共混用动态混合器的研究与应用进展
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  • 英文篇名:Research and application progress of dynamic mixers for polymer blending
  • 作者:黄凤磊 ; 刘淼 ; 李志鹏 ; 蔡子琦 ; 高正明
  • 英文作者:HUANG Fenglei;LIU Miao;LI Zhipeng;CAI Ziqi;GAO Zhengming;College of Chemical Engineering,Beijing University of Chemical Technology;
  • 关键词:聚合物共混 ; 混合理论 ; 动态混合器 ; 计算流体力学
  • 英文关键词:polymer blending;;mixing theory;;dynamic mixer;;computational fluid dynamics(CFD)
  • 中文刊名:HGJZ
  • 英文刊名:Chemical Industry and Engineering Progress
  • 机构:北京化工大学化学工程学院;
  • 出版日期:2017-10-05
  • 出版单位:化工进展
  • 年:2017
  • 期:v.36;No.313
  • 基金:国家重点研究开发计划项目(2016YFB0302801)
  • 语种:中文;
  • 页:HGJZ201710004
  • 页数:9
  • CN:10
  • ISSN:11-1954/TQ
  • 分类号:22-30
摘要
动态混合器具有提高聚合物共混过程中分散相混合质量的优点。本文从混合理论出发,重点介绍了分散和分布混合理论的研究进展。对共混用动态混合器进行了分类与整理,简述了釜式搅拌器与螺杆挤出机类动态混合器,并详细介绍了销钉式、球窝式和空穴传递式动态混合器的原理与结构。从实验和数值模拟两个方面阐述了动态混合器的研究方法,实验研究主要包括计算机图像处理技术与显微分析技术、力学性能分析技术和粒子图像测速技术,数值模拟研究方法方面则从宏观和介观两种尺度进行了简要的介绍。最后介绍了共混用动态混合器在化纤、塑料、橡胶等多个工业领域的应用,指出实验与数值模拟相结合的方法有助于提高现有研究水平,解决动态混合器设计与优化过程中的难题。
        Dynamic mixers for polymer blending have the advantage of improving the mixing quality of the dispersed phase in the polymer. In this paper, the research progress of mixing theory which focused on dispersion mixing and distribution mixing was introduced. Dynamic mixers for polymer blending were divided into kettle mixer and screw extruder,and the structures of spherical cavity type,pin type and cavity transfer type dynamic mixers were introduced in detail. The research methods of the dynamic mixer were expounded from experimental methods and numerical simulation methods.Experimental methods were described from microscopic analysis technology with computer image processing technology, mechanical performance analysis technology and particle image velocimetry technology. On the other hand, the numerical simulation methods were expounded from the macroscopic and mesoscopic scales. The application of dynamic mixer in chemical industry, plastic industry and rubber industry was introduced. This paper pointed out that the combination of experiment methods and numerical simulation methods could improve the existing research level and solve the problems in the process of design and optimization.
引文
[1]姜兆辉,付鹏,金剑,等.基于TEM图像的炭黑在聚合物基体中分散性的定量表征[J].材料工程,2011(10):72-77.JIANG Z H,FU P,JIN J,et al.Quantitative characterization dispersion of carbon black particles in polymeric matrix based on TEM images[J].Journal of Materials Engineering,2011(10):72-77.
    [2]DANCKWERTS P V.The definition and measurement of some characteristics of mixtures[J].Flow,Turbulence and Combustion,1952,3(4):268-287.
    [3]CHAKRAVARTHY V S,OTTINO J M.Mixing of two viscous fluids in a rectangular cavity[J].Chemical Engineering Science,1996,51(14):3613-3622.
    [4]喻慧文,徐百平,何亮,等.非对称同向双螺杆端面造型对混合行为影响数值模拟[J].化工学报,2012,63(5):1622-1629.YU H W,XU B P,HE L,et al.Numerical simulation of effect of different cross-section geometries on mixing performance of novel co-rotating non-twin screws[J].CIESC Journal,2012,63(5):1622-1629.
    [5]张甲敏,连照勋,王雪静,等.剪切速率对PA 6/PP共混物微观结构的影响[J].合成树脂及塑料,2009,26(2):62-65.ZHANG J M,LIAN Z X,WANG X J,et al.Impact of shear rate on microstructure of PA 6/PP blends[J].Synthetic Resin and Plastics,2009,26(2):62-65.
