水溶性高分子在分子筛合成中的应用
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摘要
分子筛作为催化剂、吸附剂和离子交换剂等被广泛应用于石油化工、精细化工等领域。常规微孔分子筛存在孔道和孔穴尺寸均较小等缺点,各项性能已不能满足各应用领域日益增长的要求。为了克服上述问题,不同类型的高性能分子筛被成功研制出来。综述了近年来以水溶性高分子为模板剂合成高性能分子筛的最新进展,介绍了合成类水溶性高分子和全(半)天然水溶性高分子在纳米分子筛、多级孔分子筛、空心分子筛和核-壳分子筛等高性能分子筛材料合成中的应用及影响因素。
Zeolites have been widely used in petrochemical and fine chemical industries as catalysis,adsorption,and ion exchange materials. Conventional microporous zeolite have disadvantages such as small channel size and small hole size,and various properties have been unable to meet the increasing requirements of various application fields. In order to overcome the above problems,various kinds of high performance zeolites have been developed successfully. The recent advances in the synthesis of high-performance zeolites using water-soluble polymers are reviewed,and the applications and effects of chemically synthesized water-soluble polymers and natural(semi-natural)water-soluble polymers in the synthesis of high performance zeolite materials such as nano-zeolite,hierarchial zeolite,hollow zeolite and core-shell zeolite are systematically introduced.
Zeolites have been widely used in petrochemical and fine chemical industries as catalysis,adsorption,and ion exchange materials. Conventional microporous zeolite have disadvantages such as small channel size and small hole size,and various properties have been unable to meet the increasing requirements of various application fields. In order to overcome the above problems,various kinds of high performance zeolites have been developed successfully. The recent advances in the synthesis of high-performance zeolites using water-soluble polymers are reviewed,and the applications and effects of chemically synthesized water-soluble polymers and natural(semi-natural)water-soluble polymers in the synthesis of high performance zeolite materials such as nano-zeolite,hierarchial zeolite,hollow zeolite and core-shell zeolite are systematically introduced.
引文
[1]Primo A,Garcia H.Zeolites as catalysts in oil refining[J].Chem Soc Rev,2014,43(22):7548-7561.
[2]Dusselier M,Davis M E.Small-pore zeolites:Synthesis and catalysis[J].Chem Rev,2018,118(11):5265-5329.
[3]Yang Jinbiao,Liu Haiyan,Diao Haiju,et al.A quasi-solid-phase approach to activate natural minerals for zeolite synthesis[J].ACS Sustain Chem Eng,2017,5(4):3233-3242.
[4]丁佳佳,刘红星,张玉贤.不同孔结构拟薄水铝石合成SAPO-34分子筛及其MTO反应性能[J].石油化工,2018,47(10):1059-1065.
[5]Linares N,Silvestre-Albero A M,Serrano E,et al.Mesoporous materials for clean energy technologies[J].Chem Soc Rev,2014,43(22):7681-7717.
[6]Mintova S,Grand J,Valtchev V.Nanosized zeolites:Quo Vadis?[J].Comptes Rendus Chimie,2016,19(1):183-191.
[7]Liu Zhaohui,Hua Yingjie,Wang Jianjian,et al.Recent progress in the direct synthesis of hierarchical zeolites:Synthetic strategies and characterization methods[J].Mater Chem Front,2017,1(11):2195-2212.
[8]Masoumifard N,Guillet-Nicolas R,Kleitz F.Synthesis of engineered zeolitic materials:From classical zeolites to hierarchical core-shell materials[J].Adv Mater,2018,30(16):1704439.
[9]刘晓玲,姜健准,张明森.纳米薄片MFI结构分子筛合成的研究进展[J].石油化工,2016,45(1):113-120.
[10]冯英杰,冯静,张明森.多级孔分子筛Silicalite-1的制备及其在合成气直接制低碳烯烃反应中的应用[J].石油化工,2018,47(8):781-787.
[11]Schwanke A,Villarroel-Rocha J,Sapag K,et al.Dandelion-like microspherical MCM-22 zeolite using BP 2000 as a hard template[J].ACS Omega,2018,3(6):6217-6223.
[12]Varzaneh A Z,Towfighi J,Sahebdelfar S.Carbon nanotube templated synthesis of metal containing hierarchical SAPO-34catalysts:Impact of the preparation method and metal avidities in the MTO reaction[J].Microporous Mesoporous Mater,2016,236:1-12.
[13]Holland B T,Abrams L,Stein A.Dual templating of macroporous silicates with zeolitic microporous frameworks[J].J Am Chem Soc,1999,121(17):4308-4309.
