非常规土壤修复技术发展及应用
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摘要
随着经济社会不断发展,城市扩展,种植业及养殖业对土地要求提高,我国面临的土壤污染问题日益严峻。在分析了我国土壤污染现状和常规土壤污染修复技术的基础上,主要对几种新兴的非常规土壤修复技术进行介绍,包括微波修复、超声波修复、电动修复、光催化降解以及渗透反应墙技术,并概述了各种方法的基本原理、修复效果以及国内外研究进展、发展趋势等。
With the development of economy and society, expansion of urban, and increasing demand for land in planting and breeding, the problem of soil pollution is becoming more and more serious in China. Based on analyzing the present situation of soil pollution in China and the existing soil remediation technology, several unconventional soil remediation technologies were introduced which are still in the laboratory research stage, including microwave repair, ultrasonic repair,electroremediation, photocatalytic degradation and permeable reactive barrier technology. Their basic principles, repair effects, research progress and development trend of various methods at home and abroad were summarized.
With the development of economy and society, expansion of urban, and increasing demand for land in planting and breeding, the problem of soil pollution is becoming more and more serious in China. Based on analyzing the present situation of soil pollution in China and the existing soil remediation technology, several unconventional soil remediation technologies were introduced which are still in the laboratory research stage, including microwave repair, ultrasonic repair,electroremediation, photocatalytic degradation and permeable reactive barrier technology. Their basic principles, repair effects, research progress and development trend of various methods at home and abroad were summarized.
引文
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[2]李光超.我国土壤污染现状与修复技术综述[J].农业与技术,2015,35(18):3-4.
[3]陈斯佳,庞恩.我国土壤污染现状及污染防治制度概况[J].科技与创新,2016(9):32-34.
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[6]张安,官昭瑛,徐国钢,等.我国土壤污染修复技术研究进展[J].安徽农业科学,2016,44(21):82-85,133.
[7]邹峁雁,韩昊展.试论中国的土壤污染现状与防控措施[J].南方农业,2018,12(6):148-149.
[8]李秀悌,顾圣啸,郑文杰,等.重金属污染土壤修复技术研究进展[J].环境科学与技术,2013,36(S2):203-208
[9]李佳,曹兴涛,隋红,等.石油污染土壤修复技术研究现状与展望[J].石油学报(石油加工)2017,33(5):811-833.
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[11]张小莎.土壤修复技术的研究与发展[J].农业与技术,2017,37(1):169-170,172.
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[15]ABRAMOVITCH R A,LIN Changqing,HICKS E,et al.Insitu remediation of soils contaminated with toxic metal ions using microwave energy[J].Chemosphere,2003,53(9):322-325.
[16]ABRAMOVITCH R A,HUANG B Z.Decomposition of PCB's and other polychlorinated aromatics in soil using microwave energy[J].Chemosphere,1998,37(8):212-216.
[17]ABRAMOVITCH R A,HUANG B Z.In situ decomposition of PCB's in soil using microwave energy[J].Chemosphere,1999,38(10):310-318.
[18]林丽.典型化工污染土壤的微修复技术研究[D].华中科技大学,博士学位论文,2010.
[19]刘爱宝,孙文全,王世强,等.微波辐照技术修复氯丹污染土壤[J].化工环保,2013,33(4):285-288.
[20]DI P K,CHANG D P Y.Investigation of polychlorinated biphenyl removal from contaminated soil using microwave generated steam[J].Journal of the Air and Waste Management Association,2001,51(4):482-488.
[21]任丽静.搬迁企业遗留典型有机污染场地土壤修复研究[D].南京大学,2012.
[22]王鑫杰,黄锦楼,刘志强.超声波辅助化学萃取对某工业场地铅污染土壤修复效果研究[J].环境科学,2013,34(9):3 704-3 708.
[23]邱琼瑶.超声波强化萃取污染土壤重金属的研究[D].中南林业科技大学,硕士学位论文,2014.
