丙烷氧化脱氢制丙烯研究进展
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摘要
开发新型丙烯制备工艺对于满足人们日益增长的丙烯需求具有重要意义。由于商业化无氧脱氢技术存在热力学平衡限制、反应温度高、催化剂易积炭等不足,近年来,人们将研究重心转向了丙烷氧化脱氢技术。本文简述了丙烷氧化脱氢制丙烯的发展现状,综述了近年来文献报道的丙烷氧化脱氢催化剂体系(V基、Cr基、Co基、Ni基、Mo基、Pt基、Ce基和非金属基催化剂)、机理研究和不同氧化剂选择,并对各自的优势和不足进行了简单分析。分析发现,虽然目前丙烷氧化脱氢催化剂的种类非常广泛,但产物丙烯的收率仍有待提高,机理研究也需要更加系统和深入。最后指出,系统研究丙烷氧化脱氢机理,并在此基础上开发先进催化剂,进一步提高丙烯的选择性和收率是未来丙烷氧化脱氢研究的重要方向。
The increasing demand of propene has motivated people to develop novel approaches to produce propene. The commercial dehydrogenation process of propane, however, has the problems of thermodynamics equilibrium limit, high reaction temperature and carbon deposition. Nowadays,increasing attention has been paid to developing the oxidative dehydrogenation of propane. In this review,we summarized the development of catalyst systems(V-, Cr-, Co-, Ni-, Mo-, Pt-, Ce-based and metalfree catalysts), mechanism studies and oxidants for propane oxidative dehydrogenation. The advantages and drawbacks for each system are analyzed. We found that although many kinds of catalysts have been developed, the propene yield is still far from commercialization. In the future, the development of the propane oxidative dehydrogenation should be directed to a deep understanding of the reaction mechanism and the rational design of advanced catalyst systems so as to improve the selectivity and yield of propene.
The increasing demand of propene has motivated people to develop novel approaches to produce propene. The commercial dehydrogenation process of propane, however, has the problems of thermodynamics equilibrium limit, high reaction temperature and carbon deposition. Nowadays,increasing attention has been paid to developing the oxidative dehydrogenation of propane. In this review,we summarized the development of catalyst systems(V-, Cr-, Co-, Ni-, Mo-, Pt-, Ce-based and metalfree catalysts), mechanism studies and oxidants for propane oxidative dehydrogenation. The advantages and drawbacks for each system are analyzed. We found that although many kinds of catalysts have been developed, the propene yield is still far from commercialization. In the future, the development of the propane oxidative dehydrogenation should be directed to a deep understanding of the reaction mechanism and the rational design of advanced catalyst systems so as to improve the selectivity and yield of propene.
引文
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[4]丙烷脱氢对丙烯市场的影响[J].石油化工,2016,45(6):724.The effect of propane dehydrogenation on propene market[J].Petrochemical Technology,2016,45(6):724.
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[8]盖希坤,田原宇,夏道宏.丙烷催化脱氢制丙烯工艺分析[J].炼油技术与工程,2010,40(12):27-32.GAI Xikun,TIAN Yuanyu,XIA Daohong. Technology progress analysis of the catalytic dehydrogenation of propane[J]. Petroleum Refinery Engineering,2010,40(12):27-32.
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[10] GAO Xingtao,RUIZ P,GUO Xiexian, et al.Effect of coexistence of magnesium vanadate phases in the selectivity oxidation of propane to propene[J]. Journal of Catalysis, 1994,148:56-67.
[11] BLASCO T,GALLI A,LOPEZ-NIETO J M,et al. Oxidative dehydrogenation of ethane and n-butane on VOx/Al2O3catalysts[J].Journal of Catalysis,1997,169:203-211.
[12] FRANK B,DINSE A,OVSITSER O,et al. Mass and heat transfer effects on the oxidative dehydrogenation of propane(ODP)over a low loaded VOx/Al2O3catalyst[J]. Applied Catalysis A:General,2007,323:66-76.
[13] LUO Qunxing,ZHANG Xiaokang,HOU Bouli,et al. Catalytic function of VOx/Al2O3for oxidative dehydrogenation of propane:support microstructure-dependent mass transfer and diffusion[J]. Catalysis Science&Technology,2018,8:4864-4876.
[14] LIU Yongmei,CAO Yong,YI Nan,et al.Vanadium oxide supported on mesoporous SBA-15 as highly selective catalysts in the oxidative dehydrogenation of propane[J].Journal of Catalysis,2004,224(2):417-428.
[15] CHAAR M A,PATEL D,KUNG H H. Selective oxidative dehydrogenation of propane over V-Mg-O catalysts[J]. Journal of Catalysis,1988,109:463-467.
