汽油加氢装置在线优化操作生产国Ⅴ汽油
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摘要
中国石油抚顺石化公司120万t/a汽油选择性加氢装置原是按照生产国Ⅳ标准设计的装置,使用的是满足国Ⅳ汽油标准的GARDES工艺和系列GARDES催化剂。通过在线调整该装置各主要参数,在不停工且不更换催化剂的情况下完成汽油质量调整全过程,成功产出满足国家车用汽油国Ⅴ标准的成品汽油。在线优化操作避免了装置停工换剂和技术改造所带来的经济损失,且装置已平稳运行1年,产品均达到国家最新环保法规要求并顺利出厂。
PetroChina Fushun Petrochemical Company's 1. 2 million t/a gasoline selective hydrogenation unit was designed originally in accordance with the national standard Ⅳ gasoline,which using the GARDES process and GARDES series of catalysts both meeting the national standard Ⅳ gasoline. By adjusting on-line the main parameters of this unit,the whole process of gasoline quality standard promotion has been achieved without stopping operation and replacing catalysts,and the national V gasoline has been produced successfully. On-line optimization operation can avoid economic losses due to conventional stopping operation,replacing catalysts and technological transformation. And this hydrogenation unit has been running smoothly for a year after on-line optimization,and the products meet China's latest environmental protection regulations.
PetroChina Fushun Petrochemical Company's 1. 2 million t/a gasoline selective hydrogenation unit was designed originally in accordance with the national standard Ⅳ gasoline,which using the GARDES process and GARDES series of catalysts both meeting the national standard Ⅳ gasoline. By adjusting on-line the main parameters of this unit,the whole process of gasoline quality standard promotion has been achieved without stopping operation and replacing catalysts,and the national V gasoline has been produced successfully. On-line optimization operation can avoid economic losses due to conventional stopping operation,replacing catalysts and technological transformation. And this hydrogenation unit has been running smoothly for a year after on-line optimization,and the products meet China's latest environmental protection regulations.
引文
[1]石冈,范煜,鲍晓军,等.催化裂化汽油加氢改质GARDES技术的开发及工业试验[J].石油炼制与化工,2013,44(9):66-72.
[2]魏芳.0.8 Mt/a催化汽油加氢脱硫装置的设计与运行[J].油技术与工程,2015,45(1):11-14.
[3]赵峰,郭贵贵,黄兴华,等.ALG技术在600 kt/a催化裂化汽油加氢装置的工业应用[J].油技术与工程,2015,45(8):12-16.
[4]吴青,彭成华,赵晨曦,等.CDOS-FRCN全馏分催化汽油选择加氢脱硫工艺技术的工业应用[J].山东化工,2015,45(8):122-124.
[5]胡媛媛,刘勇.DSO-FCC汽油加氢脱硫技术开发与应用[J].山东化工,2012,42(16):174-176.
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[9]张圣鹏,徐永强,吕恩静,等.FCC汽油选择性加氢硫转移催化剂的实验研究[J].石油学报:石油加工,2015,31(1):18-24.
[10]陈鑫,吴新辉,于向真.FCC汽油选择性加氢脱硫技术的首次工业应用[J].工业催化,2015,13(12):138-140.
[11]刘晓欣,王艳涛,赵乐平,等.FCC汽油选择性加氢脱硫降烯烃工艺技术的工业应用[J].石油炼制与化工,2006,37(8):44-48.
[12]鲁旭,兰玲,赵秦峰,等.FCC汽油预加氢对生产满足国Ⅳ排放标准汽油切割方案的影响[J].石油炼制与化工,2015,46(10):34-38.
[13]蒋锋,董喜恩,齐邦峰,等.FCC汽油中硫醇硫分布及脱除的研究[J].当代化工,2010,39(10):493-496.
[14]山红红,李春义,赵博艺,等.FCC汽油中硫分布和催化脱硫研究[J].石油大学学报:自然科学版,2001,25(6):78-80.
[15]许长辉.GARDES技术在汽油加氢脱硫装置的工业应用[J].石油炼制与化工,2015,46(1):62-67.
