预处理技术在生物质热裂解中的应用
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摘要
生物质能源是一种新型绿色可再生能源,对其开发利用已成为国内外研究热点。笔者综述了预处理技术在生物质热裂解领域中的相关应用及发展现状,重点分析比较了物理预处理、化学预处理及生物预处理等技术对热裂解产物的影响,归纳总结了生物质热裂解预处理技术的发展趋势,即根据生物质的物化特性和热裂解目标产物来选用不同的预处理方式。
Biomass energy is a kind of n ew-type green renewable energy, which attracts worldwide research on its development and utilization. This paper reviews the current development of biomass pretreatment technology and related applications, focusing on comparing the physical, chemical and biological pretreatment technology's influence on the thermal cracking products. The paper also summarizes the development trend of biomass pyrolysis pretreatment technology, namely, choosing proper pretreatment method according to the different physical and chemical characteristics of biomass and target pyrolysis products.
Biomass energy is a kind of n ew-type green renewable energy, which attracts worldwide research on its development and utilization. This paper reviews the current development of biomass pretreatment technology and related applications, focusing on comparing the physical, chemical and biological pretreatment technology's influence on the thermal cracking products. The paper also summarizes the development trend of biomass pyrolysis pretreatment technology, namely, choosing proper pretreatment method according to the different physical and chemical characteristics of biomass and target pyrolysis products.
引文
[1]朱锡峰.生物质热解原理与技术[M].合肥:中国科学技术大学出版社,2006.
[2]Bridgwater A V.Review of fast pyrolysis of biomass and product upgrading[J].Biomass Bioenergy,2012,38:68-94.
[3]Xu J M,Jiang J C,Chen J,et al.Biofuel production from catalytic cracking of woody oils[J].Bioresource Technology,2010,101(14):5586-5591.
[4]Zhang L,Liu R H,Yin R Z,et al.Upgrading of bio-oil from biomass fast pyrolysis in china:a review[J].Renewable and sustainable ener gy reviews,2013,24:66-72.
[5]Xiu S G,Shahbazi A.Bio-oil production and upgrading research:a review[J].Renewable and Sustainable Energy Reviews,2012,16(7):4406-4414.
[6]Hakim S H,Shangks B H,Dumesic J A.Catalytic upgrading of the light fraction of a simulated bio-oil over ce zr ox catalyst[J].Applied Catalysis B:Environmental,2013,142:368-376.
[7]Yu F W,Gao L C,Wang W J,et al.Bio-fuel production from the catalytic pyrolysis of soybean oil over Me-AL-MCM-41(Me=La,Ni or Fe)mesoporous materials[J].Applied Catalysis B:Environmental,2013,10:1-5.
[8]龚春晓.不同粉碎预处理方式对烘焙松木屑的影响[D].北京:中国农业大学,2016.
[9]Ibrahim R H,Darvell I,Jones J M,et al.Physicochemical characterization of torrified biomass[J].Journal of Analytical and Applied Pyrolysis,2013,103:21-30.
[10]Girard P,Shah N.Recent developments on torrified wood:an alternative to charcoal for reducing deforestation[J].REUR Technical Series,1991,20:101-114.
[11]Zheng A Q,Zhao Z L,Chang S,et al.Effect of torrefaction temperature on product distribution from two-staged pyrolysis of biomass[J].Energy&Fuels,2012,26(5):2968-2974.
[12]杨晴,梅艳阳,郝宏蒙,等.烘焙对生物质热解产物特性的影响[J].农业工程学报,2013,29(20):214-219.
[13]Sabil K M,Aziz M A,Lal B,et al.Effects of torrefaction on the physiochemical properties of oil palm empty fruit bunches,mosocarp fiber and kernel shell[J].Biomass and Bioenergy,2013,56:351-360.
[14]郝宏蒙,杨海平,刘汝杰,等.烘培对典型农业秸秆吸水性能的影响[J].中国电机工程学报,2013,33(8):90-94.
[15]Couhert C,Salvdor S,Commandre M.Impact of torrefaction on syngas production from wood[J].Fuel,2009,88(11):2286-2290.
