耐温表面活性剂在油藏开发中的研究进展
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摘要
表面活性剂驱是三次采油中稳产增产的重要手段,随着高温油藏研究开发的不断深入,耐高温表面活性剂具有更加重要的研究价值。该文根据深层油藏温度高的特点和中国油藏开发现状,在研究国内外文献资料的基础上,将具有耐高温性能的表面活性剂按阴-非离子型(Anionic-nonionic)、两性型(Amphoteric)、双子型(Gemini)和氟碳型(Fluorocarbon)分类。通过对4类表面活性剂的比较,讨论了基团、分子结构等因素对表面活性剂耐温性的影响,指出可生物降解表面活性剂是耐温表面活性剂继续发展的重要方向,同时对双子表面活性剂的合成及氟碳表面活性剂的应用提出了建议。
Surfactant flooding used in tertiary oil recovery is a kind of crucial method for stable oil production and increasing oil production. Along with the continuing research and exploitation of hightemperature reservoir, high-temperature resistant surfactants have more important research value. According to the characteristics of high-temperature reservoir and its development status in China, hightemperature resistant surfactants can be divided into four categories: anionic-nonionic, amphoteric, Gemini and fluorocarbon surfactants. By comparing the surfactants reviewed in this paper, some factors affecting their temperature resistance such as group and molecular structure are discussed. Subsequently, it is also pointed out that the biodegradable surfactant is one of the most important research directions of hightemperature resistant surfactants. At the same time, some suggestions on the synthesis of Gemini surfactants and the application of fluorocarbon surfactants are put forward.
Surfactant flooding used in tertiary oil recovery is a kind of crucial method for stable oil production and increasing oil production. Along with the continuing research and exploitation of hightemperature reservoir, high-temperature resistant surfactants have more important research value. According to the characteristics of high-temperature reservoir and its development status in China, hightemperature resistant surfactants can be divided into four categories: anionic-nonionic, amphoteric, Gemini and fluorocarbon surfactants. By comparing the surfactants reviewed in this paper, some factors affecting their temperature resistance such as group and molecular structure are discussed. Subsequently, it is also pointed out that the biodegradable surfactant is one of the most important research directions of hightemperature resistant surfactants. At the same time, some suggestions on the synthesis of Gemini surfactants and the application of fluorocarbon surfactants are put forward.
引文
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[7]Sun Tongcheng(孙同成), Cui Ya(崔亚). Research progress of deep Profile control and oil displacement agents for high temperature and high salinity reservoirs[J]. Synthetic Materials Aging and Application(合成材料老化与应用), 2016, 45(2):99-105.
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[12]ZhaoJianhui(赵健慧).Synthesis,performanceevaluationof temperature-resistantandsalinity-tolerantsurfactantandits construction of oil flooding system[D]. Qingdao:China University of Petroleum(East China)(中国石油大学), 2015.
[13]BehrAM,TuckerCJ,DaugsED.Performanceofnew biodegradabledi-sulfonatesurfactantsashydrotropesinhightemperature and salinity environments[J]. Journal of Surfactants and Detergents, 2015, 18(2):329-338.
[14]SongChenglong(宋成龙).Synthesisandperformanceresearchof nonylphenol betaine type amphoteric surfactant[D]. Daqing:Northeast Petroleum University(东北石油大学), 2015.
[15]GuoShufeng,WangHongyan,ShiJing,etal.Synthesisand properties of a novel alkyl-hydroxyl-sulfobetaine zwitterionic surfactant forenhancedoilrecovery[J].JournalofPetroleumExplorationand Production Technology, 2015, 59(3):321-326.
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[17]ZhaoJi(赵冀),FangJichao(方吉超),ZhouDaiyu(周代余),etal.SurfactantfloodinginTazhong402CⅢhigh-temperatureandhighsalinityreservoir[J].OilfieldChemistry(油田化学),2014,31(3):405-409.
[18]Zhao Guozhu(赵国柱), Jin Rengao(金仁高), Li Shengtao(李圣涛),et al. Performance and application of betaine type surfactant TCJ-5 in high temperature and high salinity reservoir[J]. Journal of Northeast Petroleum University(东北石油大学学报), 2015, 39(3):111-116.
[19]Meng Qingyang(孟庆阳), Chen Jie(陈捷), Zhao Tianjing(赵甜静),etal.InterfacialtensionandfoamingpropertiesofAPGandLC aqueoussolutionswithhighsalinityinhightemperature[J].Journal of Shanghai University(上海大学学报), 2013, 19(4):437-439.