[24]李婷婷,张玲妍,郭书海,等.完全对称电场对电动-微生物修复石油污染土壤的影响[J].环境科学研究,2010,23(10):1 262-1 267.
[25]REDDY K R,SAICHEK R E.Effect of soil type on electrokinetic removal of phenanthrene using surfactants and cosolvents[J].JEnviron Eng,2003,129(4):336-346.
[26]KO S O,SCHLAUTMAN M A,CARRAWAY E R.Partitioning of hydrophobic organic compounds to sorbed surfactants.1.Experimental studies[J].Env Sci Technol,1998,32(18):2769-2 775.
[27]ALSHAWABKEH A N,ACAR Y B.Removal of contaminants from soils by electrokinetics:A theoretical treatise[J].J Environ Sci Heal A,1992,27(7):1 835-1 861.
[28]MOHAMED A M.Remediation of heavy metal contaminated soils via integrated electrochemical processes[J].Waste Manage,1996,16(8):741-747.
[29]SHAPIRO A P,PROBSTEIN R F.Removal of contaminants from saturated clay by electroosmosis[J].Environ Sci Technol,2002,27(2):283-291.
[30]MAINI G,SHARMAN A K,KNOWLES C J,et al.Electrokinetic remediation of metals an dorganics from historically contaminated soil[J].J Chem Technol Biot,2000,75(8):657-664.
[31]马建伟,王慧,罗启仕.电动力学-新型竹炭联合作用下土壤镉的迁移吸附及其机理[J].环境科学,2007,28(8):1 829-1 834.
[32]XU S,GUO S,WU B,et al.An assessment of the effectiveness and impact of electrokinetic remediation for pyrene-contaminated soil[J].J Environ Sci,2014,26(11):2 290-2 297.
[33]高岩,刘影.二氧化钛纳米线光催化作用的研究进展[J].口腔疾病防治,2018,26(3):200-204.
[34]张文通,陈勇,陈超,等.纳米Ti O2光催化材料在环境土壤修复中的应用研究进展.材料导报A:综述篇,2015,29(6):49-54.
[35]肖俊霞,彭惠玲,王淑静,等.Ti O2光催化氧化技术在土壤修复中的研究与发展[J].环境与发展,2017,72(4):150-152.
[36]潘淑颖,高宝玉,岳钦艳,等.光催化降解表土层中DDT的影响因素研究[J].中国农学通报,2008,24(10):515-520.
[37]Higarashi MM,Jardim W E.Remediation of pesticide contaminated soil using Ti O2mediated by solar light[J].Catal Today,2002,76(2-4):201.
[38]Maurizio D'Auria,Lucia Emanuele,Rocco Racioppi.Photochemical degradation of crude oil:Comparison between direct irradiation,photocatalysis,and photocatalysis on zeolite[J].J Hazard Mater,2009,164(12):32.
[39]Gao Y M,Lee W,Trehan R,et al.Improvement of photocatalytic activity of titanium(Ⅳ):oxide by sidpersion of Au on Ti O2[J].Mater Res Bull,1991,26(12):1247.
[40]Rajeshwar K,Chenthamaralshun C R,Goeringer S,et al.Titaniabased heterogeneous photocatalysis.Materials,mechanistic issue and implications for environmental remediation[J].Pure Appl Chem,2001,73(12):1 849.
[41]Varanasi P,Fullana A,Sidhu S.Remediation of PCB conta-minated soils using iron nano-particles[J].Chemosphere,2007,66(6):1 031-1 038.
[42]张利红,陈忠林,徐成斌,等.太阳光照射土壤中多环芳烃化合物(PAHs):光催化降解动力学[J].环境化学,2010,29(3):486-490.
[43]孙庆春.渗透反应墙及电动技术修复重金属污染地下水和土壤[D].合肥工业大学硕士学位论文,2013.
[44]纪冬丽,张竞,孟凡生,等.共存离子对EK/PRB联合修复砷污染土壤的影响[J].环境工程学报,2018,12(1):172-177.
