摘要
The scattering properties of ZnO nanospheres with four different particle diameters of 10, 50, 100, and 200 nm suspended in water are investigated theoretical and experimentally in the spectral range of the entire visible range and part of the near-infrared region. The scattering properties of ZnO nanospheres suspended in water are described by employing three main parameters: the angular distribution of the scattering intensity I, the scattering extinction coefficient αscat, and the scattering cross section σscat. The results indicate that(i) at a certain wavelength, the angular distribution of the scattering intensity appears as an obviously forwardpropagating feature, and the forward-scattering intensity is dominant gradually when the particle diameter increases from 10 to 200 nm, and(ii) the scattering extinction coefficient and cross section can be determined by using the measured transmittance changes of a pure water sample and a given ZnO sample; they all are shown to be dependent on the particle size and incident wavelength. The experimental results of four different scattering samples agree well with the theoretical predictions within the given wavelength range.
The scattering properties of ZnO nanospheres with four different particle diameters of 10, 50, 100, and 200 nm suspended in water are investigated theoretical and experimentally in the spectral range of the entire visible range and part of the near-infrared region. The scattering properties of ZnO nanospheres suspended in water are described by employing three main parameters: the angular distribution of the scattering intensity I, the scattering extinction coefficient αscat, and the scattering cross section σscat. The results indicate that(i) at a certain wavelength, the angular distribution of the scattering intensity appears as an obviously forwardpropagating feature, and the forward-scattering intensity is dominant gradually when the particle diameter increases from 10 to 200 nm, and(ii) the scattering extinction coefficient and cross section can be determined by using the measured transmittance changes of a pure water sample and a given ZnO sample; they all are shown to be dependent on the particle size and incident wavelength. The experimental results of four different scattering samples agree well with the theoretical predictions within the given wavelength range.
引文
1.L.Rayleigh,Philos.Mag.47,375(1899).
2 .G.Mie,Ann.Phys.330,377(1908).
3 .J.Tyndall,Proc.R.Soc.London 17,223(1868).
4 .E.I.Franses,J.M.Caruthers,and S.Yarlagadda,J.Chem.Phys.83,1531(1985).
5 .T.Wriedt,Part.Part.Syst.Char.15,67(1998).
6 .T.Wriedt,J.Quantum Spectrosc.RA.110,833(2009).
7 .G.Gouesbet,F.Xu,and Y.P.Han,J.Quantum Spectrosc.RA.112,2249(2011).
8 .B.Schmidtke and E.A.R?ssler,J.Chem.Phys.141,044511(2014).
9 .B.Kang,Y.Cai,and L.Wang,Chin.Opt.Lett.14,070401(2016).
10 .M.Hlaing,B.Gebear-Eigzabher,A.Roa,A.Marcano,D.Radu,and C.Y.Lai,Opt.Mater.58,439(2016).
11 .I.Kim,K.S.Lee,T.S.Lee,D.S.Jung,W.S.Lee,W.M.Kim,and K.S.Lee,Synthetic Met.199,174(2015).
12 .S.Eustis and M.A.El-Sayed,Phys.Chem.B 109,16350(2005).
13 .K.Aslan,P.Holley,L.Davies,J.R.Lakowicz,and C.D.Geddes,J.Am.Chem.Soc.127,12115(2005).
14 .G.S.He,H.Y.Qin,and Q.Zheng,J.Appl.Phys.105,023110(2009).
15 .G.S.He,K.T.Yong,J.Zhu,and P.N.Prasad,Phys.Rev.A 85,043839(2012).
16 .P.J.Wyatt,Anal.Chem.86,7171(2014).
17 .M.I.Mishchenko,L.D.Travis,and A.A.Lacis,Scattering,Absorption,and Emission of Light by Small Particles(NASA Goddard Institute for Space Studies,2002).
18 .J.Shi,H.Wu,F.Yan,J.Yang,and X.He,J.Nanopart.Res.18,23(2016).
19 .P.K.Jain,K.S.Lee,I.H.El-Sayed,and M.A.El-Sayed,J.Phys.Chem.B 110,7238(2006).
20 .C.Ding,K.Yang,W.Li,W.Guo,X.Zhang,and M.Xia,Opt.Laser Technol.62,135(2014).
21 .T.Honda,M.Terakawa,and M.Obara,Appl.Phys.B 111,117(2013).
22 .A.A.Tomchenko,G.P.Harmer,B.T.Marquis,and J.W.Allen,Sens.Actuators B 93,126(2003).
23 .S.H.Chen,U.Nickel,and X.M.Ren,J.Colloid Interface Sci.176,286(1995).
24 .S.Chen,J.Shi,X.Kong,Z.Wang,and D.Liu,Laser Phys.Lett.10,055006(2013).
25 .S.J.Chen,Y.Zhou,T.R.Zhai,Z.N.Wang,and D.H.Liu,Laser Phys.Lett.9,570(2012).
26 .W.Liben and B.Goldberg,J.Opt.Soc.Am.43,347(1953).
27 .M.Born and E.Wolf,The Principles of Optics(Pergamon,1980).