[16]Bridgeman T G,Jones J M,Shield I,et al.Torrefaction of reed canary grass wheat straw and willow to enhance solid fuel qualities and combustion properities[J].Fuel,2008,87(6):844-859.
[17]Felflia F F,Luengob C A,Suarez J A,et al.Wood briquette torrefaction[J].Energy for Sustainable Development,2005,9(3):19-22.
[18]Prins M J,Ptasinski K J,Janssen F J J G.More efficient biomass gasification via torrefaction[J].Energy,2006,31(15):3458-3470.
[19]陈登宇.干燥和烘焙预处理制备高品质生物质原料的基础研究[D].合肥:中国科学技术大学,2013.
[20]陈登宇,张鸿儒,刘栋,等.烘焙预处理对秸秆热解产物品质及能量分布的影响[J].太阳能学报,2017,38(2):565-570.
[21]曾庆倬,于凤文,盛佳峰,等.微波对生物质原料预处理及热解的作用研究进展[J].过程工程学报,2013,13(6):1061-1067.
[22]Moseley J D,Kappe C O.A critical assessment of the greenness and energy efficiency of microwave-assisted organic synthesis[J].Green Chemistry,2011,13:794-806.
[23]Menendez J A,Arenillas A,Fidalgo B,et al.Microwave heating processes involving carbon materials[J].Fuel Processing Technology,2010,91(1):1-8.
[24]Huang Y F,Chen W R,Chiueh P T,et al.Microwave torrefaction of rice straw and pennisetum[J].Bioresource Technology,2012,123:1-7.
[25]Wang W H,Chen H P.The influence of microwave drying on biomass pyrolysis[J].Energy&Fuels,2008,22:67-74.
[26]刘媛,卢翠香,陈健波,等.微波干燥过程中尾巨桉木材含水率变化特性[J].广西林业科学,2017,46(3):262-265.
[27]胡国荣,张帅,王贤华,等.微波预处理对生物质干燥特性及理化性质的影响[J].太阳能学报,2017,38(10):2693-2697.
[28]唐洪涛.辐照预处理对玉米秸秆酶解产糖率的影响[D].北京:中国农业科学院,2012.
[29]胡婷春.Co-γ辐照处理降解芒草纤维质及其机理研究[D].长沙:湖南农业大学,2011.
[30]韩丹妮.稻壳预处理及稻壳中木聚糖的提取工艺研究[D].长沙:长沙理工大学,2012.
[31]徐绍华,武书彬,尉慰奇.桉木三组分在高温热水预处理及酶解糖化中的规律研究[J].林产化学与工业,2013,33(1):21-26.
[32]马静.热水预处理杨木半纤维素的局部化学溶解机理[D].北京:北京林业大学,2015.
[33]Saha B C,Yoshida T,Cotta M A,et al.Hydrothermal pretreatment and enzymatic saccharification of corn stover for efficient ethanol production[J].Industrial Crops and Products,2013,44:367-372.
[34]Kont R,Kurain M,Teugjas H,et al.Strong cellulase inhibitors from the hydrothermal pretreatment of wheat straw[J].Biotechnology for Biofuels,2013(6):135-148.
[35]邓磊,张涛,刘银河,等.水洗对生物质燃料特性及燃烧特性的影响[J].工程热物理学报,2010,31(7):1239-1242.
[36]陈东雨,刘荣厚,蔡均猛.预处理甜高粱茎秆残渣的热解动力学研究[J].农业工程学报,2007,23(2):188-194.
[37]姬登祥,黄承洁,于平,等.原料预处理对生物质热裂解动力学特性的影响[J].农业工程学报,2011,27(S1):112-117.
[38]Patwardhan P R,Satrio J A,Brown R C,et al.Influence of inorganic salts on the primary pyrolysis products of cellulose[J].Bioresource Technology,2010,101(12):4646-4655.
[39]陈威,刘苇,侯庆喜,等.不同程度稀酸预处理后杨木枝桠材的物料平衡分析[J].天津科技大学学报,2017,32(2):30-35.
