蓝光钙钛矿发光二极管:机遇与挑战
|
摘要
基于金属卤化物钙钛矿材料制备的发光二极管(LED)发展迅速,短短五年内,近红外、红光和绿光钙钛矿发光器件的外量子效率均超过了20%,在显示与照明领域展示出很好的应用前景.然而,蓝光钙钛矿LED的性能相对较差,制约了钙钛矿LED在全色显示领域的应用.目前,实现钙钛矿蓝光主要有两种方式,一种是基于卤素掺杂的组分工程,另一种是基于量子限域效应的维度调控.本文主要介绍了基于这两种方法的蓝光钙钛矿LED的发展历程,讨论了蓝光钙钛矿LED面临的主要问题,并对如何提升蓝光钙钛矿LED性能进行展望.
The great progress of light-emitting diodes(LEDs) has been made based on perovskites, and the external quantum efficiency of near infrared, red and green devices have reached > 20%, exhibiting their great potential applications in lighting and displays. However, the performance of blue perovskite LEDs is very poor, thus limiting their applications in the field of full-color displays. The blue perovskite LEDs can be achieved through mixed halides or quantum confinement effect. In this paper, we review the research progress of blue perovskite LEDs based on these two strategies, discuss the challenges to achieve high-performance perovskite LEDs and present our perspectives.
The great progress of light-emitting diodes(LEDs) has been made based on perovskites, and the external quantum efficiency of near infrared, red and green devices have reached > 20%, exhibiting their great potential applications in lighting and displays. However, the performance of blue perovskite LEDs is very poor, thus limiting their applications in the field of full-color displays. The blue perovskite LEDs can be achieved through mixed halides or quantum confinement effect. In this paper, we review the research progress of blue perovskite LEDs based on these two strategies, discuss the challenges to achieve high-performance perovskite LEDs and present our perspectives.
引文
[1]Deschler F,Price M,Pathak S,Klintberg L E,Jarausch D D,Higler R,Hüttner S,Leijtens T,Stranks S D,Snaith H J,Atatüre M,Phillips R T,Friend R H 2014 J.Phys.Chem.Lett.5 1421
[2]Tan Z K,Moghaddam R S,Lai M L,Docampo P,Higler R,Deschler F,Price M,Sadhanala A,Pazos L M,Credgington D,Hanusch F,Bein T,Snaith H J,Friend R H 2014 Nat.Nanotechnol.9 687
[3]Wang J,Wang N,Jin Y,Si J,Tan Z K,Du H,Cheng L,Dai X,Bai S,He H,Ye Z,Lai M L,Friend R H,Huang W 2015Adv.Mater.27 2311
[4]Era M,Morimoto S,Tsutsui T,Saito S 1994 Appl.Phys.Lett.65 676
[5]Lin K,Xing J,Quan L N,Arquer F P G de,Gong X,Lu J,Xie L,Zhao W,Zhang D,Yan C,Li W,Liu X,Lu Y,Kirman J,Sargent E H,Xiong Q,Wei Z 2018 Nature 562 245
[6]Cao Y,Wang N,Tian H,Guo J,Wei Y,Chen H,Miao Y,Zou W,Pan K,He Y,Cao H,Ke Y,Xu M,Wang Y,Yang M,Du K,Fu Z,Kong D,Dai D,Jin Y,Li G,Li H,Peng Q,Wang J,Huang W 2018 Nature 562 249
[7]Chiba T,Hayashi Y,Ebe H,Hoshi K,Sato J,Sato S,Pu Y J,Ohisa S,Kido J 2018 Nat.Photon.12 681
[8]Zhao B,Bai S,Kim V,Lamboll R,Shivanna R,Auras F,Richter J M,Yang L,Dai L,Alsari M,She X J,Liang L,Zhang J,Lilliu S,Gao P,Snaith H J,Wang J,Greenham NC,Friend R H,Di D 2018 Nat.Photon.12 783
[9]Xu W,Hu Q,Bai S,Bao C,Miao Y,Yuan Z,Borzda T,Barker A J,Tyukalova E,Hu Z,Kawecki M,Wang H,Yan Z,Liu X,Shi X,Uvdal K,Fahlman M,Zhang W,Duchamp M,Liu J M,Petrozza A,Wang J,Liu L M,Huang W,Gao F2019 Nat.Photon.13 418
