用于环境中Cu~(2+)检测罗丹明类荧光探针设计及识别机理研究进展
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摘要
铜离子是人体中不可缺少的微量元素,过量的Cu~(2+)会对人造成严重的器官损伤乃至死亡,因而Cu~(2+)检测对人类安全具有重要意义。本文针对罗丹明类荧光探针在环境检测、化学分析、生命科学以及相关领域的实际应用,重点介绍了近几年来用于检测重金属Cu~(2+)的罗丹明荧光探针的进展,分析了荧光探针的设计及对Cu~(2+)的识别机理,指出了该类荧光探针的研究现状并展望了该研究领域未来的发展方向和应用前景。
Copper ion is an indispensable element in human body.Excessive Cu~(2+) can cause serious organ damage and even death.Therefore,the detection of Cu~(2+) is of great significance to human safety.In view of the practical application of Rhodamine Fluorescent Probes in environmental detection、chemical analysis、 life sciences and related fields,in this paper mainly introduces the progress of Rhodamine Fluorescent Probes Used for the detection of Cu~(2+) in recent years,analyses the design of fluorescent probes and the recognition of Cu~(2+),points out the research status of this kind of fluorescent probes and looks forward to development direction and application prospect in the future of this field.
Copper ion is an indispensable element in human body.Excessive Cu~(2+) can cause serious organ damage and even death.Therefore,the detection of Cu~(2+) is of great significance to human safety.In view of the practical application of Rhodamine Fluorescent Probes in environmental detection、chemical analysis、 life sciences and related fields,in this paper mainly introduces the progress of Rhodamine Fluorescent Probes Used for the detection of Cu~(2+) in recent years,analyses the design of fluorescent probes and the recognition of Cu~(2+),points out the research status of this kind of fluorescent probes and looks forward to development direction and application prospect in the future of this field.
引文
[1] Hinge S P,Orpe M S,Sathe K V,et al.Combined removal of Rhodamine B and Thodamine 6G from wastewater using novel treatment approaches based on ultrasonic and ultraviolet irradiations[J].Desalin Water Treat,2016,(57)50:23927-23939.
[2] 王夏芳.铜离子对环境危害现状及对策研究[J].国土与自然资源研究,2015(1):55-57.
[3] 向华,丁晓英.铜污染对水体-水生植物的毒害效应研究进展[J].湖南农业科学,2009(11): 54-56.
[4] 周丽波,赵秋媛,基于高半胱氨酸-罗丹明类荧光探针的合成[J].分析实验室,2018,(37)8:893-897.
[5] 张君丽.新型罗丹明B类金属离子荧光探针的合成及应用[D].河南:河南大学, 2013,05.
[6] 颜泛,陈立,闫喜,等.罗丹明类荧光染料的合成及应用[J].化学进展,2006,18(2):252-261.
[7] Kim H N,Lee M H,Kim H J,et al.A new trend in rhodamine-based chemosen appliaction of spirolactam ring-opening to sensing ions[J].Chemical Society Reviews,2008,37(8):1465-1472.
[8] 陈钰,龚正君,杨顺生,孙彩云.改性玉米秸秆吸附Cu2+的动力学和热力学[J].环境工程学报,2013,7(2):523.
[9] You Qihua,Huang Huabin,Zhuang Zhixia,et al.A new rhodaomin-based fluorescent probe for the discrimination of Fe3+ from Fe2+[J].Bulletin of the Korean Chemical ,Society,2016,37(11):1772-1777.
[10] Tang L,Lif,Liu M R,et al.Single sensor for two metal ions:Colorimetric recognition of Cu2+and fluorescent recognition of Hg2+[J].Spectrochimica Acta Part A molecular &Biomolecular Spectroscopy,2011,78(3):1168-1172.
[11] Dujosl V,Ford F,Czarnik A W.A Long-Wavelength Fluorescent Chemodosimeter Selective for Cu(Ⅱ)Ion in Water[J].Journal of the American Chemical Society,1997,119(31):7386-7387.
[12] Kumar M,Kumar N,Bhalla V,et al.Highly selective fluorescence turn-onchemodosimeter based on rhodamine for nanomolar detection of copper ions[J].Org Lett,2012,14(1):406-409.
[13] Huo F J, Yin C X.Ultraviolet-visible light(UV-Vis)-reversible but fluorescence -irreversible chemosensor for copper in water and its application in living cells[J].Anal Chem,2012,84 (5):2219-2223.
[14] Zhang B,Diao Q P,Ma P Y,et al.A sensitive fluorescent probe for Cu2+ based on rhodamine B derivatives and its application to drinking water examination and living cells imaging[J].Sens Actuators B-Chem,2016 ,225:579-585.
