粗糙表面润湿滞后的研究进展
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摘要
润湿滞后是表界面科学中的重要参数,对于研究液滴在固体表面的铺展与运动过程具有重要意义,但是国内对润湿滞后现象的认识还较为缺乏。普遍认为,固体表面粗糙度是润湿滞后的主要影响因素。对国内外润湿滞后理论的发展历程进行回顾,归纳了润湿滞后的主要测定方法,将粗糙平面下的润湿滞后实验进行分类分析。同时浅谈了润湿滞后研究的发展趋势以及所存在的问题,以便对润湿滞后现象的研究起到参考。
Contact angle hysteresis is the significant parameter to surface interfacial science, which is important to fluid spread and motion, however,we lack the understanding of contact angle hysteresis. It is generally accepted that the surface roughness of the solid is the main influence on the contact angle hysteresis. The developing course of the theories of contact angle hysteresis in China and aboard was reviewed. And then the main testing methods of contact angle hysteresis were summarized. The classified analysis of phenomena of contact angle hysteresis on the rough solid surface was carried out. The development trend and existing problems of contact angle hysteresis research was briefly talked, which can provide references for the research of the phenomenon of contact angle hysteresis.
Contact angle hysteresis is the significant parameter to surface interfacial science, which is important to fluid spread and motion, however,we lack the understanding of contact angle hysteresis. It is generally accepted that the surface roughness of the solid is the main influence on the contact angle hysteresis. The developing course of the theories of contact angle hysteresis in China and aboard was reviewed. And then the main testing methods of contact angle hysteresis were summarized. The classified analysis of phenomena of contact angle hysteresis on the rough solid surface was carried out. The development trend and existing problems of contact angle hysteresis research was briefly talked, which can provide references for the research of the phenomenon of contact angle hysteresis.
引文
[1]Strutt J W.On the tension of water surfaces,clean and contaminated,investigated by the method of ripples[M]//Scientific Papers Cambridge University Press,2009:383-396.
[2]Morra M, Occhiello E, Garbassi F. Knowledge about polymer surfaces from contact angle measurements[J].Advances in Colloid&Interface Science,1990,32(1):79-116.
[3]Good R J. A Thermodynamic derivation of Wenzel's Modification of Young's equation for contact angles; together with a theory of hysteresis[J].Journal of the American Chemical Society,1952,74(20):5041-5042.
[4]Ruch R J, Bartell L S. Wetting of solids by solutions as a function of solute adsorption[J]. Journal of Physical Chemistry,1960,64(5):513-519.
[5]Johnson, Dettre R H.Contact angle hysteresis. III. study of an idealized heterogeneous surface[J].Journal of Physical Chemistry,1964,68(7):291-296.
[6]Neumann A W,Good R J.Thermodynamics of contact angles. I. Heterogeneous solid surfaces[J]. Journal of Colloid&Interface Science,1972,38(2):341-358.
[7]Schwartz L W, Garoff S.Contact angle hysteresis on heterogeneous surfaces[J]. Langmuir,1985(2):219-230.
[8]Pomeau Y, Vannimenus J. Contact angle on heterogeneous surfaces:weak heterogeneities[J]. Journal of Colloid&Interface Science,1985,104(2):477-488.
[9]Marmur A.Contact angle hysteresis on heterogeneous smooth surfaces[J]. Journal of Colloid&Interface Science,1994,168(1):40-46.
[10]Vergelati C, Perwuelz A, Vovelle L, et al. Poly(ethylene terephthalate)surface dynamics in air and water studied by tensiometry and molecular modelling[J]. Polymer,1994,35(2):262-270.
[11]Bikerman J J. Sliding of drops from surfaces of different roughnesses[J].Journal of Colloid Science,1950,5(4):349-359.
[12]Shanahan M E, Carre A.Viscoelastic dissipation in wetting and adhesionphenomena[J]. Langmuir,1995,11(4):1396-1402.
[13]Timmons C O,Zisman W A. The effect of liquid structure on contact angle hysteresis[J]. Journal of Colloid&Interface Science,1966,22(2):165-171.
[14]Good R J, Kotsidas E D.Contact angles on swollen polymers:the surface energy of crosslinked polystyrene[J].Journal of Adhesion,1979,10(1):17-24.
[15]Eick J D, Good R J, Neumann A W. Thermodynamics of contact angles. II. rough solid surfaces[J].Journal of Colloid&Interface Science,1975,53(2):235-248.
[16]Oliver J F, Huh C, Mason S G.The apparent contact angle of liquids on finely-grooved solid surfaces-A SEM study[J].Journal of Adhesion,1977,8(3):223-234.
