主族元素铋的应用现状
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摘要
金属有机化合物在工业、农业、医药和材料等方面有诸多广泛的应用。金属铋是元素周期表中放射性小、毒性低、比较稳定的元素,与氮、磷、砷、锑同属第五主族。我国的铋资源储量丰富、分布广泛,自然界当中大多以氧化物或硫化物的形态存在。文章主要介绍了铋类化合物在工业、医药、半导体等领域的应用。另外,对新型铋化合物在其他领域的用途进行了展望。
The organometallic compounds have broad applications in industry,agriculture,medicine and new materials. In the periodic table,bismuth is a stable heavy metal with low toxicity and low radioactivity. It belongs to the fifth main group element with nitrogen,phosphorus,arsenic and antimony. Bismuth resources have abundant reserve and extensive distributed in China,and most of bismuth exists in the form of oxides or sulfides in nature. The application status of bismuth compounds in industry,medicine,semiconductor fields were introduced. Furthermore,the application prospects of new bismuth compounds were forecasted in the end.
The organometallic compounds have broad applications in industry,agriculture,medicine and new materials. In the periodic table,bismuth is a stable heavy metal with low toxicity and low radioactivity. It belongs to the fifth main group element with nitrogen,phosphorus,arsenic and antimony. Bismuth resources have abundant reserve and extensive distributed in China,and most of bismuth exists in the form of oxides or sulfides in nature. The application status of bismuth compounds in industry,medicine,semiconductor fields were introduced. Furthermore,the application prospects of new bismuth compounds were forecasted in the end.
引文
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[6]杨亚东,肖辉,王志雄.铋系阻燃剂的研究[J].广州化工,2013,41(16):129-131.
[7]郭雪梅,王少娜,聂瑶,等.均相反应法制备钒酸铋颜料[J].过程工程学报,2018,18(1):201-209
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[9]杨楠,孙红哲.砷、锑、铋类药物的应用历史和现状[J].化学进展,2009(5):58-67.
[10]Murafuji T,Fujiwara Y,Yoshimatsu D,et al.Bismuth heterocycles based on diphenyl sulfone scaffold:Synthesis and substituent effect on the antifungal activity against Saccharomyces cerevisiae[J].Eur.J.Med.Chem.,2011,46(2):519-525.
[11]Iuchi K,Hatano Y,Yagura T.Heterocyclic organobismuth(Ⅲ)induces apoptosis of human promyelocytic leukemic cells through activation of caspases and mitochondrial perturbation[J].Biochem pharmacol,2008,76(8):974-986.
[12]Liu Y P,Lei J,Tang L W.Studies on the cytotoxicity and anticancer performance of heterocyclic hypervalent organobismuth(Ⅲ)compounds[J].Eur.J.Med.Chem.,2017,36(8):826-835.
[13]张晓申,孙熹,张思雨,等.含铋金属药物的研究进展与治疗应用[J].中国新药与临床杂志,2017,36(8):440-446.
[14]周建伟.铋系半导体光催化剂及其应用研究进展[J].化学工程师,2007(12):34-37,64.
[15]黄文帅,孙莹,王蕾,等.Bi OCl光催化改性的研究进展[J].合成材料老化与应用,2018,47(1):112-118.
[16]徐新,李新年,徐芸芸.新型有机铋化合物的极压抗磨性能[J].润滑与密封,2011,36(12):68-72.
[17]刘佳佳,王军,张霞,等.一种新型铋基光催化剂的合成及其可见光催化性能[J].环境工程学报,2015,9(6):2723-2730.
[2]钱长涛,王春红,陈耀峰.稀土金属有机配合物化学60年[J].化学学报,2014,72(8):883-905.
[3]Suzuki H,Komatsu N,Ogawa T,et al.Organobismuth Chemisty[M].Amsterdam:Elsever,2001:1-456.
[4]刘麦,裴立双.行业新星—铋晶体[J].中国金属通报,2013(40):31-33.
[5]赵天宇.铋系化合物微纳米材料的控制合成及性能研究[D].上海:上海交通大学,2012.
[6]杨亚东,肖辉,王志雄.铋系阻燃剂的研究[J].广州化工,2013,41(16):129-131.
[7]郭雪梅,王少娜,聂瑶,等.均相反应法制备钒酸铋颜料[J].过程工程学报,2018,18(1):201-209
[8]张晓文,尹双凤,伍水生,等.有机铋化学近十年的研究进展[J].化学进展,2008,20(6):878-886.
[9]杨楠,孙红哲.砷、锑、铋类药物的应用历史和现状[J].化学进展,2009(5):58-67.
[10]Murafuji T,Fujiwara Y,Yoshimatsu D,et al.Bismuth heterocycles based on diphenyl sulfone scaffold:Synthesis and substituent effect on the antifungal activity against Saccharomyces cerevisiae[J].Eur.J.Med.Chem.,2011,46(2):519-525.
[11]Iuchi K,Hatano Y,Yagura T.Heterocyclic organobismuth(Ⅲ)induces apoptosis of human promyelocytic leukemic cells through activation of caspases and mitochondrial perturbation[J].Biochem pharmacol,2008,76(8):974-986.
[12]Liu Y P,Lei J,Tang L W.Studies on the cytotoxicity and anticancer performance of heterocyclic hypervalent organobismuth(Ⅲ)compounds[J].Eur.J.Med.Chem.,2017,36(8):826-835.
[13]张晓申,孙熹,张思雨,等.含铋金属药物的研究进展与治疗应用[J].中国新药与临床杂志,2017,36(8):440-446.
[14]周建伟.铋系半导体光催化剂及其应用研究进展[J].化学工程师,2007(12):34-37,64.
[15]黄文帅,孙莹,王蕾,等.Bi OCl光催化改性的研究进展[J].合成材料老化与应用,2018,47(1):112-118.
[16]徐新,李新年,徐芸芸.新型有机铋化合物的极压抗磨性能[J].润滑与密封,2011,36(12):68-72.
[17]刘佳佳,王军,张霞,等.一种新型铋基光催化剂的合成及其可见光催化性能[J].环境工程学报,2015,9(6):2723-2730.