消焰剂对煤矿许用乳化炸药热稳定性的影响
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摘要
利用改进的铁板实验测试了NaCl、KCl两种消焰剂对煤矿许用乳化炸药热稳定性的影响。实验结果表明:乳化炸药样品的发火延滞期均随着外界环境温度的增加而减小,最高发火温度随外界环境温度的升高而增加;在相同的环境温度下,含有NaCl的煤矿许用乳化炸药的发火延滞期最长,最高发火温度最高,表观活化能最大,含有KCl的乳化炸药次之,乳化炸药最小。研究表明消焰剂的加入可使得乳化炸药的延滞期延长,最高发火温度和表观活化能增加;在含量相同的情况下,含NaCl的乳化炸药的热稳定性优于含KCl的煤矿许用乳化炸药。
Using the improved plate test, the effects of two kinds of flame inhibitor on the thermal stability of coalmine permitted emulsion explosive were measured. The experiment results showed that the ignition delay time of emulsion explosive was decreased with the increase of the external environment temperature, while the highest ignition temperature was increased. Under the same temperature, for the emulsion explosive containing NaCl, its ignition delay time is the longest, combustion temperature and apparent activation energy are the highest, while those of the emulsion explosive are the least. The study show that the addition of flame inhibitor could make the ignition delay time of emulsion explosive extended, and the highest ignition temperature and apparent activation energy increased, under the condition of the same content, thermal stability of the emulsion explosive containing NaCl is superior to that of the emulsion explosive containing KCl.
Using the improved plate test, the effects of two kinds of flame inhibitor on the thermal stability of coalmine permitted emulsion explosive were measured. The experiment results showed that the ignition delay time of emulsion explosive was decreased with the increase of the external environment temperature, while the highest ignition temperature was increased. Under the same temperature, for the emulsion explosive containing NaCl, its ignition delay time is the longest, combustion temperature and apparent activation energy are the highest, while those of the emulsion explosive are the least. The study show that the addition of flame inhibitor could make the ignition delay time of emulsion explosive extended, and the highest ignition temperature and apparent activation energy increased, under the condition of the same content, thermal stability of the emulsion explosive containing NaCl is superior to that of the emulsion explosive containing KCl.
引文
[1]马志钢,王瑾.乳化炸药的热分解特性[J].含能材料,2004,12(5):294-296.
[2]王国利,李建军,汪旭光,唐勇.采用加速量热法评价工业炸药热安全性的研究[J].爆破器材,1997,26(6):1-5.
[3]傅智敏,冯宏图,冯长根,钱新明.用加速量热仪研究乳化炸药的热稳定性[J].安全与环境学报,2001,1(3):21-25.
[4]李建军,汪旭光,欧育湘,陈博仁.乳化炸药热分解动力学研究[J].北京理工大学学报,1996,16(6):636-642.
[2]王国利,李建军,汪旭光,唐勇.采用加速量热法评价工业炸药热安全性的研究[J].爆破器材,1997,26(6):1-5.
[3]傅智敏,冯宏图,冯长根,钱新明.用加速量热仪研究乳化炸药的热稳定性[J].安全与环境学报,2001,1(3):21-25.
[4]李建军,汪旭光,欧育湘,陈博仁.乳化炸药热分解动力学研究[J].北京理工大学学报,1996,16(6):636-642.