[15] 贾治芳,王科伟,刘慧君,等.胡椒醛-罗丹明B衍生物荧光探针的合成及其对Cu2+的识别[J].山西大同大学学报(自然科学版),2018,34(3):7-10.
[16] Xu Z,Han,S J,Lee C,et al.Development of "off-on"fluorescent probes for heavy and transition metal ions[J].Chem Commun,2010,46(10):1679.
[17] Nolan E M,Lippard S J.A "Turn-On" fluorescent sensor for the selective detection of mercuric ion in aqueous media[J].J Am Chem Soc,2003,125(47):14270-14271.
[18] He G.Zhang X,He C,et al.Ratiometric fluorescence chemosensors for copper(II) and mercury(II) based on FRET systems[J].Tetrahedron.2010,66(51):9762-9768.
[19] Fan J,Zhan P,Hu M,et al.A fluorescent ratiometric chemodosimeter for Cu2+ based on tbet and its application in living cells[J].OrganicLetters,2013,15(3):492-495.
[2] 王夏芳.铜离子对环境危害现状及对策研究[J].国土与自然资源研究,2015(1):55-57.
[3] 向华,丁晓英.铜污染对水体-水生植物的毒害效应研究进展[J].湖南农业科学,2009(11): 54-56.
[4] 周丽波,赵秋媛,基于高半胱氨酸-罗丹明类荧光探针的合成[J].分析实验室,2018,(37)8:893-897.
[5] 张君丽.新型罗丹明B类金属离子荧光探针的合成及应用[D].河南:河南大学, 2013,05.
[6] 颜泛,陈立,闫喜,等.罗丹明类荧光染料的合成及应用[J].化学进展,2006,18(2):252-261.
[7] Kim H N,Lee M H,Kim H J,et al.A new trend in rhodamine-based chemosen appliaction of spirolactam ring-opening to sensing ions[J].Chemical Society Reviews,2008,37(8):1465-1472.
[8] 陈钰,龚正君,杨顺生,孙彩云.改性玉米秸秆吸附Cu2+的动力学和热力学[J].环境工程学报,2013,7(2):523.
[9] You Qihua,Huang Huabin,Zhuang Zhixia,et al.A new rhodaomin-based fluorescent probe for the discrimination of Fe3+ from Fe2+[J].Bulletin of the Korean Chemical ,Society,2016,37(11):1772-1777.
[10] Tang L,Lif,Liu M R,et al.Single sensor for two metal ions:Colorimetric recognition of Cu2+and fluorescent recognition of Hg2+[J].Spectrochimica Acta Part A molecular &Biomolecular Spectroscopy,2011,78(3):1168-1172.
[11] Dujosl V,Ford F,Czarnik A W.A Long-Wavelength Fluorescent Chemodosimeter Selective for Cu(Ⅱ)Ion in Water[J].Journal of the American Chemical Society,1997,119(31):7386-7387.
[12] Kumar M,Kumar N,Bhalla V,et al.Highly selective fluorescence turn-onchemodosimeter based on rhodamine for nanomolar detection of copper ions[J].Org Lett,2012,14(1):406-409.
[13] Huo F J, Yin C X.Ultraviolet-visible light(UV-Vis)-reversible but fluorescence -irreversible chemosensor for copper in water and its application in living cells[J].Anal Chem,2012,84 (5):2219-2223.
[14] Zhang B,Diao Q P,Ma P Y,et al.A sensitive fluorescent probe for Cu2+ based on rhodamine B derivatives and its application to drinking water examination and living cells imaging[J].Sens Actuators B-Chem,2016 ,225:579-585.
[15] 贾治芳,王科伟,刘慧君,等.胡椒醛-罗丹明B衍生物荧光探针的合成及其对Cu2+的识别[J].山西大同大学学报(自然科学版),2018,34(3):7-10.
[16] Xu Z,Han,S J,Lee C,et al.Development of "off-on"fluorescent probes for heavy and transition metal ions[J].Chem Commun,2010,46(10):1679.
[17] Nolan E M,Lippard S J.A "Turn-On" fluorescent sensor for the selective detection of mercuric ion in aqueous media[J].J Am Chem Soc,2003,125(47):14270-14271.
[18] He G.Zhang X,He C,et al.Ratiometric fluorescence chemosensors for copper(II) and mercury(II) based on FRET systems[J].Tetrahedron.2010,66(51):9762-9768.
[19] Fan J,Zhan P,Hu M,et al.A fluorescent ratiometric chemodosimeter for Cu2+ based on tbet and its application in living cells[J].OrganicLetters,2013,15(3):492-495.