微/纳米过渡金属氧化物的液相合成及其应用
|
摘要
首先综述了多种不同形貌、结构及尺寸的过渡金属氧化物微/纳米颗粒的液相合成法(水热法、溶剂热法、沉淀法、溶胶-凝胶法和微乳液法),其次介绍了微/纳米过渡金属氧化物在催化、吸附及抗菌等领域的应用,最后对过渡金属氧化物微/纳米材料进一步发展需要重点关注的研究方向进行了展望。
Many of transition metal oxides micro/nano particles with different morphology,structure and size prepared by liquid-phase method(hydrothermal method,solvothermal method,precipitation method,sol-gel method and microemulsion method)were reviewed,firstly.And then the application of micro/nano transition metal oxides in catalysis,adsorption and antibacterial were introduced.The end was a prospect over the research direction for the development of transition metal oxides micro/nano materials.
Many of transition metal oxides micro/nano particles with different morphology,structure and size prepared by liquid-phase method(hydrothermal method,solvothermal method,precipitation method,sol-gel method and microemulsion method)were reviewed,firstly.And then the application of micro/nano transition metal oxides in catalysis,adsorption and antibacterial were introduced.The end was a prospect over the research direction for the development of transition metal oxides micro/nano materials.
引文
[1]Gao D,Yang G,Li J,et al.Room-temperature ferromagnetism of flowerlike CuO nanostructures[J].The Journal of Physical Chemistry C,2010,114(43):18347.
[2]Li X,Zhang B,Ju C,et al.Morphology-controlled synthesis and electromagnetic properties of porous Fe3O4 nanostructures from iron alkoxide precursors[J].The Journal of Physical Chemistry C,2011,115(25):12350-12357.
[3]Xuan S,Hao L,Jiang W,et al.A FeCO3precursor-based route to microsized peanutlike Fe3O4[J].Crystal Growth&Design,2007,7(2):430.
[4]Ai Z,Deng K,Wan Q,et al.Facile microwave-assisted synthesis and magnetic and gas sensing properties of Fe3O4nanoroses[J].The Journal of Physical Chemistry C,2010,114(14):6237.
[5]Zhang D E,Zhang X J,Ni X M,et al.Fabrication and characterization of Fe3O4octahedrons via an EDTA-assisted route[J].Crystal Growth&Design,2007,7(10):2117.
[6]Fan T,Pan D,Zhang H.Study on formation mechanism by monitoring the morphology and structure evolution of nearly monodispersed Fe3O4submicroparticles with controlled particle sizes[J].Industrial&Engineering Chemistry Research,2011,50(15):9009.
[7]Zhang Y,Zhu J,Song X,et al.Controlling the synthesis of CoO nanocrystals with various morphologies[J].The Journal of Physical Chemistry C,2008,112(14):5322.
[8]Yang H,Ouyang J,Tang A.Single step synthesis of high-purity CoO nanocrystals[J].The Journal of Physical Chemistry B,2007,111(28):8006.
[9]Sun G,Zhang X,Cao M,et al.Facile synthesis,characterization,and microwave absorbability of CoO nanobelts and submicrometer spheres[J].The Journal of Physical Chemistry C,2009,113(17):6948.
[10]Fazlali F,Mahjoub Areza,Abazari R.A new route for synthesis of spherical NiO nanoparticles via emulsion nano-reactors with enhanced photocatalytic activity[J].Solid State Sciences,2015,48:263.
[11]Wang X,Yu L,Hu P,et al.Synthesis of single-crystalline hollow octahedral NiO[J].Crystal Growth and Design,2007,7(12):2415.
[12]Cui Y,Wang C,Wu S,et al.Lotus-root-like NiO nanosheets and flower-like NiO microspheres:synthesis and magnetic properties[J].Cryst Eng Comm,2011,13(15):4930.
[13]朱脉勇.过渡金属铁,铜氧化物纳米材料的制备及催化应用研究[D].扬州:扬州大学,2011.