[40]郑燕,陈登宇,朱锡锋.酸洗预处理对稻壳快速热解产物的影响[J].太阳能学报,2014,35(6):925-930.
[41]李攀,杨海平,王贤华,等.不同酸处理条件下生物质热解产物特性分析[J].太阳能学报,2015,36(9):2065-2070.
[42]谭洪,王树荣.酸预处理对生物质热裂解规律影响的实验研究[J].燃料化学学报,2009,37(6):668-672.
[43]孙江纬,郑安庆,蒋丽群,等.有机酸预处理对桉木解构组分热解特性的影响[J].新能源进展,2017,5(3):170-176.
[44]Sherman S R,Goodell J J,Milliken C E,et al.A new process developed for separation of lignin from ammonium hydroxide pretreatment solutions[J].Environmental Progress&Sustainable Energy,2012,31(1):130-138.
[45]崔丽.农作物秸秆热裂解制取生物燃料的研究[D].杭州:浙江工业大学,2014.
[46]马善为,李明,陈怡欣,等.毛竹热解制备高附加值化学品[J].化工学报,2014,65(8):3237-3242.
[47]魁彦萍.生物质热裂解制氢的试验研究及机理分析[D].杭州:浙江工业大学,2012.
[48]曾叶霖.预处理对生物质热解特性的影响研究[D].武汉:华中科技大学,2009.
[49]Zeng Y,Yang X,Yu H,et al.Comparative studies on thermochemical characterization of corn stover pretreated by white-rot and brownrot fungi[J].Journal of Agricultural&Food Chemistry,2011,59(18):9965-9971.
[50]师静,林占熺,林冬梅,等.巨菌草纤维素的酶解条件[J].草业科学,2014,31(4):760-765.
[51]Wyman C E.An introduction to the special section on application of leading pretreatments to switchgrass by the Biomass Refining Consortium for Applied Fundamentals and Innovation(CAFI)[J].Bioresource Technology,2011,102(24):11051.
[52]Panneerselvam A,Sharma-Shivappa R R,Kolar P,et al.Potential of ozonolysis as a pretreatment for energy grasses[J].Bioresource Technology,2013,148:242-248.
[53]Lee J M,Jameel H,Venditti R A.A comparison of the autohydrolysis and ammonia fiber explosion(AFEX)pretreatments on the subsequent enzymatic hydrolysis of coastal Bermuda grass[J].Bioresource Technology,2010,101(14):5449-5458.
[54]罗影龄,薛智权,易炜林,等.离子液体预处理生物质提高糖化产率[J].应用化学,2014,31(1):54-60.
[55]吴南南,蒋丽群,郑安庆,等.离子液体预处理对甘蔗渣快速热解产物的影响[J].可再生能源,2017,35(4):495-501.
[2]Bridgwater A V.Review of fast pyrolysis of biomass and product upgrading[J].Biomass Bioenergy,2012,38:68-94.
[3]Xu J M,Jiang J C,Chen J,et al.Biofuel production from catalytic cracking of woody oils[J].Bioresource Technology,2010,101(14):5586-5591.
[4]Zhang L,Liu R H,Yin R Z,et al.Upgrading of bio-oil from biomass fast pyrolysis in china:a review[J].Renewable and sustainable ener gy reviews,2013,24:66-72.
[5]Xiu S G,Shahbazi A.Bio-oil production and upgrading research:a review[J].Renewable and Sustainable Energy Reviews,2012,16(7):4406-4414.
[6]Hakim S H,Shangks B H,Dumesic J A.Catalytic upgrading of the light fraction of a simulated bio-oil over ce zr ox catalyst[J].Applied Catalysis B:Environmental,2013,142:368-376.
[7]Yu F W,Gao L C,Wang W J,et al.Bio-fuel production from the catalytic pyrolysis of soybean oil over Me-AL-MCM-41(Me=La,Ni or Fe)mesoporous materials[J].Applied Catalysis B:Environmental,2013,10:1-5.
[8]龚春晓.不同粉碎预处理方式对烘焙松木屑的影响[D].北京:中国农业大学,2016.
