超级电容器用镍钴硫化物电极材料的研究进展
|
摘要
超级电容器(supercapacitor,SC)是近年出现的高功率、高能量密度和长循环寿命的新型储能装置,利用表面双电层储能或在材料表面及近表面与特定离子发生快速可逆的法拉第反应储能。镍钴硫化物电极材料具有比单一硫化物和相应氧化物更高的导电性,同时两种金属离子的协同作用使其具有优异的电化学性能。结合近年相关文献报导,综述了镍钴硫化物电极材料的工作原理、制备方法、电化学性能及其优缺点,展望了其在储能机理和结构设计上的研究前景。
Using electric double layers or rapidly reversible Faraday's reactions with special ion on or near the surface,supercapacitor(SC)is a new energy storage device of high power/energy density and long cycle life in recent years.The study of nickel-cobalt sulfide electrode material has been gotten more attentions,because of their higher electrical conductivity than single sulfides or oxides,and excellent electrochemical performance resulted by synergy effects of two metal ions.According to the related literatures reported in recent years,working principles,preparation methods,electrochemical performance and merits/demerits of nickel-cobalt sulfide are reviewed,and researches of its storage mechanism and structure design are prospected.
Using electric double layers or rapidly reversible Faraday's reactions with special ion on or near the surface,supercapacitor(SC)is a new energy storage device of high power/energy density and long cycle life in recent years.The study of nickel-cobalt sulfide electrode material has been gotten more attentions,because of their higher electrical conductivity than single sulfides or oxides,and excellent electrochemical performance resulted by synergy effects of two metal ions.According to the related literatures reported in recent years,working principles,preparation methods,electrochemical performance and merits/demerits of nickel-cobalt sulfide are reviewed,and researches of its storage mechanism and structure design are prospected.
引文
[1]Kong W,Lu C,Zhang W,et al.Homogeneous core-shell NiCo2S4nanostructures supported on nickel foam for supercapacitors[J].Journal of Materials Chemistry A,2015,3(23):12452-12460.
[2]Gonzlez A,Goikolea E,Barrena J A,et al.Review on supercapacitors:technologies and materials[J].Renewable&Sustainable Energy Reviews,2016,580(2016):1189-1206.
[3]Chen Kunfeng,Xue Dongfeng.Evaluation of specific capacitance of colloidal ionic supercapacitor systems[J].Chinese Journal of Applied Chemistry,2016,33(1):18-24(in Chinese).陈昆峰,薛冬峰.胶体离子超级电容器的比容量评价[J].应用化学,2016,33(1):18-24.
[4]Yan J,Wang Q,Wei T,et al.Supercapacitors:recent advances in design and fabrication of electrochemical supercapacitors with high energy densities[J].Advanced Energy Materials,2014,4(4):157-164.
[5]Yang Z,Zhu X,Wang K,et al.Preparation of NiCo2S4flaky arrays on Ni foam as binder-free supercapacitor electrode[J].Applied Surface Science,2015,347:690-695.
[6]Lv Shenghua,Deng Lijuan.Research progress graphenebased supercapacitor[J].Journal of Functional Materials,2015,46(24):24015-24022(in Chinese).吕生华,邓丽娟.石墨烯基超级电容器的研究进展[J].功能材料,2015,46(24):24015-24022.
[7]Zeng Y X,Yu M H,Meng Y,et al.Iron-based supercapacitor electrodes:advances and challenges[J].Advanced Energy Materials,2016,24(6):1601053.
[8]Simon P,Gogotsi Y.Materials for electrochemical capacitors[J].Nature Materials,2008,7(11):845-854.
[9]You Chunqin,Luo Min,Kan Xiamei,et al.One-step hydrothermal synthesis of mesoporous ruffle-like sulfide microspheres for supercapacitors[J].Chinese Journal of Applied Chemistry,2015,32(12):1455-1461(in Chinese).尤春琴,罗民,阚夏梅,等.皱褶表面介孔镍钴硫化物微球的制备及其超电性能[J].应用化学,2015,32(12):1455-1461.
[10]Xiong X,Waller G,Ding D,et al.Controlled synthesis of NiCo2S4 nanostructured arrays on carbon fiber paper for high-performance pseudocapacitors[J].Nano Energy,2015,16:71-80.
[11]Zeng Z F,Wang D Z,Zhu J L,et al.NiCo2S4nanoparticles/activated balsam pear pulp for asymmetric hybrid capacitors[J].Cryst Eng Comm,2016,18(13):2363-2374.
