阳离子交换树脂应用研究进展
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摘要
阳离子交换树脂以选择、交换、吸附和催化等功能来实现生物、环境、医药和有机合成等方面的应用。本文主要介绍了阳离子交换树脂在废水处理、化工生产、生物医药、食品安全以及冶金工业等方面的应用进展,指出了阳离子交换树脂的不足,展望了阳离子交换树脂在有机催化和吸附剂等领域的发展趋势。
Cation exchange resin had select, exchange, absorption and catalytic functions to achieve biological, environmental, pharmaceutical and organic synthesis applications. The application of cation exchange resin in wastewater treatment, chemical production, biomedicine, food safety and metallurgical industry were mainly introduced. The lack of cation exchange resin was pointed out. The development trend of cation exchange resin in organic catalysis and adsorbent was prospected.
Cation exchange resin had select, exchange, absorption and catalytic functions to achieve biological, environmental, pharmaceutical and organic synthesis applications. The application of cation exchange resin in wastewater treatment, chemical production, biomedicine, food safety and metallurgical industry were mainly introduced. The lack of cation exchange resin was pointed out. The development trend of cation exchange resin in organic catalysis and adsorbent was prospected.
引文
[1]张帆,李菁,谭建华,等.吸附法处理重金属废水的研究进展[J].化工进展,2013,32(11):2749-2755.
[2]Qianqian Shi,Aimin Li.Adsorption of naphthalene onto a high-surface-area carbon from waste ion exchange resin[J].Journal of Environmental Sciences,2013,25(1):188-194.
[3]Princy Gupta,Satya Paul.Solid acids:Green alternatives for acid catalysis[J].Catalysis Today,2014,236:153-170.
[4]Fabregas Vidal,Jose Luis.Solid pharmaceutical composition of cation exchange resin:US,20150174065[P].2015-06-25.
[5]黄艳,尚宇,周健,等.离子交换树脂在工业废水处理中的研究进展[J].煤炭与化工,2014,37(1):48-50.
[6]石艳利,李振雨.离子交换树脂处理重金属废水的研究进展[J].广州化工,2015,42(14):107.
[7]陈勇,王晓玉,陈蕾,等.一种改性阳离子交换树脂净水器滤芯:CN,201710579060.7[P].2017-07-17.
[8]毕向光,余建民,杨金富,等.阳离子树脂净化铂族金属溶液的研究[J].矿业工程,2015,35(3):87-90.
[9]鲁雪梅,熊鹰,张广之,等.锰氧化物-阳离子交换树脂复合材料的制备及其对水中重金属的吸附性能[J].环境化学,2012,31(10):1580-1589.
[10]WANG MILAN.Copper and Mercury Ions Adsorption on Ion Exchangers[D].UC Irvine.,2016.
[11]Qimeng Li,Lichun Fu,et al.Synthesis and characterization of a novel magnetic cation exchange resin and its application for efficient removal of Cu2+and Ni2+from aqueous solutions[J].Journal of Cleaner Production,2017,165:801.
[12]YongGang Zeng,Long Li.Study on Treatment of Heavy Metal Lons of Chemical Wastewater by Ion Exchange Resin[J].Advanced Materials Research,2014,955:2230-2233.
[13]Edebali,Serpil,Pehlivan,et al.Evaluation of chelate and cation exchange resins to remove copper ions[J].Powder Technology,2016,301:520-525.
[14]牛玉标,徐小青,赵海洋,等.淡水室填充阳离子交换树脂的EDI膜堆对镍离子溶液分离性能的研究[J].中国工程科学,2014,16(7):62-67.
[15]郭浩.732钠型阳离子交换树脂对Pb2+的去除特性及机理研究[D].武汉:华中科技大学,2013.
[16]贺子良,王丽娟,朱利军,等.采用强酸型阳离子交换树脂分离铝离子和磷酸盐[J].环境工程学报,2017(5):2640-2645.
[17]罗圣熙,杨春平,龙智勇,等.离子交换树脂对高浓度氨氮废水的吸附研究[J].环境科学学报,2015,35(8):2457-2463.
[18]赵飞,惠晓梅,郭栋生.阳离子交换树脂吸附焦化废水中氨氮影响因素研究[J].水处理技术,2011,37(11):34-37.
[19]左卫元,仝海娟,李健,等.锰氧化物改性离子交换树脂对甲醛的吸附研究[J].无机盐工业,2017,49(1):15-18.