[16]向永生,黄金刚,石冈,等.GARDES工艺在FCC汽油加氢装置的工业应用[J].工业催化,2015,23(2):131-135.
[17]吴杰,张忠东,李艳晗,等.GARDES技术在大庆石化130万吨/年汽油加氢改质装置的工业应用[J].化工进展,2014,33(9):2506-2509.
[18]向永生,王玉兴,崔彦君,等.GARDES系列加氢催化剂在催化裂化汽油加氢补充脱硫装置的工业应用[J].石化技术与应用,2015,33(1):50-53.
[19]郁兰锋.GDS催化剂在汽油加氢装置的应用[J].炼油与化工,2014,25(4):12-14.
[20]李大东.加氢处理工艺与工程[M].北京:中国石化出版社,2004:93-1063.
[21]林世雄,徐春明,杨朝和.石油炼制工程[M].北京:石油工业出版社,2010:99-113.
[2]魏芳.0.8 Mt/a催化汽油加氢脱硫装置的设计与运行[J].油技术与工程,2015,45(1):11-14.
[3]赵峰,郭贵贵,黄兴华,等.ALG技术在600 kt/a催化裂化汽油加氢装置的工业应用[J].油技术与工程,2015,45(8):12-16.
[4]吴青,彭成华,赵晨曦,等.CDOS-FRCN全馏分催化汽油选择加氢脱硫工艺技术的工业应用[J].山东化工,2015,45(8):122-124.
[5]胡媛媛,刘勇.DSO-FCC汽油加氢脱硫技术开发与应用[J].山东化工,2012,42(16):174-176.
[6]花小兵.FCC汽油加氢改质GARDES技术工业应用[J].油技术与工程,2015,45(10):11-14.
[7]刘春红,方礼理.FCC汽油加氢脱硫催化剂研究进展[J].当代化工,2015,44(4):812-814.
[8]刘笑,高静洁,罗辉,等.FCC汽油加氢脱硫反应过程及其催化剂研究进展[J].当代化工,2011,40(3):276-280.
[9]张圣鹏,徐永强,吕恩静,等.FCC汽油选择性加氢硫转移催化剂的实验研究[J].石油学报:石油加工,2015,31(1):18-24.
[10]陈鑫,吴新辉,于向真.FCC汽油选择性加氢脱硫技术的首次工业应用[J].工业催化,2015,13(12):138-140.
[11]刘晓欣,王艳涛,赵乐平,等.FCC汽油选择性加氢脱硫降烯烃工艺技术的工业应用[J].石油炼制与化工,2006,37(8):44-48.
[12]鲁旭,兰玲,赵秦峰,等.FCC汽油预加氢对生产满足国Ⅳ排放标准汽油切割方案的影响[J].石油炼制与化工,2015,46(10):34-38.
[13]蒋锋,董喜恩,齐邦峰,等.FCC汽油中硫醇硫分布及脱除的研究[J].当代化工,2010,39(10):493-496.
[14]山红红,李春义,赵博艺,等.FCC汽油中硫分布和催化脱硫研究[J].石油大学学报:自然科学版,2001,25(6):78-80.
[15]许长辉.GARDES技术在汽油加氢脱硫装置的工业应用[J].石油炼制与化工,2015,46(1):62-67.
[16]向永生,黄金刚,石冈,等.GARDES工艺在FCC汽油加氢装置的工业应用[J].工业催化,2015,23(2):131-135.
[17]吴杰,张忠东,李艳晗,等.GARDES技术在大庆石化130万吨/年汽油加氢改质装置的工业应用[J].化工进展,2014,33(9):2506-2509.
[18]向永生,王玉兴,崔彦君,等.GARDES系列加氢催化剂在催化裂化汽油加氢补充脱硫装置的工业应用[J].石化技术与应用,2015,33(1):50-53.
[19]郁兰锋.GDS催化剂在汽油加氢装置的应用[J].炼油与化工,2014,25(4):12-14.
[20]李大东.加氢处理工艺与工程[M].北京:中国石化出版社,2004:93-1063.
[21]林世雄,徐春明,杨朝和.石油炼制工程[M].北京:石油工业出版社,2010:99-113.