金属有机框架物薄膜中的传质（英文）
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摘要
金属有机框架物(MOF)是由金属节点和有机配体依靠配位键结合组装而成的晶体材料,具有规则的孔道结构和巨大的比表面积.自1990年被提出以来, MOF便引起了广泛关注;同时MOF薄膜的成功制备扩大了其应用范围,使其应用于诸多领域.在MOF薄膜的应用中,跨膜传质过程至关重要.本文首先综述了近年来MOF薄膜材料的制备方法,接着分别详细讨论了气体分子、液体分子和离子的选择性跨膜传输.在传质过程中, MOF的窗口尺寸、配体上修饰的功能基团以及孔道中的客体分子均会对离子传输产生影响.具有选择性传输特性的MOF薄膜在分离、催化和能量存储和转化领域均有潜在应用.
Metal-organic frameworks(MOFs), which are composed of metal nodes and organic ligands, possess crystal phase, ordered well-defined porous structure and large surface area. Since first reported in 1990, MOFs have attracted extensive attention and the fabrication of MOF membranes has expanded their applications and endowed them with a bright future in various fields. The mass transportation process through MOF membranes is vital during their diverse applications. In this review, the strategies of preparing continuous and well-intergrown MOF membranes are presented firstly.The selective transportation processes of gas molecules, liquid molecules and ions through MOF membranes are discussed in detail, respectively. The effects of pore entrance size, interaction, functional groups decorating on the ligands and guest components on mass transportation have been summarized in this review as well. In addition, MOF membranes with selective transportation performance demonstrate potential in separation, catalysis, energy transformation and storage devices,and so on.
Metal-organic frameworks(MOFs), which are composed of metal nodes and organic ligands, possess crystal phase, ordered well-defined porous structure and large surface area. Since first reported in 1990, MOFs have attracted extensive attention and the fabrication of MOF membranes has expanded their applications and endowed them with a bright future in various fields. The mass transportation process through MOF membranes is vital during their diverse applications. In this review, the strategies of preparing continuous and well-intergrown MOF membranes are presented firstly.The selective transportation processes of gas molecules, liquid molecules and ions through MOF membranes are discussed in detail, respectively. The effects of pore entrance size, interaction, functional groups decorating on the ligands and guest components on mass transportation have been summarized in this review as well. In addition, MOF membranes with selective transportation performance demonstrate potential in separation, catalysis, energy transformation and storage devices,and so on.
引文
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