热镀锌工业设备用钢铁材料耐锌液腐蚀的研究进展
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摘要
在进行热镀锌工艺生产时,稳定辊、沉没辊、轴套等设备在连续运转过程中与锌液发生强烈腐蚀反应,明显降低设备使用的寿命,是热镀锌行业亟待解决的问题之一。针对热镀锌工业钢铁设备存在的腐蚀问题,从材料和机理角度综述了几类工业设备用钢铁材料的耐锌液研究进展,总结了研究中存在的不足,介绍了对锌液腐蚀产生重要影响的"Sandelin"效应,指出基于"Sandelin"效应研究耐锌液腐蚀性材料将成为今后重要的研究方向。
During the production of hot-dip galvanizing process,the stable roll,sunken roll,bushing and other devices in the continuous operation process often corrode due to the intense reaction with the zinc liquid,significantly reducing the life of the equipment. This is one of the problems to be solved urgently in the hot galvanizing industry. In view of the corrosion problems of iron and steel equipment in hot-dip galvanizing industry,the research progress of zinc-resistant fluids for several types of steel materials of industrial equipment was summarized from the perspective of materials and mechanisms. Besides,the deficiencies in research were pointed out. Furthermore,the"Sandelin"effect,which had the important impact on the corrosion of zinc liquids,was introduced. Finally,it was pointed out that the study on zinc-liquid corrosion-resistant materials based on the "Sandelin"effect would become an important research direction in the future.
During the production of hot-dip galvanizing process,the stable roll,sunken roll,bushing and other devices in the continuous operation process often corrode due to the intense reaction with the zinc liquid,significantly reducing the life of the equipment. This is one of the problems to be solved urgently in the hot galvanizing industry. In view of the corrosion problems of iron and steel equipment in hot-dip galvanizing industry,the research progress of zinc-resistant fluids for several types of steel materials of industrial equipment was summarized from the perspective of materials and mechanisms. Besides,the deficiencies in research were pointed out. Furthermore,the"Sandelin"effect,which had the important impact on the corrosion of zinc liquids,was introduced. Finally,it was pointed out that the study on zinc-liquid corrosion-resistant materials based on the "Sandelin"effect would become an important research direction in the future.
引文
[1]张清辉,陈冷,毛卫民,等.钢带热镀锌技术研究进展[J].金属热处理,2009,34(12):78-82.
[2] PERSSON D,THIERRY D,KARLSSON O. Corrosion and corrosion products of hot-dip galvanized steel during long term atmospheric exposure at different Sites world-wide[J].Corrosion Science,2017,(126):152-165.
[3] DING W,HEDSTROM P,LI Y. Heat treatment,microstructure and mechanical properties of a C-Mn-Al-P hot dip galvanizing trip steel[J]. Materials Science and Engineering A,2016,674:151-157.
[4]李会谦,梅雪珍,刘建明,等.沉没辊表面抗锌液腐蚀材料的研究[J].热喷涂技术,2010,2(1):24-29.
[5]李德,张楠楠,高峰.耐熔融锌液腐蚀材料的发展现状[J].材料导报,2014,18(5):61-64.
[6]车淳山,朱井军,王世卫,等. 3种低碳钢锌锅板在450℃铁饱和锌液中的腐蚀行为[J].材料保护,2014,47(11):47-49.
[7]李远鹏,江社明,张启富.高强度热镀锌双相钢的可镀性问题研究[J].钢铁研究学报,2012,24(4):1-5.
[8] RAINER G,SCHIANSKY F G,WEGMANN G.Spray forming of Ti48.9A1(at%)and subsequent hot isostatic pressing and forging[J]. Materials Science and Engineering,2002,A326(1):73-78.
[9]邓春明,刘敏,曾翠丽,等.耐锌液腐蚀热喷涂涂层的研发现状[J].腐蚀科学与防护技术,2011,23(6):453-456.
[10]孙鹏飞,张来启,林均品. 304不锈钢/Ti-45Al-8Nb电火花沉积涂层在熔锌中的腐蚀行为[J].材料热处理学报,2014,35(2):151-156.
