山西柳林泉域岩溶地下水溶解无机碳特征及控制因素
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摘要
稳定碳同位素可指示岩溶动力系统无机碳循环过程及流域水文地球化形成演化。为揭示山西柳林泉域岩溶地下水循环演化规律及控制因素。本研究对泉域补给区、径流区、排泄区、深埋区29个岩溶地下水的主要离子组分和碳同位素进行测试分析。研究结果表明,流域内岩溶地下水的δ~(13)C_(DIC,VPDB)(DIC—溶解无机碳)具有较大的变化范围,最大值为-8.19‰,最小值为-13.35‰,平均值为-10.09‰。从补给区、到径流区、到排泄区,到深埋区δ~(13)C_(DIC,VPDB)值呈不断增重的变化规律。补给区来源于土壤CO_2的比例最高,范围为46.22%～58.04%,平均值为51.13%,其次是径流区,范围为36.22%～58.37%,平均值为42.05%,排泄区和深埋区最小,范围分别为37.61%～41.52%和35.61%～42.26%,平均值分别为39.38%和38.28%。从补给区到径流区、到排泄区、到深埋区,随着径流途径增大和硫酸参与溶蚀的比例增加,DIC(溶解无机碳)中来源于土壤CO_2的比例减小,碳酸盐岩来源的碳的比例增加。
Objectives: Stable carbon isotope is a useful and powerful tool for tracing the cycle process of dissloved inorganic carbon(DIC) in karst dynamics system and studying the formation and evolution of geohydrochemistry of groundwater in a watershed.Methods: For revealing the evolution and control factors of karst groundwater in Liulin spring area,the main ion components and carbon isotopes of dissloved inorganic carbon(δ~(13)C_(DIC,VPDB)) in 29 karst groundwater from spring supply area,runoff area,discharge area and deep buried area,were sampled and analyzed.Results: The results showed that the δ~(13)C_(DIC,VPDB)of karst groundwater in the study area has a large variation range,with a maximum value of-8.19‰,a minimum value of-13.35‰,and the mean value of-10.09‰. The δ~(13)C_(DIC,VPDB)values from the recharge area,to the runoff area,to the discharge area and then to the deep buried area show a constant weight gain. The proportion of CO_2 in DIC from soil is the highest in recharge area,ranging from 46.22 % to 58.04 %,with a mean value of 51.13 %,followed by runoff area,ranging from 36.22 % to 58.37 %,with a mean value of 42. 05 %,and the lowest proportion in discharge area and deep burial area,ranging from 37.61 % to 41.52 % and 35.61 % to 42.26 %,with a mean value of 39.38 % and 38.28 %,respectively.Conclusions: Thus,from the recharge area to the runoff area,to the discharge area and then to the deep burial area,the proportion of CO_2 in DIC from soil decreases and the proportion of carbon from carbonate rocks increases due to the increase of runoff path and sulfuric acid participation in carbonate dissolution.
Objectives: Stable carbon isotope is a useful and powerful tool for tracing the cycle process of dissloved inorganic carbon(DIC) in karst dynamics system and studying the formation and evolution of geohydrochemistry of groundwater in a watershed.Methods: For revealing the evolution and control factors of karst groundwater in Liulin spring area,the main ion components and carbon isotopes of dissloved inorganic carbon(δ~(13)C_(DIC,VPDB)) in 29 karst groundwater from spring supply area,runoff area,discharge area and deep buried area,were sampled and analyzed.Results: The results showed that the δ~(13)C_(DIC,VPDB)of karst groundwater in the study area has a large variation range,with a maximum value of-8.19‰,a minimum value of-13.35‰,and the mean value of-10.09‰. The δ~(13)C_(DIC,VPDB)values from the recharge area,to the runoff area,to the discharge area and then to the deep buried area show a constant weight gain. The proportion of CO_2 in DIC from soil is the highest in recharge area,ranging from 46.22 % to 58.04 %,with a mean value of 51.13 %,followed by runoff area,ranging from 36.22 % to 58.37 %,with a mean value of 42. 05 %,and the lowest proportion in discharge area and deep burial area,ranging from 37.61 % to 41.52 % and 35.61 % to 42.26 %,with a mean value of 39.38 % and 38.28 %,respectively.Conclusions: Thus,from the recharge area to the runoff area,to the discharge area and then to the deep burial area,the proportion of CO_2 in DIC from soil decreases and the proportion of carbon from carbonate rocks increases due to the increase of runoff path and sulfuric acid participation in carbonate dissolution.