[10]Cheng L,Cao Y,Ge R,Wei Y Q,Wang N N,Wang J P,Huang W 2017 Chin.Chem.Lett.28 29
[11]Li Z,Chen Z,Yang Y,Xue Q,Yip H L,Cao Y 2019 Nat.Commun.10 1027
[12]Sadhanala A,Ahmad S,Zhao B,Giesbrecht N,Pearce P M,Deschler F,Hoye R L Z,G?del K C,Bein T,Docampo P,Dutton S E,de Volder M F L,Friend R H 2015 Nano Lett.15 6095
[13]Kumawat N K,Dey A,Kumar A,Gopinathan S P,Narasimhan K L,Kabra D 2015 ACS Appl.Mater.Interfaces7 13119
[14]Kim H P,Kim J,Kim B S,Kim H M,Kim J,Yusoff A R bin M,Jang J,Nazeeruddin M K 2017 Adv.Opt.Mater.51600920
[15]Song J,Li J,Li X,Xu L,Dong Y,Zeng H 2015 Adv.Mater.27 7162
[16]Hou S,Gangishetty M K,Quan Q,Congreve D N 2018 Joule2 2421
[17]Chen Z,Zhang C,Jiang X F,Liu M,Xia R,Shi T,Chen D,Xue Q,Zhao Y J,Su S,Yip H L,Cao Y 2017 Adv.Mater.29 1603157
[18]Xing J,Zhao Y,Askerka M,Quan L N,Gong X,Zhao W,Zhao J,Tan H,Long G,Gao L,Yang Z,Voznyy O,Tang J,Lu Z H,Xiong Q,Sargent E H 2018 Nat.Commun.9 3541
[19]Jiang Y,Qin C,Cui M,He T,Liu K,Huang Y,Luo M,Zhang L,Xu H,Li S,Wei J,Liu Z,Wang H,Kim G H,Yuan M,Chen J 2019 Nat.Commun.10 1868
[20]Wang K H,Peng Y,Ge J,Jiang S,Zhu B S,Yao J,Yin Y C,Yang J N,Zhang Q,Yao H B 2019 ACS Photon.6 667
[21]Vashishtha P,Ng M,Shivarudraiah S B,Halpert J E 2019Chem.Mater.31 83
[22]Gangishetty M K,Hou S,Quan Q,Congreve D N 2018 Adv.Mater.30 1706226
[23]Wang N,Cheng L,Ge R,Zhang S,Miao Y,Zou W,Yi C,Sun Y,Cao Y,Yang R,Wei Y,Guo Q,Ke Y,Yu M,Jin Y,Liu Y,Ding Q,Di D,Yang L,Xing G,Tian H,Jin C,Gao F,Friend R H,Wang J,Huang W 2016 Nat.Photon.10 699
[24]Sun Y,Zhang L,Wang N,Zhang S,Cao Y,Miao Y,Xu M,Zhang H,Li H,Yi C,Wang J,Huang W 2018 npj Flexible Electron.2 12
[25]Zou W,Li R,Zhang S,Liu Y,Wang N,Cao Y,Miao Y,Xu M,Guo Q,Di D,Zhang L,Yi C,Gao F,Friend R H,Wang J,Huang W 2018 Nat.Commun.9 608
[26]Li G,Rivarola F W R,Davis N J L K,Bai S,Jellicoe T C,de la Pe?a F,Hou S,Ducati C,Gao F,Friend R H,Greenham N C,Tan Z K 2016 Adv.Mater.28 3528
[27]Yang M,Wang N,Zhang S,Zou W,He Y,Wei Y,Xu M,Wang J,Huang W 2018 J.Phys.Chem.Lett.9 2038
[28]Ke Y,Wang N,Kong D,Cao Y,He Y,Zhu L,Wang Y,Xue C,Peng Q,Gao F,Huang W,Wang J 2019 J.Phys.Chem.Lett.10 380
[29]Wang F,Geng W,Zhou Y,Fang H H,Tong C J,Loi M A,Liu L M,Zhao N 2016 Adv.Mater.28 9986
[30]Li C,Guerrero A,Huettner S,Bisquert J 2018 Nat.Commun.9 5113
[31]Zhang J,Yang Y,Deng H,Farooq U,Yang X,Khan J,Tang J,Song H 2017 ACS Nano 11 9294
[32]Jun T,Sim K,Iimura S,Sasase M,Kamioka H,Kim J,Hosono H 2018 Adv.Mater.30 1804547
[2]Tan Z K,Moghaddam R S,Lai M L,Docampo P,Higler R,Deschler F,Price M,Sadhanala A,Pazos L M,Credgington D,Hanusch F,Bein T,Snaith H J,Friend R H 2014 Nat.Nanotechnol.9 687
[3]Wang J,Wang N,Jin Y,Si J,Tan Z K,Du H,Cheng L,Dai X,Bai S,He H,Ye Z,Lai M L,Friend R H,Huang W 2015Adv.Mater.27 2311
[4]Era M,Morimoto S,Tsutsui T,Saito S 1994 Appl.Phys.Lett.65 676
[5]Lin K,Xing J,Quan L N,Arquer F P G de,Gong X,Lu J,Xie L,Zhao W,Zhang D,Yan C,Li W,Liu X,Lu Y,Kirman J,Sargent E H,Xiong Q,Wei Z 2018 Nature 562 245
[6]Cao Y,Wang N,Tian H,Guo J,Wei Y,Chen H,Miao Y,Zou W,Pan K,He Y,Cao H,Ke Y,Xu M,Wang Y,Yang M,Du K,Fu Z,Kong D,Dai D,Jin Y,Li G,Li H,Peng Q,Wang J,Huang W 2018 Nature 562 249