[14]Yang Z,Xu J,Zhang W,et al.Controlled synthesis of CuOnanostructures by a simple solution route[J].Journal of Solid State Chemistry,2007,180(4):1390.
[15]Anandan S,Lee G J,Wu J J.Sonochemical synthesis of CuOnanostructures with different morphology[J].Ultrasonics Sonochemistry,2012,19(3):682.
[16]Zhang C,Wang Y,Bi S,et al.Preparation of mesoporous ZnOmicrospheres through a membrane-dispersion microstructured reactor and a hydrothermal treatment[J].Industrial&Engineering Chemistry Research,2011,50(23):13355.
[17]孙建兴.金属氧化物纳米材料的制备及光学特性研究[D].南昌:南昌航空大学,2014.
[18]Zhang L,Zhao J,Lu H,et al.High sensitive and selective formaldehyde sensors based on nanoparticle-assembled ZnOmicro-octahedrons synthesized by homogeneous precipitation method[J].Sensors and Actuators B:Chemical,2011,160(1):364.
[19]Mo M,Yu J C,Zhang L,et al.Self-assembly of ZnO nanorods and nanosheets into Hollow microhemispheres and microspheres[J].Advanced Materials,2005,17(6):756.
[20]Wang H,Xie C,Zeng D,et al.Controlled organization of ZnObuilding blocks into complex nanostructures[J].Journal of Colloid and Interface Science,2006,297(2):570.
[21]Askarinejad A,Morsali A.Synthesis of cadmium(Ⅱ)hydroxide,cadmium(Ⅱ)carbonate and cadmium(Ⅱ)oxide nanoparticles;investigation of intermediate products[J].Chemical Engineering Journal,2009,150(2):569.
[22]Tadjarodi A,Imani M,Kerdari H,et al.Preparation of CdOrhombus-like nanostructure and its photocatalytic degradation of azo dyes from aqueous solution[J].Nanomaterials and Nanotechnology,2014,4:16.
[23]Tadjarodi A,Imani M,Kerdari H.Application of a facile solidstate process to synthesize the CdO spherical nanoparticles[J].International Nano Letters,2013,3(1):43.
[24]Tadjarodi A,Imani M,Kerdari H.Application of experimental design to optimize the synthesis of CdO cauliflower-like nanostructure using mechanochemical method[J].Journal of Nanostructures,2012,1(2):127.
[25]Fu X,Liu J,Han T,et al.A three-dimensional hierarchical CdO nanostructure:preparation and its improved gas-diffusing performance in gas sensor[J].Sensors and Actuators B:Chemical,2013,184:260.
[26]Raj D S,Krishnakumar T,Jayaprakash R,et al.CO sensing characteristics of hexagonal-shaped CdO nanostructures prepared by microwave irradiation[J].Sensors and Actuators B:Chemical,2012,171:853.
[27]Hayat K,Gondal M A,Khaled M M,et al.Nano ZnO synthesis by modified sol gel method and its application in heterogeneous photocatalytic removal of phenol from water[J].Applied Catalysis A:General,2011,393(1):122.
[28]Xu L,Sithambaram S,Zhang Y,et al.Novel urchin-like CuOsynthesized by a facile reflux method with efficient olefin epoxidation catalytic performance[J].Chemistry of Materials,2009,21(7):1253.
[29]董明东.多孔过渡金属氧化物纳米材料的制备及其对高氯酸铵的催化性能研究[D].苏州:江苏大学,2015.
[30]邢静.系列纳米过渡金属氧化物的制备及其吸附性能研究[D].青岛:青岛科技大学,2016.
[31]Li X,Si Z,Lei Y,et al.Hierarchically structured Fe3O4 microspheres:morphology control and their application in wastewater treatment[J].Cryst Eng Comm,2011,13(2):642.