引文
高宝玉,梁永平,王维泰.2008.柳林泉域岩溶水特点与地质背景条件分析.中国岩溶,27(3):209～214.
黄奇波,覃小群,刘朋雨,唐萍萍.2015b.酸雨对桂林枯水期岩溶地下水δ13CDIC及碳汇效应的影响.地球科学—中国地质大学学报,40(7):1237～1247.
黄奇波,覃小群,刘朋雨,张连凯,苏春田.2015a.硫酸对乌江中上游段岩溶水化学及δ13CDIC的影响.环境科学,36(9):102～111.
黄奇波,覃小群,刘朋雨,张连凯,苏春田.2016.人为活动对乌江上游段岩溶地下水δ13CDIC及碳汇效应的影响.第四纪研究,36(6):1358～1369.
黄奇波,覃小群,刘朋雨,张连凯,苏春田.2017.非岩溶水和硫酸参与溶蚀对湘南地区地下河流域岩溶碳汇通量的影响.地球科学进展,32(3):307～318.
黄奇波,覃小群,唐萍萍,刘朋雨.2012.不同岩溶环境条件下岩溶地下水中δ13CDIC特征.地球与环境,40(4):505～511.
贾振兴,臧红飞,郑秀清.2015.柳林泉域滞流区岩溶水的热源及其 Na+、Cl-来源探讨.中国岩溶,34(6):570～576.
蒋勇军,袁道先.2014.城市发展对岩溶地下水质影响的地球化学示踪—以重庆南山老龙洞地下河系统为例.第四纪研究,34(5):1044～1053.
康志强,袁道先,常勇,李清艳,何师意,严毅萍.2011.岩溶碳汇的主控因子—水循环.吉林大学学报(地球科学版),41(5):1542～1547.
郎赟超,刘丛强,赵志琦,李思亮,韩贵琳.2005.贵阳市地表水地下水化学组成:喀斯特水文系统水—岩反应及污染特征.水科学进展,16(5):826～832.
梁永平,韩行瑞,时坚,尹立河.2005.鄂尔多斯盆地周边岩溶地下水系统模式及特点.地球学报,26(4):365～369.
梁永平,王维泰.2010.中国北方岩溶水系统划分与系统特征.地球学报,31(6):860～868.
刘再华.2012.岩石风化碳汇研究的最新进展和展望.科学通报,57(2～3):95～102
马腾,王国卿,张庆保.1997.山西省柳林泉域地表径流渗漏量的灰色预测.地球科学.中国地质大学学报,22(1):90～93.
蒲俊兵,袁道先,蒋勇军,苟鹏飞,殷建军.2010.重庆岩溶地下河水文地球化学特征及环境意义.水科学进展,21 (5):628～636.
蒲俊兵.2013.重庆地区岩溶地下河水溶解无机碳及其稳定同位素特征.中国岩溶,32(2):123～132
王数,左强.1997.柳林泉泉区裂隙水流的数值模拟与分析.中国农业大学学报,(S2):50～56.
王雅捷,王国卿,郝永红,李华敏,赵娇娟.2011.人类活动对柳林泉域水文过程影响研究.水文,31(3):82～87.
王焰新,马腾,罗朝晖,李永敏.1998.山西柳林泉域水岩相互作用地球化学模拟.地球科学.中国地质大学学报,23(5):519～522.
魏晓鸥,郑秀清,顾江海.2012.柳林泉域岩溶地下水水化学特征及演化分析.人民黄河,34(1):72～77.
吴吉春,薛禹群,黄海,张政治.2001.山两柳林泉局部区域溶质运营二维数值模拟.水利学报,32(8):38～43.
杨慧,陈家瑞,梁建宏,曹建华.2017.桂林丫吉岩溶区土壤有机碳和 pH 值与钙形态分布的关系初探.地质论评,63(4):1117～1126.
