石墨烯在防腐防污涂料中的应用进展
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摘要
石墨烯具有极好的阻隔性能、屏蔽性能及化学稳定性,其在防腐防污涂料中的应用已经被深入研究。介绍了石墨烯对防腐防污涂层性能的影响:降低水、氧气等腐蚀介质的渗透率,加强抗生物附着性,抑制微生物腐蚀。分析了石墨烯在涂料中的应用缺陷及产生原因:极强的范德华力导致石墨烯在涂料中分散性差、易团聚,高化学稳定性及疏水性导致石墨烯与成膜物质结合性差,超高的导电性导致石墨烯膜在失效时加速金属腐蚀。综述了为应对石墨烯在防腐防污涂料中的应用缺陷,国内外学者采用的主要方法:采用改性处理方法制备改性石墨烯(GO、RGO、FG)以及合成石墨烯复合颗粒(石墨烯修饰纳米粒子,即GO-Al_2O_3颗粒、GO-TiO_2颗粒、GO-SiO_2颗粒等;树脂负载石墨烯复合填料,即石墨烯/聚苯胺复合填料等)。最后展望了石墨烯及其衍生物在防腐防污涂料中的发展。
Graphene has excellent barrier, shielding and chemical stability, the application of graphene in anti-corrosion and anti-fouling coatings has been deeply studied. Studies have shown that adding a certain amount of graphene to traditional coatings can significantly reduce the permeability to corrosive media such as water, oxygen, etc., and can enhance the bioadhesion of coatings and inhibit microbial corrosion. However, some disadvantages also appear in applications of graphene. For example,the strong van der Waals force between graphene lamellae leads to poor agglomeration and dispersion of graphene in coatings;the high chemical stability and hydrophobicity of graphene lead to poor adhesion between graphene and film-forming materials;and the superconductivity of graphene leads to the acceleration of metal corrosion when graphene film fails. In order to diminish the disadvantages of graphene during application, many methods have been explored, in which modified graphene(GO, RGO,FG) and synthetic graphene composite particles(graphene modified nanoparticles: GO-Al_2O_3 particles, GO-TiO_2 particles,GO-SiO_2 particles, etc.; resin-supported graphene composite filler: graphene/polyaniline composite filler, etc.) are main methods. Finally, the development of graphene and its derivatives in anticorrosive and antifouling coatings is prospected.
Graphene has excellent barrier, shielding and chemical stability, the application of graphene in anti-corrosion and anti-fouling coatings has been deeply studied. Studies have shown that adding a certain amount of graphene to traditional coatings can significantly reduce the permeability to corrosive media such as water, oxygen, etc., and can enhance the bioadhesion of coatings and inhibit microbial corrosion. However, some disadvantages also appear in applications of graphene. For example,the strong van der Waals force between graphene lamellae leads to poor agglomeration and dispersion of graphene in coatings;the high chemical stability and hydrophobicity of graphene lead to poor adhesion between graphene and film-forming materials;and the superconductivity of graphene leads to the acceleration of metal corrosion when graphene film fails. In order to diminish the disadvantages of graphene during application, many methods have been explored, in which modified graphene(GO, RGO,FG) and synthetic graphene composite particles(graphene modified nanoparticles: GO-Al_2O_3 particles, GO-TiO_2 particles,GO-SiO_2 particles, etc.; resin-supported graphene composite filler: graphene/polyaniline composite filler, etc.) are main methods. Finally, the development of graphene and its derivatives in anticorrosive and antifouling coatings is prospected.
引文
[1]BUNCH J S,VERBRIDGE S S,ALDEN J S,et al.Impermeable atomic membranes from graphene sheets[J].Nano letters,2008,8(8):2458-2462.
[2]SREEVATSA S,BANERJEE A,HAIM G.Graphene as a permeable ionic barrier[J].Ecs transactions,2009,19(5):259-264.
[3]YU L,LIM Y S,HAN J H,et al.A graphene oxide oxygen barrier film deposited via a self-assembly coating method[J].Synthetic metals,2012,162(7-8):710-714.