[14]Zhu Haibo,Liu Zhicheng,Wang Yangdong,et al.Nanosized CaCO3 as hard template for creation of intracrystal pores within Silicalite-1 crystal[J].Chem Mater,2008,20(3):1134-1139.
[15]Zampieri A,Mabande G T P,Selvam T,et al.Biotemplating of luffa cylindrica sponges to self-supporting hierarchical zeolite macrostructures for bio-inspired structured catalytic reactors[J].Mater Sci Eng,C,2006,26(1):130-135.
[16]Yao Jianfeng,Wang Huanting,Ringer S P,et al.Growth of SAPO-34 in polymer hydrogels through vapor-phase transport[J].Microporous Mesoporous Mater,2005,85(3):267-272.
[17]Han Li,Yao Jianfeng,Li Dan,et al.Hollow zeolite structures formed by crystallization in crosslinked polyacrylamide hydrogels[J].J Mater Chem,2008,18(28):3337-3341.
[18]Jiang Jinlong,Yang Yong,Duanmu C,et al.Preparation of hollow ZSM-5 crystals in the presence of polyacrylamide[J].Microporous Mesoporous Mater,2012,163:11-20.
[19]Han Li,Jiang Xinge,Lu Tianliang,et al.Preparation of composite zeolites in polymer hydrogels and their catalytic performances in the methanol-to-olefin reaction[J].Fuel Process Technol,2017,165:87-93.
[20]Xiao Fengshou,Wang Lifeng,Yin Chengyang,et al.Catalytic properties of hierarchical mesoporous zeolites templated with a mixture of small organic ammonium salts and mesoscale cationic polymers[J].Angew Chem,2006,118(19):3162-3165.
[21]Wang Lifeng,Zhang Zhe,Yin Chengyang,et al.Hierarchical mesoporous zeolites with controllable mesoporosity templated from cationic polymers[J].Microporous Mesoporous Mater,2010,131(113):58-67.
[22]Liu Shuzhen,Cao Xuejing,Li Liansheng,et al.Preformed zeolite precursor route for synthesis of mesoporous X zeolite[J].Colloids Surf,A,2008,318(1):269-274.
[23]Zhu Jie,Zhu Yihan,Zhu Liangkui,et al.Highly mesoporous single-crystalline zeolite beta synthesized using a nonsurfactant cationic polymer as a dual-function template[J].J Am Chem Soc,2014,136(6):2503-2510.
[24]Dong Angang,Wang Yajun,Wang Deju,et al.Fabrication of hollow zeolite microcapsules with tailored shapes and functionalized interiors[J].Microporous Mesoporous Mater,2003,64(1/3):69-81.
[25]Venna S R,Carreon M A.Synthesis of SAPO-34 crystals in the presence of crystal growth inhibitors[J].J Phys Chem B,2008,112(51):16261-16265.
[26]Tao Haixiang,Yang Hong,Liu Xiaohui,et al.Highly stable hierarchical ZSM-5 zeolite with intra-and inter-crystalline porous structures[J].Chem Eng J,2013,225:686-694.
[27]Koohsaryan E,Anbia M.Facile and rapid synthesis of highly crystalline mesoporous zeolite FAU[J].Mater Lett,2019,236:390-393.
[28]Tian Dayong,Yan Wenfu,Cao Xuejing,et al.Morphology changes of transition-metal-substituted aluminophosphate molecular sieve AlPO4-5 crystals[J].Chem Mater,2008,20(6):2160-2164.
[29]Tao Yousheng,Kanoh H,Kaneko K.ZSM-5 monolith of uniform mesoporous channels[J].J Am Chem Soc,2003,125(20):6044-6045.
[30]Tao Yousheng,Kanoh H,Kaneko K.Uniform mesopore-donated zeolite Y using carbon aerogel templating[J].J Phys Chem B,2003,107(40):10974-10976.
[31]Yousheng T,Hirofumi K,Katsumi K.Synthesis of mesoporous zeolite A by resorcinol-formaldehyde aerogel templating[J].Langmuir ACS J Surf Colloids,2005,21(2):504-507.
[32]Yousheng T,Yoshiyuki H,Akihiko M,et al.Comparative study on pore structures of mesoporous ZSM-5 from resorcinolformaldehyde aerogel and carbon aerogel templating[J].JPhys Chem B,2005,109(1):194-199.
[33]Kang Yijin,Wei Shan,Wu Jingyi,et al.Uniform nanozeolite microspheres with large secondary pore architecture[J].Chem Mater,2006,18(7):1861-1866.