[11]孙宏飞,徐勇,于美杰,等.耐熔锌腐蚀涂层在热镀锌设备中的应用[J].腐蚀科学与防护技术,2004,16(6):378-380.
[12]王忠民,张忠诚,毛磊,等.铸铁件表面熔铸渗硼层锌液腐蚀性能研究[J].铸造技术,2011,32(4):531-534.
[13]丁丁,张磊,李峰,等.耐锌液侵蚀保护套管材料研究现状[J].材料导报,2017,31(s1):514-518.
[14]赵磊,阎殿然,何继宁,等.耐液锌腐蚀材料的研究进展[J].材料保护,2008,41(5):62-64.
[15]樊自栓.熔融锌对热镀锌沉没辊的浸蚀机理及对策[J].热喷涂技术,2010,2(1):1-7.
[16] WANG W J,LIN J P,WANG Y L,et al. The corrosion ofFe3Al alloy in liquid zinc[J]. Corrosion Science,2007,49:1 340-1 349.
[17] WANG Y,XING J,MA S,et al. effect of 0.3 wt.%Al Addition in Flowing Liquid Zinc on the Erosion-Corrosion Behavior of Fe-3. 5 wt.%B alloy[J]. Journal of Materials Engineering and Performance,2015,24(6):2 444-2 450.
[18]刘广柱,邢建东,马胜强,等.定向凝固Fe-3.5B合金耐锌液冲蚀性能研究[J].稀有金属材料与工程2016,38(2):2 568-2 572.
[19]孙忠波.Fe2B相在Fe基合金中性质和改性研究[D].天津:河北工业大学,2007:1-3.
[20] WANG Y,XING J,MA S,et al. Interfacial morphologies and erosion-corrosion behavior of directional Fe-3. 5 wt.%B steel in flowing liquid Zn containing 0.30 wt.%Al[J]. Corrosion Science,2016,112:25-35.
[21] MA S Q,XING J,YI D,et al. Microstructure and corrosion behavior of cast Fe-B alloys dipped into liquid zinc bath[J].Materials Characterization,2010,61(9):866-872.
[22] PARAMONOV A V,ADAMOV A S,CHERNETSOV V Y.Production problems of hot dip galvanized metal structures[J]. Metallurgist,2011,54(11/12):793-796.
[23]张启富,刘邦津,黄建中.现代钢带连续热镀锌[M].北京:冶金工业出版社,2007:42-44
[24] KHAN F F,BAE G,KANG K,et al. Development of cermet coatings by kinetic spray technology for the application of die-soldering and erosion resistance[J]. Surface and Coatings Technology,2009,204(3):345-352.
[25]车淳山,卢锦堂,陈锦虹,等.热镀锌中圣德林效应微观机理的解释模型[J].材料保护,2004,37(8):26-28.
[26]苏旭平,李智,尹付成,等.热浸镀中硅反应性研究[J].金属学报,2008,44(6):718-722.
[27]赵满秀.合金元素对热浸镀锌界面反应影响及相关相平衡研究[D].湘潭:湘潭大学,2012:34-35
[28]马瑞娜,曹晓明,温鸣,等. Si对Fe-2.5B合金在锌液中腐蚀机制的影响[J].材料科学与工程学报,2006,24(4):592-596.
[29]张艺,李洪波,刘俊友.硅对铁基合金耐液锌腐蚀的影响[J].腐蚀与防护,2009,30(10):704-707.
[30]李虹云,马瑞娜,曹晓明,等. Fe-B共晶合金在锌液中的腐蚀行为[J].腐蚀与防护,2010,31(12):905-908.
[31]冯立丽.定向Fe-B合金锌液静态腐蚀的“Sandelin”效应研究[D].阜新:辽宁工程技术大学,2018:22-25.
[32] CULCASI J D,SERE P R,ELSNER C I,et al.. Control of the growth of zinc-iron phases in the hot-dip galvanizing process[J]. Surface and Coatings Technology,1999,122(1):21-23.