[20]Gao Jinhao(高进浩), Shen Yiding(沈一丁), Wang Lei(王磊), et al.Developmentandperformanceoftemperaturetolerancesurfactant GY-9[J].ModernChemicalIndustry(现代化工),2015,35(10):91-94.
[21]KamalMS,HussainSMS,SultanAS.Developmentofnovel amidosulfobetainesurfactant-polymersystemsforEORapplications[J]. Journal of Surfactants and Detergents, 2016, 19:989-997.
[22]Kamal M S. A review of Gemini surfactants:potential application in enhancedoilrecovery[J].JournalofSurfactantsandDetergents,2016, 19(2):223-236.
[23]Chen Wenjie(陈文杰), Shao Bo(邵波), Liu Yong(刘勇), et al. The applicationofGeminisurfactantinthedevelopmentofoilandgas fields[J].JournalofYangtzeUniversity(长江大学学报),2016,13(34):66-70.
[24]GaoDapeng(高大鹏),GaoJingbin(高景滨).Studyofrheologyof anionic Gemini surfactant solution at high temperature[J]. Advances in Fine Petrochemicals(精细石油化工进展), 2012, 13(5):37-39.
[25]Salehi M, Johnson S J, Liang J T. Enhanced wettability alteration by surfactantswithmultiplehydrophilicmoieties[J].Journalof Surfactants and Detergents, 2010, 13(3):243-246.
[26]Shen Zhiqin(沈之芹), Li Yingcheng(李应成), Sha Ou(沙鸥), et al.Synthesis and properties of nonionic-anionic Gemini surfactants with high activity[J]. Advances in Fine Petrochemicals(精细石油化工进展), 2011, 12(9):25-28.
[27]Su Xin(苏鑫), Wang Biqing(王碧清), Li Junxiu(李俊秀), et al. The effectsofhightemperatureandhighsalinityonsurfaceactivityof cationicGeminisurfactant[J].InnerMongoliaPetrochemical Industry(内蒙古石油化工), 2011,(7):1-3.
[28]Hussain S M S, Kamal M S, Sultan A S. Amido-amine-based cationic Geminisurfactants:thermalandinterfacialpropertiesand interactionswithcationicpolyacrylamide[J].JournalofSurfactants and Detergents, 2017, 20(1):47-55.
[29]WuJunwen(武俊文),XiongChunming(熊春明),LeiQun(雷群),et al. Application of Gemini surfactant in preparing foaming drainage agent with resistance to high temperature and high salinity[J]. Oil Drilling&Production Technology(石油钻采工艺), 2016, 38(2):256-259.
[30]FodorC,KaliG,IvánB.Poly(N-vinylimidazole)-1-po-ly(tetrahydrofuran)amphiphilicconetworksandgels:Synthesis characterizationthermalandswellingbehavior[J].American Chemical Society, 2011, 44(11):4496-4502.
[31]LiFan(李凡),LuoYue(罗跃),SuGaoshen(苏高申),etal.ExperimentalstudyontemperatureandoilresistantfluorinecontainingfoamingagentsforCO2flooding[J].Speciality Petrochemicals(精细石油化工), 2016, 33(2):44-49.
[32]ZhouJiehua(周杰华).Synthesisandperformanceofnovel perfluoropolyetherderivativedfluorocarbonsurfactants[D].Shanghai:Donghua University(东华大学), 2013.
[33]KamalMS,SultanAS,Al-MubaiyedhUA,etal.Evaluationof rheologicalandthermalpropertiesofanewfluorocarbon surfactant-polymer system for EOR applications in high-temperature andhigh-salinityoilreservoirs[J].JournalofSurfactantsand Detergents, 2014, 17:985-993.
[34]Wang Qiwei(王其伟). Present situation and development prospect of foamflooding[J].OilDrilling&ProductionTechnology(石油钻采工艺), 2013, 35(2):94-97.
[35]ZhangWenke(张文柯).Progressofresearchonsurfactantoil displacement systems[J]. Guangdong Chemical Industry(广东化工),2013, 40(4):166-169.
[36]KamalMS,HussienIA,SultanAS,etal.Rheologicalstudyon ATBS-AMcopolymer-surfactantsysteminhigh-temperatureand high-salinity environment[J]. Journal of Chemistry, 2013:801570.
[37]DongZ,ZhengY,ZhaoJ.Synthesis,physico-chemicalproperties and enhanced oil recovery flooding evaluation of novel zwitterionic Geminisurfactants[J].JournalofSurfactantsandDetergents,2014,17(6):1213-1222.
