膨胀石墨材料的研究进展及其应用综述
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摘要
本文从膨胀石墨的插层与膨胀制备工艺出发阐述了其制备原理方法及特点,根据膨胀石墨所具有的耐高低温、导电导热,强吸附性、粘结性、压缩回弹性、密封性等特点,综述了其在环保、医学、密封阻燃材料等方面的应用现状,重点介绍了其作为油类物质吸附材料的原理及研究应用现状,剖析了目前膨胀石墨在吸附材料领域开发及应用过程中的一些不足,提出了今后膨胀石墨在该领域研究的主要发展趋势。
In this paper, the preparation methods and application of the expanded graphite were introduced. First, the usual intercalation and expansion technologies were summarized, and then based on the high and low temperature resistance, electrical and thermal conductivity, high adsorption property, cohesiveness, resilience and resilient property,sealing charateristics, the applications of expanded graphite in environmental protection, medicine, sealing material and fire retardant areas were reviewed, and its application and mechanism for the oil adsorption were introduced detailed especially. In the last, the application problem of expanded graphite were introduced and analyzed, and its future development trend was proposed.
In this paper, the preparation methods and application of the expanded graphite were introduced. First, the usual intercalation and expansion technologies were summarized, and then based on the high and low temperature resistance, electrical and thermal conductivity, high adsorption property, cohesiveness, resilience and resilient property,sealing charateristics, the applications of expanded graphite in environmental protection, medicine, sealing material and fire retardant areas were reviewed, and its application and mechanism for the oil adsorption were introduced detailed especially. In the last, the application problem of expanded graphite were introduced and analyzed, and its future development trend was proposed.
引文
[1]张秀荣.石墨/石蜡复合相变储热材料的热性能研究[J].材料研究学报,2010(3):332-336.
[2]李云涛.二十二烷/膨胀石墨复合相变材料的制备与表征[J].功能材料,2016(11):11081-11086.
[3]Lueking,A.D.,et al.,Effect of expanded graphite lattice in exfoliated graphite nanofibers on hydrogen storage.Journal of Physical Chemistry B,2005,109(26):12710-12717.
[4]赵纪金.分步插层法制备高倍膨胀石墨及其微观结构[J].光学精密工程,2014(5):1267-1273.
[5]Lueking,A.D.,et al.,Hydrogen storage in graphite nanofibers:effect of synthesis catalyst and pretreatment conditions.Langmuir,2004,20(3):714-721.
[6]Nechaev,Y.S.,et al.,Fundamental Open Questions on Engineering of“Super”Hydrogen Sorption in Graphite Nanofibers:Relevance for Clean Energy Applications.American Journal of Analytical Chemistry,2014,5(16):1151-1165.
[7]Liu,C.,et al.,Preparation and structure analysis of expanded graphite-based composites made by phosphoric acid activation.Journal of Porous Materials,2010,17(4):425-428.
[8]Chung,D.D.L.,A review of exfoliated graphite.Journal of Materials Science,2016,51(1):554-568.
[9]陈祖耀,朱继平,张增辉,等.可膨胀石墨的化学氧化法制备及其表征[J]中国科学技术大学学报,1998(2):76-81.
[10]王厚山.膨胀石墨的化学氧化法制备研究进展[J].中国非金属矿工业导刊,2008(4):18-20.
[11]林雪梅.可膨胀石墨的化学氧化法制备研究进展[J].炭素,2005(4):44-48.
[12]刘开平,周敬恩.膨胀石墨化学氧化法制备技术研究进展[J].地球科学与环境学报,2003(4):85-91.
[13]徐涛.电化学辅助制备大尺寸石墨烯及其在锂电池负极上的应用研究[D].北京化工大学,2017.
[14]冯晓彤.电化学法制备可膨胀石墨的研究[D].黑龙江科技大学,2016.
[15]刘定福.可膨胀石墨电化学氧化法制备工艺研究进展[J].炭素技术,2013(3):49-51,56.
[16]陈洪亮,王树林,夏立珍,石墨烯-氧化锌纳米棒复合材料的超声法制备及其光催化性能.功能材料,2014(6):6097-6101.
[17]郭晓琴.超声剥离二次膨胀石墨制备石墨烯纳米片[J].功能材料,2013(12):1800-1803.
[18]罗立群,安峰文,田金星.石墨插层技术的筛选和应用现状[J].现代化工,2016(11):32-36,38.
[19]Chen,Y.P.,et al.Optimization of initial redox potential in the preparation of expandable graphite by chemical oxidation.New Carbon Materials,2013,28(6):435-441.
[20]Li,S.,et al.,Vaseline-loaded expanded graphite as a new adsorbent for toluene.Chemical Engineering Journal,2010,162(2):546-551.