[34]Tosheva L,Mihailova B,Valtchev V,et al.Silicalite-1macrostructures-preparation and structural features[J].Microporous Mesoporous Mater,2000,39(112):91-101.
[35]Tosheva L,Valtchev V,Sterte J.Silicalite-1 containing microspheres prepared using shape-directing macro-templates[J].Microporous Mesoporous Mater,2000,35(136):621-629.
[36]Wang Hui,Pinnavaia T J.MFI zeolite with small and uniform intracrystal mesopores[J].Angew Chem,2006,118(45):7765-7768.
[37]Park D H,Kim S S,Wang Hui,et al.Selective petroleum refining over a zeolite catalyst with small intracrystal mesopores[J].Angew Chem,Int Ed,2009,48(41):7645-7648.
[38]Jo C,Seo Y,Cho K,et al.Random-graft polymer-directed synthesis of inorganic mesostructures with ultrathin frameworks[J].Angew Chem,Int Ed,2014,53(20):5117-5121.
[39]Zhang B,Davis S A,Mann S.Starch gel templating of spongelike macroporous silicalite monoliths and mesoporous films[J].Chem Mater,2002,14(3):1369-1375.
[40]刘志成,孔德金,王仰东.淀粉模板法合成介孔ZSM-5分子筛[J].石油学报:石油加工,2008,24(z1):124-126,135.
[41]Zhang Miaorong,Liu Xinmei,Yan Zifeng.Soluble starch as in-situ template to synthesize ZSM-5 zeolite with intracrystal mesopores[J].Mater Lett,2016,164:543-546.
[42]Liu Yong,Zhang Weiping,Liu Zhicheng,et al.Direct observation of the mesopores in ZSM-5 zeolites with hierarchical porous structures by laser-hyperpolarized 129Xe NMR[J].JPhys Chem,2008,112(39):15375-15381.
[43]Wang Lifeng,Yin Chengyang,Shan Zhichao,et al.Bread-template synthesis of hierarchical mesoporous ZSM-5zeolite with hydrothermally stable mesoporosity[J].Colloids Surf,A,2009,340(1):126-130.
[44]Yao Jianfeng,Li Dan,Zhang Xinyi,et al.Cubes of zeolite a with an amorphous core[J].Angew Chem,2008,120(44):8525-8527.
[45]Greer H,Wheatley P S,Ashbrook S E,et al.Early stage reversed crystal growth of zeolite a and its phase transformation to sodalite[J].J Am Chem Soc,2009,131(49):17986-17992.
[46]Li Dan,Huang Yi,Ratinac K R,et al.Zeolite crystallization in crosslinked chitosan hydrogels:Crystal size control and chitosan removal[J].Microporous Mesoporous Mater,2008,116(1/3):416-423.
[47]Wang Huanting,Holmberg B A,Yan Yushan.Synthesis of template-free zeolite nanocrystals by using in situ thermoreversible polymer hydrogels[J].J Am Chem Soc,2003,125(33):9928-9929.
[48]Tao Haixiang,Li Changlin,Ren Jiawen,et al.Synthesis of mesoporous zeolite single crystals with cheap porogens[J].JSolid State Chem,2011,184(7):1820-1827.
[49]Pan Meng,Zheng Jiajun,Liu Yujian,et al.Big world in the small space:Constructing hollow zeolite microspheres using a sustainable template[J].Cryst Growth Des,2017,17(9):4900-4907.
[2]Dusselier M,Davis M E.Small-pore zeolites:Synthesis and catalysis[J].Chem Rev,2018,118(11):5265-5329.
[3]Yang Jinbiao,Liu Haiyan,Diao Haiju,et al.A quasi-solid-phase approach to activate natural minerals for zeolite synthesis[J].ACS Sustain Chem Eng,2017,5(4):3233-3242.
[4]丁佳佳,刘红星,张玉贤.不同孔结构拟薄水铝石合成SAPO-34分子筛及其MTO反应性能[J].石油化工,2018,47(10):1059-1065.
[5]Linares N,Silvestre-Albero A M,Serrano E,et al.Mesoporous materials for clean energy technologies[J].Chem Soc Rev,2014,43(22):7681-7717.
[6]Mintova S,Grand J,Valtchev V.Nanosized zeolites:Quo Vadis?[J].Comptes Rendus Chimie,2016,19(1):183-191.
[7]Liu Zhaohui,Hua Yingjie,Wang Jianjian,et al.Recent progress in the direct synthesis of hierarchical zeolites:Synthetic strategies and characterization methods[J].Mater Chem Front,2017,1(11):2195-2212.