[4]HASLAM G E,CHIN X Y,BURSTEIN G T.Passivity and electrocatalysis of nanostructured nickel encapsulated in carbon[J].Physical chemistry chemical physics,201113(28):12968-12974.
[5]COMPTON O C,SOYOUNG K,CYNTHIA P,et al.Crumpled graphene nanosheets as highly effective barrier property enhancers[J].Advanced materials,2010,22(42):4759-4763.
[6]YANG Y,LAURA B,PRIOLO M A,et al.Super gas barrier and selectivity of graphene oxide-polymer multilayer thin films[J].Advanced materials,2013,25(4):503-508.
[7]UNALAN I U,WAN C,FIGIEL?,et al.Exceptional oxygen barrier performance of pullulan nanocomposites with ultra-low loading of graphene oxide[J].Nanotechnology,2015,26(27):275703.
[8]YOUSEFI N,GUDARZI M M,ZHENG Q,et al.Highly aligned,ultralarge-size reduced graphene oxide/polyurethane nanocomposites:Mechanical properties and moisture permeability[J].Composites part A applied science&manufacturing,2013,49:42-50.
[9]LI J,CUI J,YANG J,et al.Reinforcement of graphene and its derivatives on the anticorrosive properties of waterborne polyurethane coatings[J].Composites science&technology,2016,129:30-37.
[10]DAFFORN K A,LEWIS J A,JOHNSTON E L.Antifouling strategies:history and regulation,ecological impacts and mitigation[J].Marine pollution bulletin,2011,62(3):453-465.
[11]JELVESTAM M,EDRUD S,PETRONIS S,et al.Biomimetic materials with tailored surface micro-architecture for prevention of marine biofouling[J].Surface&interface analysis,2003,35(2):168-173.
[12]ZHAO Q,LIU Y,WANG C,et al.Effect of surface free energy on the adhesion of biofouling and crystalline fouling[J].Chemical engineering science,2005,60(17):4858-4865.
[13]HO K C,TEOW Y H,ANG W L,et al.Novel GO/OMWCNTs mixed-matrix membrane with enhanced antifouling property for palm oil mill effluent treatment[J].Separation&purification technology,2017,177:337-349.
[14]YOSHIOKA K,OKUDA T,FUJII H,et al.Effect of TiO2,nanoparticles aggregation in silicate thin coating films on photocatalytic behavior for antifouling materials[J].Advanced powder technology,2013,24(5):886-890.
[15]AYYARU S,AHN Y H.Application of sulfonic acid group functionalized graphene oxide to improve hydrophilicity,permeability,and antifouling of PVDF nanocomposite ultrafiltration membranes[J].Journal of membrane science,2017,525:210-219.
[16]PARRA C,DORTA F,JIMENEZ E,et al.A nanomolecular approach to decrease adhesion of biofoulingproducing bacteria to graphene-coated material[J].Journal of nanobiotechnology,2015,13(1):1-10.
[17]KRISHNAMURTHY A,GADHAMSHETTY V,MUK-HERJEE R,et al.Passivation of microbial corrosion using a graphene coating[J].Carbon,2013,56(5):45-49.
[18]姜逢维,吴英豪,刘刚,等.耐腐蚀氧化石墨烯复合涂层的研究进展[J].表面技术,2017,46(11):126-134.JIANG Feng-wei,WU Ying-hao,LIU Gang,et al.Research progress of corrosion resistant graphene oxide composite coatings[J].Surface technology,2017,46(11):126-134.
[19]LI Y,YANG Z,QIU H,et al.Self-aligned graphene as anticorrosive barrier in waterborne polyurethane composite coatings[J].Journal of materials chemistry A,2014,2(34):14139-14145.
[20]YU Z,DI H,MA Y,et al.Fabrication of graphene oxidealumina hybrids to reinforce the anti-corrosion performance of composite epoxy coatings[J].Applied surface science,2015,351:986-996.
[21]CHANG K,CHEN W.l-cysteine-assisted synthesis of layered Mo S2/graphene composites with excellent electrochemical performances for lithium ion batteries[J].ACS nano,2011,5(6):4720-4728.
[22]CHANG C H,HUANG T C,PENG C W,et al.Novel anticorrosion coatings prepared from polyaniline/graphene composites[J].Carbon,2012,50(14):5044-5051.