[33]王晖,张广伟,孟晓霞,等.热镀锌沉没辊的耐锌腐蚀失效过程[J].中国表面工程,2012,25(3):42-46.
[34]李鹏.喷涂陶瓷涂层316L不锈钢的耐熔锌腐蚀性能[D].呼和浩特:内蒙古工业大学,2013:36-37.
[35]叶四友,刘建永,杨伟.激光熔覆316L不锈钢涂层组织和性能的研究[J].表面技术,2018(3):48-53.
[36] JORDAN C,MARDER A. Fe-Zn phase formation in interstitial-free steels hot-dip galvanized at 450℃[J]. Journal of Materials science. 1997,32(21):5 593-5 602.
[37]孔纲,卢锦堂.热浸镀浴中少量铝对镀层性能的影响[J],材料保护,2002,35(7):17-19.
[38]马永庆,王庆华,齐育红,等. Al-Si合金铸铁抗锌液腐蚀的研究[J].材料保护,1999,32(3):37-39.
[39]李永梅,马瑞娜,曹晓明,等.纯铁和Fe-Al金属间化合物在液锌中的腐蚀研究[J].热加工工艺,2009,38(8):1-6.
[2] PERSSON D,THIERRY D,KARLSSON O. Corrosion and corrosion products of hot-dip galvanized steel during long term atmospheric exposure at different Sites world-wide[J].Corrosion Science,2017,(126):152-165.
[3] DING W,HEDSTROM P,LI Y. Heat treatment,microstructure and mechanical properties of a C-Mn-Al-P hot dip galvanizing trip steel[J]. Materials Science and Engineering A,2016,674:151-157.
[4]李会谦,梅雪珍,刘建明,等.沉没辊表面抗锌液腐蚀材料的研究[J].热喷涂技术,2010,2(1):24-29.
[5]李德,张楠楠,高峰.耐熔融锌液腐蚀材料的发展现状[J].材料导报,2014,18(5):61-64.
[6]车淳山,朱井军,王世卫,等. 3种低碳钢锌锅板在450℃铁饱和锌液中的腐蚀行为[J].材料保护,2014,47(11):47-49.
[7]李远鹏,江社明,张启富.高强度热镀锌双相钢的可镀性问题研究[J].钢铁研究学报,2012,24(4):1-5.
[8] RAINER G,SCHIANSKY F G,WEGMANN G.Spray forming of Ti48.9A1(at%)and subsequent hot isostatic pressing and forging[J]. Materials Science and Engineering,2002,A326(1):73-78.
[9]邓春明,刘敏,曾翠丽,等.耐锌液腐蚀热喷涂涂层的研发现状[J].腐蚀科学与防护技术,2011,23(6):453-456.
[10]孙鹏飞,张来启,林均品. 304不锈钢/Ti-45Al-8Nb电火花沉积涂层在熔锌中的腐蚀行为[J].材料热处理学报,2014,35(2):151-156.
[11]孙宏飞,徐勇,于美杰,等.耐熔锌腐蚀涂层在热镀锌设备中的应用[J].腐蚀科学与防护技术,2004,16(6):378-380.
[12]王忠民,张忠诚,毛磊,等.铸铁件表面熔铸渗硼层锌液腐蚀性能研究[J].铸造技术,2011,32(4):531-534.
[13]丁丁,张磊,李峰,等.耐锌液侵蚀保护套管材料研究现状[J].材料导报,2017,31(s1):514-518.
[14]赵磊,阎殿然,何继宁,等.耐液锌腐蚀材料的研究进展[J].材料保护,2008,41(5):62-64.
[15]樊自栓.熔融锌对热镀锌沉没辊的浸蚀机理及对策[J].热喷涂技术,2010,2(1):1-7.
[16] WANG W J,LIN J P,WANG Y L,et al. The corrosion ofFe3Al alloy in liquid zinc[J]. Corrosion Science,2007,49:1 340-1 349.