    [6]杨立忠.螺杆挤压机混合能力的分析[J].合成技术及应用,2002,17(3):58-60.YANG L Z.Analysis on mixing capability of screw extruder[J].Synthetic Technology and Application,2002,17(3):58-60.
    [7]SHIGA S,FURUTA M.Processability of EPR in an internal mixer(II)–morphological changes of carbon black agglomerates during mixing[J].Rubber Chemistry&Technology,1985,58(1):1-22.
    [8]MANAS-ZLOCZOWER I,FEKE D L.Analysis of agglomerate rupture in linear flow fields[J].International Polymer Processing Journal of the Polymer Processing Society,1989,4(1):3-8.
    [9]庄金雨,安瑛,谭晶,等.固体粉末在聚合物基体中分散混合的数值模拟研究[J].橡胶工业,2015,62(8):464-468.ZHUANG J Y,AN Y,TAN J,et al.Numerical simulation on fillerdispersion in polymer matrix[J].China Rubber Industry,2015,62(8):464-468.
    [10]POTENTE H,KRETSCHMER K,FLECKE J.A physicalmathematical model for the dispersion process in continuous mixers[J].Polymer Engineering&Science,2002,42(1):19-32.
    [11]XIE L,LI P,MA Y,et al.A representation method for describing a deagglomerating process in continuous mixer[J].Polymer Composites,2012,33(4):476-483.
    [12]ELMENDORP J J.A study on polymer blending microrheology[J].Polymer Engineering&Science,1986,26(6):418-426.
    [13]CHEN X,XU J,GUO B.Development of dispersed phase size and its dependence on processing parameters[J].Journal of Applied Polymer Science,2006,102(4):3201-3211.
    [14]李树,揣成智,刘凤芝.注射机中腔穴传递式混合器的结构与混合机理[J].上海塑料,2005(2):32-35.LI S,CHUAI C Z,LIU F Z.Structure and mixing mechanism of cavity transfer mixer in injection moulding machine[J].Shanghai Plastics,2005(2):32-35.
    [15]郭英.聚合物熔体在销钉混合型螺杆中的分流数计算[J].北京服装学院学报(自然科学版),1993,13(1):47-50.GUO Y.Calculation of the number of the striations of polymer melt for pin mixing screw[J].Journal of Beijing Institute of Clothing Technology(Science and Technology),1993,13(1):47-50.
    [16]蒋金云,孔令熙,李健,等.凹槽型高效动态混合器分流数混合效果评价[J].塑料,2014,43(3):100-102.JIANG J Y,KONG L X,LI J,et al.Assessment of groove type dynamic mixer with high efficiency by number of striations[J].Plastics,2014,43(3):100-102.
    [17]吴雨,张力钧,宋忠俊.静态混合器在石油化工中的应用[J].天然气与石油,2014,32(3):23-26.WU Y,ZHANG L J,SONG Z J.Application of static mixer in petrochemical industry[J].Natural Gas and Oil,2014,32(3):23-26.
    [18]骆培成,程易,汪展文,等.液-液快速混合设备研究进展[J].化工进展,2005,24(12):1319-1326.LUO P C,CHENG Y,WANG Z W,et al.Research progress of liquid-liquid fast mixing equipment[J].Chemical Industry and Engineering Progress,2005,24(12):1319-1326.
    [19]马小欣.搅拌不同粘度溶液的搅拌器选择[J].中国新技术新产品,2016(7):63-63.MA X X.Stirring the agitator with different viscosity solutions[J].Journal of China's New Technology and New Products,2016(7):63-63.
    [20]林祥,任冬云,王奎升.基于拉伸破碎原理的单螺杆拉伸混炼元件的研究[J].中国塑料,2011(12):90-94.LIN X,REN D Y,WANG K S.Investigation of extensional flow mixer for single-screw extruder based on extensional disagglomeration[J].China Plastics,2011(12):90-94.
    [21]黄元昌.单螺杆挤出机混炼效果[J].橡塑技术与装备,2014(6):37-39.HUANG Y C.Mixing effect of single-screw extruder[J].China Rubber/Plastics Technology and Equipment,2014(6):37-39.
