吸附法处理地下水污染的应用研究进展
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摘要
随着全球工业化的高速发展和人类活动的加剧,地下水的污染日益严重,主要污染物有无机离子和有机大分子物质,在众多治理地下水污染的方法中,吸附法以成本低、工艺简单、吸附速率快、处理效果显著等特点被广泛应用。综述了碳质吸附剂、矿物材料吸附剂、生物材料吸附剂、电吸附法的特性、作用机理和应用于地下水污染的研究现状,并对今后吸附剂处理地下水污染的发展前景提出建议。
The contamination of groundwater is becoming more and more serious, which is mainly caused by the industrialization and human activities. Inorganic ions and organic macromolecule are the main pollutant. The adsorption method has been widely used to treat groundwater contamination due to its low cost, simple process, high removal efficiency and significant effects. In this paper, characteristics and mechanisms of carbonaceous adsorbents, mineral material adsorbents, biological material adsorbents and electric absorption were introduced as well as their application in groundwater pollution treatment. Finally, some suggestions on the development of adsorbents for treating groundwater contamination were put forward.
The contamination of groundwater is becoming more and more serious, which is mainly caused by the industrialization and human activities. Inorganic ions and organic macromolecule are the main pollutant. The adsorption method has been widely used to treat groundwater contamination due to its low cost, simple process, high removal efficiency and significant effects. In this paper, characteristics and mechanisms of carbonaceous adsorbents, mineral material adsorbents, biological material adsorbents and electric absorption were introduced as well as their application in groundwater pollution treatment. Finally, some suggestions on the development of adsorbents for treating groundwater contamination were put forward.
引文
[1]唐朝春,陈惠民,叶鑫,等.吸附法去除地下水铁锰的研究进展[J].长江科学学院院报,2016,33(6):18-23.
[2]Ma Weifang,Liu Fang,Cheng Xiang,et al.Environmental evaluation of the application of compost sewage sludge to landscaping as soil amendments:a field experiment on the grassland soils in Beijing[J].Desalination and Water Treatment,2015,54(4/5):1118-1126.
[3]Fenglian Fu,Qi Wang.Removal of heavy metal ions from wastewaters:A reviw[J].Journal of Environmental Management,2011,92(3):407-418.
[4]陈秀成,曹瑞钰.地下水污染治理技术的进展[J].中国给水排水,2001,17(4):23-26.
[5]陈志冉,闫凯.活性炭对地下水中锰的动态吸附实验研究[J].工业安全与环保,2013,39(5):17-19.
[6]沙雯雯.油田地下水中有机污染物分析与去除方法研究[D].沈阳:沈阳师范大学,2012.
[7]陈桥,宋召军,芦清水,等.碳吸附对海水入侵区地下水氟及其他性质影响[J].科学技术与工程,2014,14(17):260-264.
[8]李冰璟,胡娟,左军,等.生物活性炭吸附工艺去除地下水中甲基叔丁基醚的可行性研究[J].环境污染与防治,2011,33(3):20-27.
[9]陈芳.氧化与吸附联用处理高铁锰微污染地下水研究[D].沈阳:沈阳建筑大学,2012.
[10]刘广阳.粉末活性炭-膜生物反应器处理含铁、含锰、含氨氮地下水研究[D].黑龙江:哈尔滨工业大学,2015.
[11]马琳.砷污染地下水修复的渗透反应墙材料筛选及除砷机理研究[D].武汉:华中农业大学,2010.
[12]王慧敏,岳建华,黄建洪,等.天然浮石去除水中As(V)的试验研究[J].安全与环境学报,2015,15(5):214-218.
[13]唐朝春,段先月,叶鑫,等.天然沸石处理地下水中铁锰吸附性能研究[J].长江科学学院院报,2016,33:1-5.
[14]曾婧滢,秦迪岚,毕军平,等.天然矿物组合材料渗透反应墙修复地下水镉污染[J].环境工程学报,2014,8(6):2435-2442.
[15]李浙英.化学与生物成因施氏矿物的矿物学特征及其对水中As(Ⅲ)吸附去除效果的研究[D].南京:南京农业大学,2010.
[16]Schwertmann U,Bigham J M,Murad E.The first occurrence of schwertmannite in a natural stream environment[J].European Journal of Mineralogy,1995,7:547-552.
[17]冯海刚,井柳新,李頔.天然矿物吸附地下水中重金属的研究进展[J].水处理技术,2011,37(11):1-4.
[18]张颖,鲁岩,赵佳英.稻壳灰对地下水中铁离子动态吸附研究[J].东北农业大学学报,2015,46(10):68-73.
[19]赖坤容,李梦耀,周维博.壳聚糖对高锰地下水的吸附研究[J].应用化工,2010,39(8):1167-1169.
[20]N.Viswanathan,S Meenakshi.Development of chitosan supported zirconium(Ⅳ)tungstophosphate composite for fluoride removal[J].Journal of Hazardous Materials,2010,176(1):459-465.
[21]余宙.改性壳聚糖对地下水重金属吸附性能研究[D].上海:上海交通大学,2010.
[22]游亚平,陈丽芳,周志华等.去除地下水中铁锰的复合微生物材料制备[J].安全与环境学报,2011,11(6):53-56.
[23]郭学军,陈甫华.载铁棉纤维素吸附剂固定床去除地下水砷[J].化工学报,2005,56(9):1757-1764.
[24]刘海静,张鸿涛,孙晓慰.电吸附法去除地下水中离子的试验研究[J].中国给水排水,2003,19(11):36-38.