[45]Zhirong Li,Songhu Yuan,Jinzhong Wan等.A combination of electrokinetics and Pd/Fe PRB for the remediation of pentachlorophenol-contaminated soil[J].Journal of Contaminant Hydrology,2011,124(11):99-107.
[46]庄国泰.我国土壤污染现状与防控策略.中国科学院院刊,2015,4(6):477-483.
[2]李光超.我国土壤污染现状与修复技术综述[J].农业与技术,2015,35(18):3-4.
[3]陈斯佳,庞恩.我国土壤污染现状及污染防治制度概况[J].科技与创新,2016(9):32-34.
[4]赵金艳,李莹,李珊珊,等.我国污染土壤修复技术及产业现状[J].中国环保产业,2013(3):53-57.
[5]全国土壤污染状况调查公报[J].中国环保产业,2014(5):10-11.
[6]张安,官昭瑛,徐国钢,等.我国土壤污染修复技术研究进展[J].安徽农业科学,2016,44(21):82-85,133.
[7]邹峁雁,韩昊展.试论中国的土壤污染现状与防控措施[J].南方农业,2018,12(6):148-149.
[8]李秀悌,顾圣啸,郑文杰,等.重金属污染土壤修复技术研究进展[J].环境科学与技术,2013,36(S2):203-208
[9]李佳,曹兴涛,隋红,等.石油污染土壤修复技术研究现状与展望[J].石油学报(石油加工)2017,33(5):811-833.
[10]王春艳.强化生物通风修复柴油污染土壤的正交实验[D].中国地质大学(北京),2009.
[11]张小莎.土壤修复技术的研究与发展[J].农业与技术,2017,37(1):169-170,172.
[12]周际海,黄荣霞,樊后保,等.污染土壤修复技术研究进展[J].水土保持研究,2016,23(3):366-372.
[13]马海云,韩永忠,李茂,等.污染土壤的微波辐照技术研究进展[J].环境污染与防治,2007,29(3):221-225.
[14]王绍林.微波加热原理及其应用,北京农业工程大学学报,1993,13(4):85.
[15]ABRAMOVITCH R A,LIN Changqing,HICKS E,et al.Insitu remediation of soils contaminated with toxic metal ions using microwave energy[J].Chemosphere,2003,53(9):322-325.
[16]ABRAMOVITCH R A,HUANG B Z.Decomposition of PCB's and other polychlorinated aromatics in soil using microwave energy[J].Chemosphere,1998,37(8):212-216.
[17]ABRAMOVITCH R A,HUANG B Z.In situ decomposition of PCB's in soil using microwave energy[J].Chemosphere,1999,38(10):310-318.
[18]林丽.典型化工污染土壤的微修复技术研究[D].华中科技大学,博士学位论文,2010.
[19]刘爱宝,孙文全,王世强,等.微波辐照技术修复氯丹污染土壤[J].化工环保,2013,33(4):285-288.
[20]DI P K,CHANG D P Y.Investigation of polychlorinated biphenyl removal from contaminated soil using microwave generated steam[J].Journal of the Air and Waste Management Association,2001,51(4):482-488.
[21]任丽静.搬迁企业遗留典型有机污染场地土壤修复研究[D].南京大学,2012.
[22]王鑫杰,黄锦楼,刘志强.超声波辅助化学萃取对某工业场地铅污染土壤修复效果研究[J].环境科学,2013,34(9):3 704-3 708.
[23]邱琼瑶.超声波强化萃取污染土壤重金属的研究[D].中南林业科技大学,硕士学位论文,2014.
[24]李婷婷,张玲妍,郭书海,等.完全对称电场对电动-微生物修复石油污染土壤的影响[J].环境科学研究,2010,23(10):1 262-1 267.
[25]REDDY K R,SAICHEK R E.Effect of soil type on electrokinetic removal of phenanthrene using surfactants and cosolvents[J].JEnviron Eng,2003,129(4):336-346.