[20]郑宁来.生物柴油制备新工艺[J].炼油技术与工程,2015(7):24.
[21]吕鹏梅,刘莉梅,杨玲梅,等.苯乙烯型阳离子交换树脂催化废煎炸油的酯化反应[J].农业机械学报,2014,45(11):201-205.
[22]霍稳周,史作然,刘野,等.耐高温强酸性阳离子交换树脂催化桐油酯化反应性能研究[J].中国油脂,2014,39(12):58-60.
[23]冯耀辉,何本桥,李建新.阳离子交换树脂填充固定床连续催化酯化制备生物柴油[J].化工进展,2010,29(A1):712-713.
[24]Fu Junying,Li Zhibing,Xing Shiyou,et al.Cation exchange resin catalysed biodiesel production from used cooking oil(UCO):Investigation of impurities effect[J].Fuel,2016,181:1058-1065.
[25]Benqiao He,Yixuan Shao,Yanbiao Ren,et al.Continuous biodiesel production from acidic oil using a combination of cation-and anion-exchange resins[J].Fuel Processing Technology,2015,130:1-6.
[26]李亚男,何文军,俞峰萍,等.离子交换树脂在有机催化反应中的应用进展[J].应用化学,2015,32(12):1343-1357.
[27]赵志刚,邵太丽,秦国正.H-732阳离子交换树脂催化酯化反应[J].化工进展,2012,31(7):1592-1596.
[28]仝海娟,左卫员,史兵方,等.SnCl4/强酸性离子交换树脂催化合成乙酸甲酯研究[J].天然气化工,2016,41(4):33-37.
[29]孔维宝,张娟,景洋,等.强酸性阳离子交换树脂催化合成棕榈酸甲酯[J].中国油脂,2013,38(10):52-55.
[30]廖安平,左卫元,蓝平,等.强酸性阳离子交换树脂催化合成乙酸酯[J].食品科技,2012,37(9):262-265.
[31]Lingling Ma,Ying Han,Kaian Sun.et al.Optimization of acidified oil esterification catalyzed by sulfonated cation exchange resin using response surface methodology[J].Energy Conversion and Management,2015,98:46-53.
[32]李运山.金属负载型阳离子树脂催化合成琥珀酸单乙酯[J].化工技术与开发,2012,41(8):7-10.
[33]杨雪云,王祚芳,周建.大孔强酸性阳离子交换树脂催化合成3,3’-二氯-4,4’-二氨基二苯甲烷[J].聚氨酯工业,2014,29(3):14-16.
[34]喻益,胡益共,刘殿华,等.大孔阳离子交换树脂催化裂解二醋酸亚乙酯制取醋酸乙烯的研究[J].天然气化工:C1化学与化工,2017(4):38-42.
[35]Xiangpo He,Ruyin Xu,Lingling Zhang,et al.Alkoxylation of camphene catalyzed by cation exchange resins[J].Chemical Engineering Research and Design,2016,114:60-68.
[36]袁长荣,廖春龙,余桂春,等.一种阳离子交换树脂催化合成甜菊糖苷RM的方法:CN,201610012806.1[P].2016-01-08.
[37]李伟男,南洋,杨德强,等.离子交换树脂在中药制剂中的应用[J].中医药学报,2011,39(3):101-102.
[38]王蒙,匡海学.离子交换树脂在天然药物化学中的应用进展[J].化学工程师,2015(7):41-43.
[39]周军辉,李杨,孙颖,等.披针叶黄华地上部分金雀花碱的分离纯化工艺研究[J].西北药学杂志,2016,31(2):132-136.
[40]王信,代龙,孙志强,等.阳离子交换树脂分离纯化钩藤总生物碱的工艺研究[J].中草药,2011,42(10):1973-1976.
[41]黄勇,刘凡,廖森泰,等.采用大孔树脂与阳离子交换树脂分离纯化桑叶活性物质的效果分析[J].蚕业科学,2012(6):1079-1085.
[42]Kaifei Chen,Gang Luo,Zhongfang Lei,et al.Chromatographic separation of glucose,xylose and arabinose from lignocellulosic hydrolysates using cation exchange resin[J].Separation and Purification Technology,2018,195:288-294.
[43]张致慧,杨续生,张琪,等.一种卤代强酸型阳离子交换树脂的合成方法及其用于高纯度阿卡波糖的制备:CN,201610843831.4[P].2016-09-22.