[2]DonnellyJ.Thethirdinternationaloiltechnologyconferencefocusingonfutureenergyneeds[J].ForeignOil&GasInformation(石油科技动态), 2009,(8):8-9.
[3]Anonym. New deep-reservoir diagnostics under development[EB/OL].http://www.gulfoilandgas.com/webpro1/MAIN/Mainnews.asp?id=4646. 2007.
[4]Vermolen E C M, Haasterecht M J T V, Masalmeh S K, et al. Pushing theenvelopeforpolymerfloodingtowardshigh-temperatureand high-salinity reservoirs with polyacrylamide based ter-polymers[C]//SPE Middle East Oil and Gas Show and Conference, United States:Society of Petroleum Engineers, 2011:1-13.
[5]Cheng Yun(程云). Synthesis of a kind of surfactant for EOR and its performancemeasurement[D].Nanjing:NanjingUniversityof Science&Technology(南京理工大学), 2014.
[6]DingWei(丁伟),XingXinxin(邢欣欣),YuTao(于涛),etal. Propertyofhydroxylsulfobetainesurfactantappropriateforhightemperatureandhigh-salinityreservoir[J].OilfieldChemistry(油田化学), 2013, 30(4):562-564.
[7]Sun Tongcheng(孙同成), Cui Ya(崔亚). Research progress of deep Profile control and oil displacement agents for high temperature and high salinity reservoirs[J]. Synthetic Materials Aging and Application(合成材料老化与应用), 2016, 45(2):99-105.
[8]WangPeng(王鹏).Studyonchemicalfloodingagentforhigh temperatureandhighsalinityreservoir[J].ShandongIndustrial Technology(山东工业技术), 2016, 19:4.
[9]TangHongjiao(唐红娇),HouJirui(侯吉瑞),ZhaoFenglan(赵凤兰),etal.Applicationprogressofnonionicandanionic-nonionic surfactants used in oil field[J]. Oilfield Chemistry(油田化学), 2011,28(1):115-117.
[10]Yang Wenxin(杨文新), Sha Ou(沙鸥), He Jianhua(何建华), et al.Applicationoftemperatureresistantandsalttolerantanionicnonionicsurfactants[J].OilfieldChemistry(油田化学),2013,30(3):416-419.
[11]Chen Xin(陈欣), Zhou Ming(周明), Xia Liangliang(夏亮亮), et al.Propertiesoftwokindsofanionic-nonionicsurfactantsusedinoil field[J]. Oilfield Chemistry(油田化学), 2016, 33(1):103-106.
[12]ZhaoJianhui(赵健慧).Synthesis,performanceevaluationof temperature-resistantandsalinity-tolerantsurfactantandits construction of oil flooding system[D]. Qingdao:China University of Petroleum(East China)(中国石油大学), 2015.
[13]BehrAM,TuckerCJ,DaugsED.Performanceofnew biodegradabledi-sulfonatesurfactantsashydrotropesinhightemperature and salinity environments[J]. Journal of Surfactants and Detergents, 2015, 18(2):329-338.
[14]SongChenglong(宋成龙).Synthesisandperformanceresearchof nonylphenol betaine type amphoteric surfactant[D]. Daqing:Northeast Petroleum University(东北石油大学), 2015.
[15]GuoShufeng,WangHongyan,ShiJing,etal.Synthesisand properties of a novel alkyl-hydroxyl-sulfobetaine zwitterionic surfactant forenhancedoilrecovery[J].JournalofPetroleumExplorationand Production Technology, 2015, 59(3):321-326.
[16]XingXinxin(邢欣欣).Synthesisandpropertiesofzwitterionic surfactantsapplicableforuseinpooroilreservoir[D].Daqing:Northeast Petroleum University(东北石油大学), 2013.
[17]ZhaoJi(赵冀),FangJichao(方吉超),ZhouDaiyu(周代余),etal.SurfactantfloodinginTazhong402CⅢhigh-temperatureandhighsalinityreservoir[J].OilfieldChemistry(油田化学),2014,31(3):405-409.
[18]Zhao Guozhu(赵国柱), Jin Rengao(金仁高), Li Shengtao(李圣涛),et al. Performance and application of betaine type surfactant TCJ-5 in high temperature and high salinity reservoir[J]. Journal of Northeast Petroleum University(东北石油大学学报), 2015, 39(3):111-116.
[19]Meng Qingyang(孟庆阳), Chen Jie(陈捷), Zhao Tianjing(赵甜静),etal.InterfacialtensionandfoamingpropertiesofAPGandLC aqueoussolutionswithhighsalinityinhightemperature[J].Journal of Shanghai University(上海大学学报), 2013, 19(4):437-439.