[17]Patankar N A, Neelesh A.Hysteresis with regard to cassie and wenzel states on superhydrophobic surfaces[J].Langmuir,2010,26(10):7498-7503.
[18]He B, Lee J, Patankar N A. Contact angle hysteresis on rough hydrophobic surfaces[J].Colloids&Surfaces A:Physicochemical&Engineering Aspects,2016,248(1):101-104.
[19]Iliev S, Pesheva N, Iliev P. Contact angle hysteresis on doubly periodic smooth rough surfaces in Wenzel's regime:The role of the contact line depinning mechanism[J].Physical Review E,2018,97(1):28-38.
[20]Busscher H J, Pelt A W J V, Boer P D, et al. The effect of surface roughening of polymers on measured contact angles of liquids[J]. Colloids&Surfaces,1984,9(4):319-331.
[21]Milne A J B, Amirfazli A.The Cassie equation:How it is meant to be used[J].Advances in Colloid&Interface Science,2012,170(1/2):48.
[22]Sliwinska B M, Sterczynska A, Long Y, et al. Influence of microroughness on the wetting properties of nano-porous silica matrices[J].Molecular Physics,2014,112(17):2365-2371.
[23]Kim D, Pugno N, Ryu S.Wetting theory for small droplets on textured solid surfaces[J].Scientific Reports,2016(6):37813.
[24]Young T. An essay on the cohesion of fluids[J]. Philosophical Transactions of the Royal Society of London,1805,95:65-87.
[25]Wenzel R N. Resistance of solid surfaces to wetting by water[J]. Ind. Eng. Chem,1936,28(8):988-994.
[26]Busscher H J, Pelt A W J V, Boer P D, et al. The effect of surface roughening of polymers on measured contact angles of liquids[J].Colloids&Surfaces,1984,9(4):319-331.
[27]Neumann A W.Contact angles and their temperature dependence:thermodynamic status,measurement,interpretation and application[J].Advances in Colloid&Interface Science,1974,4(2):105-191.
[28]Cassie A B D, Baxter S. Wettability of porous surfaces[J].Trans Faraday Soc,1944,40(1):546-551.
[29]李外郎,顾惕人.润湿现象与接触角[J].精细化工,1986(2):4-10.
[30]朱亮,冯焱颖,叶雄英,等.粗糙表面的可控润湿性研究[J].传感技术学报,2006,19(5):1709-1712.
[31]王宝和,强伟丽,王甜,等.纳米水滴在纳米粗糙壁面上润湿行为的分子动力学模拟[J].高校化学工程学报,2017,31(5):1169-1176.
[32]Adam N K, Jessop G.CCL.Angles of contact and polarity of solid surfaces[J]. Journal of the Chemical Society Transactions,1925,127:1863-1868.
[33]Yarnold G D.The motion of a mercury index in a capillary tube[J].Proceedings of the Physical Society,1938,50(4):540.
[34]Frenkel Y I.On the behavior of liquid drops on a solid surface. 1. The sliding of drops on an inclined surface[J].Physics,2005.
[35]Masashi Miwa, Akira Nakajima, Akira Fujishima, et al.Effects of the Surface Roughness on Sliding Angles of Water Droplets on Superhydrophobic Surfaces[J]. Langmuir,2000,16(13):5754-5760.
[36]Lv C, Yang C, Hao P, et al. Sliding of water droplets on microstructured hydrophobic surfaces[J]. Langmuir,2010,26(11):8704-8709.
[37]Hayes R A, Ralston J. Forced liquid movement on low energy surfaces[J]. Journal of Colloid&Interface Science,1993,159(2):429-438.
[38]Behrooz Raeesi, Norman R.Contact amgle hysteresis at smooth and rough surfaces[J].Intefration,2013(2):78-79.
[39]Kwok D Y, Lin R, Mui M, et al. Low-rate dynamic and static contact angles and the determination of solid surface tensions[J]. Colloids&Surfaces A Physicochemical&Engineering Aspects,1996,116(1/2):63-77.
[40]Morrow N R. The Effects of surface roughness on contact:angle with special reference to petroleum recovery[J].Journal of Canadian Petroleum Technology,1975,14(4):42-53.
[41]Erbil Yildirim, Mc Hale G, Rowan S M, et al. Determination of the receding contact angle of sessile drops on polymer surfaces by evaporation[J]. Langmuir,1999,15(21):379-392.
[42]Lander L M, Siewierski L M, Brittain W J, et al.A systematic comparison of contact angle methods[J]. Langmuir,1993,9(8):2237-2239.