[44]石云,孔祥珍,华欲飞.离子交换树脂纯化大豆糖蜜上清液[J].大豆科学,2016,35(1):130-135.
[45]宋玉龙,周金燕,杨杰,等.阳离子交换树脂对新奥霉素的吸附性能分析与研究[J].离子交换与吸附,2014,30(2):97-107.
[46]王美玲.新型抗富血压药物褐藻氨酸的含成与分离纯化[D].青岛:青岛科技大学,2015.
[47]刘华.醋甲唑胺药物树脂复合物的制备及质量评价[J].中国处方药,2016,14(1):21-22.
[48]陈春,王艳艳,彭敏.阳离子交换树脂:HPLC法测定伊立替康脂质体包封率[J].现代中药研究与实践,2012,26(6):41-44.
[49]Siti Nur Hazwani-Oslan,Joo Shun Tan,Mohd Zamri Saad,et al.Improved cultivation of gdhA derivative Pasteurella multocida B:2 for high density of viable cells through in situ ammonium removal using cation-exchange resin for use as animal vaccine[J].Process Biochemistry,2017,56:1-7.
[50]Xu Yating,Liu Ju,Zhang Hongyang,et al.Hypercrosslinked strong cation-exchange polymers for selective extraction of serum purine metabolites associated with gout[J].Talanta,2016,151:172-178.
[51]杨川,张婷婷,蔡珊玲,等.鲍鱼性腺多糖中有害重金属的脱除[J].中国食品学报,2017,17(2):148-151.
[52]覃淑宁.改性大孔树脂分离纯化甜菊糖甙的研究[J].中外食品工业,2015(1):64.
[53]张卜升,许万祥,吴贤,等.合金渣中钛铪的离子交换分离研究[J].有色金属(冶炼部分),2015(6):55-58.
[54]陈童,严峰鹤,王辉,等.多种核级阳离子交换树脂的有机溶出物研究[J].水处理技术,2013,39(11):33-35.
[55]程亮,侯翠红,徐丽,等.纳米腐殖酸基离子交换复合树脂动态吸附-脱附冶金镍镉废水[J].化工学报,2016,67(1):149-357.
[56]周康根,陈泉洲,姜科,等.铜负载螯合树脂对氨氮的解吸及循环吸附性能[J].中南大学学报(自然科学版),2015,46(11):3999-4004.
[57]刘玮,王振平.阳离子交换树脂对氢电导率测量的影响[J].热力发电,2013,42(10):137-140.
[58]吴娜,何亮,柴欣生.一种快速测定强酸性阳离子交换树脂交换容量的顶空气相色谱法[J].造纸科学与技术,2017(4):62-65.
[59]Pavel Bulejko,Eli?ka Stránská.The effect of initial moisture content of cation-exchange resin on the preparation and properties of heterogeneous cation-exchange membranes[J].Materials Chemistry and Physics,2018,205:470-479.
[2]Qianqian Shi,Aimin Li.Adsorption of naphthalene onto a high-surface-area carbon from waste ion exchange resin[J].Journal of Environmental Sciences,2013,25(1):188-194.
[3]Princy Gupta,Satya Paul.Solid acids:Green alternatives for acid catalysis[J].Catalysis Today,2014,236:153-170.
[4]Fabregas Vidal,Jose Luis.Solid pharmaceutical composition of cation exchange resin:US,20150174065[P].2015-06-25.
[5]黄艳,尚宇,周健,等.离子交换树脂在工业废水处理中的研究进展[J].煤炭与化工,2014,37(1):48-50.
[6]石艳利,李振雨.离子交换树脂处理重金属废水的研究进展[J].广州化工,2015,42(14):107.
[7]陈勇,王晓玉,陈蕾,等.一种改性阳离子交换树脂净水器滤芯:CN,201710579060.7[P].2017-07-17.
[8]毕向光,余建民,杨金富,等.阳离子树脂净化铂族金属溶液的研究[J].矿业工程,2015,35(3):87-90.
[9]鲁雪梅,熊鹰,张广之,等.锰氧化物-阳离子交换树脂复合材料的制备及其对水中重金属的吸附性能[J].环境化学,2012,31(10):1580-1589.
[10]WANG MILAN.Copper and Mercury Ions Adsorption on Ion Exchangers[D].UC Irvine.,2016.
