含植物皂基的低泡高活性厨房洗涤剂的制备
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摘要
以精练植物油的副产品粗脂肪酸为原料,经过皂化盐析等方法处理后,与适当比例的其他助剂混合配制,从而得到一种含天然皂基的厨房专用洗涤剂。通过对制备的含天然皂基洗涤剂的去油污能力(平均净洗力)和去农药残留能力(去除力)的测定,及对市售产品的对比研究,鉴定其应用效力。结果表明,以市售化学品洗涤液为阳性对照:当测得的市售洗涤剂的平均净洗力为98.60%时,含植物皂基的该低泡厨房洗涤剂的平均净洗力为92.65%。进一步采用气相色谱法(GC)和薄层层析(TLC)法定性分析表明,GC分析显示该洗涤剂对敌百虫和高效氯氰菊酯农药都有较好的去除力;同时TLC分析表明,制备的该低泡厨房洗涤剂对敌百虫的去除力高于市售洗涤剂,对高效氯氰菊酯农药的去除力与市售洗涤剂功效接近。
The crude fatty acid by-product of refined plant oil as raw material,after being treated by saponification and salting out,and other methods, the product is mixed with other auxiliary agents in proper proportion,so as to obtain a kind of efficacy kitchen detergent.The degreasing capacity(average cleaning capacity) and pesticide residue removal capacity(removal capacity) of the detergent are measured.The results show that the commercial chemical cleaning solution is the positive control,when the average net cleaning power of the market detergent is 98.60%,the average net cleaning power of the kitchen detergent of containing vegetable soap base is 92.65%.GC and TLC methods are used for qualitative analysis and commercial detergents are used as positive controls.GC analysis shows that the saponious hypo foam kitchen detergents have better efficacy in the removal of dichlorvos and high-efficiency cypermethrin pesticides.TLC analysis and comparison,containing plant natural saponins low-bubble kitchen detergent to dichlorobacteria than the municipal detergent removal,high efficiency of cypermethrin pesticides and the efficacy of marketing detergent close.
The crude fatty acid by-product of refined plant oil as raw material,after being treated by saponification and salting out,and other methods, the product is mixed with other auxiliary agents in proper proportion,so as to obtain a kind of efficacy kitchen detergent.The degreasing capacity(average cleaning capacity) and pesticide residue removal capacity(removal capacity) of the detergent are measured.The results show that the commercial chemical cleaning solution is the positive control,when the average net cleaning power of the market detergent is 98.60%,the average net cleaning power of the kitchen detergent of containing vegetable soap base is 92.65%.GC and TLC methods are used for qualitative analysis and commercial detergents are used as positive controls.GC analysis shows that the saponious hypo foam kitchen detergents have better efficacy in the removal of dichlorvos and high-efficiency cypermethrin pesticides.TLC analysis and comparison,containing plant natural saponins low-bubble kitchen detergent to dichlorobacteria than the municipal detergent removal,high efficiency of cypermethrin pesticides and the efficacy of marketing detergent close.
引文
[1] 尹卫平,吕本莲.精细化工产品及工艺[M].上海:华东理工大学出版社,2009.
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[3] 杜志平,王万绪,刘晓英.洗涤原理及洗涤性能评价[J].中国洗涤用品工业,2006(5):27-21.
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[5] 张玉峰,段岢君.椰油餐具洗涤剂的配制及性能评价[J].日用化学工业,2015,45(5):265-268.
[6] 刘自平,赵菲,范丹丹.天然果蔬洗涤剂的应用现状与发展前景[J].农业与技术,2013(3):91.
[7] 宗荣芬,刘文卫,梅建新.蔬果洗涤剂对农药残留去除率的研究[J].中国卫生检验杂志,2003,13(4):441-445.
[8] 闫贻洋,黄炳海,朱本宏,等.蔬菜中农残分析方法及残留农药去除率的研究[J].应用化工,2009,38(12):1708-1716.