[43]王晓东,彭晓峰,陆建峰,等.接触角测试技术及粗糙表面上接触角的滞后性—Ⅰ:接触角测试技术[J].应用基础与工程科学学报,2003,11(2):174-184.
[44]Anderson W G.Wettability literature survey part 2:wettability measurement[J].Journal of Petroleum Technology,1986,38(11):1246-1262.
[45]Sun M, Luo C, Xu L, et al. Artificial lotus leaf by nanocasting[J].Langmuir,2005,21(19):8978.
[46]Bartell F E, Shepard J W.Surface roughness as related to hysteresis of contact angles. I.The system paraffin-water-air[J]. Journal of Physical Chemistry,1953,57(2):211-215.
[47]Shepard J W, Bartell F E.Surface roughness as related to hysteresis of contact angles. III. the systems paraffin ethylene glycol-air,paraffin-methyl cellosolve-air and paraffin methanol air[J]. Journal of Physical Chemistry,1953,57(4):458-463.
[48]Kamusewitz H, Possart W, Paul D.The relation between Young’s equilibrium contact angle and the hysteresis on rough paraffin wax surfaces[J]. Colloids&Surfaces A:Physicochemical&Engineering Aspects,1999,156(1/3):271-279.
[49]Shuttleworth R, Bailey G L J.The spreading of a liquid over a rough solid[J]. Discuss Faraday Soc,1948,3(5):16-22.
[50]Johnson R E, Dettre R H.Contact angle hysteresis,Part 1.Study of an idealized rough surface[J]. Adv. Chem. Ser.,1964,43:112-135.
[51]王晓东,彭晓峰,闵敬春.接触角滞后现象的理论分析[J].工程热物理学报,2002,23(1):67-70.
[52]王晓东,彭晓峰,陆建峰,等.粗糙表面接触角滞后现象分析[J].热科学与技术,2003,2(3):230-234.
[53]王晓东,彭晓峰,陆建峰,等.接触角测试技术及粗糙表面上接触角的滞后性Ⅱ:粗糙不锈钢表面接触角的滞后性[J].应用基础与工程科学学报,2003,11(3):296-303.
[54]Schulze R D, Possart W, Kamusewitz H, et al.Young's equilibrium contact angle on rough solid surfaces. Part I.An empirical determination[J]. Journal of Adhesion Science&Technology,1989,3(1):39-48.
[55]Kamusewitz H, Possart W.Wetting and scanning force microscopy on rough polymer surfaces:Wenzel’s roughness factor and the thermodynamic contact angle[J].Applied Physics A,2003,76(6):899-902.
[56]Herzberg W J, Marian J E.Relationship between contact angle and drop size[J]. Journal of Colloid&Interface Science,1970,33(1):161-163.
[57]Good R J, Koo M N.The effect of drop size on contact angle[J]. Journal of Colloid&Interface Science,1979,71(2):283-292.
[58]Wang W, Gupta A.Investigation of the effect of temperature and pressure on wettability using modified pendant drop method[C]//Meeting of the Society of Petroleum Engineers.Society of Petroleum Engineers,1995.
[59]Cassie A B D.Contact angles[J].Discussions of the Faraday Society,1948,3(5):11-16.
[2]Morra M, Occhiello E, Garbassi F. Knowledge about polymer surfaces from contact angle measurements[J].Advances in Colloid&Interface Science,1990,32(1):79-116.
[3]Good R J. A Thermodynamic derivation of Wenzel's Modification of Young's equation for contact angles; together with a theory of hysteresis[J].Journal of the American Chemical Society,1952,74(20):5041-5042.
[4]Ruch R J, Bartell L S. Wetting of solids by solutions as a function of solute adsorption[J]. Journal of Physical Chemistry,1960,64(5):513-519.
[5]Johnson, Dettre R H.Contact angle hysteresis. III. study of an idealized heterogeneous surface[J].Journal of Physical Chemistry,1964,68(7):291-296.
[6]Neumann A W,Good R J.Thermodynamics of contact angles. I. Heterogeneous solid surfaces[J]. Journal of Colloid&Interface Science,1972,38(2):341-358.
[7]Schwartz L W, Garoff S.Contact angle hysteresis on heterogeneous surfaces[J]. Langmuir,1985(2):219-230.
[8]Pomeau Y, Vannimenus J. Contact angle on heterogeneous surfaces:weak heterogeneities[J]. Journal of Colloid&Interface Science,1985,104(2):477-488.