[25]梁峰,邹国防,朱慧杰.简易板式电极法去除地下水中As(Ⅲ)[J].过程工程学报,2016,16(5):751-756.
[26]孙文童.碳气凝胶电吸附水中F-的研究[D].北京:北京林业大学.2014.
[27]胡欣琪,杨硕,张旭,等.电增强载铝活性炭纤维吸附除氟的效果与影响因素[J].环境工程学报,2013,7(3):951-956.
[28]黄玉洁,张焕祯,等.改性粉煤灰处理含铬(Ⅵ)地下水的实验研究[J].环境工程,2012,30(增刊):20-22.
[29]郑玉虎,吴明洲,徐爱兰,等.电考虑土壤吸附作用的地下水污染物运移特征研究[J].地下水,2017,39(3):4-7.
[30]崔自敏.铁铝复合吸附剂共除地下水中砷和氟的研究[D].黑龙江:哈尔滨工业大学,2011.
[2]Ma Weifang,Liu Fang,Cheng Xiang,et al.Environmental evaluation of the application of compost sewage sludge to landscaping as soil amendments:a field experiment on the grassland soils in Beijing[J].Desalination and Water Treatment,2015,54(4/5):1118-1126.
[3]Fenglian Fu,Qi Wang.Removal of heavy metal ions from wastewaters:A reviw[J].Journal of Environmental Management,2011,92(3):407-418.
[4]陈秀成,曹瑞钰.地下水污染治理技术的进展[J].中国给水排水,2001,17(4):23-26.
[5]陈志冉,闫凯.活性炭对地下水中锰的动态吸附实验研究[J].工业安全与环保,2013,39(5):17-19.
[6]沙雯雯.油田地下水中有机污染物分析与去除方法研究[D].沈阳:沈阳师范大学,2012.
[7]陈桥,宋召军,芦清水,等.碳吸附对海水入侵区地下水氟及其他性质影响[J].科学技术与工程,2014,14(17):260-264.
[8]李冰璟,胡娟,左军,等.生物活性炭吸附工艺去除地下水中甲基叔丁基醚的可行性研究[J].环境污染与防治,2011,33(3):20-27.
[9]陈芳.氧化与吸附联用处理高铁锰微污染地下水研究[D].沈阳:沈阳建筑大学,2012.
[10]刘广阳.粉末活性炭-膜生物反应器处理含铁、含锰、含氨氮地下水研究[D].黑龙江:哈尔滨工业大学,2015.
[11]马琳.砷污染地下水修复的渗透反应墙材料筛选及除砷机理研究[D].武汉:华中农业大学,2010.
[12]王慧敏,岳建华,黄建洪,等.天然浮石去除水中As(V)的试验研究[J].安全与环境学报,2015,15(5):214-218.
[13]唐朝春,段先月,叶鑫,等.天然沸石处理地下水中铁锰吸附性能研究[J].长江科学学院院报,2016,33:1-5.
[14]曾婧滢,秦迪岚,毕军平,等.天然矿物组合材料渗透反应墙修复地下水镉污染[J].环境工程学报,2014,8(6):2435-2442.
[15]李浙英.化学与生物成因施氏矿物的矿物学特征及其对水中As(Ⅲ)吸附去除效果的研究[D].南京:南京农业大学,2010.
[16]Schwertmann U,Bigham J M,Murad E.The first occurrence of schwertmannite in a natural stream environment[J].European Journal of Mineralogy,1995,7:547-552.
[17]冯海刚,井柳新,李頔.天然矿物吸附地下水中重金属的研究进展[J].水处理技术,2011,37(11):1-4.
[18]张颖,鲁岩,赵佳英.稻壳灰对地下水中铁离子动态吸附研究[J].东北农业大学学报,2015,46(10):68-73.
[19]赖坤容,李梦耀,周维博.壳聚糖对高锰地下水的吸附研究[J].应用化工,2010,39(8):1167-1169.
[20]N.Viswanathan,S Meenakshi.Development of chitosan supported zirconium(Ⅳ)tungstophosphate composite for fluoride removal[J].Journal of Hazardous Materials,2010,176(1):459-465.
[21]余宙.改性壳聚糖对地下水重金属吸附性能研究[D].上海:上海交通大学,2010.
[22]游亚平,陈丽芳,周志华等.去除地下水中铁锰的复合微生物材料制备[J].安全与环境学报,2011,11(6):53-56.
[23]郭学军,陈甫华.载铁棉纤维素吸附剂固定床去除地下水砷[J].化工学报,2005,56(9):1757-1764.
[24]刘海静,张鸿涛,孙晓慰.电吸附法去除地下水中离子的试验研究[J].中国给水排水,2003,19(11):36-38.
[25]梁峰,邹国防,朱慧杰.简易板式电极法去除地下水中As(Ⅲ)[J].过程工程学报,2016,16(5):751-756.
[26]孙文童.碳气凝胶电吸附水中F-的研究[D].北京:北京林业大学.2014.
[27]胡欣琪,杨硕,张旭,等.电增强载铝活性炭纤维吸附除氟的效果与影响因素[J].环境工程学报,2013,7(3):951-956.
[28]黄玉洁,张焕祯,等.改性粉煤灰处理含铬(Ⅵ)地下水的实验研究[J].环境工程,2012,30(增刊):20-22.
[29]郑玉虎,吴明洲,徐爱兰,等.电考虑土壤吸附作用的地下水污染物运移特征研究[J].地下水,2017,39(3):4-7.
[30]崔自敏.铁铝复合吸附剂共除地下水中砷和氟的研究[D].黑龙江:哈尔滨工业大学,2011.