杨敏,卢耀如,张凤娥,张胜,殷密英,吴国庆.2018.柳林泉域岩溶水化学演化及地球化学模拟.南水北调与水利科技,16(1):127～134.
袁道先.2011.地质作用与碳循环研究的回顾和展望.科学通报,56(26):2157.
袁道先.2015.国岩溶资源环境领域的创新问题.中国岩溶,34(2):98～100.
臧红飞,贾振兴,郑秀清,秦作栋,黄小丹.2013.林泉域岩溶水水化学及碳硫同位素特征.水电能源科学,31(12):28～32.
臧红飞,郑秀清,张永波,杨展.2017.柳林泉域岩溶水中 SO42～的来源探讨.水文地质工程地质,44(1):9～15.
张连凯,覃小群,刘朋雨,黄奇波.2016.硫酸参与的长江流域岩石化学风化速率与大气CO2消耗.地质学报,90(8):1933～1943.
张陶,蒲俊兵,袁道先,李建鸿.2016.广西官村岩溶溪流中生物地球化学控制的DIC和 NO3～昼夜变化研究.地质学报,90(8):1965～1976.
张兴波,蒋勇军,邱述兰,曹敏,胡毅军.2012.农业活动对岩溶作用碳汇的影响:以重庆青木关地下河流域为例.地球科学进展,27(4):466～476.
赵娇娟,郝永红,李华敏,王亚捷.2011.基于地下水压力波传播过程的泉水流量灰色系统模型.水文地质工程地质,38(6):1～7.
Cane G,Clark I.1999.Tracing ground water recharge in an agricultural watershed with isotopes.Ground Water,37(1):133～139.
Gao Baoyu,Liang Yongping,Wang Weitai.2008&.Features of karst water and geologic background in Liulin spring basin.Carsologica Sinica,27(3):209～214.
Huang Q B,Qin X Q,Liu P Y,Zhang L K,Su C T.2017.Impact of sulfuric and nitric acids on carbonate dissolution,and the associated deficit of CO2 uptake in the upper—middle reaches of the Wujiang River,China.Journal of Contaminant Hydrology,203:18～27.
Huang Qibo,Qin Xiaoqun,Liu Pengyu,Tang Pingping.2015b&.The impact of acid rain to δ13CDIC of karst groundwater and carbon sink in dry season in Guilin.Earth Science—Journal of China University of Geosciences,40(7):1237～1247.
Huang Qibo,Qin Xiaoqun,Liu Pengyu,Zhang Liankai,Su Chuntian.2016&.The impact of human activities to δ13CDIC of karst groundwater and carbon sink in the upper and middle reaches of of Wu River.Quaternary Science,36(6):1358～1369.
Huang Qibo,Qin Xiaoqun,Liu Pengyu,Zhang Liankai,Su Chuntian.2017&.The influence of allogenic water and sulfuric acid to karst carbon sink in karst subterranean river in southern Hunan.Advances in Earth Science,32(3):307～318.
Huang Qibo,Qin Xiaoqun,Liu Pengyu,Zhang Liankai,Su Chuntian.2015a&.Influence of sulfuric acid to karst hydrochemical and δ13CDIC in the upper and middle reaches of Wu River.Environmental Science,36(9):102～111.
Huang Qibo,Qin Xiaoqun,Tang Pingping,Liu Pengyu.2012&.The δ13C characteristics of groundwater in different karst environmental conditions.Earth and Environment,40(4):505～511.
Jia Zhengxin,Zang Hongfei,Zheng Xiuqing.2015&.The origin of Na+,C1-and thermal source of karst groundwater in the stagnant area of Liulin spring basin.Carsologica Sinica,34(6):570～576.
Jiang Y J.2013.The contribution of human activities to dissolved inorganic carbon fluxes in a karst underground river system:Evidence from major elements and δ13CDIC in Nandong,Southwest China.Journal of Contaminant Hydrology,152:1～11.
Jiang Yongjun and Yuan Daoxian.2014&.Geochemical tracers to characterize effects of urbanization on karst groundwater quality from Nanshan underground river system,SW China.Quaternary Science,34(5):1044～1053.
Jiang Z C,Yuan D X.1999.CO2 source-sink in karst processes in karst areas of China.Episodes,22(1):33～35.