[23]RAMEZANZADEH B,NIROUMANDRAD S,AHMADIA,et al.Enhancement of barrier and corrosion protection performance of an epoxy coating through wet transfer of amino functionalized graphene oxide[J].Corrosion science,2016,103:283-304.
[24]CHANG K C,HSU M H,LU H,et al.Room-temperature cured hydrophobic epoxy/graphene composites as corrosion inhibitor for cold-rolled steel[J].Carbon,2014,66(2):144-153.
[25]LIU D,ZHAO W,LIU S,et al.Comparative tribological and corrosion resistance properties of epoxy composite coatings reinforced with functionalized fullerene C60 and graphene[J].Surface&coatings technology,2016,286:354-364.
[26]QI K,SUN Y,DUAN H,et al.A corrosion-protective coating based on a solution-processable polymer-grafted graphene oxide nanocomposite[J].Corrosion science2015,98:500-506.
[27]KRISHNAMOORTHY K,JEYASUBRAMANIAN K,PREMANATHAN M,et al.Graphene oxide nanopaint[J].Carbon,2014,72(3):328-337.
[28]YU Y H,LIN Y Y,LIN C H,et al.High-performance polystyrene/graphene-based nanocomposites with excellent anti-corrosion properties[J].Polymer chemistry,2013,5(2):535-550.
[29]CHANG K C,JI W F,LI C W,et al.The effect of varying carboxylic group content in reduced graphene oxides on the anticorrosive properties of PMMA/graphene composites[J].Express polymer letters,2014,8(12):908-919.
[30]MO M,ZHAO W,CHEN Z,et al.Excellent tribological and anti-corrosion performance of polyurethane composite coatings reinforced with functionalized graphene and graphene oxide nanosheets[J].RSC advances,2015,5(70):56486-56497.
[31]MO M,ZHAO W,CHEN Z,et al.Corrosion inhibition of functional graphene reinforced polyurethane nanocomposite coatings with regular textures[J].RSC advances2016,6(10):7780-7790.
[32]CHRISTOPHER G,KULANDAINATHAN M A,HARI-CHANDRAN G.Comparative study of effect of corrosion on mild steel with waterborne polyurethane dispersion containing graphene oxide versus carbon black nanocomposites[J].Progress in organic coatings,2015,89:199-211.
[33]徐孝敏,刘奕,侯文佳,等.碳材料在抗海洋生物污损领域中应用的研究进展[J].表面技术,2017,46(11):172-182.XU Xiao-min,LIU Yi,HOU Wen-jia,et al.Progress in the application of carbon materials in the field of marine biofouling resistance[J].Surface technology,2017,46(11):172-182.
[34]SUN W,WANG L,WU T,et al.Inhibiting the corrosion-promotion activity of graphene[J].Chemistry of materials,2015,27(7):2367-2373.
[35]LI Y,YANG Z,QIU H,et al.Self-aligned graphene as anticorrosive barrier in waterborne polyurethane composite coatings[J].Journal of materials chemistry A,2014,2(34):14139-14145.
[36]WANG M H,LI Q,LI X,et al.Effect of oxygen-containing functional groups in epoxy/reduced graphene oxide composite coatings on corrosion protection and antimicrobial properties[J].Applied surface science,2018,448:351-361.
[37]房亚楠,刘栓,赵文杰,等.石墨烯/氟碳涂层的制备及其耐蚀性能[J].表面技术,2016,45(11):67-75.FANG Ya-nan,LIU Shuan,ZHAO Wen-jie,et al.Preparation and corrosion resistance of graphene/fluorocarbon coatings[J].Surface technology,2016,45(11):67-75.
[38]YEE M S,KHIEW P S,CHIU W S,et al.Green synthesis of graphene-silver nanocomposites and its application as a potent marine antifouling agent[J].Colloids&surfaces B:Biointerfaces,2016,148:392-401.
[39]FENG Z,SU Z,YU T.Antifouling improvement of graphene/TiO2 modified polyurethane coatings[J].Journal of controlled release,2017,259:e33.