[12]Peng T,Yi H,Sun P,et al.In situ growth of binderfree CNTs@Ni-Co-S nanosheets core/shell hybrids on Ni mesh for high energy density asymmetric supercapacitors[J].Journal of Materials Chemistry A,2016,4(22):8888-8897.
[13]Chen Z,Wan Z,Yang T,et al.Preparation of nickel cobalt sulfide hollow nanocolloids with enhanced electrochemical property for supercapacitors application[J].Scientific Reports,2016,6:25151.
[14]Xia C,Li P,Gandi A,et al.Is NiCo2S4really a semiconductor[J].Chemistry of Materials,2015,27(19):6482-6485.
[15]Du W,Zhu Z,Wang Y,et al.One-step synthesis of CoNi2S4nanoparticles for supercapacitor electrodes[J].Rsc Advances,2014,4(14):6998-7002.
[16]Chen T,Tang Y,Guo W,et al.Synergistic effect of cobalt and nickel on the superior electrochemical performances of rGO anchored nickel cobalt binary sulfides[J].Electrochimica Acta,2016,212:294-302.
[17]Yang J,Yu C,Fan X,et al.Electroactive edge site-enriched nickel-cobalt sulfide into graphene frameworks for high-performance asymmetric supercapacitors[J].Energy&Environmental Science,2016,9(4):1299-1307.
[18]Wan Lian.Preparation and characterization of three dimensional nanoarrays electrode based on Co-Ni sulfides[D].Wuhan:Huazhong University of Science and Technology,2015:3-5.万莲.基于(Co,Ni)硫化物的三维纳米阵列电极的构建及其超电容特性研究[D].武汉:华中科技大学,2015:3-5.
[19]Chen Haichao.Investigation of the pseudocapacitice properties of nickel cobalt bimetallic compounds[D].Wuhan:Huazhong University of Science and Technology,2014:86-88.陈海潮.镍钴双金属化合物的赝电容特性研究[D].武汉:华中科技大学,2014:86-88.
[20]Cai D,Wang D,Wang C,et al.Construction of desirable NiCo2S4nanotube arrays on nickel foam substrate for pseudocapacitors with enhanced performance[J].Electrochimica Acta,2015,151:35-41.
[21]Yu L,Zhang L,Wu H B,et al.Formation of NixCo3-x S4 hollow nanoprisms with enhanced pseudocapacitive properties[J].Angewandte Chemie International Edition,2014,53(14):3711-3714.
[22]Zhang Xiaoyan.The preparation of MnO2and the study on its application of supercapacitors[D].Taiyuan:Taiyuan University of Technology,2015:16-18.张小燕.超级电容器电极材料二氧化锰的合成优化和性能的研究[D].太原:太原理工大学,2015:16-18.
[23]Wang S L,Li W,Xin L P,et al.High-performance nickel cobalt sulfides materials via low-cost preparation for advanced asymmetric supercapacitors[J].RSC Advances,2016,48(6):42633-42642.
[24]Shen L,Yu L,Wu H B,et al.Formation of nickel cobalt sulfide ball-in-ball hollow spheres with enhanced electrochemical pseudocapacitive properties[J].Nature Communications,2015,6:7694-7701.
[25]Chen Haian.The study and preparation of nano Ni-Co sulfide with solvothermal method as supercapacitors[D].Chongqing:Chongqing University,2015:7-10.陈海岸.溶剂热法制备纳米镍钴硫化物及其超级电容性能研究[D].重庆:重庆大学,2015:7-10.
[26]Liu Y,Zhang J,Wang S,et al.Facilely constructing 3D porous NiCo2S4 nanonetworks for high-performance supercapacitors[J].New Journal of Chemistry,2014,38(9):4045-4048.
[27]Chen H,Jiang J,Zhang L,et al.In situ growth of NiCo2S4 nanotube arrays on Ni foam for supercapacitors:Maximizing utilization efficiency at high mass loading to achieve ultrahigh areal pseudocapacitance[J].Journal of Power Sources,2014,254:249-257.
[28]Hao L,Shen L F,Wang J,et al.Hollow NiCo2S4nanotube arrays grown on carbon textile as a self-supported electrode for asymmetric supercapacitors[J].RSC Advances,2016,6(12):9950-9957.
[29]Zhu Y,Wu Z,Jing M,et al.Mesoporous NiCo2S4nanoparticles as high-performance electrode materials for supercapacitors[J].Journal of Power Sources,2015,273:584-590.