Kang Zhiqiang,Yuan Daoxian,Chang Yong,Li Qingyan,He Shiyi,Yanyiping.2011&.The Main Controlling Factor of Karst Carbon Sequestration:About Water Cycle.Journal of Jilin University (Earth Science Edition),41(5):1542～1547.
Lang Yunchao,Liu Congqiang,Zhao Zhiqi,Li Siliang Han Guiling.2005&.Chemical compositions of surface and ground waters of Guiyang city:discussion of water—rock interaction and contamination in karstic hydrological system.Advances in Water Science,16(5):826～832.
Li X D,Liu C Q,Harue M,Li S L,Liu X L.2010.The use of environmental isotopic (C,Sr,S) and hydrochemical tracers to characterize anthropogenic effects on karst groundwater quality:A case study of the Shuicheng Basin,SW China.Applied Geochemistry,25:1924～1936.
Liang Yongping,Han Xingrui,Shi Jiang,Ying Lihe.2005&.The karst groundwater system in the peripheral area of Ordos Basin:Its patterns and characteristics .Acta Geoscientica Sinica,26 (4):365～369.
Liang Yongping,Wang Weitai.2010&.The division and characteristics of karst water systems in Northern China.Acta Geoscientica Sinica,31(6):860～868.
Liu Z,Dreybrodt W,Wang H.2010.A new direction in effective accounting for the atmospheric CO2 budget:considering the combined action of carbonate dissolution,the global water cycle and photosynthetic uptake of DIC by aquatic organisms.Earth-Science Reviews,99:162～172.
Liu Zaihua.2012&.New progress and prospects in the study of rock-weathering-related carbon sinks.Chinese Science Bulletin,57(2～3):95～102
Ma Teng,Wang Guoqing,Zhang Qinbao.1997&.A grey system approach to prediction of surface runoff Leakage:with an example from the Liulin karst water system in Shanxi Province.Earth Science-Journal of China University of Geosciences,22(1):90～93.
Nordt L C,Hallmark C T,Wilding L P,Boutton T W.1998.Quantifying pedogenic carbonate accumulations using stable carbon isotopes.Geoderma,82(1～3):115～136.
Pu J,Yuan D,Zhao H,Shen L.2014.Hydrochemical and P(CO2) variations of a cave stream in a subtropical karst area,Chongqing,SW China:Piston effects,dilution effects,soil CO2 and buffer effects.Environmental Earth Sciences,71( 9) :4039～4049.
Pu Junbing,Yuan Daoxian,Jiang Yongjun,Guo Pengfei,Yin Jianjun.2010&.Hydrogeochemistry and environmental meaning of Chongqing subterranean karst streams in China.Advances in Water Science,21(5):628～636
Pu Junbing.2013&.Dissolved inorganic carbon and stable carbon isotope in karst subterranean streams in Chongqing,China.Carsologica Sinica,32(2):123～132.
Telmer K,Veizer J.1999.Carbon fluxes,pCO2,and substrate weathering in a large northern river basin,Canada:Carbon isotope perspectives.Chemical Geology,159(1～4):61～86.
Wang Shu,Zuo Qiang.1997&.The Numerical simulation and analysis of fractured flow in Liulin Spring area.Journal of China Agricultural University,(S2):50～56.
Wang Yajie,Wang Guoqin,Hao Yonghong,Li Huaming,Zhao Jiaojuang .2011&.Effect of human activities on hydrological process of Liulin springs .Journal of China Hydrology,31(3):82～87.
Wang Yanxin,Ma Teng,Luo Zhaohui,Li Yongmin.1998&.Geochemical modeling of water—rock interactions in the Liulin karst system,Shanxi Province.Earth Science—Journal of China University of Geosciences,23(5):519～522.
Wei Xiaoou,Zheng Xiuqing,Gu Jianghai.2012&.Analysis of hydrochemical characteristics and evolution of karstic groundwater in Liulin spring catchment.Yellow River,34(1):72～77.
Wu Jichun,Xue Yuqun,Huang Hai,Zhang Zhengzhi.2001&.Two dimensional numerical simulation of solute transport in Liulin spring local area.Shuili Xuebao,(8):38～43.