[8]Masoumifard N,Guillet-Nicolas R,Kleitz F.Synthesis of engineered zeolitic materials:From classical zeolites to hierarchical core-shell materials[J].Adv Mater,2018,30(16):1704439.
[9]刘晓玲,姜健准,张明森.纳米薄片MFI结构分子筛合成的研究进展[J].石油化工,2016,45(1):113-120.
[10]冯英杰,冯静,张明森.多级孔分子筛Silicalite-1的制备及其在合成气直接制低碳烯烃反应中的应用[J].石油化工,2018,47(8):781-787.
[11]Schwanke A,Villarroel-Rocha J,Sapag K,et al.Dandelion-like microspherical MCM-22 zeolite using BP 2000 as a hard template[J].ACS Omega,2018,3(6):6217-6223.
[12]Varzaneh A Z,Towfighi J,Sahebdelfar S.Carbon nanotube templated synthesis of metal containing hierarchical SAPO-34catalysts:Impact of the preparation method and metal avidities in the MTO reaction[J].Microporous Mesoporous Mater,2016,236:1-12.
[13]Holland B T,Abrams L,Stein A.Dual templating of macroporous silicates with zeolitic microporous frameworks[J].J Am Chem Soc,1999,121(17):4308-4309.
[14]Zhu Haibo,Liu Zhicheng,Wang Yangdong,et al.Nanosized CaCO3 as hard template for creation of intracrystal pores within Silicalite-1 crystal[J].Chem Mater,2008,20(3):1134-1139.
[15]Zampieri A,Mabande G T P,Selvam T,et al.Biotemplating of luffa cylindrica sponges to self-supporting hierarchical zeolite macrostructures for bio-inspired structured catalytic reactors[J].Mater Sci Eng,C,2006,26(1):130-135.
[16]Yao Jianfeng,Wang Huanting,Ringer S P,et al.Growth of SAPO-34 in polymer hydrogels through vapor-phase transport[J].Microporous Mesoporous Mater,2005,85(3):267-272.
[17]Han Li,Yao Jianfeng,Li Dan,et al.Hollow zeolite structures formed by crystallization in crosslinked polyacrylamide hydrogels[J].J Mater Chem,2008,18(28):3337-3341.
[18]Jiang Jinlong,Yang Yong,Duanmu C,et al.Preparation of hollow ZSM-5 crystals in the presence of polyacrylamide[J].Microporous Mesoporous Mater,2012,163:11-20.
[19]Han Li,Jiang Xinge,Lu Tianliang,et al.Preparation of composite zeolites in polymer hydrogels and their catalytic performances in the methanol-to-olefin reaction[J].Fuel Process Technol,2017,165:87-93.
[20]Xiao Fengshou,Wang Lifeng,Yin Chengyang,et al.Catalytic properties of hierarchical mesoporous zeolites templated with a mixture of small organic ammonium salts and mesoscale cationic polymers[J].Angew Chem,2006,118(19):3162-3165.
[21]Wang Lifeng,Zhang Zhe,Yin Chengyang,et al.Hierarchical mesoporous zeolites with controllable mesoporosity templated from cationic polymers[J].Microporous Mesoporous Mater,2010,131(113):58-67.
[22]Liu Shuzhen,Cao Xuejing,Li Liansheng,et al.Preformed zeolite precursor route for synthesis of mesoporous X zeolite[J].Colloids Surf,A,2008,318(1):269-274.
[23]Zhu Jie,Zhu Yihan,Zhu Liangkui,et al.Highly mesoporous single-crystalline zeolite beta synthesized using a nonsurfactant cationic polymer as a dual-function template[J].J Am Chem Soc,2014,136(6):2503-2510.
[24]Dong Angang,Wang Yajun,Wang Deju,et al.Fabrication of hollow zeolite microcapsules with tailored shapes and functionalized interiors[J].Microporous Mesoporous Mater,2003,64(1/3):69-81.
[25]Venna S R,Carreon M A.Synthesis of SAPO-34 crystals in the presence of crystal growth inhibitors[J].J Phys Chem B,2008,112(51):16261-16265.
[26]Tao Haixiang,Yang Hong,Liu Xiaohui,et al.Highly stable hierarchical ZSM-5 zeolite with intra-and inter-crystalline porous structures[J].Chem Eng J,2013,225:686-694.
[27]Koohsaryan E,Anbia M.Facile and rapid synthesis of highly crystalline mesoporous zeolite FAU[J].Mater Lett,2019,236:390-393.
[28]Tian Dayong,Yan Wenfu,Cao Xuejing,et al.Morphology changes of transition-metal-substituted aluminophosphate molecular sieve AlPO4-5 crystals[J].Chem Mater,2008,20(6):2160-2164.