    [22]李晓翠,彭炯,陈晋南.销钉单螺杆混炼段分布混合性能的数值研究[J].中国塑料,2010(2):109-112.LI X C,PENG J,CHEN J N.Numerical study on distributive mixing performance of mixing section of pin single-screw extruders[J].China Plastics,2010(2):109-112.
    [23]柳天磊,王建鸿,杜遥雪.注塑机螺杆混炼元件混炼性能对比研究[J].工程塑料应用,2013(4):51-54.LIU T L,WANG J H,DU Y X.Comparative study on plasticizing properties of screw mixing units for injection machine[J].Engineering Plastics Application,2013(4):51-54.
    [24]赵式英,王宝灵.球窝型动态混合器结构和机理的研究[J].合成纤维工业,1991(5):26-31.ZHAO S Y,WANG B L.Research of the structure and mechanism of spherical cavity type dynamic mixer[J].Synthetic Fiber Industry,1991(5):26-31.
    [25]姜兆辉,金剑,肖长发.熔体直纺在线添加制备差别化聚酯纤维研究进展[J].高分子通报,2011(5):10-16.JIANG Z H,JIN J,XIAO C F.The progress in preparation of differential polyester fiber by directly melt spinning[J].Chinese Polymer Bulletin,2011(5):10-16.
    [26]李树,揣成智.空穴传递混合器的结构原理与应用[J].天津科技大学学报,2006,21(3):31-33.LI S,CHUAI C Z.Structure mechanism and application of cavity transfer mixer[J].Journal of Tianjin University of Science&Technology,2006,21(3):31-33.
    [27]揣成智,EDWARDS M F.腔穴传递式混合器的工作原理和特性[J].塑料,1993(6):16-19.CHUAI C Z,EDWARDS M F.Operating characteristic and principle of cavity transfer mixer[J].Plastics,1993(6):16-19.
    [28]SUSAN J,FOCKE W W.Poly(ethylene-vinyl co-vinyl acetate)/clay nanocomposites:mechanical,morphology,and thermal behavior[J].Polymer Composites,2011,32(2):252-258.
    [29]许正军,陈瑞琪.应用图像处理技术评定聚合物混合效果的研究[J].东华大学学报(自然科学版),1998(1):88-90.XU Z J,CHEN R Q.Study on mixed effect analysis of polymeric mixture by means of image processing technology[J].Journal of Donghua University(Science and Technology),1998(1):88-90.
    [30]姜兆辉,金剑,肖长发,等.高均一性聚丙烯/炭黑薄膜的制备及炭黑分散性的定量表征[J].分析测试学报,2011,30(3):330-335.JIANG Z H,JIN J,XIAO C F.et al.Preparation of high homogeneity polypropylene/carbon black films and quantitative characterization on carbon black dispersion[J].Journal of Instrumental Analysis,2011,30(3):330-335.
    [31]姜兆辉,金剑,肖长发,等.炭黑母粒分散性的定量表征[J].纺织学报,2011,32(11):17-22.JIANG Z H,JIN J,XIAO C F.et al.Quantitative characterization of dispersion of carbon black masterbatch[J].Journal of Textile Research,2011,32(11):17-22.
    [32]易庆锋,赵智源,姜苏俊,等.球形氧化铝在填充PA10T中的分散性研究及其对材料性能的影响[J].塑料工业,2015,43(8):112-114.YI Q F,ZHAO Z Y,JIANG S J,et al.Study on the dispersion of spherical alumina filled in PA10T and the effect to properties of composites[J].China Plastics Industry,2015,43(8):112-114.
    [33]DEEN N G.Two-phase PIV bubbly flows:status and trend[J].Experiments in Fluids,2002,25(1):97-101.
    [34]LEHWALD A,JANIGA G,THéVENIN D,et al.Simultaneous investigation of macro-and micro-mixing in a static mixer[J].Chemical Engineering Science,2012,79(37):8-18.
    [35]RODRíGUEZ-GONZáLEZ F,PéREZ-GONZáLEZ J,VARGAS L D,et al.Rheo-PIV analysis of the slip flow of a metallocene linearlow-density polyethylene melt[J].Rheologica Acta,2009,49(2):145-154.