[21]徐众.天然鳞片石墨制备可膨胀石墨的工艺研究[J].无机盐工业,2016(5):30-34.
[22]曹晓燕.膨胀石墨的制备及其吸附性能[J].水处理技术,2007(1):95-99.
[23]张东田胜力肖德炎,微波法制备纳米多孔石墨[J].非金属矿,2004(6):22-24.
[24]Tryba,B.,A.W.Morawski and M.Inagaki,Preparation of exfoliated graphite by microwave irradiation.Carbon,2005,43(11):2417-2419.
[25]陈文亮.液体苯系物等类油物质吸附材料综述[J].材料导报,2017(S2):222-226.
[26]杨波,戴兵.石油化工行业产业政策与污染物排放特征探析[J].化工进展,2009(S1):505-507.
[27]翟瑞国.载钛膨胀石墨在油水体系中对油的吸附性能研究[D].天津大学,2012.
[28]稻垣道夫沈万慈,曹乃珍,温诗铸,等.膨胀石墨对有机化合物的吸附[J].炭素技术,1996(3):1-5.
[29]Wang,G.,et al.Sorption and regeneration of magnetic exfoliated graphite as a new sorbent for oil pollution.Desalination,2010,263(1):183-188.
[30]Yue,X.Q.,et al.Decomposition of crude oil absorbed into expanded g raphite/TiO2/NiO composites.Desalination,2010,252(1-3):163-166.
[31]许霞.膨胀石墨对油类的吸附及其再生性能的研究[D].哈尔滨工业大学,2006.
[32]Tryba,B.,et al.,Exfoliated Graphite as a New Sorbent for Removal of Engine Oils from Wastewater.Spill Science&Technology Bulletin,2003,8(5-6):569-571.
[33]陈志刚,张勇,杨娟,等.膨胀石墨的制备、结构和应用[J].江苏大学学报:自然科学版,2005(3):248-252.
[34]王国建,纪振鹏.可膨胀石墨在膨胀型钢结构防火涂料中的应用研究[J].涂料工业,2009(3):1-5.
[35]张龙,王建祺.新型无卤可膨胀石墨防火涂料[J].北京理工大学学报,2001(5):649-652.
[36]凌子夜.基于膨胀石墨基复合相变材料的动力电池热管理系统性能研究[D].华南理工大学,2016.
[37]杜超.乙烯基酯树脂/膨胀石墨燃料电池复合双极板[J].电源技术,2010(7):667-671.
[38]吕建中,于爱香,史绯绯,等.膨胀石墨用于烧伤创面的研究[J].中华烧伤杂志,2002(2):55.
[39]沈万慈,曹乃珍,李晓峰,等.多孔石墨吸附材料的生物医学应用研究[J].新型碳材料,1998(1):50-54.
[40]郑宾国.膨胀石墨及其复合材料在水处理领域的应用研究[J].化工新型材料,2017(6):239-241.
[41]王鲁宁,陈希,郑永平,等.膨胀石墨处理毛纺厂印染废水的应用研究[J].中国非金属矿工业导刊,2004(5):59-62.
[42]郜攀,张连红,单晓宇.膨胀石墨制备方法的研究进展[J].合成化学,2016(9):832-836.
[43]罗永勤.膨胀石墨的制备工艺及应用研究进展[J].化工生产与技术,2015(5):29-34.
[2]李云涛.二十二烷/膨胀石墨复合相变材料的制备与表征[J].功能材料,2016(11):11081-11086.
[3]Lueking,A.D.,et al.,Effect of expanded graphite lattice in exfoliated graphite nanofibers on hydrogen storage.Journal of Physical Chemistry B,2005,109(26):12710-12717.
[4]赵纪金.分步插层法制备高倍膨胀石墨及其微观结构[J].光学精密工程,2014(5):1267-1273.
[5]Lueking,A.D.,et al.,Hydrogen storage in graphite nanofibers:effect of synthesis catalyst and pretreatment conditions.Langmuir,2004,20(3):714-721.
[6]Nechaev,Y.S.,et al.,Fundamental Open Questions on Engineering of“Super”Hydrogen Sorption in Graphite Nanofibers:Relevance for Clean Energy Applications.American Journal of Analytical Chemistry,2014,5(16):1151-1165.
[7]Liu,C.,et al.,Preparation and structure analysis of expanded graphite-based composites made by phosphoric acid activation.Journal of Porous Materials,2010,17(4):425-428.
[8]Chung,D.D.L.,A review of exfoliated graphite.Journal of Materials Science,2016,51(1):554-568.
[9]陈祖耀,朱继平,张增辉,等.可膨胀石墨的化学氧化法制备及其表征[J]中国科学技术大学学报,1998(2):76-81.
[10]王厚山.膨胀石墨的化学氧化法制备研究进展[J].中国非金属矿工业导刊,2008(4):18-20.