[40]SAFARPOUR M,VATANPOUR V,KHATAEE A.Preparation and characterization of graphene oxide/TiO2,blended PES nanofiltration membrane with improved antifouling and separation performance[J].Desalination,2016,393:65-78.
[41]ZHU Z,ZHOU F,ZHAN S,et al.Study on the bactericidal performance of graphene/TiO2 composite photocatalyst in the coating of PEVE[J].Applied surface science,2017,430:116-124.
[42]CHEN C,HE Y,XIAO G,et al.Two-dimensional hybrid materials:MoS2-RGO nanocomposites enhanced the barrier properties of epoxy coating[J].Applied surface science,2018,444:511-521.
[43]YU D,WEN S,YANG J,et al.RGO modified ZnAlLDH as epoxy nanostructure filler:A novel synthetic approach to anticorrosive waterborne coating[J].Surface&coatings technology,2017,326:207-215.
[44]DI H,YU Z,MA Y,et al.Anchoring calcium carbonate on graphene oxide reinforced with anticorrosive properties of composite epoxy coatings[J].Polymers for advanced technologies,2016,27(7):915-921.
[45]SONG Z,ZHANG Y,LIU W,et al.Hydrothermal synthesis and electrochemical performance of Co3O4/reduced graphene oxide nanosheet composites for supercapacitors[J].Electrochimica acta,2013,112(12):120-126.
[46]YU Z,DI H,MA Y,et al.Preparation of graphene oxide modified by titanium dioxide to enhance the anticorrosion performance of epoxy coatings[J].Surface&coatings technology,2015,276:471-478.
[47]YU Z,DI H,MA Y,et al.Fabrication of graphene oxide-alumina hybrids to reinforce the anti-corrosion performance of composite epoxy coatings[J].Applied surface science,2015,351:986-996.
[48]MA Y,DI H,YU Z,et al.Fabrication of silica-decorated graphene oxide nanohybrids and the properties of composite epoxy coatings research[J].Applied surface science,2016,360:936-945.
[49]SMAOUI H,MIR L E L,GUERMAZI H,et al.Study of dielectric relaxations in zinc oxide-epoxy resin nanocomposites[J].Journal of alloys&compounds,2009477(1-2):316-321.
[50]HUANG L,ZHU P,LI G,et al.Core-shell Si O@RGOhybrids for epoxy composites with low percolation threshold and enhanced thermo-mechanical properties[J].Journal of materials chemistry A,2014,2(43):18246-18255.
[51]YOUSEFZADEH S,FARAJI M,NIEN Y T,et al.CdSnanoparticle sensitized titanium dioxide decorated graphene for enhancing visible light induced photoanode[J].Applied surface science,2014,320:772-779.
[52]MANSOURPANAH Y,SHAHEBRAHIMI H,KOLV-ARI E.PEG-modified GO nanosheets,a desired additive to increase the rejection and antifouling characteristics of polyamide thin layer membranes[J].Chemical engineering research&design,2015,104:530-540.
[53]SUN W,WANG L,WU T,et al.Synthesis of lowelectrical-conductivity graphene/pernigraniline composites and their application in corrosion protection[J].Carbon,2014,79(1):605-614.
[54]范壮军,魏彤,闫俊,等.一种基于聚苯胺与石墨烯复合材料的防腐涂料及制备方法:中国,CN102604533A[P].2012.FAN Zhuang-jun,WEI Tong,YAN Jun,et al.An anticorrosive coating based on Polyaniline and graphene composite and its preparation method:China,CN102604533A[P].2012.
[55]康佳,刘胜林,李自军,等.聚苯胺/石墨烯原位复合水性防腐涂料耐蚀性能的研究[J].表面技术,2017,46(11):287-291.KANG Jia,LIU Sheng-lin,LI Zi-jun,et al.Study on corrosion resistance of polyaniline/graphene in-situ composite waterborne anticorrosive coatings[J].Surface technology,2017,46(11):287-291.
[2]SREEVATSA S,BANERJEE A,HAIM G.Graphene as a permeable ionic barrier[J].Ecs transactions,2009,19(5):259-264.