Yang Hui,Chen Jiarui,Liang Jianhong,Cao Jianhua.2017&.Preliminary study on the relationship between soil organic carbon and pH value and calcium species in Yaji Karst Region,Guilin.Geological Review,63(4):1117～1126.
Yang Ming,Lu Yaoru,Zhang fene,Zhang Sheng,Yin Miying,Wu Guoqing.2018&.Hydrochemical evolution and geochemical simulation of karst groundwater in Liulin springs.South-to-North Water Transfers and Water Science & Technology,16(1):127～134.
Yuan Daoxian.2011#.Review and Prospect in the study on karst processes and Carbon Cycle Research.Chinese Science Bulletin,56(26):2157.
Yuan Daoxian.2015&.Scientific innovation in karst resources and environment research field of China.Carsologica Sinica,34(2):98～100.
Zang Hongfei,Jia Zhengxin,Zheng Xiuqing,Qin Zuodong,Huang Xiaodan.2013&.Characteristics of hydrochemical and carbon—sulfur isotopic for karst water in Liulin spring area .Water Resources and Power,31(12):28～32.
Zang Hongfei,Zheng Xiuqing,Zhang Yongbo,Yang Zhan .2017&.Source of SO■ in karst groundwater in the Liulin spring area.Hydrogeology & Engineering Geology,44(1):9～15.
Zhang Liankai,Qin Xiaoqun,Liu Pengyu,Huang Qibo.2016&.Chemical Denudation Rate and Atmospheric CO2 Consumption byH2CO3 and H2SO4 in the Yangtze River Catchment.Geological Bulletin of China,90(8):1933～1943.
Zhang Tao,PU Junbing,Yuan Daoxian,LI Jianhong.2016&.Biogeochemical controls on daily cycling of DIC and NO-3 of guancun karst stream in Guangxi.Geological Bulletin of China,90(8):1965～1976.
Zhang Xingbo,Jiang Yongjun,Qiu Shulan,Cao Ming,Hu Yijun.2012&.Agricultural activities and carbon cycling in Karst areas in Southwest China:dissolving carbonate rocks and CO2 sink.Advances in Earth Science,27( 4) :466～476.
Zhao Jiaojuang,Hao Yonghong,Li Huaming,Wang Yajie.2011&.Grey model for karst spring discharge based on propagation process of groundwater pressure wave.Hydrogeology & Engineering Geology,38(6):1～7.
黄奇波,覃小群,刘朋雨,唐萍萍.2015b.酸雨对桂林枯水期岩溶地下水δ13CDIC及碳汇效应的影响.地球科学—中国地质大学学报,40(7):1237～1247.
黄奇波,覃小群,刘朋雨,张连凯,苏春田.2015a.硫酸对乌江中上游段岩溶水化学及δ13CDIC的影响.环境科学,36(9):102～111.
黄奇波,覃小群,刘朋雨,张连凯,苏春田.2016.人为活动对乌江上游段岩溶地下水δ13CDIC及碳汇效应的影响.第四纪研究,36(6):1358～1369.
黄奇波,覃小群,刘朋雨,张连凯,苏春田.2017.非岩溶水和硫酸参与溶蚀对湘南地区地下河流域岩溶碳汇通量的影响.地球科学进展,32(3):307～318.
黄奇波,覃小群,唐萍萍,刘朋雨.2012.不同岩溶环境条件下岩溶地下水中δ13CDIC特征.地球与环境,40(4):505～511.
贾振兴,臧红飞,郑秀清.2015.柳林泉域滞流区岩溶水的热源及其 Na+、Cl-来源探讨.中国岩溶,34(6):570～576.
蒋勇军,袁道先.2014.城市发展对岩溶地下水质影响的地球化学示踪—以重庆南山老龙洞地下河系统为例.第四纪研究,34(5):1044～1053.
康志强,袁道先,常勇,李清艳,何师意,严毅萍.2011.岩溶碳汇的主控因子—水循环.吉林大学学报(地球科学版),41(5):1542～1547.
郎赟超,刘丛强,赵志琦,李思亮,韩贵琳.2005.贵阳市地表水地下水化学组成:喀斯特水文系统水—岩反应及污染特征.水科学进展,16(5):826～832.
