由异烟酰腙构建的多孔状Zn(Ⅱ) 配位聚合物{[Zn(L)_2(H_2O)_2]·4H_2O}_n的合成及其晶体结构
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摘要
以邻甲酰基苯磺酸钠和异烟肼为原料在乙醇/水溶液中制备了一种酰腙类Schiff碱配体(NaL),采用常规溶液挥发法合成了由该配体构筑的Zn((Ⅱ)配位聚合物{[Zn(L)2(H2O)2]·4H2O}n。利用元素分析、IR、TGA和X-射线单晶衍射分析对配合物进行了表征。配合物晶体属三斜晶系,P1空间群,晶胞参数a=0.786 98(4)nm,b=0.869 26(5)nm,c=1.180 44(7)nm,α=103.353(5)°,β=100.965(4)°,γ=93.123(4)°,Z=1,V=0.767 24(7)nm3,Dc=1.697 g·cm-3。每个Zn(Ⅱ)离子被2个配体L-阴离子双重桥联形成二核环状结构单元,并通过共用锌离子形成一维链配位聚合物,链与链之间通过氢键扩展为具有一维开放孔道的三维超分子网络结构。
An acylhydrazone-type Schiff base ligand(NaL) was synthesized by reaction of sodium 2-formylbenzene sulfonate with isoniazide in a mixture of ethanol and water.A Zn(Ⅱ) coordination polymer {[Zn(L)2(H2O)2]·4H2O}n have been synthesized by employing the solution preparation method at room temperature and characterized by elemental analysis,IR,TGA and X-ray diffraction structural analysis.Crystal data:triclinic system,space group P1,a=0.786 98(4) nm,b=0.869 26(5) nm,c=1.180 44(7) nm,α=103.353(5)°,β=100.965(4)°,γ=93.123(4)°,Z=1,V =0.767 24(7) nm3,Dc=1.697 g·cm-3.Each Zn (Ⅱ) ion is bridged by two L-ligands in the monodentatemonodentate mode to form a ring-like dimer units,and a one-dimensional chain is built by sharing a Zn (Ⅱ) ion between the units.The adjacent chains are linked into a 3D supramolecular network structure via hydrogen bonds and π-π interactions with a 1D open channel that are occupied by solvent molecules.CCDC:934292.
An acylhydrazone-type Schiff base ligand(NaL) was synthesized by reaction of sodium 2-formylbenzene sulfonate with isoniazide in a mixture of ethanol and water.A Zn(Ⅱ) coordination polymer {[Zn(L)2(H2O)2]·4H2O}n have been synthesized by employing the solution preparation method at room temperature and characterized by elemental analysis,IR,TGA and X-ray diffraction structural analysis.Crystal data:triclinic system,space group P1,a=0.786 98(4) nm,b=0.869 26(5) nm,c=1.180 44(7) nm,α=103.353(5)°,β=100.965(4)°,γ=93.123(4)°,Z=1,V =0.767 24(7) nm3,Dc=1.697 g·cm-3.Each Zn (Ⅱ) ion is bridged by two L-ligands in the monodentatemonodentate mode to form a ring-like dimer units,and a one-dimensional chain is built by sharing a Zn (Ⅱ) ion between the units.The adjacent chains are linked into a 3D supramolecular network structure via hydrogen bonds and π-π interactions with a 1D open channel that are occupied by solvent molecules.CCDC:934292.
引文
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[4]Jena H S,Manivannan V.Inorg.Chim.Acta,2013,394:210-219
[5]R覿is覿nen M T,Korpi H,Sundberg M R,et al.Inorg.Chim.Acta,2013,394:203-209
[6]WEI Tai-Bao(魏太保),LEN Yan-Li(冷艳丽),WANG YongCheng(王永成),et al.Chinese J.Org.Chem.(有机化学),2009,29(2):216-221
[7]YI De-Shuai(尹德帅),XU Xing-You(许兴友),CHEN ZhiDong(陈智栋),et al.J.Synthetic Crystals(人工晶体学报),2009,38(4):1037-1041
[8]JIN Li-Xia(金黎霞),LIU Zheng(刘峥),XIA Ji-Hong(夏金虹).J.Synthetic Crystals(人工晶体学报),2007,36(3):705-710
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[10]ZHANG Ying-Xue(张莹雪),TIAN Yu-Ping(田玉平),LI Yan(李琰)et al.Chem.Res.(化学研究),2011,22(6):13-16
[11]Pouralimardan O,Chamayou A-C,Janiak C,et al.Inorg.Chim.Acta,2006,360:1599-1608
[12]CAI Tie-Jun(蔡铁军),PENG Zhen-Shan(彭振山),DENG Qian(邓谦),et al.Chinese J.Inorg.Chem.(无机化学学报),2004,20:731-733
[13]WU Wen-Shi(吴文士),FENG Yun-Long(冯云龙),LAN XinRen(蓝心仁),et al.Chinese J.Appl.Chem.(应用化学),2004,21(2):135-139
[14]HUANG Zhi-Wei(黄志伟),LIU Xing(刘星),LI Zhong-Liang(黎中良).Chem.Res.and Appl.(化学研究与应用),2011,23(4):457-461
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[18]Chen C T,Suslick K S.Coord.Chem.Rev.,1993,128(1/2):293-322
[19]FANG Xiang-Qian(方向倩),CHEN Peng-Gang(陈鹏刚),ZHU Zhi-Biao(朱志彪),et al.Chinese J.Inorg.Chem.(无机化学学报),2011,27:1733-1737
[20]CHU Zhao-Hua(储召华),XIE Qing-Fan(解庆范),CHEN Yan-Min(陈延民).Chinese J.Inorg.Chem.(无机化学学报),2013,29:1893-1896
[21]Sheldrick G M.SHELX-97,Program for X-ray Crystal Structure Solution and Refinement,University of Gttingen,Germany,1997.
[22]Zaman G,Delibas N C,Necefoglu H,et al.Acta Cryst.,2013,E69:m198-m199
[23]HUO Yong-Qian(霍涌前),WANG Sheng-Wen(王升文),CUI Hua-Li(崔华莉),et al.Chinese J.Inorg.Chem.(无机化学学报),2010,26:1274-1478
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[25]SONG Jing-Hao(宋金浩),GU Ya-Kun(顾雅琨),LI Xia(李夏).Chinese J.Inorg.Chem.(无机化学学报),2010,26:1457-1462
[26]HU Jing-Shong(胡劲松),LIU Xi-Hui(刘希慧),SHI Jian-Jun(石建军),et al.Chinese J.Inorg.Chem.(无机化学学报),2013,29:444-448
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[28]CHEN Man-Sheng(陈满生),HUANG Miao-Lin(黄妙龄),DENG Yi-Fang(邓奕芳),et al.Chinese J.Inorg.Chem.(无机化学学报),2011,27:561-564
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