[3]YU L,LIM Y S,HAN J H,et al.A graphene oxide oxygen barrier film deposited via a self-assembly coating method[J].Synthetic metals,2012,162(7-8):710-714.
[4]HASLAM G E,CHIN X Y,BURSTEIN G T.Passivity and electrocatalysis of nanostructured nickel encapsulated in carbon[J].Physical chemistry chemical physics,201113(28):12968-12974.
[5]COMPTON O C,SOYOUNG K,CYNTHIA P,et al.Crumpled graphene nanosheets as highly effective barrier property enhancers[J].Advanced materials,2010,22(42):4759-4763.
[6]YANG Y,LAURA B,PRIOLO M A,et al.Super gas barrier and selectivity of graphene oxide-polymer multilayer thin films[J].Advanced materials,2013,25(4):503-508.
[7]UNALAN I U,WAN C,FIGIEL?,et al.Exceptional oxygen barrier performance of pullulan nanocomposites with ultra-low loading of graphene oxide[J].Nanotechnology,2015,26(27):275703.
[8]YOUSEFI N,GUDARZI M M,ZHENG Q,et al.Highly aligned,ultralarge-size reduced graphene oxide/polyurethane nanocomposites:Mechanical properties and moisture permeability[J].Composites part A applied science&manufacturing,2013,49:42-50.
[9]LI J,CUI J,YANG J,et al.Reinforcement of graphene and its derivatives on the anticorrosive properties of waterborne polyurethane coatings[J].Composites science&technology,2016,129:30-37.
[10]DAFFORN K A,LEWIS J A,JOHNSTON E L.Antifouling strategies:history and regulation,ecological impacts and mitigation[J].Marine pollution bulletin,2011,62(3):453-465.
[11]JELVESTAM M,EDRUD S,PETRONIS S,et al.Biomimetic materials with tailored surface micro-architecture for prevention of marine biofouling[J].Surface&interface analysis,2003,35(2):168-173.
[12]ZHAO Q,LIU Y,WANG C,et al.Effect of surface free energy on the adhesion of biofouling and crystalline fouling[J].Chemical engineering science,2005,60(17):4858-4865.
[13]HO K C,TEOW Y H,ANG W L,et al.Novel GO/OMWCNTs mixed-matrix membrane with enhanced antifouling property for palm oil mill effluent treatment[J].Separation&purification technology,2017,177:337-349.
[14]YOSHIOKA K,OKUDA T,FUJII H,et al.Effect of TiO2,nanoparticles aggregation in silicate thin coating films on photocatalytic behavior for antifouling materials[J].Advanced powder technology,2013,24(5):886-890.
[15]AYYARU S,AHN Y H.Application of sulfonic acid group functionalized graphene oxide to improve hydrophilicity,permeability,and antifouling of PVDF nanocomposite ultrafiltration membranes[J].Journal of membrane science,2017,525:210-219.
[16]PARRA C,DORTA F,JIMENEZ E,et al.A nanomolecular approach to decrease adhesion of biofoulingproducing bacteria to graphene-coated material[J].Journal of nanobiotechnology,2015,13(1):1-10.
[17]KRISHNAMURTHY A,GADHAMSHETTY V,MUK-HERJEE R,et al.Passivation of microbial corrosion using a graphene coating[J].Carbon,2013,56(5):45-49.
[18]姜逢维,吴英豪,刘刚,等.耐腐蚀氧化石墨烯复合涂层的研究进展[J].表面技术,2017,46(11):126-134.JIANG Feng-wei,WU Ying-hao,LIU Gang,et al.Research progress of corrosion resistant graphene oxide composite coatings[J].Surface technology,2017,46(11):126-134.
[19]LI Y,YANG Z,QIU H,et al.Self-aligned graphene as anticorrosive barrier in waterborne polyurethane composite coatings[J].Journal of materials chemistry A,2014,2(34):14139-14145.
[20]YU Z,DI H,MA Y,et al.Fabrication of graphene oxidealumina hybrids to reinforce the anti-corrosion performance of composite epoxy coatings[J].Applied surface science,2015,351:986-996.