[29]Tao Yousheng,Kanoh H,Kaneko K.ZSM-5 monolith of uniform mesoporous channels[J].J Am Chem Soc,2003,125(20):6044-6045.
[30]Tao Yousheng,Kanoh H,Kaneko K.Uniform mesopore-donated zeolite Y using carbon aerogel templating[J].J Phys Chem B,2003,107(40):10974-10976.
[31]Yousheng T,Hirofumi K,Katsumi K.Synthesis of mesoporous zeolite A by resorcinol-formaldehyde aerogel templating[J].Langmuir ACS J Surf Colloids,2005,21(2):504-507.
[32]Yousheng T,Yoshiyuki H,Akihiko M,et al.Comparative study on pore structures of mesoporous ZSM-5 from resorcinolformaldehyde aerogel and carbon aerogel templating[J].JPhys Chem B,2005,109(1):194-199.
[33]Kang Yijin,Wei Shan,Wu Jingyi,et al.Uniform nanozeolite microspheres with large secondary pore architecture[J].Chem Mater,2006,18(7):1861-1866.
[34]Tosheva L,Mihailova B,Valtchev V,et al.Silicalite-1macrostructures-preparation and structural features[J].Microporous Mesoporous Mater,2000,39(112):91-101.
[35]Tosheva L,Valtchev V,Sterte J.Silicalite-1 containing microspheres prepared using shape-directing macro-templates[J].Microporous Mesoporous Mater,2000,35(136):621-629.
[36]Wang Hui,Pinnavaia T J.MFI zeolite with small and uniform intracrystal mesopores[J].Angew Chem,2006,118(45):7765-7768.
[37]Park D H,Kim S S,Wang Hui,et al.Selective petroleum refining over a zeolite catalyst with small intracrystal mesopores[J].Angew Chem,Int Ed,2009,48(41):7645-7648.
[38]Jo C,Seo Y,Cho K,et al.Random-graft polymer-directed synthesis of inorganic mesostructures with ultrathin frameworks[J].Angew Chem,Int Ed,2014,53(20):5117-5121.
[39]Zhang B,Davis S A,Mann S.Starch gel templating of spongelike macroporous silicalite monoliths and mesoporous films[J].Chem Mater,2002,14(3):1369-1375.
[40]刘志成,孔德金,王仰东.淀粉模板法合成介孔ZSM-5分子筛[J].石油学报:石油加工,2008,24(z1):124-126,135.
[41]Zhang Miaorong,Liu Xinmei,Yan Zifeng.Soluble starch as in-situ template to synthesize ZSM-5 zeolite with intracrystal mesopores[J].Mater Lett,2016,164:543-546.
[42]Liu Yong,Zhang Weiping,Liu Zhicheng,et al.Direct observation of the mesopores in ZSM-5 zeolites with hierarchical porous structures by laser-hyperpolarized 129Xe NMR[J].JPhys Chem,2008,112(39):15375-15381.
[43]Wang Lifeng,Yin Chengyang,Shan Zhichao,et al.Bread-template synthesis of hierarchical mesoporous ZSM-5zeolite with hydrothermally stable mesoporosity[J].Colloids Surf,A,2009,340(1):126-130.
[44]Yao Jianfeng,Li Dan,Zhang Xinyi,et al.Cubes of zeolite a with an amorphous core[J].Angew Chem,2008,120(44):8525-8527.
[45]Greer H,Wheatley P S,Ashbrook S E,et al.Early stage reversed crystal growth of zeolite a and its phase transformation to sodalite[J].J Am Chem Soc,2009,131(49):17986-17992.
[46]Li Dan,Huang Yi,Ratinac K R,et al.Zeolite crystallization in crosslinked chitosan hydrogels:Crystal size control and chitosan removal[J].Microporous Mesoporous Mater,2008,116(1/3):416-423.
[47]Wang Huanting,Holmberg B A,Yan Yushan.Synthesis of template-free zeolite nanocrystals by using in situ thermoreversible polymer hydrogels[J].J Am Chem Soc,2003,125(33):9928-9929.
[48]Tao Haixiang,Li Changlin,Ren Jiawen,et al.Synthesis of mesoporous zeolite single crystals with cheap porogens[J].JSolid State Chem,2011,184(7):1820-1827.
[49]Pan Meng,Zheng Jiajun,Liu Yujian,et al.Big world in the small space:Constructing hollow zeolite microspheres using a sustainable template[J].Cryst Growth Des,2017,17(9):4900-4907.