乙炔氢氯化合成氯乙烯催化剂的研究进展
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摘要
随着"水俣公约"实施日期的逐渐逼近,低/非汞催化剂的研究成为电石法生产氯乙烯的关键性因素,概述了近几年来国内外电石法乙炔氢氯化合成氯乙烯催化剂的研究现状,主要调查了低汞催化剂,以Au为代表的非汞贵金属催化剂,以Cu,Ni,Fe,Co等为代表的非汞非贵金属催化剂,以及以C–N复合材料为代表的非金属催化剂的研究现状,重点综述了不同催化剂的改性处理手段和催化机理的研究现状。指出在各种催化剂中,贵金属催化剂价格昂贵,很难实现工业化;非贵金属催化剂性能仍需进一步提升;新兴的C–N复合材料具有优越的催化性能,有很大的应用前景,此类非金属材料催化剂将成为新的研究热点。
With the approaching of the date of the application of "Minamata convention",researches on the low/non-mercury catalysts for the production of chloroethylene of calcium carbide method becomes the key factor. The status of the catalysts for ethylene hydrochlorinate to prepare chloroethylene in China and other countries were reviewed. The progress of the low-mercury catalysts,the precious metal based catalysts that delegated by gold,the non-precious metal based catalyst that delegated by copper,nickel,iron,cobalt and carbon-nitrogen delegated non-metal based composite catalysts was summarized. The emphasis was played on the status of the modification of different catalysts and catalytic mechanism. It is pointed out that in all of the catalysts,the price of the precious metal based catalysts is high,which make it difficult to be industrialized;the performance of non-precious metal based catalyst still need to be improved;as a novel catalyst,the carbon-nitrogen based composite catalysts show superior performance and have promising prospect for application,which will be a hot-point for researches in non-metal based material fields.
With the approaching of the date of the application of "Minamata convention",researches on the low/non-mercury catalysts for the production of chloroethylene of calcium carbide method becomes the key factor. The status of the catalysts for ethylene hydrochlorinate to prepare chloroethylene in China and other countries were reviewed. The progress of the low-mercury catalysts,the precious metal based catalysts that delegated by gold,the non-precious metal based catalyst that delegated by copper,nickel,iron,cobalt and carbon-nitrogen delegated non-metal based composite catalysts was summarized. The emphasis was played on the status of the modification of different catalysts and catalytic mechanism. It is pointed out that in all of the catalysts,the price of the precious metal based catalysts is high,which make it difficult to be industrialized;the performance of non-precious metal based catalyst still need to be improved;as a novel catalyst,the carbon-nitrogen based composite catalysts show superior performance and have promising prospect for application,which will be a hot-point for researches in non-metal based material fields.
引文
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[2]Shinoda K.Chemistry Letters,1975,4(3):219-220.
[3]唐晓宁,等.功能材料,2015(B12):88-92.Tang Xiaoning,et al.Journal of Functional Materials,2015(B12):88-92.
[4]李武斌,等.石油炼制与化工,2017,48(12):74-77.Li Wubin,et al.Petroleum Processing and Petrochemicals,2017,48(12):74-77.
[5]支林轩,等.化学反应工程与工艺,2015,31(4):343-351.Zhi Linxuan,et al.Chemical Reaction Engineering and Technology,2015,31(4):343-351.
[6]Liu C,et al.Chinese Journal of Chemical Engineering,2018,26(2):364-372.
[7]Hutchings G J.Journal of Catalysis,1985,96(1):292-295.
[8]Nkosi B,et al.Journal of Catalysis,1991,128(2):378-386.
[9]王琴琴,等.石河子大学学报:自科版,2015,33(1):1-6.Wang Qinqin,et al.Journal of Shihezi University:Natural Science,2015,33(1):1-6.
[10]Zhang H Y,et al.Journal of Catalysis,2014,316(7):141-148.
[11]Ma J,et al.Reaction Kinetics Mechanisms&Catalysis,2013,110(1):177-186.
[12]王声洁,等.石油学报(石油加工),2010,26(2):201-207.Wang Shengjie,et al.Acta Petrolei Sinica,2010,26(2):201-207.
[13]王声洁,等.华东理工大学学报:自然科学版,2010,36(1):20-24.Wang Shengjie,et al.Journal of East China University of Science and Technology:Social Science Edition,2010,36(1):20-24.
[14]王声洁.乙炔氢氯化非汞催化反应制取氯乙烯单体研究[D].上海:华东理工大学,2010.Wang Shengjie.Study on non-mercury catalytic acetylene hydrochlorinadon to produce vinyl chloride monomer(VCM)[D].Shanghai:East China University of Science and Technology,2010.
[15]曾军建,等.现代化工,2016(2):72-76.Zeng Junjian,et al.Modern Chemical Industry,2016(2):72-76.
[16]Wang L,et al.Canadian Journal of Chemical Engineering,2017,95(6):1 069-1 075.
[17]Wan F,et al.Catalysis Communications,2017,101:120-124.
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[19]杨琴,等.四川化工,2007,10(5):13-15.Yang Qin,et al.Sichuan Chemical Industry,2007,10(5):13-15.
[20]戴卉,等.石河子大学学报:自科版,2014,32(6):677-682.Dai Hui,et al.Journal of Shihezi University:Natural Science,2014,32(6):677-682.
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[22]Wang B,et al.Organometallics,2017,36(3):523-529.
[23]赵璞君,等.分子催化,2014,28(3):259-267.Zhao Pujun,et al.Journal of Molecular Catalysis,2014,28(3):259-267.
[24]魏小波,等.过程工程学报,2008,8(6):1 218-1 222.Wei Xiaobo,et al.The Chinese Journal of Process Engineering,2008,8(6):1 218-1 222.
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[27]郭燕燕,等.应用化学,2014,31(5):624-626.Guo Yanyan,et al.Chinese Journal of Applied Chemistry,2014,31(5):624-626.
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[30]Xu H,et al.International Journal of Chemical Reactor Engineering,2017,15(4):1 542-1 580.
[31]Dai H,et al.Journal of Industrial&Engineering Chemistry,2017,50:72-78.
[32]Dai H,et al.Catalysts,2017,7(7):200-213.
[33]Chao S,et al.Sci Rep,2017,7:39 789-39 796.
[34]Li X,et al.Journal of Materials Science,2018,53(7):4 913-4 926.
[35]Li P,et al.Acs Catalysis,2017,7:8 572-8 577.
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