[32]Zhu T,Chen J S,Lou X W.Highly efficient removal of organic dyes from waste water using hierarchical NiO spheres with high surface area[J].The Journal of Physical Chemistry C,2012,116(12):6873.
[33]Akhtar M J,Ahamed M,Kumar S,et al.Zinc oxide nanoparticles selectively induce apoptosis in human cancer cells through reactive oxygen species[J].International Journal of Nanomedicine,2012,7:845.
[34]Shukla M,Kumari S,Shukla S,et al.Potent antibacterial activity of nano CdO synthesized via microemulsion scheme[J].J Mater Environ Sci,2012,3(4):678.
[35]Ren G,Hu D,Cheng E W C,et al.Characterisation of copper oxide nanoparticles for antimicrobial applications[J].International Journal of Antimicrobial Agents,2009,33(6):587.
[2]Li X,Zhang B,Ju C,et al.Morphology-controlled synthesis and electromagnetic properties of porous Fe3O4 nanostructures from iron alkoxide precursors[J].The Journal of Physical Chemistry C,2011,115(25):12350-12357.
[3]Xuan S,Hao L,Jiang W,et al.A FeCO3precursor-based route to microsized peanutlike Fe3O4[J].Crystal Growth&Design,2007,7(2):430.
[4]Ai Z,Deng K,Wan Q,et al.Facile microwave-assisted synthesis and magnetic and gas sensing properties of Fe3O4nanoroses[J].The Journal of Physical Chemistry C,2010,114(14):6237.
[5]Zhang D E,Zhang X J,Ni X M,et al.Fabrication and characterization of Fe3O4octahedrons via an EDTA-assisted route[J].Crystal Growth&Design,2007,7(10):2117.
[6]Fan T,Pan D,Zhang H.Study on formation mechanism by monitoring the morphology and structure evolution of nearly monodispersed Fe3O4submicroparticles with controlled particle sizes[J].Industrial&Engineering Chemistry Research,2011,50(15):9009.
[7]Zhang Y,Zhu J,Song X,et al.Controlling the synthesis of CoO nanocrystals with various morphologies[J].The Journal of Physical Chemistry C,2008,112(14):5322.
[8]Yang H,Ouyang J,Tang A.Single step synthesis of high-purity CoO nanocrystals[J].The Journal of Physical Chemistry B,2007,111(28):8006.
[9]Sun G,Zhang X,Cao M,et al.Facile synthesis,characterization,and microwave absorbability of CoO nanobelts and submicrometer spheres[J].The Journal of Physical Chemistry C,2009,113(17):6948.
[10]Fazlali F,Mahjoub Areza,Abazari R.A new route for synthesis of spherical NiO nanoparticles via emulsion nano-reactors with enhanced photocatalytic activity[J].Solid State Sciences,2015,48:263.
[11]Wang X,Yu L,Hu P,et al.Synthesis of single-crystalline hollow octahedral NiO[J].Crystal Growth and Design,2007,7(12):2415.
[12]Cui Y,Wang C,Wu S,et al.Lotus-root-like NiO nanosheets and flower-like NiO microspheres:synthesis and magnetic properties[J].Cryst Eng Comm,2011,13(15):4930.
[13]朱脉勇.过渡金属铁,铜氧化物纳米材料的制备及催化应用研究[D].扬州:扬州大学,2011.
[14]Yang Z,Xu J,Zhang W,et al.Controlled synthesis of CuOnanostructures by a simple solution route[J].Journal of Solid State Chemistry,2007,180(4):1390.
[15]Anandan S,Lee G J,Wu J J.Sonochemical synthesis of CuOnanostructures with different morphology[J].Ultrasonics Sonochemistry,2012,19(3):682.
[16]Zhang C,Wang Y,Bi S,et al.Preparation of mesoporous ZnOmicrospheres through a membrane-dispersion microstructured reactor and a hydrothermal treatment[J].Industrial&Engineering Chemistry Research,2011,50(23):13355.
[17]孙建兴.金属氧化物纳米材料的制备及光学特性研究[D].南昌:南昌航空大学,2014.