[21]CHANG K,CHEN W.l-cysteine-assisted synthesis of layered Mo S2/graphene composites with excellent electrochemical performances for lithium ion batteries[J].ACS nano,2011,5(6):4720-4728.
[22]CHANG C H,HUANG T C,PENG C W,et al.Novel anticorrosion coatings prepared from polyaniline/graphene composites[J].Carbon,2012,50(14):5044-5051.
[23]RAMEZANZADEH B,NIROUMANDRAD S,AHMADIA,et al.Enhancement of barrier and corrosion protection performance of an epoxy coating through wet transfer of amino functionalized graphene oxide[J].Corrosion science,2016,103:283-304.
[24]CHANG K C,HSU M H,LU H,et al.Room-temperature cured hydrophobic epoxy/graphene composites as corrosion inhibitor for cold-rolled steel[J].Carbon,2014,66(2):144-153.
[25]LIU D,ZHAO W,LIU S,et al.Comparative tribological and corrosion resistance properties of epoxy composite coatings reinforced with functionalized fullerene C60 and graphene[J].Surface&coatings technology,2016,286:354-364.
[26]QI K,SUN Y,DUAN H,et al.A corrosion-protective coating based on a solution-processable polymer-grafted graphene oxide nanocomposite[J].Corrosion science2015,98:500-506.
[27]KRISHNAMOORTHY K,JEYASUBRAMANIAN K,PREMANATHAN M,et al.Graphene oxide nanopaint[J].Carbon,2014,72(3):328-337.
[28]YU Y H,LIN Y Y,LIN C H,et al.High-performance polystyrene/graphene-based nanocomposites with excellent anti-corrosion properties[J].Polymer chemistry,2013,5(2):535-550.
[29]CHANG K C,JI W F,LI C W,et al.The effect of varying carboxylic group content in reduced graphene oxides on the anticorrosive properties of PMMA/graphene composites[J].Express polymer letters,2014,8(12):908-919.
[30]MO M,ZHAO W,CHEN Z,et al.Excellent tribological and anti-corrosion performance of polyurethane composite coatings reinforced with functionalized graphene and graphene oxide nanosheets[J].RSC advances,2015,5(70):56486-56497.
[31]MO M,ZHAO W,CHEN Z,et al.Corrosion inhibition of functional graphene reinforced polyurethane nanocomposite coatings with regular textures[J].RSC advances2016,6(10):7780-7790.
[32]CHRISTOPHER G,KULANDAINATHAN M A,HARI-CHANDRAN G.Comparative study of effect of corrosion on mild steel with waterborne polyurethane dispersion containing graphene oxide versus carbon black nanocomposites[J].Progress in organic coatings,2015,89:199-211.
[33]徐孝敏,刘奕,侯文佳,等.碳材料在抗海洋生物污损领域中应用的研究进展[J].表面技术,2017,46(11):172-182.XU Xiao-min,LIU Yi,HOU Wen-jia,et al.Progress in the application of carbon materials in the field of marine biofouling resistance[J].Surface technology,2017,46(11):172-182.
[34]SUN W,WANG L,WU T,et al.Inhibiting the corrosion-promotion activity of graphene[J].Chemistry of materials,2015,27(7):2367-2373.
[35]LI Y,YANG Z,QIU H,et al.Self-aligned graphene as anticorrosive barrier in waterborne polyurethane composite coatings[J].Journal of materials chemistry A,2014,2(34):14139-14145.
[36]WANG M H,LI Q,LI X,et al.Effect of oxygen-containing functional groups in epoxy/reduced graphene oxide composite coatings on corrosion protection and antimicrobial properties[J].Applied surface science,2018,448:351-361.
[37]房亚楠,刘栓,赵文杰,等.石墨烯/氟碳涂层的制备及其耐蚀性能[J].表面技术,2016,45(11):67-75.FANG Ya-nan,LIU Shuan,ZHAO Wen-jie,et al.Preparation and corrosion resistance of graphene/fluorocarbon coatings[J].Surface technology,2016,45(11):67-75.
[38]YEE M S,KHIEW P S,CHIU W S,et al.Green synthesis of graphene-silver nanocomposites and its application as a potent marine antifouling agent[J].Colloids&surfaces B:Biointerfaces,2016,148:392-401.