[30]Han Gui,Lu Jinhua,Wang Min,et al.Research progress on absorber layers of Cu2ZnSnS4(CZTS)thin film solar cell prepared by electrodeposition[J].Materials Review,2016,30(11):50-56(in Chinese).韩贵,陆金花,王敏,等.电沉积法制备铜锌锡硫薄膜太阳能电池吸收层的研究进展[J].材料导报,2016,30(11):50-56.
[31]Chen W,Xia C,Alshareef H.One-step electrodeposited nickel cobalt sulfide nanosheet arrays for high-performance asymmetric supercapacitors[J].Acs Nano,2014,8(9):9531-9541.
[32]Yuan C,Li J,Hou L,et al.Ultrathin mesoporous NiCo2O4nanosheets supported on Ni foam as advanced electrodes for supercapacitors[J].Advanced Functional Materials,2012,22(21):4592-4597.
[33]Chen H,Jiang J,Zhang L,et al.Highly conductive NiCo2S4urchin-like nanostructures for high-rate pseudocapacitors[J].Nanoscale,2013,5(19):8879-8883.
[34]Zhang Y,Ma M,Yang J,et al.Shape-controlled synthesis of NiCo2S4and their charge storage characteristics in supercapacitors[J].Nanoscale,2014,6(16):9824-9830.
[35]Peng S,Li L,Li C,et al.In situ growth of NiCo2S4nanosheets on graphene for high-performance supercapacitors[J].Chemical Communications,2013,49(86):10178-10180.
[36]Shen L,Wang J,Xu G,et al.NiCo2S4 nanosheets grown on nitrogen-doped carbon foams as an advanced electrode for supercapacitors[J].Advanced Energy Materials,2015,5(3):1400977.
[37]Wang H,Wang C,Qing C,et al.Construction of carbonnickel cobalt sulphide hetero-structured arrays on nickel foam for high performance asymmetric supercapacitors[J].Electrochimica Acta,2015,174:1104-1112.
[38]Nguyen V H,Lamiel C,Shim J J.Hierarchical mesoporous graphene@Ni-Co-S arrays on nickel foam for high-performance supercapacitors[J].Electrochimica Acta,2015,161:351-357.
[39]Xiao J,Wan L,Yang S,et al.Design hierarchical electrodes with highly conductive NiCo2S4 nanotube arrays grown on carbon fiber paper for high-performance pseudocapacitors[J].Nano Letters,2014,14(2):831-838.
[40]Chen H C,Jiang J J,Zhao Y D,et al.One-pot synthesis of porous nickel cobalt sulphides:tuning the composition for superior pseudocapacitance[J].Journal of Materials Chemistry A,2015,3(1):428-437.
[41]Li Y,Cao L,Qiao L,et al.Ni-Co sulfide nanowires on nickel foam with ultrahigh capacitance for asymmetric supercapacitors[J].Journal of Materials Chemistry A,2014,2(18):6540-6548.
[42]Zhu Y,Ji X,Wu Z,et al.NiCo2S4hollow microsphere decorated by acetylene black for high-performance asymmetric supercapacitor[J].Electrochimica Acta,2015,186:562-571.
[43]Peng T,Qian Z,Wang J,et al.Construction of masscontrollable mesoporous NiCo2S4electrodes for high performance supercapacitors[J].Journal of Materials Chemistry A,2014,2(45):19376-19382.
[2]Gonzlez A,Goikolea E,Barrena J A,et al.Review on supercapacitors:technologies and materials[J].Renewable&Sustainable Energy Reviews,2016,580(2016):1189-1206.
[3]Chen Kunfeng,Xue Dongfeng.Evaluation of specific capacitance of colloidal ionic supercapacitor systems[J].Chinese Journal of Applied Chemistry,2016,33(1):18-24(in Chinese).陈昆峰,薛冬峰.胶体离子超级电容器的比容量评价[J].应用化学,2016,33(1):18-24.
[4]Yan J,Wang Q,Wei T,et al.Supercapacitors:recent advances in design and fabrication of electrochemical supercapacitors with high energy densities[J].Advanced Energy Materials,2014,4(4):157-164.
[5]Yang Z,Zhu X,Wang K,et al.Preparation of NiCo2S4flaky arrays on Ni foam as binder-free supercapacitor electrode[J].Applied Surface Science,2015,347:690-695.
[6]Lv Shenghua,Deng Lijuan.Research progress graphenebased supercapacitor[J].Journal of Functional Materials,2015,46(24):24015-24022(in Chinese).吕生华,邓丽娟.石墨烯基超级电容器的研究进展[J].功能材料,2015,46(24):24015-24022.