[26]KO S O,SCHLAUTMAN M A,CARRAWAY E R.Partitioning of hydrophobic organic compounds to sorbed surfactants.1.Experimental studies[J].Env Sci Technol,1998,32(18):2769-2 775.
[27]ALSHAWABKEH A N,ACAR Y B.Removal of contaminants from soils by electrokinetics:A theoretical treatise[J].J Environ Sci Heal A,1992,27(7):1 835-1 861.
[28]MOHAMED A M.Remediation of heavy metal contaminated soils via integrated electrochemical processes[J].Waste Manage,1996,16(8):741-747.
[29]SHAPIRO A P,PROBSTEIN R F.Removal of contaminants from saturated clay by electroosmosis[J].Environ Sci Technol,2002,27(2):283-291.
[30]MAINI G,SHARMAN A K,KNOWLES C J,et al.Electrokinetic remediation of metals an dorganics from historically contaminated soil[J].J Chem Technol Biot,2000,75(8):657-664.
[31]马建伟,王慧,罗启仕.电动力学-新型竹炭联合作用下土壤镉的迁移吸附及其机理[J].环境科学,2007,28(8):1 829-1 834.
[32]XU S,GUO S,WU B,et al.An assessment of the effectiveness and impact of electrokinetic remediation for pyrene-contaminated soil[J].J Environ Sci,2014,26(11):2 290-2 297.
[33]高岩,刘影.二氧化钛纳米线光催化作用的研究进展[J].口腔疾病防治,2018,26(3):200-204.
[34]张文通,陈勇,陈超,等.纳米Ti O2光催化材料在环境土壤修复中的应用研究进展.材料导报A:综述篇,2015,29(6):49-54.
[35]肖俊霞,彭惠玲,王淑静,等.Ti O2光催化氧化技术在土壤修复中的研究与发展[J].环境与发展,2017,72(4):150-152.
[36]潘淑颖,高宝玉,岳钦艳,等.光催化降解表土层中DDT的影响因素研究[J].中国农学通报,2008,24(10):515-520.
[37]Higarashi MM,Jardim W E.Remediation of pesticide contaminated soil using Ti O2mediated by solar light[J].Catal Today,2002,76(2-4):201.
[38]Maurizio D'Auria,Lucia Emanuele,Rocco Racioppi.Photochemical degradation of crude oil:Comparison between direct irradiation,photocatalysis,and photocatalysis on zeolite[J].J Hazard Mater,2009,164(12):32.
[39]Gao Y M,Lee W,Trehan R,et al.Improvement of photocatalytic activity of titanium(Ⅳ):oxide by sidpersion of Au on Ti O2[J].Mater Res Bull,1991,26(12):1247.
[40]Rajeshwar K,Chenthamaralshun C R,Goeringer S,et al.Titaniabased heterogeneous photocatalysis.Materials,mechanistic issue and implications for environmental remediation[J].Pure Appl Chem,2001,73(12):1 849.
[41]Varanasi P,Fullana A,Sidhu S.Remediation of PCB conta-minated soils using iron nano-particles[J].Chemosphere,2007,66(6):1 031-1 038.
[42]张利红,陈忠林,徐成斌,等.太阳光照射土壤中多环芳烃化合物(PAHs):光催化降解动力学[J].环境化学,2010,29(3):486-490.
[43]孙庆春.渗透反应墙及电动技术修复重金属污染地下水和土壤[D].合肥工业大学硕士学位论文,2013.
[44]纪冬丽,张竞,孟凡生,等.共存离子对EK/PRB联合修复砷污染土壤的影响[J].环境工程学报,2018,12(1):172-177.
[45]Zhirong Li,Songhu Yuan,Jinzhong Wan等.A combination of electrokinetics and Pd/Fe PRB for the remediation of pentachlorophenol-contaminated soil[J].Journal of Contaminant Hydrology,2011,124(11):99-107.
[46]庄国泰.我国土壤污染现状与防控策略.中国科学院院刊,2015,4(6):477-483.