梁永平,韩行瑞,时坚,尹立河.2005.鄂尔多斯盆地周边岩溶地下水系统模式及特点.地球学报,26(4):365～369.
梁永平,王维泰.2010.中国北方岩溶水系统划分与系统特征.地球学报,31(6):860～868.
刘再华.2012.岩石风化碳汇研究的最新进展和展望.科学通报,57(2～3):95～102
马腾,王国卿,张庆保.1997.山西省柳林泉域地表径流渗漏量的灰色预测.地球科学.中国地质大学学报,22(1):90～93.
蒲俊兵,袁道先,蒋勇军,苟鹏飞,殷建军.2010.重庆岩溶地下河水文地球化学特征及环境意义.水科学进展,21 (5):628～636.
蒲俊兵.2013.重庆地区岩溶地下河水溶解无机碳及其稳定同位素特征.中国岩溶,32(2):123～132
王数,左强.1997.柳林泉泉区裂隙水流的数值模拟与分析.中国农业大学学报,(S2):50～56.
王雅捷,王国卿,郝永红,李华敏,赵娇娟.2011.人类活动对柳林泉域水文过程影响研究.水文,31(3):82～87.
王焰新,马腾,罗朝晖,李永敏.1998.山西柳林泉域水岩相互作用地球化学模拟.地球科学.中国地质大学学报,23(5):519～522.
魏晓鸥,郑秀清,顾江海.2012.柳林泉域岩溶地下水水化学特征及演化分析.人民黄河,34(1):72～77.
吴吉春,薛禹群,黄海,张政治.2001.山两柳林泉局部区域溶质运营二维数值模拟.水利学报,32(8):38～43.
杨慧,陈家瑞,梁建宏,曹建华.2017.桂林丫吉岩溶区土壤有机碳和 pH 值与钙形态分布的关系初探.地质论评,63(4):1117～1126.
杨敏,卢耀如,张凤娥,张胜,殷密英,吴国庆.2018.柳林泉域岩溶水化学演化及地球化学模拟.南水北调与水利科技,16(1):127～134.
袁道先.2011.地质作用与碳循环研究的回顾和展望.科学通报,56(26):2157.
袁道先.2015.国岩溶资源环境领域的创新问题.中国岩溶,34(2):98～100.
臧红飞,贾振兴,郑秀清,秦作栋,黄小丹.2013.林泉域岩溶水水化学及碳硫同位素特征.水电能源科学,31(12):28～32.
臧红飞,郑秀清,张永波,杨展.2017.柳林泉域岩溶水中 SO42～的来源探讨.水文地质工程地质,44(1):9～15.
张连凯,覃小群,刘朋雨,黄奇波.2016.硫酸参与的长江流域岩石化学风化速率与大气CO2消耗.地质学报,90(8):1933～1943.
张陶,蒲俊兵,袁道先,李建鸿.2016.广西官村岩溶溪流中生物地球化学控制的DIC和 NO3～昼夜变化研究.地质学报,90(8):1965～1976.
张兴波,蒋勇军,邱述兰,曹敏,胡毅军.2012.农业活动对岩溶作用碳汇的影响:以重庆青木关地下河流域为例.地球科学进展,27(4):466～476.
赵娇娟,郝永红,李华敏,王亚捷.2011.基于地下水压力波传播过程的泉水流量灰色系统模型.水文地质工程地质,38(6):1～7.
Cane G,Clark I.1999.Tracing ground water recharge in an agricultural watershed with isotopes.Ground Water,37(1):133～139.
Gao Baoyu,Liang Yongping,Wang Weitai.2008&.Features of karst water and geologic background in Liulin spring basin.Carsologica Sinica,27(3):209～214.
Huang Q B,Qin X Q,Liu P Y,Zhang L K,Su C T.2017.Impact of sulfuric and nitric acids on carbonate dissolution,and the associated deficit of CO2 uptake in the upper—middle reaches of the Wujiang River,China.Journal of Contaminant Hydrology,203:18～27.
Huang Qibo,Qin Xiaoqun,Liu Pengyu,Tang Pingping.2015b&.The impact of acid rain to δ13CDIC of karst groundwater and carbon sink in dry season in Guilin.Earth Science—Journal of China University of Geosciences,40(7):1237～1247.