[11]Qimeng Li,Lichun Fu,et al.Synthesis and characterization of a novel magnetic cation exchange resin and its application for efficient removal of Cu2+and Ni2+from aqueous solutions[J].Journal of Cleaner Production,2017,165:801.
[12]YongGang Zeng,Long Li.Study on Treatment of Heavy Metal Lons of Chemical Wastewater by Ion Exchange Resin[J].Advanced Materials Research,2014,955:2230-2233.
[13]Edebali,Serpil,Pehlivan,et al.Evaluation of chelate and cation exchange resins to remove copper ions[J].Powder Technology,2016,301:520-525.
[14]牛玉标,徐小青,赵海洋,等.淡水室填充阳离子交换树脂的EDI膜堆对镍离子溶液分离性能的研究[J].中国工程科学,2014,16(7):62-67.
[15]郭浩.732钠型阳离子交换树脂对Pb2+的去除特性及机理研究[D].武汉:华中科技大学,2013.
[16]贺子良,王丽娟,朱利军,等.采用强酸型阳离子交换树脂分离铝离子和磷酸盐[J].环境工程学报,2017(5):2640-2645.
[17]罗圣熙,杨春平,龙智勇,等.离子交换树脂对高浓度氨氮废水的吸附研究[J].环境科学学报,2015,35(8):2457-2463.
[18]赵飞,惠晓梅,郭栋生.阳离子交换树脂吸附焦化废水中氨氮影响因素研究[J].水处理技术,2011,37(11):34-37.
[19]左卫元,仝海娟,李健,等.锰氧化物改性离子交换树脂对甲醛的吸附研究[J].无机盐工业,2017,49(1):15-18.
[20]郑宁来.生物柴油制备新工艺[J].炼油技术与工程,2015(7):24.
[21]吕鹏梅,刘莉梅,杨玲梅,等.苯乙烯型阳离子交换树脂催化废煎炸油的酯化反应[J].农业机械学报,2014,45(11):201-205.
[22]霍稳周,史作然,刘野,等.耐高温强酸性阳离子交换树脂催化桐油酯化反应性能研究[J].中国油脂,2014,39(12):58-60.
[23]冯耀辉,何本桥,李建新.阳离子交换树脂填充固定床连续催化酯化制备生物柴油[J].化工进展,2010,29(A1):712-713.
[24]Fu Junying,Li Zhibing,Xing Shiyou,et al.Cation exchange resin catalysed biodiesel production from used cooking oil(UCO):Investigation of impurities effect[J].Fuel,2016,181:1058-1065.
[25]Benqiao He,Yixuan Shao,Yanbiao Ren,et al.Continuous biodiesel production from acidic oil using a combination of cation-and anion-exchange resins[J].Fuel Processing Technology,2015,130:1-6.
[26]李亚男,何文军,俞峰萍,等.离子交换树脂在有机催化反应中的应用进展[J].应用化学,2015,32(12):1343-1357.
[27]赵志刚,邵太丽,秦国正.H-732阳离子交换树脂催化酯化反应[J].化工进展,2012,31(7):1592-1596.
[28]仝海娟,左卫员,史兵方,等.SnCl4/强酸性离子交换树脂催化合成乙酸甲酯研究[J].天然气化工,2016,41(4):33-37.
[29]孔维宝,张娟,景洋,等.强酸性阳离子交换树脂催化合成棕榈酸甲酯[J].中国油脂,2013,38(10):52-55.
[30]廖安平,左卫元,蓝平,等.强酸性阳离子交换树脂催化合成乙酸酯[J].食品科技,2012,37(9):262-265.
[31]Lingling Ma,Ying Han,Kaian Sun.et al.Optimization of acidified oil esterification catalyzed by sulfonated cation exchange resin using response surface methodology[J].Energy Conversion and Management,2015,98:46-53.
[32]李运山.金属负载型阳离子树脂催化合成琥珀酸单乙酯[J].化工技术与开发,2012,41(8):7-10.
[33]杨雪云,王祚芳,周建.大孔强酸性阳离子交换树脂催化合成3,3’-二氯-4,4’-二氨基二苯甲烷[J].聚氨酯工业,2014,29(3):14-16.
[34]喻益,胡益共,刘殿华,等.大孔阳离子交换树脂催化裂解二醋酸亚乙酯制取醋酸乙烯的研究[J].天然气化工:C1化学与化工,2017(4):38-42.
[35]Xiangpo He,Ruyin Xu,Lingling Zhang,et al.Alkoxylation of camphene catalyzed by cation exchange resins[J].Chemical Engineering Research and Design,2016,114:60-68.