    [36]WANG C,ICA M.Flow field analysis of a cavity transfer mixer[J].Polymer Engineering&Science,1994,34(15):1224-1230.
    [37]RAZA A H,LAI-FOOK R A,LAWRENCE C J,et al.Theoretical and experimental characterization of emulsion flow in a cavity transfer mixer[C]//ASME/JSME 2003,Joint Fluids Summer Engineering Conference.2003:2391-2398.
    [38]JIANG Z,GUO Z,JIA Z,et al.Mixing mechanism and evaluation of the dispersion effect of a 3D dynamic mixer[J].Journal of Testing&Evaluation,2016,44(1):367-375
    [39]BUICK J M,Cosgrove J A.Numerical simulation of the flow field in the mixing section of a screw extruder by the lattice Boltzmann model[J].Chemical Engineering Science,2006,61(10):3323-3326.
    [40]BUICK J M.Lattice Boltzmann simulation of power-law fluid flow in the mixing section of a single-screw extruder[J].Chemical Engineering Science,2009,64(1):52-58.
    [41]DICKMEIΒF,ALEXANDER J,杨铖.现代纺丝设备中的添加剂注入和混合[J].国际纺织导报,2014,42(2):16-22.DICKMEIΒF,ALEXANDER J,YANG C.Additive injection and mixing in modern spinning equipment[J].Melliand China,2014,42(2):16-22.
    [42]DICKMEIΒF,邹海霞.颜料注射-合成纤维的纺前染色[J].国际纺织导报,2002(1):32-37.DICKMEIΒF,ZHOU H X.Color injection-mass-dyeing of synthetic fibers[J].Melliand China,2002(1):32-37.
    [43]崔利,庄耀中,姚敏刚,等.267 dtex/288 f竹炭涤纶预取向丝的生产开发[J].合成纤维,2015,44(6):19-21.CUI L,ZHUANG Y Z,YAO M G,et al.Development of 267dtex/288 f bamboo charcoal polyester pre-oriented yarn[J].Synthetic Fiber in China,2015,44(6):19-21.
    [44]张志强,王大中,叶南飚.双螺杆挤出机的排气原理及在改性ABS中的应用[J].塑料工业,2013,41(12):39-43.ZHANG Z Q,WANG D Z,YE N B.The exhaust principle of twin-screw extruder and application in modified ABS[J].China Plastics Industry,2013,41(12):39-43.
    [45]贾朝阳,张小莹,梁晓刚.同向双螺杆挤出机在聚合物脱挥中的应用研究[J].中国塑料,2012,26(8):107-110.JIA C Y,ZHANG X Y,LIAO X G.Application of co-rotating twin-screw extruder in devolatilization of polymer[J].China Plastics,2012,26(8):107-110.
    [46]徐能,金志明,薛平.行星挤出机的研究与应用进展[J].塑料工业,2011,39(9):9-10.XU N,JIN Z M,XUE P.Research and application progress of planetary extruder[J].China Plastics Industry,2011,39(9):9-10.
    [47]尤作虎,郝恩全,宋云鹤.行星挤出机在PVC压延薄膜生产线上的应用[J].现代塑料加工应用,2006,18(1):26-27.YOU Z H,HAO E Q,SONG Y H.Application of planetany extruder to production line of PVC calendering films[J].Modern Plastics Processing and Applications,2006,18(1):26-27.
    [48]刘晶,薛平,金志明.行星螺杆挤出机的发展[J].中国塑料,2013,27(3):1-5.LIU J,XUE P,JIN Z M.Development of planetary roller extruders[J].China Plastics,2013,27(3):1-5.
    [49]张婧婧,黄耿群.双螺杆挤出制备低密度聚乳酸微孔泡沫塑料[J].塑料,2015,44(3):4-6.ZHANG J J,HUANG G Q.Preparation of low density microcellular pla foams through twin-screw extrusion[J].Plastics,2015,44(3):4-6.
    [50]TANG Y.Recycled rubber processing and performance enhancement:US6590042 B1[P].2003-07-08.
    [51]MOURI M,USUKI A,MURASE A,et al.Method of manufacturing devulcanized rubber using high temperature and shearing pressure:US6133413 A[P].2000-10-17.

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