Huang Qibo,Qin Xiaoqun,Liu Pengyu,Zhang Liankai,Su Chuntian.2016&.The impact of human activities to δ13CDIC of karst groundwater and carbon sink in the upper and middle reaches of of Wu River.Quaternary Science,36(6):1358～1369.
Huang Qibo,Qin Xiaoqun,Liu Pengyu,Zhang Liankai,Su Chuntian.2017&.The influence of allogenic water and sulfuric acid to karst carbon sink in karst subterranean river in southern Hunan.Advances in Earth Science,32(3):307～318.
Huang Qibo,Qin Xiaoqun,Liu Pengyu,Zhang Liankai,Su Chuntian.2015a&.Influence of sulfuric acid to karst hydrochemical and δ13CDIC in the upper and middle reaches of Wu River.Environmental Science,36(9):102～111.
Huang Qibo,Qin Xiaoqun,Tang Pingping,Liu Pengyu.2012&.The δ13C characteristics of groundwater in different karst environmental conditions.Earth and Environment,40(4):505～511.
Jia Zhengxin,Zang Hongfei,Zheng Xiuqing.2015&.The origin of Na+,C1-and thermal source of karst groundwater in the stagnant area of Liulin spring basin.Carsologica Sinica,34(6):570～576.
Jiang Y J.2013.The contribution of human activities to dissolved inorganic carbon fluxes in a karst underground river system:Evidence from major elements and δ13CDIC in Nandong,Southwest China.Journal of Contaminant Hydrology,152:1～11.
Jiang Yongjun and Yuan Daoxian.2014&.Geochemical tracers to characterize effects of urbanization on karst groundwater quality from Nanshan underground river system,SW China.Quaternary Science,34(5):1044～1053.
Jiang Z C,Yuan D X.1999.CO2 source-sink in karst processes in karst areas of China.Episodes,22(1):33～35.
Kang Zhiqiang,Yuan Daoxian,Chang Yong,Li Qingyan,He Shiyi,Yanyiping.2011&.The Main Controlling Factor of Karst Carbon Sequestration:About Water Cycle.Journal of Jilin University (Earth Science Edition),41(5):1542～1547.
Lang Yunchao,Liu Congqiang,Zhao Zhiqi,Li Siliang Han Guiling.2005&.Chemical compositions of surface and ground waters of Guiyang city:discussion of water—rock interaction and contamination in karstic hydrological system.Advances in Water Science,16(5):826～832.
Li X D,Liu C Q,Harue M,Li S L,Liu X L.2010.The use of environmental isotopic (C,Sr,S) and hydrochemical tracers to characterize anthropogenic effects on karst groundwater quality:A case study of the Shuicheng Basin,SW China.Applied Geochemistry,25:1924～1936.
Liang Yongping,Han Xingrui,Shi Jiang,Ying Lihe.2005&.The karst groundwater system in the peripheral area of Ordos Basin:Its patterns and characteristics .Acta Geoscientica Sinica,26 (4):365～369.
Liang Yongping,Wang Weitai.2010&.The division and characteristics of karst water systems in Northern China.Acta Geoscientica Sinica,31(6):860～868.
Liu Z,Dreybrodt W,Wang H.2010.A new direction in effective accounting for the atmospheric CO2 budget:considering the combined action of carbonate dissolution,the global water cycle and photosynthetic uptake of DIC by aquatic organisms.Earth-Science Reviews,99:162～172.
Liu Zaihua.2012&.New progress and prospects in the study of rock-weathering-related carbon sinks.Chinese Science Bulletin,57(2～3):95～102
Ma Teng,Wang Guoqing,Zhang Qinbao.1997&.A grey system approach to prediction of surface runoff Leakage:with an example from the Liulin karst water system in Shanxi Province.Earth Science-Journal of China University of Geosciences,22(1):90～93.
Nordt L C,Hallmark C T,Wilding L P,Boutton T W.1998.Quantifying pedogenic carbonate accumulations using stable carbon isotopes.Geoderma,82(1～3):115～136.
Pu J,Yuan D,Zhao H,Shen L.2014.Hydrochemical and P(CO2) variations of a cave stream in a subtropical karst area,Chongqing,SW China:Piston effects,dilution effects,soil CO2 and buffer effects.Environmental Earth Sciences,71( 9) :4039～4049.