[36]袁长荣,廖春龙,余桂春,等.一种阳离子交换树脂催化合成甜菊糖苷RM的方法:CN,201610012806.1[P].2016-01-08.
[37]李伟男,南洋,杨德强,等.离子交换树脂在中药制剂中的应用[J].中医药学报,2011,39(3):101-102.
[38]王蒙,匡海学.离子交换树脂在天然药物化学中的应用进展[J].化学工程师,2015(7):41-43.
[39]周军辉,李杨,孙颖,等.披针叶黄华地上部分金雀花碱的分离纯化工艺研究[J].西北药学杂志,2016,31(2):132-136.
[40]王信,代龙,孙志强,等.阳离子交换树脂分离纯化钩藤总生物碱的工艺研究[J].中草药,2011,42(10):1973-1976.
[41]黄勇,刘凡,廖森泰,等.采用大孔树脂与阳离子交换树脂分离纯化桑叶活性物质的效果分析[J].蚕业科学,2012(6):1079-1085.
[42]Kaifei Chen,Gang Luo,Zhongfang Lei,et al.Chromatographic separation of glucose,xylose and arabinose from lignocellulosic hydrolysates using cation exchange resin[J].Separation and Purification Technology,2018,195:288-294.
[43]张致慧,杨续生,张琪,等.一种卤代强酸型阳离子交换树脂的合成方法及其用于高纯度阿卡波糖的制备:CN,201610843831.4[P].2016-09-22.
[44]石云,孔祥珍,华欲飞.离子交换树脂纯化大豆糖蜜上清液[J].大豆科学,2016,35(1):130-135.
[45]宋玉龙,周金燕,杨杰,等.阳离子交换树脂对新奥霉素的吸附性能分析与研究[J].离子交换与吸附,2014,30(2):97-107.
[46]王美玲.新型抗富血压药物褐藻氨酸的含成与分离纯化[D].青岛:青岛科技大学,2015.
[47]刘华.醋甲唑胺药物树脂复合物的制备及质量评价[J].中国处方药,2016,14(1):21-22.
[48]陈春,王艳艳,彭敏.阳离子交换树脂:HPLC法测定伊立替康脂质体包封率[J].现代中药研究与实践,2012,26(6):41-44.
[49]Siti Nur Hazwani-Oslan,Joo Shun Tan,Mohd Zamri Saad,et al.Improved cultivation of gdhA derivative Pasteurella multocida B:2 for high density of viable cells through in situ ammonium removal using cation-exchange resin for use as animal vaccine[J].Process Biochemistry,2017,56:1-7.
[50]Xu Yating,Liu Ju,Zhang Hongyang,et al.Hypercrosslinked strong cation-exchange polymers for selective extraction of serum purine metabolites associated with gout[J].Talanta,2016,151:172-178.
[51]杨川,张婷婷,蔡珊玲,等.鲍鱼性腺多糖中有害重金属的脱除[J].中国食品学报,2017,17(2):148-151.
[52]覃淑宁.改性大孔树脂分离纯化甜菊糖甙的研究[J].中外食品工业,2015(1):64.
[53]张卜升,许万祥,吴贤,等.合金渣中钛铪的离子交换分离研究[J].有色金属(冶炼部分),2015(6):55-58.
[54]陈童,严峰鹤,王辉,等.多种核级阳离子交换树脂的有机溶出物研究[J].水处理技术,2013,39(11):33-35.
[55]程亮,侯翠红,徐丽,等.纳米腐殖酸基离子交换复合树脂动态吸附-脱附冶金镍镉废水[J].化工学报,2016,67(1):149-357.
[56]周康根,陈泉洲,姜科,等.铜负载螯合树脂对氨氮的解吸及循环吸附性能[J].中南大学学报(自然科学版),2015,46(11):3999-4004.
[57]刘玮,王振平.阳离子交换树脂对氢电导率测量的影响[J].热力发电,2013,42(10):137-140.
[58]吴娜,何亮,柴欣生.一种快速测定强酸性阳离子交换树脂交换容量的顶空气相色谱法[J].造纸科学与技术,2017(4):62-65.
[59]Pavel Bulejko,Eli?ka Stránská.The effect of initial moisture content of cation-exchange resin on the preparation and properties of heterogeneous cation-exchange membranes[J].Materials Chemistry and Physics,2018,205:470-479.