[16] LIU Lulu,HAN Xinyou,ZHOU Juan,et al. Oxidative dehydrogenation of propane over three-dimensionally ordered macroporous VMgO catalysts with different vanadium doping[J]. Journal of Porous Materials,2018,25(4):955-963.
[17] AYANDIRAN A A,BAKARE I A,BINOUS H,et al. Oxidative dehydrogenation of propane to propylene over VOx/CaO-γ-Al2O3using lattice oxygen[J]. Catalysis Science&Technology,2016,6(13):5154-5167.
[18] SOLSONA B,BLASCO T,LOPEZ-NIETO J M,et al.Vanadium oxide supported on mesoporous MCM-41 as selective catalysts in the oxidative dehydrogenation of alkanes[J]. Journal of Catalysis,2001,203(2):443-452.
[19] DINSE A,FRANK B,HESS C,et al.Oxidative dehydrogenation of propane over low-loaded vanadia catalysts:impact of the support material on kinetics and selectivity[J].Journal of Molecular Catalysis A:Chemical,2008,289(1/2):28-37.
[20] LIU Yongmei,FENG Weiliang,LI Tingcheng,et al. Structure and catalytic properties of vanadium oxide supported on mesocellulous silica foams(MCF)for the oxidative dehydrogenation of propane to propylene[J]. Journal of Catalysis,2006,239(1):125-136.
[21] ROZANSKA X,FORTRIE R,SAUER J. Size-dependent catalytic activity of supported vanadium oxide species:oxidative dehydrogenation of propane[J]. Journal of the American Chemical Society,2014,136(21):7751-7761.
[22] BARMAN S,MAITY N,BHATTE K,et al.Single-site VOx moieties generated on silica by surface organometallic chemistry:a way to enhance the catalytic activity in the oxidative dehydrogenation of propane[J]. ACS Catalysis,2016,6(9):5908:5921.
[23] JIBRIL B Y. Propane oxidative dehydrogenation over chromium oxidebased catalysts[J]. Applied Catalysis A:General,2004,264(2):193-202.
[24] JIBRIL B Y,AL-ZAHRANI S M,ABASAEED A E,et al.Effects of reducibility on propane oxidative dehydrogenation overγ-Al2O3-supported chromium oxide-based catalysts[J]. Catalysis Letters,2003,87(3/4):121-132.
[25] DAVIES T E,GARCIA T,SOLSONA B,et al.Nanocrystalline cobalt oxide:a catalyst for selective alkane oxidation under ambient conditions[J]. Chemical Communications,2006(32):3417-3419.
[26] HUANG Mingxiang,WU Xin,YI Xiaodong,et al.Highly dispersed CoOx in layered double oxides for oxidative dehydrogenation of propane:guest-host interactions[J]. RSC Advance,2017,7(24):14846-14856.
[27] LI Zhanyong,PETERS A W,BERNALES V,et al. Metal-organic framework supported cobalt catalysts for the oxidative dehydrogenation of propane at low temperature[J].ACS Central Science,2017,3(1):31-38.
[28] BOIZUMAULT-MORICEAU P,PENNEAUIN A,GRZYBOWSKA B,et al.Oxidative dehydrogenation of propane on Ni-Ce-O oxide:effect of the preparation method, effect of potassium addition and physical characterization[J]. Applied Catalysis A:General, 2003,245(1):55-67.
[29] WU Ying,HE Yiming,CHEN Tong,et al.Low temperature catalytic performance of nanosized Ti-Ni-O for oxidative dehydrogenation of propane to propene[J]. Applied Surface Science,2006,252(14):5220-5226.
[30] HE Yiming,WU Ying,CHEN Tong,et al.Low-temperature catalytic performance for oxidative dehydrogenation of propane on nanosized Ti(Zr)-Ni-O prepared by modified sol-gel method[J]. Catalysis Communications,2006,7(5):268-271.
[31] HERACLEOUS E,LEMONIDOU A A.Ni-Me-O mixed metal oxides for the effective oxidative dehydrogenation of ethane to ethylene—Effect of promoting metal Me[J]. Journal of Catalysis,2010,270:67-75.
[32] ZHU Haibo,DEVON C R,MOUSSAB H,et al.Ni-M-O(M=Sn, Ti,W)catalysts prepared by a dry mixing method for oxidative dehydrogenation of ethane[J]. ACS Catalysis,2016,6:2852-2866.
[33] LI Jianhui,WANG Caicai,HUNG Chuanjing,et al. Mesoporous nickel oxides as effective catalysts for oxidative dehydrogenation of propane to propene[J]. Applied Catalysis A:General,2010,382(1),99-105.
[34] ABELLO M C,GOMEZ M F,FERRETTI O. Mo/γ-Al2O3catalysts for the oxidative dehydrogenation of propane:effect of Mo loading[J].Applied Catalysis A:General,2001,207(1):421-431.
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