[11]林雪梅.可膨胀石墨的化学氧化法制备研究进展[J].炭素,2005(4):44-48.
[12]刘开平,周敬恩.膨胀石墨化学氧化法制备技术研究进展[J].地球科学与环境学报,2003(4):85-91.
[13]徐涛.电化学辅助制备大尺寸石墨烯及其在锂电池负极上的应用研究[D].北京化工大学,2017.
[14]冯晓彤.电化学法制备可膨胀石墨的研究[D].黑龙江科技大学,2016.
[15]刘定福.可膨胀石墨电化学氧化法制备工艺研究进展[J].炭素技术,2013(3):49-51,56.
[16]陈洪亮,王树林,夏立珍,石墨烯-氧化锌纳米棒复合材料的超声法制备及其光催化性能.功能材料,2014(6):6097-6101.
[17]郭晓琴.超声剥离二次膨胀石墨制备石墨烯纳米片[J].功能材料,2013(12):1800-1803.
[18]罗立群,安峰文,田金星.石墨插层技术的筛选和应用现状[J].现代化工,2016(11):32-36,38.
[19]Chen,Y.P.,et al.Optimization of initial redox potential in the preparation of expandable graphite by chemical oxidation.New Carbon Materials,2013,28(6):435-441.
[20]Li,S.,et al.,Vaseline-loaded expanded graphite as a new adsorbent for toluene.Chemical Engineering Journal,2010,162(2):546-551.
[21]徐众.天然鳞片石墨制备可膨胀石墨的工艺研究[J].无机盐工业,2016(5):30-34.
[22]曹晓燕.膨胀石墨的制备及其吸附性能[J].水处理技术,2007(1):95-99.
[23]张东田胜力肖德炎,微波法制备纳米多孔石墨[J].非金属矿,2004(6):22-24.
[24]Tryba,B.,A.W.Morawski and M.Inagaki,Preparation of exfoliated graphite by microwave irradiation.Carbon,2005,43(11):2417-2419.
[25]陈文亮.液体苯系物等类油物质吸附材料综述[J].材料导报,2017(S2):222-226.
[26]杨波,戴兵.石油化工行业产业政策与污染物排放特征探析[J].化工进展,2009(S1):505-507.
[27]翟瑞国.载钛膨胀石墨在油水体系中对油的吸附性能研究[D].天津大学,2012.
[28]稻垣道夫沈万慈,曹乃珍,温诗铸,等.膨胀石墨对有机化合物的吸附[J].炭素技术,1996(3):1-5.
[29]Wang,G.,et al.Sorption and regeneration of magnetic exfoliated graphite as a new sorbent for oil pollution.Desalination,2010,263(1):183-188.
[30]Yue,X.Q.,et al.Decomposition of crude oil absorbed into expanded g raphite/TiO2/NiO composites.Desalination,2010,252(1-3):163-166.
[31]许霞.膨胀石墨对油类的吸附及其再生性能的研究[D].哈尔滨工业大学,2006.
[32]Tryba,B.,et al.,Exfoliated Graphite as a New Sorbent for Removal of Engine Oils from Wastewater.Spill Science&Technology Bulletin,2003,8(5-6):569-571.
[33]陈志刚,张勇,杨娟,等.膨胀石墨的制备、结构和应用[J].江苏大学学报:自然科学版,2005(3):248-252.
[34]王国建,纪振鹏.可膨胀石墨在膨胀型钢结构防火涂料中的应用研究[J].涂料工业,2009(3):1-5.
[35]张龙,王建祺.新型无卤可膨胀石墨防火涂料[J].北京理工大学学报,2001(5):649-652.
[36]凌子夜.基于膨胀石墨基复合相变材料的动力电池热管理系统性能研究[D].华南理工大学,2016.
[37]杜超.乙烯基酯树脂/膨胀石墨燃料电池复合双极板[J].电源技术,2010(7):667-671.
[38]吕建中,于爱香,史绯绯,等.膨胀石墨用于烧伤创面的研究[J].中华烧伤杂志,2002(2):55.
[39]沈万慈,曹乃珍,李晓峰,等.多孔石墨吸附材料的生物医学应用研究[J].新型碳材料,1998(1):50-54.
[40]郑宾国.膨胀石墨及其复合材料在水处理领域的应用研究[J].化工新型材料,2017(6):239-241.
[41]王鲁宁,陈希,郑永平,等.膨胀石墨处理毛纺厂印染废水的应用研究[J].中国非金属矿工业导刊,2004(5):59-62.
[42]郜攀,张连红,单晓宇.膨胀石墨制备方法的研究进展[J].合成化学,2016(9):832-836.
[43]罗永勤.膨胀石墨的制备工艺及应用研究进展[J].化工生产与技术,2015(5):29-34.