[9]Ibrahim R H,Darvell I,Jones J M,et al.Physicochemical characterization of torrified biomass[J].Journal of Analytical and Applied Pyrolysis,2013,103:21-30.
[10]Girard P,Shah N.Recent developments on torrified wood:an alternative to charcoal for reducing deforestation[J].REUR Technical Series,1991,20:101-114.
[11]Zheng A Q,Zhao Z L,Chang S,et al.Effect of torrefaction temperature on product distribution from two-staged pyrolysis of biomass[J].Energy&Fuels,2012,26(5):2968-2974.
[12]杨晴,梅艳阳,郝宏蒙,等.烘焙对生物质热解产物特性的影响[J].农业工程学报,2013,29(20):214-219.
[13]Sabil K M,Aziz M A,Lal B,et al.Effects of torrefaction on the physiochemical properties of oil palm empty fruit bunches,mosocarp fiber and kernel shell[J].Biomass and Bioenergy,2013,56:351-360.
[14]郝宏蒙,杨海平,刘汝杰,等.烘培对典型农业秸秆吸水性能的影响[J].中国电机工程学报,2013,33(8):90-94.
[15]Couhert C,Salvdor S,Commandre M.Impact of torrefaction on syngas production from wood[J].Fuel,2009,88(11):2286-2290.
[16]Bridgeman T G,Jones J M,Shield I,et al.Torrefaction of reed canary grass wheat straw and willow to enhance solid fuel qualities and combustion properities[J].Fuel,2008,87(6):844-859.
[17]Felflia F F,Luengob C A,Suarez J A,et al.Wood briquette torrefaction[J].Energy for Sustainable Development,2005,9(3):19-22.
[18]Prins M J,Ptasinski K J,Janssen F J J G.More efficient biomass gasification via torrefaction[J].Energy,2006,31(15):3458-3470.
[19]陈登宇.干燥和烘焙预处理制备高品质生物质原料的基础研究[D].合肥:中国科学技术大学,2013.
[20]陈登宇,张鸿儒,刘栋,等.烘焙预处理对秸秆热解产物品质及能量分布的影响[J].太阳能学报,2017,38(2):565-570.
[21]曾庆倬,于凤文,盛佳峰,等.微波对生物质原料预处理及热解的作用研究进展[J].过程工程学报,2013,13(6):1061-1067.
[22]Moseley J D,Kappe C O.A critical assessment of the greenness and energy efficiency of microwave-assisted organic synthesis[J].Green Chemistry,2011,13:794-806.
[23]Menendez J A,Arenillas A,Fidalgo B,et al.Microwave heating processes involving carbon materials[J].Fuel Processing Technology,2010,91(1):1-8.
[24]Huang Y F,Chen W R,Chiueh P T,et al.Microwave torrefaction of rice straw and pennisetum[J].Bioresource Technology,2012,123:1-7.
[25]Wang W H,Chen H P.The influence of microwave drying on biomass pyrolysis[J].Energy&Fuels,2008,22:67-74.
[26]刘媛,卢翠香,陈健波,等.微波干燥过程中尾巨桉木材含水率变化特性[J].广西林业科学,2017,46(3):262-265.
[27]胡国荣,张帅,王贤华,等.微波预处理对生物质干燥特性及理化性质的影响[J].太阳能学报,2017,38(10):2693-2697.
[28]唐洪涛.辐照预处理对玉米秸秆酶解产糖率的影响[D].北京:中国农业科学院,2012.
[29]胡婷春.Co-γ辐照处理降解芒草纤维质及其机理研究[D].长沙:湖南农业大学,2011.
[30]韩丹妮.稻壳预处理及稻壳中木聚糖的提取工艺研究[D].长沙:长沙理工大学,2012.
[31]徐绍华,武书彬,尉慰奇.桉木三组分在高温热水预处理及酶解糖化中的规律研究[J].林产化学与工业,2013,33(1):21-26.
[32]马静.热水预处理杨木半纤维素的局部化学溶解机理[D].北京:北京林业大学,2015.