[9] 胡西洲,程运斌,胡定金,等.QuEchERS法测定蔬菜中有机磷类农药多残留分析[J].中国测试技术,2006,32(3):132-133.
[10] 中华人民共和国国家标准GB/T 24691-2009,果蔬洗涤剂对残留农药洗除效果的验证方法[S].
[11] GB/T5009.20-1996,食品中有机磷农药残留量的测定方法[S].1996.
[12] 刘腾飞,顾俊荣,邓金龙,等.气象色谱测定生菜中的高效氯氰菊酯残留[J].光谱实验室,2013,30(6):2841-2845.
[13] 陆雪芳,季海东,夏雪,等.敌百虫原药中敌百虫和三氯乙醛的液相色谱分析[J].南通职业技术学院学报,2012,26(4):82-84.
[14] 葛洪,汪世新,陆自强,等.植物园蔬果农药残留洗涤剂的研究[J].扬州大学学报,2003,24(4):86-89.
[15] 任喜平,陶艳.蔬果中残留农药去除率的测定方法研究[J].浙江化工,2011,42(5):33-35.
[16] 张存政,骆爱兰,王冬兰,等.消解去除食用叶菜中高效氯氰菊酯残留方法的研究[J].农业环境科学学报,2004,24(1):196-200.
[17] 成冬亮,薛文平,徐恒振,等.5种有机磷农药标准物质高效液相制备技术的研究[J].环境科学与技术,2011,34(5):113-116.
[2] 易云峰,迟姚玲,冀德昆,等.溶解度系数原理在厨房重垢洗涤剂配方中的应用[J].日用化学品科学,2010,33(2):26-32.
[3] 杜志平,王万绪,刘晓英.洗涤原理及洗涤性能评价[J].中国洗涤用品工业,2006(5):27-21.
[4] 中华人民共和国国家标准GB9985-2000,手洗餐具洗涤剂去污力的测定[S].
[5] 张玉峰,段岢君.椰油餐具洗涤剂的配制及性能评价[J].日用化学工业,2015,45(5):265-268.
[6] 刘自平,赵菲,范丹丹.天然果蔬洗涤剂的应用现状与发展前景[J].农业与技术,2013(3):91.
[7] 宗荣芬,刘文卫,梅建新.蔬果洗涤剂对农药残留去除率的研究[J].中国卫生检验杂志,2003,13(4):441-445.
[8] 闫贻洋,黄炳海,朱本宏,等.蔬菜中农残分析方法及残留农药去除率的研究[J].应用化工,2009,38(12):1708-1716.
[9] 胡西洲,程运斌,胡定金,等.QuEchERS法测定蔬菜中有机磷类农药多残留分析[J].中国测试技术,2006,32(3):132-133.
[10] 中华人民共和国国家标准GB/T 24691-2009,果蔬洗涤剂对残留农药洗除效果的验证方法[S].
[11] GB/T5009.20-1996,食品中有机磷农药残留量的测定方法[S].1996.
[12] 刘腾飞,顾俊荣,邓金龙,等.气象色谱测定生菜中的高效氯氰菊酯残留[J].光谱实验室,2013,30(6):2841-2845.
[13] 陆雪芳,季海东,夏雪,等.敌百虫原药中敌百虫和三氯乙醛的液相色谱分析[J].南通职业技术学院学报,2012,26(4):82-84.
[14] 葛洪,汪世新,陆自强,等.植物园蔬果农药残留洗涤剂的研究[J].扬州大学学报,2003,24(4):86-89.
[15] 任喜平,陶艳.蔬果中残留农药去除率的测定方法研究[J].浙江化工,2011,42(5):33-35.
[16] 张存政,骆爱兰,王冬兰,等.消解去除食用叶菜中高效氯氰菊酯残留方法的研究[J].农业环境科学学报,2004,24(1):196-200.
[17] 成冬亮,薛文平,徐恒振,等.5种有机磷农药标准物质高效液相制备技术的研究[J].环境科学与技术,2011,34(5):113-116.