[7]Chiba T,Hayashi Y,Ebe H,Hoshi K,Sato J,Sato S,Pu Y J,Ohisa S,Kido J 2018 Nat.Photon.12 681
[8]Zhao B,Bai S,Kim V,Lamboll R,Shivanna R,Auras F,Richter J M,Yang L,Dai L,Alsari M,She X J,Liang L,Zhang J,Lilliu S,Gao P,Snaith H J,Wang J,Greenham NC,Friend R H,Di D 2018 Nat.Photon.12 783
[9]Xu W,Hu Q,Bai S,Bao C,Miao Y,Yuan Z,Borzda T,Barker A J,Tyukalova E,Hu Z,Kawecki M,Wang H,Yan Z,Liu X,Shi X,Uvdal K,Fahlman M,Zhang W,Duchamp M,Liu J M,Petrozza A,Wang J,Liu L M,Huang W,Gao F2019 Nat.Photon.13 418
[10]Cheng L,Cao Y,Ge R,Wei Y Q,Wang N N,Wang J P,Huang W 2017 Chin.Chem.Lett.28 29
[11]Li Z,Chen Z,Yang Y,Xue Q,Yip H L,Cao Y 2019 Nat.Commun.10 1027
[12]Sadhanala A,Ahmad S,Zhao B,Giesbrecht N,Pearce P M,Deschler F,Hoye R L Z,G?del K C,Bein T,Docampo P,Dutton S E,de Volder M F L,Friend R H 2015 Nano Lett.15 6095
[13]Kumawat N K,Dey A,Kumar A,Gopinathan S P,Narasimhan K L,Kabra D 2015 ACS Appl.Mater.Interfaces7 13119
[14]Kim H P,Kim J,Kim B S,Kim H M,Kim J,Yusoff A R bin M,Jang J,Nazeeruddin M K 2017 Adv.Opt.Mater.51600920
[15]Song J,Li J,Li X,Xu L,Dong Y,Zeng H 2015 Adv.Mater.27 7162
[16]Hou S,Gangishetty M K,Quan Q,Congreve D N 2018 Joule2 2421
[17]Chen Z,Zhang C,Jiang X F,Liu M,Xia R,Shi T,Chen D,Xue Q,Zhao Y J,Su S,Yip H L,Cao Y 2017 Adv.Mater.29 1603157
[18]Xing J,Zhao Y,Askerka M,Quan L N,Gong X,Zhao W,Zhao J,Tan H,Long G,Gao L,Yang Z,Voznyy O,Tang J,Lu Z H,Xiong Q,Sargent E H 2018 Nat.Commun.9 3541
[19]Jiang Y,Qin C,Cui M,He T,Liu K,Huang Y,Luo M,Zhang L,Xu H,Li S,Wei J,Liu Z,Wang H,Kim G H,Yuan M,Chen J 2019 Nat.Commun.10 1868
[20]Wang K H,Peng Y,Ge J,Jiang S,Zhu B S,Yao J,Yin Y C,Yang J N,Zhang Q,Yao H B 2019 ACS Photon.6 667
[21]Vashishtha P,Ng M,Shivarudraiah S B,Halpert J E 2019Chem.Mater.31 83
[22]Gangishetty M K,Hou S,Quan Q,Congreve D N 2018 Adv.Mater.30 1706226
[23]Wang N,Cheng L,Ge R,Zhang S,Miao Y,Zou W,Yi C,Sun Y,Cao Y,Yang R,Wei Y,Guo Q,Ke Y,Yu M,Jin Y,Liu Y,Ding Q,Di D,Yang L,Xing G,Tian H,Jin C,Gao F,Friend R H,Wang J,Huang W 2016 Nat.Photon.10 699
[24]Sun Y,Zhang L,Wang N,Zhang S,Cao Y,Miao Y,Xu M,Zhang H,Li H,Yi C,Wang J,Huang W 2018 npj Flexible Electron.2 12
[25]Zou W,Li R,Zhang S,Liu Y,Wang N,Cao Y,Miao Y,Xu M,Guo Q,Di D,Zhang L,Yi C,Gao F,Friend R H,Wang J,Huang W 2018 Nat.Commun.9 608
[26]Li G,Rivarola F W R,Davis N J L K,Bai S,Jellicoe T C,de la Pe?a F,Hou S,Ducati C,Gao F,Friend R H,Greenham N C,Tan Z K 2016 Adv.Mater.28 3528
[27]Yang M,Wang N,Zhang S,Zou W,He Y,Wei Y,Xu M,Wang J,Huang W 2018 J.Phys.Chem.Lett.9 2038
[28]Ke Y,Wang N,Kong D,Cao Y,He Y,Zhu L,Wang Y,Xue C,Peng Q,Gao F,Huang W,Wang J 2019 J.Phys.Chem.Lett.10 380
[29]Wang F,Geng W,Zhou Y,Fang H H,Tong C J,Loi M A,Liu L M,Zhao N 2016 Adv.Mater.28 9986
[30]Li C,Guerrero A,Huettner S,Bisquert J 2018 Nat.Commun.9 5113
[31]Zhang J,Yang Y,Deng H,Farooq U,Yang X,Khan J,Tang J,Song H 2017 ACS Nano 11 9294
[32]Jun T,Sim K,Iimura S,Sasase M,Kamioka H,Kim J,Hosono H 2018 Adv.Mater.30 1804547