[9]Marmur A.Contact angle hysteresis on heterogeneous smooth surfaces[J]. Journal of Colloid&Interface Science,1994,168(1):40-46.
[10]Vergelati C, Perwuelz A, Vovelle L, et al. Poly(ethylene terephthalate)surface dynamics in air and water studied by tensiometry and molecular modelling[J]. Polymer,1994,35(2):262-270.
[11]Bikerman J J. Sliding of drops from surfaces of different roughnesses[J].Journal of Colloid Science,1950,5(4):349-359.
[12]Shanahan M E, Carre A.Viscoelastic dissipation in wetting and adhesionphenomena[J]. Langmuir,1995,11(4):1396-1402.
[13]Timmons C O,Zisman W A. The effect of liquid structure on contact angle hysteresis[J]. Journal of Colloid&Interface Science,1966,22(2):165-171.
[14]Good R J, Kotsidas E D.Contact angles on swollen polymers:the surface energy of crosslinked polystyrene[J].Journal of Adhesion,1979,10(1):17-24.
[15]Eick J D, Good R J, Neumann A W. Thermodynamics of contact angles. II. rough solid surfaces[J].Journal of Colloid&Interface Science,1975,53(2):235-248.
[16]Oliver J F, Huh C, Mason S G.The apparent contact angle of liquids on finely-grooved solid surfaces-A SEM study[J].Journal of Adhesion,1977,8(3):223-234.
[17]Patankar N A, Neelesh A.Hysteresis with regard to cassie and wenzel states on superhydrophobic surfaces[J].Langmuir,2010,26(10):7498-7503.
[18]He B, Lee J, Patankar N A. Contact angle hysteresis on rough hydrophobic surfaces[J].Colloids&Surfaces A:Physicochemical&Engineering Aspects,2016,248(1):101-104.
[19]Iliev S, Pesheva N, Iliev P. Contact angle hysteresis on doubly periodic smooth rough surfaces in Wenzel's regime:The role of the contact line depinning mechanism[J].Physical Review E,2018,97(1):28-38.
[20]Busscher H J, Pelt A W J V, Boer P D, et al. The effect of surface roughening of polymers on measured contact angles of liquids[J]. Colloids&Surfaces,1984,9(4):319-331.
[21]Milne A J B, Amirfazli A.The Cassie equation:How it is meant to be used[J].Advances in Colloid&Interface Science,2012,170(1/2):48.
[22]Sliwinska B M, Sterczynska A, Long Y, et al. Influence of microroughness on the wetting properties of nano-porous silica matrices[J].Molecular Physics,2014,112(17):2365-2371.
[23]Kim D, Pugno N, Ryu S.Wetting theory for small droplets on textured solid surfaces[J].Scientific Reports,2016(6):37813.
[24]Young T. An essay on the cohesion of fluids[J]. Philosophical Transactions of the Royal Society of London,1805,95:65-87.
[25]Wenzel R N. Resistance of solid surfaces to wetting by water[J]. Ind. Eng. Chem,1936,28(8):988-994.
[26]Busscher H J, Pelt A W J V, Boer P D, et al. The effect of surface roughening of polymers on measured contact angles of liquids[J].Colloids&Surfaces,1984,9(4):319-331.
[27]Neumann A W.Contact angles and their temperature dependence:thermodynamic status,measurement,interpretation and application[J].Advances in Colloid&Interface Science,1974,4(2):105-191.
[28]Cassie A B D, Baxter S. Wettability of porous surfaces[J].Trans Faraday Soc,1944,40(1):546-551.
[29]李外郎,顾惕人.润湿现象与接触角[J].精细化工,1986(2):4-10.
[30]朱亮,冯焱颖,叶雄英,等.粗糙表面的可控润湿性研究[J].传感技术学报,2006,19(5):1709-1712.
[31]王宝和,强伟丽,王甜,等.纳米水滴在纳米粗糙壁面上润湿行为的分子动力学模拟[J].高校化学工程学报,2017,31(5):1169-1176.
[32]Adam N K, Jessop G.CCL.Angles of contact and polarity of solid surfaces[J]. Journal of the Chemical Society Transactions,1925,127:1863-1868.
[33]Yarnold G D.The motion of a mercury index in a capillary tube[J].Proceedings of the Physical Society,1938,50(4):540.
[34]Frenkel Y I.On the behavior of liquid drops on a solid surface. 1. The sliding of drops on an inclined surface[J].Physics,2005.
[35]Masashi Miwa, Akira Nakajima, Akira Fujishima, et al.Effects of the Surface Roughness on Sliding Angles of Water Droplets on Superhydrophobic Surfaces[J]. Langmuir,2000,16(13):5754-5760.