[7]Zeng Y X,Yu M H,Meng Y,et al.Iron-based supercapacitor electrodes:advances and challenges[J].Advanced Energy Materials,2016,24(6):1601053.
[8]Simon P,Gogotsi Y.Materials for electrochemical capacitors[J].Nature Materials,2008,7(11):845-854.
[9]You Chunqin,Luo Min,Kan Xiamei,et al.One-step hydrothermal synthesis of mesoporous ruffle-like sulfide microspheres for supercapacitors[J].Chinese Journal of Applied Chemistry,2015,32(12):1455-1461(in Chinese).尤春琴,罗民,阚夏梅,等.皱褶表面介孔镍钴硫化物微球的制备及其超电性能[J].应用化学,2015,32(12):1455-1461.
[10]Xiong X,Waller G,Ding D,et al.Controlled synthesis of NiCo2S4 nanostructured arrays on carbon fiber paper for high-performance pseudocapacitors[J].Nano Energy,2015,16:71-80.
[11]Zeng Z F,Wang D Z,Zhu J L,et al.NiCo2S4nanoparticles/activated balsam pear pulp for asymmetric hybrid capacitors[J].Cryst Eng Comm,2016,18(13):2363-2374.
[12]Peng T,Yi H,Sun P,et al.In situ growth of binderfree CNTs@Ni-Co-S nanosheets core/shell hybrids on Ni mesh for high energy density asymmetric supercapacitors[J].Journal of Materials Chemistry A,2016,4(22):8888-8897.
[13]Chen Z,Wan Z,Yang T,et al.Preparation of nickel cobalt sulfide hollow nanocolloids with enhanced electrochemical property for supercapacitors application[J].Scientific Reports,2016,6:25151.
[14]Xia C,Li P,Gandi A,et al.Is NiCo2S4really a semiconductor[J].Chemistry of Materials,2015,27(19):6482-6485.
[15]Du W,Zhu Z,Wang Y,et al.One-step synthesis of CoNi2S4nanoparticles for supercapacitor electrodes[J].Rsc Advances,2014,4(14):6998-7002.
[16]Chen T,Tang Y,Guo W,et al.Synergistic effect of cobalt and nickel on the superior electrochemical performances of rGO anchored nickel cobalt binary sulfides[J].Electrochimica Acta,2016,212:294-302.
[17]Yang J,Yu C,Fan X,et al.Electroactive edge site-enriched nickel-cobalt sulfide into graphene frameworks for high-performance asymmetric supercapacitors[J].Energy&Environmental Science,2016,9(4):1299-1307.
[18]Wan Lian.Preparation and characterization of three dimensional nanoarrays electrode based on Co-Ni sulfides[D].Wuhan:Huazhong University of Science and Technology,2015:3-5.万莲.基于(Co,Ni)硫化物的三维纳米阵列电极的构建及其超电容特性研究[D].武汉:华中科技大学,2015:3-5.
[19]Chen Haichao.Investigation of the pseudocapacitice properties of nickel cobalt bimetallic compounds[D].Wuhan:Huazhong University of Science and Technology,2014:86-88.陈海潮.镍钴双金属化合物的赝电容特性研究[D].武汉:华中科技大学,2014:86-88.
[20]Cai D,Wang D,Wang C,et al.Construction of desirable NiCo2S4nanotube arrays on nickel foam substrate for pseudocapacitors with enhanced performance[J].Electrochimica Acta,2015,151:35-41.
[21]Yu L,Zhang L,Wu H B,et al.Formation of NixCo3-x S4 hollow nanoprisms with enhanced pseudocapacitive properties[J].Angewandte Chemie International Edition,2014,53(14):3711-3714.
[22]Zhang Xiaoyan.The preparation of MnO2and the study on its application of supercapacitors[D].Taiyuan:Taiyuan University of Technology,2015:16-18.张小燕.超级电容器电极材料二氧化锰的合成优化和性能的研究[D].太原:太原理工大学,2015:16-18.
[23]Wang S L,Li W,Xin L P,et al.High-performance nickel cobalt sulfides materials via low-cost preparation for advanced asymmetric supercapacitors[J].RSC Advances,2016,48(6):42633-42642.
[24]Shen L,Yu L,Wu H B,et al.Formation of nickel cobalt sulfide ball-in-ball hollow spheres with enhanced electrochemical pseudocapacitive properties[J].Nature Communications,2015,6:7694-7701.