[18]Zhang L,Zhao J,Lu H,et al.High sensitive and selective formaldehyde sensors based on nanoparticle-assembled ZnOmicro-octahedrons synthesized by homogeneous precipitation method[J].Sensors and Actuators B:Chemical,2011,160(1):364.
[19]Mo M,Yu J C,Zhang L,et al.Self-assembly of ZnO nanorods and nanosheets into Hollow microhemispheres and microspheres[J].Advanced Materials,2005,17(6):756.
[20]Wang H,Xie C,Zeng D,et al.Controlled organization of ZnObuilding blocks into complex nanostructures[J].Journal of Colloid and Interface Science,2006,297(2):570.
[21]Askarinejad A,Morsali A.Synthesis of cadmium(Ⅱ)hydroxide,cadmium(Ⅱ)carbonate and cadmium(Ⅱ)oxide nanoparticles;investigation of intermediate products[J].Chemical Engineering Journal,2009,150(2):569.
[22]Tadjarodi A,Imani M,Kerdari H,et al.Preparation of CdOrhombus-like nanostructure and its photocatalytic degradation of azo dyes from aqueous solution[J].Nanomaterials and Nanotechnology,2014,4:16.
[23]Tadjarodi A,Imani M,Kerdari H.Application of a facile solidstate process to synthesize the CdO spherical nanoparticles[J].International Nano Letters,2013,3(1):43.
[24]Tadjarodi A,Imani M,Kerdari H.Application of experimental design to optimize the synthesis of CdO cauliflower-like nanostructure using mechanochemical method[J].Journal of Nanostructures,2012,1(2):127.
[25]Fu X,Liu J,Han T,et al.A three-dimensional hierarchical CdO nanostructure:preparation and its improved gas-diffusing performance in gas sensor[J].Sensors and Actuators B:Chemical,2013,184:260.
[26]Raj D S,Krishnakumar T,Jayaprakash R,et al.CO sensing characteristics of hexagonal-shaped CdO nanostructures prepared by microwave irradiation[J].Sensors and Actuators B:Chemical,2012,171:853.
[27]Hayat K,Gondal M A,Khaled M M,et al.Nano ZnO synthesis by modified sol gel method and its application in heterogeneous photocatalytic removal of phenol from water[J].Applied Catalysis A:General,2011,393(1):122.
[28]Xu L,Sithambaram S,Zhang Y,et al.Novel urchin-like CuOsynthesized by a facile reflux method with efficient olefin epoxidation catalytic performance[J].Chemistry of Materials,2009,21(7):1253.
[29]董明东.多孔过渡金属氧化物纳米材料的制备及其对高氯酸铵的催化性能研究[D].苏州:江苏大学,2015.
[30]邢静.系列纳米过渡金属氧化物的制备及其吸附性能研究[D].青岛:青岛科技大学,2016.
[31]Li X,Si Z,Lei Y,et al.Hierarchically structured Fe3O4 microspheres:morphology control and their application in wastewater treatment[J].Cryst Eng Comm,2011,13(2):642.
[32]Zhu T,Chen J S,Lou X W.Highly efficient removal of organic dyes from waste water using hierarchical NiO spheres with high surface area[J].The Journal of Physical Chemistry C,2012,116(12):6873.
[33]Akhtar M J,Ahamed M,Kumar S,et al.Zinc oxide nanoparticles selectively induce apoptosis in human cancer cells through reactive oxygen species[J].International Journal of Nanomedicine,2012,7:845.
[34]Shukla M,Kumari S,Shukla S,et al.Potent antibacterial activity of nano CdO synthesized via microemulsion scheme[J].J Mater Environ Sci,2012,3(4):678.
[35]Ren G,Hu D,Cheng E W C,et al.Characterisation of copper oxide nanoparticles for antimicrobial applications[J].International Journal of Antimicrobial Agents,2009,33(6):587.