[20]Gao Jinhao(高进浩), Shen Yiding(沈一丁), Wang Lei(王磊), et al.Developmentandperformanceoftemperaturetolerancesurfactant GY-9[J].ModernChemicalIndustry(现代化工),2015,35(10):91-94.
[21]KamalMS,HussainSMS,SultanAS.Developmentofnovel amidosulfobetainesurfactant-polymersystemsforEORapplications[J]. Journal of Surfactants and Detergents, 2016, 19:989-997.
[22]Kamal M S. A review of Gemini surfactants:potential application in enhancedoilrecovery[J].JournalofSurfactantsandDetergents,2016, 19(2):223-236.
[23]Chen Wenjie(陈文杰), Shao Bo(邵波), Liu Yong(刘勇), et al. The applicationofGeminisurfactantinthedevelopmentofoilandgas fields[J].JournalofYangtzeUniversity(长江大学学报),2016,13(34):66-70.
[24]GaoDapeng(高大鹏),GaoJingbin(高景滨).Studyofrheologyof anionic Gemini surfactant solution at high temperature[J]. Advances in Fine Petrochemicals(精细石油化工进展), 2012, 13(5):37-39.
[25]Salehi M, Johnson S J, Liang J T. Enhanced wettability alteration by surfactantswithmultiplehydrophilicmoieties[J].Journalof Surfactants and Detergents, 2010, 13(3):243-246.
[26]Shen Zhiqin(沈之芹), Li Yingcheng(李应成), Sha Ou(沙鸥), et al.Synthesis and properties of nonionic-anionic Gemini surfactants with high activity[J]. Advances in Fine Petrochemicals(精细石油化工进展), 2011, 12(9):25-28.
[27]Su Xin(苏鑫), Wang Biqing(王碧清), Li Junxiu(李俊秀), et al. The effectsofhightemperatureandhighsalinityonsurfaceactivityof cationicGeminisurfactant[J].InnerMongoliaPetrochemical Industry(内蒙古石油化工), 2011,(7):1-3.
[28]Hussain S M S, Kamal M S, Sultan A S. Amido-amine-based cationic Geminisurfactants:thermalandinterfacialpropertiesand interactionswithcationicpolyacrylamide[J].JournalofSurfactants and Detergents, 2017, 20(1):47-55.
[29]WuJunwen(武俊文),XiongChunming(熊春明),LeiQun(雷群),et al. Application of Gemini surfactant in preparing foaming drainage agent with resistance to high temperature and high salinity[J]. Oil Drilling&Production Technology(石油钻采工艺), 2016, 38(2):256-259.
[30]FodorC,KaliG,IvánB.Poly(N-vinylimidazole)-1-po-ly(tetrahydrofuran)amphiphilicconetworksandgels:Synthesis characterizationthermalandswellingbehavior[J].American Chemical Society, 2011, 44(11):4496-4502.
[31]LiFan(李凡),LuoYue(罗跃),SuGaoshen(苏高申),etal.ExperimentalstudyontemperatureandoilresistantfluorinecontainingfoamingagentsforCO2flooding[J].Speciality Petrochemicals(精细石油化工), 2016, 33(2):44-49.
[32]ZhouJiehua(周杰华).Synthesisandperformanceofnovel perfluoropolyetherderivativedfluorocarbonsurfactants[D].Shanghai:Donghua University(东华大学), 2013.
[33]KamalMS,SultanAS,Al-MubaiyedhUA,etal.Evaluationof rheologicalandthermalpropertiesofanewfluorocarbon surfactant-polymer system for EOR applications in high-temperature andhigh-salinityoilreservoirs[J].JournalofSurfactantsand Detergents, 2014, 17:985-993.
[34]Wang Qiwei(王其伟). Present situation and development prospect of foamflooding[J].OilDrilling&ProductionTechnology(石油钻采工艺), 2013, 35(2):94-97.
[35]ZhangWenke(张文柯).Progressofresearchonsurfactantoil displacement systems[J]. Guangdong Chemical Industry(广东化工),2013, 40(4):166-169.
[36]KamalMS,HussienIA,SultanAS,etal.Rheologicalstudyon ATBS-AMcopolymer-surfactantsysteminhigh-temperatureand high-salinity environment[J]. Journal of Chemistry, 2013:801570.
[37]DongZ,ZhengY,ZhaoJ.Synthesis,physico-chemicalproperties and enhanced oil recovery flooding evaluation of novel zwitterionic Geminisurfactants[J].JournalofSurfactantsandDetergents,2014,17(6):1213-1222.