[36]Lv C, Yang C, Hao P, et al. Sliding of water droplets on microstructured hydrophobic surfaces[J]. Langmuir,2010,26(11):8704-8709.
[37]Hayes R A, Ralston J. Forced liquid movement on low energy surfaces[J]. Journal of Colloid&Interface Science,1993,159(2):429-438.
[38]Behrooz Raeesi, Norman R.Contact amgle hysteresis at smooth and rough surfaces[J].Intefration,2013(2):78-79.
[39]Kwok D Y, Lin R, Mui M, et al. Low-rate dynamic and static contact angles and the determination of solid surface tensions[J]. Colloids&Surfaces A Physicochemical&Engineering Aspects,1996,116(1/2):63-77.
[40]Morrow N R. The Effects of surface roughness on contact:angle with special reference to petroleum recovery[J].Journal of Canadian Petroleum Technology,1975,14(4):42-53.
[41]Erbil Yildirim, Mc Hale G, Rowan S M, et al. Determination of the receding contact angle of sessile drops on polymer surfaces by evaporation[J]. Langmuir,1999,15(21):379-392.
[42]Lander L M, Siewierski L M, Brittain W J, et al.A systematic comparison of contact angle methods[J]. Langmuir,1993,9(8):2237-2239.
[43]王晓东,彭晓峰,陆建峰,等.接触角测试技术及粗糙表面上接触角的滞后性—Ⅰ:接触角测试技术[J].应用基础与工程科学学报,2003,11(2):174-184.
[44]Anderson W G.Wettability literature survey part 2:wettability measurement[J].Journal of Petroleum Technology,1986,38(11):1246-1262.
[45]Sun M, Luo C, Xu L, et al. Artificial lotus leaf by nanocasting[J].Langmuir,2005,21(19):8978.
[46]Bartell F E, Shepard J W.Surface roughness as related to hysteresis of contact angles. I.The system paraffin-water-air[J]. Journal of Physical Chemistry,1953,57(2):211-215.
[47]Shepard J W, Bartell F E.Surface roughness as related to hysteresis of contact angles. III. the systems paraffin ethylene glycol-air,paraffin-methyl cellosolve-air and paraffin methanol air[J]. Journal of Physical Chemistry,1953,57(4):458-463.
[48]Kamusewitz H, Possart W, Paul D.The relation between Young’s equilibrium contact angle and the hysteresis on rough paraffin wax surfaces[J]. Colloids&Surfaces A:Physicochemical&Engineering Aspects,1999,156(1/3):271-279.
[49]Shuttleworth R, Bailey G L J.The spreading of a liquid over a rough solid[J]. Discuss Faraday Soc,1948,3(5):16-22.
[50]Johnson R E, Dettre R H.Contact angle hysteresis,Part 1.Study of an idealized rough surface[J]. Adv. Chem. Ser.,1964,43:112-135.
[51]王晓东,彭晓峰,闵敬春.接触角滞后现象的理论分析[J].工程热物理学报,2002,23(1):67-70.
[52]王晓东,彭晓峰,陆建峰,等.粗糙表面接触角滞后现象分析[J].热科学与技术,2003,2(3):230-234.
[53]王晓东,彭晓峰,陆建峰,等.接触角测试技术及粗糙表面上接触角的滞后性Ⅱ:粗糙不锈钢表面接触角的滞后性[J].应用基础与工程科学学报,2003,11(3):296-303.
[54]Schulze R D, Possart W, Kamusewitz H, et al.Young's equilibrium contact angle on rough solid surfaces. Part I.An empirical determination[J]. Journal of Adhesion Science&Technology,1989,3(1):39-48.
[55]Kamusewitz H, Possart W.Wetting and scanning force microscopy on rough polymer surfaces:Wenzel’s roughness factor and the thermodynamic contact angle[J].Applied Physics A,2003,76(6):899-902.
[56]Herzberg W J, Marian J E.Relationship between contact angle and drop size[J]. Journal of Colloid&Interface Science,1970,33(1):161-163.
[57]Good R J, Koo M N.The effect of drop size on contact angle[J]. Journal of Colloid&Interface Science,1979,71(2):283-292.
[58]Wang W, Gupta A.Investigation of the effect of temperature and pressure on wettability using modified pendant drop method[C]//Meeting of the Society of Petroleum Engineers.Society of Petroleum Engineers,1995.
[59]Cassie A B D.Contact angles[J].Discussions of the Faraday Society,1948,3(5):11-16.