[25]Chen Haian.The study and preparation of nano Ni-Co sulfide with solvothermal method as supercapacitors[D].Chongqing:Chongqing University,2015:7-10.陈海岸.溶剂热法制备纳米镍钴硫化物及其超级电容性能研究[D].重庆:重庆大学,2015:7-10.
[26]Liu Y,Zhang J,Wang S,et al.Facilely constructing 3D porous NiCo2S4 nanonetworks for high-performance supercapacitors[J].New Journal of Chemistry,2014,38(9):4045-4048.
[27]Chen H,Jiang J,Zhang L,et al.In situ growth of NiCo2S4 nanotube arrays on Ni foam for supercapacitors:Maximizing utilization efficiency at high mass loading to achieve ultrahigh areal pseudocapacitance[J].Journal of Power Sources,2014,254:249-257.
[28]Hao L,Shen L F,Wang J,et al.Hollow NiCo2S4nanotube arrays grown on carbon textile as a self-supported electrode for asymmetric supercapacitors[J].RSC Advances,2016,6(12):9950-9957.
[29]Zhu Y,Wu Z,Jing M,et al.Mesoporous NiCo2S4nanoparticles as high-performance electrode materials for supercapacitors[J].Journal of Power Sources,2015,273:584-590.
[30]Han Gui,Lu Jinhua,Wang Min,et al.Research progress on absorber layers of Cu2ZnSnS4(CZTS)thin film solar cell prepared by electrodeposition[J].Materials Review,2016,30(11):50-56(in Chinese).韩贵,陆金花,王敏,等.电沉积法制备铜锌锡硫薄膜太阳能电池吸收层的研究进展[J].材料导报,2016,30(11):50-56.
[31]Chen W,Xia C,Alshareef H.One-step electrodeposited nickel cobalt sulfide nanosheet arrays for high-performance asymmetric supercapacitors[J].Acs Nano,2014,8(9):9531-9541.
[32]Yuan C,Li J,Hou L,et al.Ultrathin mesoporous NiCo2O4nanosheets supported on Ni foam as advanced electrodes for supercapacitors[J].Advanced Functional Materials,2012,22(21):4592-4597.
[33]Chen H,Jiang J,Zhang L,et al.Highly conductive NiCo2S4urchin-like nanostructures for high-rate pseudocapacitors[J].Nanoscale,2013,5(19):8879-8883.
[34]Zhang Y,Ma M,Yang J,et al.Shape-controlled synthesis of NiCo2S4and their charge storage characteristics in supercapacitors[J].Nanoscale,2014,6(16):9824-9830.
[35]Peng S,Li L,Li C,et al.In situ growth of NiCo2S4nanosheets on graphene for high-performance supercapacitors[J].Chemical Communications,2013,49(86):10178-10180.
[36]Shen L,Wang J,Xu G,et al.NiCo2S4 nanosheets grown on nitrogen-doped carbon foams as an advanced electrode for supercapacitors[J].Advanced Energy Materials,2015,5(3):1400977.
[37]Wang H,Wang C,Qing C,et al.Construction of carbonnickel cobalt sulphide hetero-structured arrays on nickel foam for high performance asymmetric supercapacitors[J].Electrochimica Acta,2015,174:1104-1112.
[38]Nguyen V H,Lamiel C,Shim J J.Hierarchical mesoporous graphene@Ni-Co-S arrays on nickel foam for high-performance supercapacitors[J].Electrochimica Acta,2015,161:351-357.
[39]Xiao J,Wan L,Yang S,et al.Design hierarchical electrodes with highly conductive NiCo2S4 nanotube arrays grown on carbon fiber paper for high-performance pseudocapacitors[J].Nano Letters,2014,14(2):831-838.
[40]Chen H C,Jiang J J,Zhao Y D,et al.One-pot synthesis of porous nickel cobalt sulphides:tuning the composition for superior pseudocapacitance[J].Journal of Materials Chemistry A,2015,3(1):428-437.
[41]Li Y,Cao L,Qiao L,et al.Ni-Co sulfide nanowires on nickel foam with ultrahigh capacitance for asymmetric supercapacitors[J].Journal of Materials Chemistry A,2014,2(18):6540-6548.
[42]Zhu Y,Ji X,Wu Z,et al.NiCo2S4hollow microsphere decorated by acetylene black for high-performance asymmetric supercapacitor[J].Electrochimica Acta,2015,186:562-571.
[43]Peng T,Qian Z,Wang J,et al.Construction of masscontrollable mesoporous NiCo2S4electrodes for high performance supercapacitors[J].Journal of Materials Chemistry A,2014,2(45):19376-19382.