36(5):7–14.Li Chongjun,Liu Jianjun,Liu Yongqiong,et al.An engineering manufacturing and application of PAN-based carbon fibers[J].HiTech Fiber&Application,2011,36(5):7–14.
[8]石峰晖,代志双,张宝艳.碳纤维表面性质分析及其对复合材料界面性能的影响[J].航空材料学报,2010,30(3):43–47.Shi Fenghui,Dai Zhishuang,Zhang Baoyan.Properties of carbon fibers and interfacial properties of carbon fibers reinforced matrix composite[J].Journal of Aeronautical Materials,2010,30(3):43–47.
[9]罗云烽,李阳,肇研,等.国产T800级炭纤维表面特性及其复合材料微观界面性能[J].材料工程,2014(9):83–88.Luo Yunfeng,Li Yang,Zhao Yan,et al.Surface characteristics of domestic T800-grade carbon fibers and microscopic interphase properties of composites[J].Journal of Materials Engineering,2014(9):83–88.
[10]陈淙洁,张明,王春红,等.四种碳纤维表面理化特性研究[J].玻璃钢/复合材料,2012(S1):73–80.Chen Zongjie,Zhang Ming,Wang Chunhong,et al.Study on surface physicochemical properties of four types carbon fibers[J].Fiber Reinforced Plastics/Composites Supplement,2012(S1):73–80.
[11]崔荣庆,谌磊,李春红,等.电化学氧化处理对PAN基碳纤维表面浸润性的影响[J].材料导报,2012,26(1):40–48.Cui Rongqing,Chen Lei,Li Chunhong,et al.Study on wettability of electrochemically oxidized PAN-based carbon fibers[J].Materials Review,2012,26(1):40–48.
[12]钱鑫,支建海,张永刚,等.炭纤维表面化学结构对其增强环氧树脂基复合材料性能的影响[J].材料工程,2014(6):84–88.Qian Xin,Zhi Jianhai,Zhang Yonggang,et al.Effect of surface chemical structure of carbon fiber/epoxy composites[J].Journal of Marerials Engineering,2014(6):84–88.
[13]管培强,李艳霞,李敏,等.碳纤维环氧界面相准静态纳米压痕表征方法分析[J].玻璃钢/复合材料,2012(6):23–27.Guan Peiqiang,Li Yanxia,Li Min,et al.Characterization on the interphase of carbon fiber/epoxy resin composites using the nanoindentation method[J].Fiber Reinforced Plastics/Composites,2012(6):23–27.
[14]王百亚,张康助,雷海峰,等.F-12纤维/RE14复合材料压力容器成型工艺研究[J].宇航材料工艺,2003,33(4):39–42.Wang Baiya,Zhang Kangzhu,Lei Haifeng,et al.A study of manufacturing process for F-12 fiber/RE14 composite pressure vessels[J].Aerospace Materials&Technology,2003,33(4):39–42.
[15]王晓洁,张炜,谢群炜.热塑性树脂改性环氧基体配方研究[J].宇航材料工艺,1999,29(2):21–23.Wang Xiaojie,Zhang Wei,Xie Qunwei.Research on epoxy system modified by thermoplastic resin[J].Aerospace Materials&Technology,1999,29(2):21–23.
[16]陈平,蹇锡高,陈辉.碳纤维复合材料发动机壳体用韧性环氧树脂基体的研究[J].复合材料学报,2002(2):24–27.Chen Ping,Jian Xigao,Chen Hui.Study for toughened epoxy resins matrix for carbon fibercomposite motor case[J].Acta Materiae Compositae Sinica,2002(2):24–27.
[17]郭峰,张炜,王晓洁,等.碳纤维/环氧固体火箭发动机壳体补强现状[J].纤维复合材料,2008,35(3):35–38.Guo Feng,Zhang Wei,Wang Xiaojie,et al.The present reinforcement state of carbon fiber/epoxy solid rocket motor shell[J].Fiber Composites,2008,35(3):35–38.
[18]王晓洁,张炜,刘炳禹.碳纤维湿法缠绕基体配方及成型研究[J].固体火箭技术,2001,24(1):60–63.Wang Xiaojie,Zhang Wei,Liu Bingyu.Study on the matrix formulation and forming for carbon fiber composites in wet-winding process[J].Journal of Solid Rocket Technology,2001,24(1):60–63.
[19]王晓洁,梁国正,李辅安,等.T–1000碳纤维/环氧树脂基复合材料性能研究[J].材料科学与工艺,2005,13(5):540–543.Wang Xiaojie,Liang Guozheng,Li Fuan,et al.Study on the property of T–1000 carbon fiber/epoxy resin composite[J].Materials Science and Technology,2005,13(5):540–543.
[20]黄业青,张康助,王晓洁.碳纤维湿法缠绕用环氧树脂基体研究[J].热固性树脂,2007,22(1):27–29.Wang Yeqing,Zhang Kangzhu,Wang Xiaojie.Research on epoxy resin matrix/carbon fiber composite by wet winding[J].Thermosetting Resin,2007,22(1):27–29.