[39]FENG Z,SU Z,YU T.Antifouling improvement of graphene/TiO2 modified polyurethane coatings[J].Journal of controlled release,2017,259:e33.
[40]SAFARPOUR M,VATANPOUR V,KHATAEE A.Preparation and characterization of graphene oxide/TiO2,blended PES nanofiltration membrane with improved antifouling and separation performance[J].Desalination,2016,393:65-78.
[41]ZHU Z,ZHOU F,ZHAN S,et al.Study on the bactericidal performance of graphene/TiO2 composite photocatalyst in the coating of PEVE[J].Applied surface science,2017,430:116-124.
[42]CHEN C,HE Y,XIAO G,et al.Two-dimensional hybrid materials:MoS2-RGO nanocomposites enhanced the barrier properties of epoxy coating[J].Applied surface science,2018,444:511-521.
[43]YU D,WEN S,YANG J,et al.RGO modified ZnAlLDH as epoxy nanostructure filler:A novel synthetic approach to anticorrosive waterborne coating[J].Surface&coatings technology,2017,326:207-215.
[44]DI H,YU Z,MA Y,et al.Anchoring calcium carbonate on graphene oxide reinforced with anticorrosive properties of composite epoxy coatings[J].Polymers for advanced technologies,2016,27(7):915-921.
[45]SONG Z,ZHANG Y,LIU W,et al.Hydrothermal synthesis and electrochemical performance of Co3O4/reduced graphene oxide nanosheet composites for supercapacitors[J].Electrochimica acta,2013,112(12):120-126.
[46]YU Z,DI H,MA Y,et al.Preparation of graphene oxide modified by titanium dioxide to enhance the anticorrosion performance of epoxy coatings[J].Surface&coatings technology,2015,276:471-478.
[47]YU Z,DI H,MA Y,et al.Fabrication of graphene oxide-alumina hybrids to reinforce the anti-corrosion performance of composite epoxy coatings[J].Applied surface science,2015,351:986-996.
[48]MA Y,DI H,YU Z,et al.Fabrication of silica-decorated graphene oxide nanohybrids and the properties of composite epoxy coatings research[J].Applied surface science,2016,360:936-945.
[49]SMAOUI H,MIR L E L,GUERMAZI H,et al.Study of dielectric relaxations in zinc oxide-epoxy resin nanocomposites[J].Journal of alloys&compounds,2009477(1-2):316-321.
[50]HUANG L,ZHU P,LI G,et al.Core-shell Si O@RGOhybrids for epoxy composites with low percolation threshold and enhanced thermo-mechanical properties[J].Journal of materials chemistry A,2014,2(43):18246-18255.
[51]YOUSEFZADEH S,FARAJI M,NIEN Y T,et al.CdSnanoparticle sensitized titanium dioxide decorated graphene for enhancing visible light induced photoanode[J].Applied surface science,2014,320:772-779.
[52]MANSOURPANAH Y,SHAHEBRAHIMI H,KOLV-ARI E.PEG-modified GO nanosheets,a desired additive to increase the rejection and antifouling characteristics of polyamide thin layer membranes[J].Chemical engineering research&design,2015,104:530-540.
[53]SUN W,WANG L,WU T,et al.Synthesis of lowelectrical-conductivity graphene/pernigraniline composites and their application in corrosion protection[J].Carbon,2014,79(1):605-614.
[54]范壮军,魏彤,闫俊,等.一种基于聚苯胺与石墨烯复合材料的防腐涂料及制备方法:中国,CN102604533A[P].2012.FAN Zhuang-jun,WEI Tong,YAN Jun,et al.An anticorrosive coating based on Polyaniline and graphene composite and its preparation method:China,CN102604533A[P].2012.
[55]康佳,刘胜林,李自军,等.聚苯胺/石墨烯原位复合水性防腐涂料耐蚀性能的研究[J].表面技术,2017,46(11):287-291.KANG Jia,LIU Sheng-lin,LI Zi-jun,et al.Study on corrosion resistance of polyaniline/graphene in-situ composite waterborne anticorrosive coatings[J].Surface technology,2017,46(11):287-291.