Pu Junbing,Yuan Daoxian,Jiang Yongjun,Guo Pengfei,Yin Jianjun.2010&.Hydrogeochemistry and environmental meaning of Chongqing subterranean karst streams in China.Advances in Water Science,21(5):628～636
Pu Junbing.2013&.Dissolved inorganic carbon and stable carbon isotope in karst subterranean streams in Chongqing,China.Carsologica Sinica,32(2):123～132.
Telmer K,Veizer J.1999.Carbon fluxes,pCO2,and substrate weathering in a large northern river basin,Canada:Carbon isotope perspectives.Chemical Geology,159(1～4):61～86.
Wang Shu,Zuo Qiang.1997&.The Numerical simulation and analysis of fractured flow in Liulin Spring area.Journal of China Agricultural University,(S2):50～56.
Wang Yajie,Wang Guoqin,Hao Yonghong,Li Huaming,Zhao Jiaojuang .2011&.Effect of human activities on hydrological process of Liulin springs .Journal of China Hydrology,31(3):82～87.
Wang Yanxin,Ma Teng,Luo Zhaohui,Li Yongmin.1998&.Geochemical modeling of water—rock interactions in the Liulin karst system,Shanxi Province.Earth Science—Journal of China University of Geosciences,23(5):519～522.
Wei Xiaoou,Zheng Xiuqing,Gu Jianghai.2012&.Analysis of hydrochemical characteristics and evolution of karstic groundwater in Liulin spring catchment.Yellow River,34(1):72～77.
Wu Jichun,Xue Yuqun,Huang Hai,Zhang Zhengzhi.2001&.Two dimensional numerical simulation of solute transport in Liulin spring local area.Shuili Xuebao,(8):38～43.
Yang Hui,Chen Jiarui,Liang Jianhong,Cao Jianhua.2017&.Preliminary study on the relationship between soil organic carbon and pH value and calcium species in Yaji Karst Region,Guilin.Geological Review,63(4):1117～1126.
Yang Ming,Lu Yaoru,Zhang fene,Zhang Sheng,Yin Miying,Wu Guoqing.2018&.Hydrochemical evolution and geochemical simulation of karst groundwater in Liulin springs.South-to-North Water Transfers and Water Science & Technology,16(1):127～134.
Yuan Daoxian.2011#.Review and Prospect in the study on karst processes and Carbon Cycle Research.Chinese Science Bulletin,56(26):2157.
Yuan Daoxian.2015&.Scientific innovation in karst resources and environment research field of China.Carsologica Sinica,34(2):98～100.
Zang Hongfei,Jia Zhengxin,Zheng Xiuqing,Qin Zuodong,Huang Xiaodan.2013&.Characteristics of hydrochemical and carbon—sulfur isotopic for karst water in Liulin spring area .Water Resources and Power,31(12):28～32.
Zang Hongfei,Zheng Xiuqing,Zhang Yongbo,Yang Zhan .2017&.Source of SO■ in karst groundwater in the Liulin spring area.Hydrogeology & Engineering Geology,44(1):9～15.
Zhang Liankai,Qin Xiaoqun,Liu Pengyu,Huang Qibo.2016&.Chemical Denudation Rate and Atmospheric CO2 Consumption byH2CO3 and H2SO4 in the Yangtze River Catchment.Geological Bulletin of China,90(8):1933～1943.
Zhang Tao,PU Junbing,Yuan Daoxian,LI Jianhong.2016&.Biogeochemical controls on daily cycling of DIC and NO-3 of guancun karst stream in Guangxi.Geological Bulletin of China,90(8):1965～1976.
Zhang Xingbo,Jiang Yongjun,Qiu Shulan,Cao Ming,Hu Yijun.2012&.Agricultural activities and carbon cycling in Karst areas in Southwest China:dissolving carbonate rocks and CO2 sink.Advances in Earth Science,27( 4) :466～476.
Zhao Jiaojuang,Hao Yonghong,Li Huaming,Wang Yajie.2011&.Grey model for karst spring discharge based on propagation process of groundwater pressure wave.Hydrogeology & Engineering Geology,38(6):1～7.