[33]Saha B C,Yoshida T,Cotta M A,et al.Hydrothermal pretreatment and enzymatic saccharification of corn stover for efficient ethanol production[J].Industrial Crops and Products,2013,44:367-372.
[34]Kont R,Kurain M,Teugjas H,et al.Strong cellulase inhibitors from the hydrothermal pretreatment of wheat straw[J].Biotechnology for Biofuels,2013(6):135-148.
[35]邓磊,张涛,刘银河,等.水洗对生物质燃料特性及燃烧特性的影响[J].工程热物理学报,2010,31(7):1239-1242.
[36]陈东雨,刘荣厚,蔡均猛.预处理甜高粱茎秆残渣的热解动力学研究[J].农业工程学报,2007,23(2):188-194.
[37]姬登祥,黄承洁,于平,等.原料预处理对生物质热裂解动力学特性的影响[J].农业工程学报,2011,27(S1):112-117.
[38]Patwardhan P R,Satrio J A,Brown R C,et al.Influence of inorganic salts on the primary pyrolysis products of cellulose[J].Bioresource Technology,2010,101(12):4646-4655.
[39]陈威,刘苇,侯庆喜,等.不同程度稀酸预处理后杨木枝桠材的物料平衡分析[J].天津科技大学学报,2017,32(2):30-35.
[40]郑燕,陈登宇,朱锡锋.酸洗预处理对稻壳快速热解产物的影响[J].太阳能学报,2014,35(6):925-930.
[41]李攀,杨海平,王贤华,等.不同酸处理条件下生物质热解产物特性分析[J].太阳能学报,2015,36(9):2065-2070.
[42]谭洪,王树荣.酸预处理对生物质热裂解规律影响的实验研究[J].燃料化学学报,2009,37(6):668-672.
[43]孙江纬,郑安庆,蒋丽群,等.有机酸预处理对桉木解构组分热解特性的影响[J].新能源进展,2017,5(3):170-176.
[44]Sherman S R,Goodell J J,Milliken C E,et al.A new process developed for separation of lignin from ammonium hydroxide pretreatment solutions[J].Environmental Progress&Sustainable Energy,2012,31(1):130-138.
[45]崔丽.农作物秸秆热裂解制取生物燃料的研究[D].杭州:浙江工业大学,2014.
[46]马善为,李明,陈怡欣,等.毛竹热解制备高附加值化学品[J].化工学报,2014,65(8):3237-3242.
[47]魁彦萍.生物质热裂解制氢的试验研究及机理分析[D].杭州:浙江工业大学,2012.
[48]曾叶霖.预处理对生物质热解特性的影响研究[D].武汉:华中科技大学,2009.
[49]Zeng Y,Yang X,Yu H,et al.Comparative studies on thermochemical characterization of corn stover pretreated by white-rot and brownrot fungi[J].Journal of Agricultural&Food Chemistry,2011,59(18):9965-9971.
[50]师静,林占熺,林冬梅,等.巨菌草纤维素的酶解条件[J].草业科学,2014,31(4):760-765.
[51]Wyman C E.An introduction to the special section on application of leading pretreatments to switchgrass by the Biomass Refining Consortium for Applied Fundamentals and Innovation(CAFI)[J].Bioresource Technology,2011,102(24):11051.
[52]Panneerselvam A,Sharma-Shivappa R R,Kolar P,et al.Potential of ozonolysis as a pretreatment for energy grasses[J].Bioresource Technology,2013,148:242-248.
[53]Lee J M,Jameel H,Venditti R A.A comparison of the autohydrolysis and ammonia fiber explosion(AFEX)pretreatments on the subsequent enzymatic hydrolysis of coastal Bermuda grass[J].Bioresource Technology,2010,101(14):5449-5458.
[54]罗影龄,薛智权,易炜林,等.离子液体预处理生物质提高糖化产率[J].应用化学,2014,31(1):54-60.
[55]吴南南,蒋丽群,郑安庆,等.离子液体预处理对甘蔗渣快速热解产物的影响[J].可再生能源,2017,35(4):495-501.