[17] WANG Y,XING J,MA S,et al. effect of 0.3 wt.%Al Addition in Flowing Liquid Zinc on the Erosion-Corrosion Behavior of Fe-3. 5 wt.%B alloy[J]. Journal of Materials Engineering and Performance,2015,24(6):2 444-2 450.
[18]刘广柱,邢建东,马胜强,等.定向凝固Fe-3.5B合金耐锌液冲蚀性能研究[J].稀有金属材料与工程2016,38(2):2 568-2 572.
[19]孙忠波.Fe2B相在Fe基合金中性质和改性研究[D].天津:河北工业大学,2007:1-3.
[20] WANG Y,XING J,MA S,et al. Interfacial morphologies and erosion-corrosion behavior of directional Fe-3. 5 wt.%B steel in flowing liquid Zn containing 0.30 wt.%Al[J]. Corrosion Science,2016,112:25-35.
[21] MA S Q,XING J,YI D,et al. Microstructure and corrosion behavior of cast Fe-B alloys dipped into liquid zinc bath[J].Materials Characterization,2010,61(9):866-872.
[22] PARAMONOV A V,ADAMOV A S,CHERNETSOV V Y.Production problems of hot dip galvanized metal structures[J]. Metallurgist,2011,54(11/12):793-796.
[23]张启富,刘邦津,黄建中.现代钢带连续热镀锌[M].北京:冶金工业出版社,2007:42-44
[24] KHAN F F,BAE G,KANG K,et al. Development of cermet coatings by kinetic spray technology for the application of die-soldering and erosion resistance[J]. Surface and Coatings Technology,2009,204(3):345-352.
[25]车淳山,卢锦堂,陈锦虹,等.热镀锌中圣德林效应微观机理的解释模型[J].材料保护,2004,37(8):26-28.
[26]苏旭平,李智,尹付成,等.热浸镀中硅反应性研究[J].金属学报,2008,44(6):718-722.
[27]赵满秀.合金元素对热浸镀锌界面反应影响及相关相平衡研究[D].湘潭:湘潭大学,2012:34-35
[28]马瑞娜,曹晓明,温鸣,等. Si对Fe-2.5B合金在锌液中腐蚀机制的影响[J].材料科学与工程学报,2006,24(4):592-596.
[29]张艺,李洪波,刘俊友.硅对铁基合金耐液锌腐蚀的影响[J].腐蚀与防护,2009,30(10):704-707.
[30]李虹云,马瑞娜,曹晓明,等. Fe-B共晶合金在锌液中的腐蚀行为[J].腐蚀与防护,2010,31(12):905-908.
[31]冯立丽.定向Fe-B合金锌液静态腐蚀的“Sandelin”效应研究[D].阜新:辽宁工程技术大学,2018:22-25.
[32] CULCASI J D,SERE P R,ELSNER C I,et al.. Control of the growth of zinc-iron phases in the hot-dip galvanizing process[J]. Surface and Coatings Technology,1999,122(1):21-23.
[33]王晖,张广伟,孟晓霞,等.热镀锌沉没辊的耐锌腐蚀失效过程[J].中国表面工程,2012,25(3):42-46.
[34]李鹏.喷涂陶瓷涂层316L不锈钢的耐熔锌腐蚀性能[D].呼和浩特:内蒙古工业大学,2013:36-37.
[35]叶四友,刘建永,杨伟.激光熔覆316L不锈钢涂层组织和性能的研究[J].表面技术,2018(3):48-53.
[36] JORDAN C,MARDER A. Fe-Zn phase formation in interstitial-free steels hot-dip galvanized at 450℃[J]. Journal of Materials science. 1997,32(21):5 593-5 602.
[37]孔纲,卢锦堂.热浸镀浴中少量铝对镀层性能的影响[J],材料保护,2002,35(7):17-19.
[38]马永庆,王庆华,齐育红,等. Al-Si合金铸铁抗锌液腐蚀的研究[J].材料保护,1999,32(3):37-39.
[39]李永梅,马瑞娜,曹晓明,等.纯铁和Fe-Al金属间化合物在液锌中的腐蚀研究[J].热加工工艺,2009,38(8):1-6.